The evolution of microstructure and texture in Mg-3Al-1Zn-1Ca alloy sheets subjected to in-plane shear(IPS)loading was investigated using experimental techniques and viscoplastic self-consistent(VPSC)modeling.The spec...The evolution of microstructure and texture in Mg-3Al-1Zn-1Ca alloy sheets subjected to in-plane shear(IPS)loading was investigated using experimental techniques and viscoplastic self-consistent(VPSC)modeling.The specimens were deformed under varying degrees of IPS strain(γ12=0.05,0.10,and 0.15)using a customized jig.Electron backscatter diffraction(EBSD)observations revealed profuse tensile twinning(TTW)even at an IPS strain of 0.05,with its intensity continuously increased as the IPS strain increased.The TTWs progressively engulfed parent grains with increasing shear strain,evolving into an unusual deformation twin morphology.Furthermore,VPSC model predictions confirmed basal slip as the dominant deformation mode at low IPS strains,transitioning to prismatic slip dominance at higher IPS strains.The activity of the TTW mode was significantly higher during the initial stages of IPS strain and saturated to lower values at higher strains.VPSC simulation results also indicated preferential shear accumulation on a single twin system,explaining the phenomenon of a single twin variant engulfing a parent grain.Additionally,the influence of individual slip and twin modes on texture evolution was evaluated through orientation tracking of representative grains at various shear strain increments using VPSC simulation.The simulation results quantitatively highlighted the activities of basal slip,prismatic slip,and tensile twinning,establishing a correlation between texture evolution and the underlying deformation mechanisms.展开更多
Exploring earth-abundant,highly active bifunctional electrocatalysts for efficient hydrogen and oxygen evolution is crucial for water splitting.However,due to their distinct free energies and conducting behaviors(elec...Exploring earth-abundant,highly active bifunctional electrocatalysts for efficient hydrogen and oxygen evolution is crucial for water splitting.However,due to their distinct free energies and conducting behaviors(electron/hole),balancing the catalytic efficiency between hydrogen and oxygen evolution remains challenging for achieving bifunctional electrocatalysts.Here,we report a locally-doped MoS_(2)monolayer with an in-plane heterostructure acting as a bifunctional electrocatalyst and apply it to the overall water splitting.In this heterostructure,the core region contains Mo/S vacancies,while the ring region was doped by Fe atoms(in two substitution configurations:1FeMo and 3FeMo-VS clusters)with a p-type conductive characteristic.Our micro-cell measurements,combined with density functional theory(DFT)calculations,reveal that the vacancies-rich core region presents remarkable hydrogen evolution reaction(HER)activity while the Fe-doped ring gives an excellent oxygen evolution reaction(OER)activity,thus forming an in-plane bifunctional electrocatalyst.Finally,as a proof-of-concept for overall water splitting,we constructed a full-cell configuration based on a locally-doped MoS_(2)monolayer,which achieved a cell voltage of 1.87 V at 10 mA·cm^(-2),demonstrating outstanding performance in strong acid electrolytes.Our work provides insight into the hetero-integration of bifunctional electrocatalysts at the atomic level,paving the way for designing transition metal dichalcogenide catalysts with activity-manipulated regions capable of multiple reactions.展开更多
Two-dimensional van der Waals(vdW)magnetic materials,characterized by their tunable magnetism,spin transport properties,and remarkable quantum effects,provide significant promise for the development of efficient,low-p...Two-dimensional van der Waals(vdW)magnetic materials,characterized by their tunable magnetism,spin transport properties,and remarkable quantum effects,provide significant promise for the development of efficient,low-power spintronic devices.Intriguingly,the rare earth tritelluride(RTe3)materials have attracted great attention due to their unique magnetic structure,exotic electronic properties,multiple charge density wave(CDW),and superconductivity under pressure.Here,we report the successful synthesis of high-quality DyTe_(3)single crystals using a self-flux method.DyTe_(3)shows an antiferromagnetic transition at 4.5 K and demonstrates the magnetic field-induced ferromagnetism.The high-quality DyTe_(3)single crystal demonstrates outstanding transport properties,featuring a high carrier mobility of approximately1.4×10^(4)cm^(2)·V^(-1)·s^(-1)and large linear magnetoresistance of 1300%.Furthermore,distinct Shubnikov-de Haas(SdH)oscillations are observed in DyTe_(3),revealing a small Fermi pocket and an effective mass of 0.24 me.Remarkably,the unconventional in-plane negative magnetoresistances appear along the a-axis below 2 T and c-axis until 9 T from 2 K to17 K,which are attributed to the complex helimagnetic structures caused by CDW coupling and weak single-ion anisotropy.Our findings offer a significant platform for understanding the complex magnetoresistance behavior and quantum transport effects in RTe3-type materials,holding great promise for advancing applications in electronic and spintronic devices.展开更多
The in-plane optical anisotropy(IPOA) of c-plane In Ga N/Ga N quantum disks(Qdisks) in nanowires grown on MoS_(2)/Mo and Ti/Mo substrates is investigated using reflectance difference spectroscopy(RDS) at room temperat...The in-plane optical anisotropy(IPOA) of c-plane In Ga N/Ga N quantum disks(Qdisks) in nanowires grown on MoS_(2)/Mo and Ti/Mo substrates is investigated using reflectance difference spectroscopy(RDS) at room temperature. A large IPOA related to defect or impurity states is observed. The IPOA of samples grown on MoS_(2)/Mo is approximately one order of magnitude larger than that of samples grown on Ti/Mo substrates. Numerical calculations based on the envelope function approximation have been performed to analyze the origin of the IPOA. It is found that the IPOA primarily results from the segregation of indium atoms in the In Ga N/Ga N Qdisks. This work highlights the significant influence of substrate materials on the IPOA of semiconductor heterostructures.展开更多
Texture regulation is a prominent method to modify the mechanical properties and anisotropy of magnesium alloy.In this work,the Mg-1Al-0.3Ca-0.5Mn-0.2Gd(wt.%)alloy sheet with TD-tilted and circular texture was fabrica...Texture regulation is a prominent method to modify the mechanical properties and anisotropy of magnesium alloy.In this work,the Mg-1Al-0.3Ca-0.5Mn-0.2Gd(wt.%)alloy sheet with TD-tilted and circular texture was fabricated by unidirectional rolling(UR)and multidirectional rolling(MR)method,respectively.Unlike generating a strong in-plane mechanical anisotropy in conventional TD-tilted texture,the novel circular texture sample possessed a weak in-plane yield anisotropy.This can be rationalized by the similar proportion of soft grains with favorable orientation for basalslip and{10.12}tensile twinning during the uniaxial tension of circular-texture sample along different directions.Moreover,compared with the TD-tilted texture,the circular texture improved the elongation to failure both along the rolling direction(RD)and transverse direction(TD).By quasi-in-situ EBSD-assisted slip trace analysis,higher activation of basal slip was observed in the circular-texture sample during RD tension,contributing to its excellent ductility.When loading along the TD,the TD-tilted texture promoted the activation of{10.12}tensile twins significantly,thus providing nucleation sites for cracks and deteriorating the ductility.This research may shed new insights into the development of formable and ductile Mg alloy sheets by texture modification.展开更多
Tri-axial fracturing studies were carried out to understand the impact of lateral mechanical parameters on fracture propagation from multiple in-plane perforations in horizontal wells. Additionally, the discussion cov...Tri-axial fracturing studies were carried out to understand the impact of lateral mechanical parameters on fracture propagation from multiple in-plane perforations in horizontal wells. Additionally, the discussion covered the effects of geology, treatment, and perforation characteristics on the non-planar propagation behavior. According to experimental findings, two parallel transverse fractures can be successfully initiated from in-plane perforation clusters in the horizontal well because of the in-plane perforation, the guide nonuniform fishbone structure fracture propagation still can be exhibited. The emergence of transverse fractures and axial fractures combined as complex fractures under low horizontal principal stress difference and large pump rate conditions. The injection pressure was also investigated, and the largest breakdown pressure can be also found for samples under these conditions.The increase in perforation number or decrease in the cluster spacing could provide more chances to increase the complexity of the target stimulated zone, thus affecting the pressure fluctuation. In a contrast, the increase in fracturing fluid viscosity can reduce the multiple fracture complexity. The fracture propagation is significantly affected by the change in the rock mechanical properties. The fracture geometry in the high brittle zone seems to be complicated and tends to induce fracture reorientation from the weak-brittle zone. The stress shadow effect can be used to explain the fracture attraction, branch, connection, and repulsion in the multiple perforation clusters for the horizontal well.The increase in the rock heterogeneity can enhance the stress shadow effect, resulting in more complex fracture geometry. In addition, the variable density perforation and temporary plugging fracturing were also conducted, demonstrating higher likelihood for non-uniform multiple fracture propagation. Thus, to increase the perforation efficiency along the horizontal well, it is necessary to consider the lateral fracability of the horizontal well on target formation.展开更多
This contribution attempts to model the alteration of the in-plane elastic properties in laminates caused by stitching, and to predict the in-plane effective tensile strength of the stitched composite laminates. The d...This contribution attempts to model the alteration of the in-plane elastic properties in laminates caused by stitching, and to predict the in-plane effective tensile strength of the stitched composite laminates. The distortion of in-plane fibers is considered to be the main cause that affects the in-plane mechanical properties. A fiber distortion model is proposed to characterize the fiber misalignment and the fiber content concentration due to stitching. The undistorted region, the fiber distortion region, the resin-rich pocket and the through-thickness reinforcement section are taken into account. The fiber misalignment and inhomogeneous fiber content due to stitching have been formulated by introducing two parameters, the distortion width and maximum misalignment. It has been found that the ply stress concentration in stitched laminates is influenced by the two concurrent factors, the stitch hole and inhomogeneous fiber content. The stitch hole brings about the stress concentration whereas the higher fiber content at the local region induced by stitching restrains the local deformation of the composite. The model is used to predict the tensile strength of the [0/45/0/-45/90/45/0/-45]58 T300/QY9512 composite laminate stitched by Kevlar 29 yarn with different stitching configurations, showing an acceptable agreement with experimental data.展开更多
The thermal and mechanical properties of the chemically imidized polyimide(CIPI) films and thermally imidized polyimide(TIPI) films were investigated systematically. Experimental results indicated that the CIPI films ...The thermal and mechanical properties of the chemically imidized polyimide(CIPI) films and thermally imidized polyimide(TIPI) films were investigated systematically. Experimental results indicated that the CIPI films show dramatically enhanced tensile strength and modulus with obviously reduced coefficient of thermal expansion(CTE) in comparison with TIPI films. These enhancements results from the high in-plane orientation and close packing of the CIPI backbones. Compared with thermal imidization which starts at about 140 °C, the chemical imidization activated by acetic anhydride and isoquinoline initiates the cyclization even at room temperature.The resulting imide rings restrict the mobility of polymer chains and lead to the in-plane orientation with solvent evaporation.Additionally, fewer small molecules remain in the films after treated at 120 °C by chemical imidization than by thermal imidization. The polymer chain plasticization caused by the evaporation of small molecules at high temperature is obviously restricted. Moreover, the partially imidized polymer inhibits the decomposition of mainchains that occurs at subsequent high temperature process, being beneficial to the formation of high molecular weight PI films. Hence, chemical imidization pathway shows apparent advantage to produce PI films with great combined properties, including high modulus, strength and toughness, as well as high thermal dimension stability etc.展开更多
A 1D finite element method in time domain is developed in this paper and applied to calculate in-plane wave motions of free field exited by SV or P wave oblique incidence in an elastic layered half-space. First, the l...A 1D finite element method in time domain is developed in this paper and applied to calculate in-plane wave motions of free field exited by SV or P wave oblique incidence in an elastic layered half-space. First, the layered half-space is discretized on the basis of the propagation characteristic of elastic wave according to the Snell law. Then, the finite element method with lumped mass and the central difference method are incorporated to establish 2D wave motion equations, which can be transformed into 1D equations by discretization principle and explicit finite element method. By solving the 1D equations, the displacements of nodes in any vertical line can be obtained, and the wave motions in layered half-space are finally determined based on the characteristic of traveling wave. Both the theoretical analysis and the numerical results demonstrate that the proposed method has high accuracy and good stability.展开更多
Electrochemical nitrogen reduction reaction (eNRR) is an alternative promising manner for sustainable N2 fixation with low-emission. The major challenge for developing an efficient electrocatalyst is the cleaving of t...Electrochemical nitrogen reduction reaction (eNRR) is an alternative promising manner for sustainable N2 fixation with low-emission. The major challenge for developing an efficient electrocatalyst is the cleaving of the stable Ntriple bondN triple bonds. Herein, we design a new MoS_(2) with in-plane defect cluster through a bottom-up approach for the first time, where the defect cluster is composed of three adjacent S vacancies. The well-defined in-plane defect clusters could contribute to the strong chemical adsorption and activation towards inert nitrogen, achieving an excellent eNRR performance with an ammonia yield rate of 43.4 ± 3 μg h^(−1) mgcat.^(−1) and a Faradaic efficiency of 16.8 ± 2% at −0.3 V (vs. RHE). The performance is much higher than that of MoS_(2) with the edge defect. Isotopic labeling confirms that N atoms of produced NH4+ originate from N2. Furthermore, the in-plane defect clusters realized the alternate hydrogenation of nitrogen in a side-on way to synthesize ammonia. This work provides a prospecting strategy for fine-tuning in-plane defects in a catalyst, and also promotes the progress of eNRR.展开更多
In this work, a set of GTN （Gurson-Tvergaard-Needleman） parameters of the Alloy52M dissimilar metal welded joint （DMWJ） have been calibrated, and a micromechanical analysis of in-plane constraint effects on the lo...In this work, a set of GTN （Gurson-Tvergaard-Needleman） parameters of the Alloy52M dissimilar metal welded joint （DMWJ） have been calibrated, and a micromechanical analysis of in-plane constraint effects on the local fracture behavior of two cracks, which located in the weakest regions of the DMWJ, has been investigated by the local approach based on the GTN damage model. The results show that the partition of the material and the variation of the q2 parameter make the J-resistance curves obtained by numerical simulations close to the experimental values. The numerical J-resistance curves and crack growth paths are consistent with the experiment results, which show that the GTN damage model can incorporate the in-plane constraint effect. Furthermore, after the stress, strain and damage fields at the crack tip during the crack propagation process have been calculated, and the change of the J-resistance curves, crack growth paths and fracture mechanism with in-plane constraint have been analyzed.展开更多
The Green function method （GFM） is utilized to analyze the in-plane forced vibration of curved pipe conveying fluid, where the randomicity and distribution of the external excitation and the added mass and damping r...The Green function method （GFM） is utilized to analyze the in-plane forced vibration of curved pipe conveying fluid, where the randomicity and distribution of the external excitation and the added mass and damping ratio are considered. The Laplace transform is used, and the Green functions with various boundary conditions are obtained subsequently. Numerical calculations are performed to validate the present solutions, and the effects of some key parameters on both tangential and radial displacements are further investigated. The forced vibration problems with linear and nonlinear motion constraints are also discussed briefly. The method can be radiated to study other forms of forced vibration problems related with pipes or more extensive issues.展开更多
The Al-Mg-Mn alloy sheets with and without trace Sc and Zr were investigated by means of tensile test,X-ray diffraction,optical microscope,and transmission electron microscope.The indexes of in-plane anisotropy(IIPA)o...The Al-Mg-Mn alloy sheets with and without trace Sc and Zr were investigated by means of tensile test,X-ray diffraction,optical microscope,and transmission electron microscope.The indexes of in-plane anisotropy(IIPA)of their tensile mechanical properties were calculated and their inverse pole figures were obtained by Harris method.The two alloy sheets have the same law of in-plane anisotropy and remarkable in-plane anisotropy of mechanical properties,and the IIPA of the alloy sheet with Sc and Zr is bigger than that of the alloy sheet without Sc and Zr.The relationships of the in-plane anisotropy and the anisotropy of the crystallographic texture were analyzed based on the model of monocrystal.It is the common action of the anisotropy of crystallography and microstructures that causes the in-plane anisotropy of their mechanical properties,but the major cause is the{110}〈112〉crystallographic texture.The trace Sc and Zr can promote the formation and stabilization of the{110}〈112〉texture,inhibit the formation of the{100}〈001〉texture,and increase the in-plane anisotropy of the alloy sheet containing trace Sc and Zr.展开更多
Bi2O2Se thin film could be one of the promising material candidates for the next-generation electronic and optoelectronic applications. However, the performance of Bi2O2Se thin film-based device is not fully explored ...Bi2O2Se thin film could be one of the promising material candidates for the next-generation electronic and optoelectronic applications. However, the performance of Bi2O2Se thin film-based device is not fully explored in the photodetecting area. Considering the fact that the electrical properties such as carrier mobility, work function, and energy band structure of Bi2O2Se are thickness-dependent, the in-plane Bi2O2Se homojunctions consisting of layers with different thicknesses are successfully synthesized by the chemical vapor deposition(CVD) method across the terraces on the mica substrates,where terraces are created in the mica surface layer peeling off process. In this way, effective internal electrical fields are built up along the Bi2O2Se homojunctions, exhibiting diode-like rectification behavior with an on/off ratio of 102, what is more, thus obtained photodetectors possess highly sensitive and ultrafast features, with a maximum photoresponsivity of 2.5 A/W and a lifetime of 4.8 μs. Comparing with the Bi2O2Se uniform thin films, the photo-electric conversion efficiency is greatly improved for the in-plane homojunctions.展开更多
Ultrasonic motors have the merits of high ratio of torque to volume, high positioning precision, intrinsic holding torque, etc., compared to the conventional electromagnetic motors. There have been several potential a...Ultrasonic motors have the merits of high ratio of torque to volume, high positioning precision, intrinsic holding torque, etc., compared to the conventional electromagnetic motors. There have been several potential applications for this type of motor in aerospace exploration, but bearings and bonding mechanism of the piezoelectric ring in the motors limit the performance of them in the space operation conditions. It is known that the Langevin type transducer has excel- lent energy efficiency and reliability. Hence using the Langevin type transducer in ultrasonic motors may improve the reliability of piezoelectric motors for space applications. In this study, a novel in-plane mode rotary ultrasonic motor is designed, fabricated, and characterized. The proposed motor operates in in-plane vibration mode which is excited by four Langevin-type bending vibra- tors separately placed around a ring-shaped stator. Two tapered rotors are assembled to the inner ring of the stator and clamped together by a screw nut. In order to make the motor more stable and convenient to fix, a thin cylindrical support is placed under the stator ring. Due to its no-bearing structure and Langevin transducer excitation, the prototype ultrasonic motor may operate well in aeronautic and astronautic environments.展开更多
The analysis method of lattice dynamics in classical physics is extended to study the properties of in-plane wave motion in the hybrid-mass finite element model in this paper. The dispersion equations of P and SV wave...The analysis method of lattice dynamics in classical physics is extended to study the properties of in-plane wave motion in the hybrid-mass finite element model in this paper. The dispersion equations of P and SV waves in the discrete model are first obtained by means of separating the characteristic equation of the motion equation, and then used to analyse the properties of P-and SV-homogeneous, inhomogeneous waves and other types of motion in the model. The dispersion characters, cut-off frequencies of P and SV waves, the polarization drift and appendent anisotropic property of wave motion caused by the discretization are finally discussed.展开更多
Sheet-metal products are integral parts of engineering industries and academia research. Various testing techniques have revealed the deformation behaviors of sheet metals under complex stress states. Information obta...Sheet-metal products are integral parts of engineering industries and academia research. Various testing techniques have revealed the deformation behaviors of sheet metals under complex stress states. Information obtained from tensile and compression tests, however, are insufficient for the identification of material parameters relevant to modern constitutive laws, which require experimental setups capable of generating various loading conditions and applying great amounts of strain to sheet metals. In-plane shear testing has emerged as an important method to overcome the challenges associated with tension and compression tests and can provide additional information about deformation behaviors under large plastic strains. Materials such as Mg alloys with poor levels of both ductility and formability cannot accommodate large plastic strains. Therefore, tension and compression tests have limitations in explaining the material behaviors that occur during sheet metal forming where large plastic strains are introduced. Many studies have been conducted to explain the deformation behaviors of Mg alloys under shear deformation techniques. These include severe plastic deformation(SPD), especially the equal channel angular pressing(ECAP)and equal channel angular extrusion, rolling combined with shear deformation i.e. differential speed rolling(DSR), and also in-plane shear for sheet metals, particularly under large levels of plastic strain. These in-plane shear technique involves the Miyauchi shear test, ASTM shear test, and twin bridge shear tests. Moreover, many experimental results have revealed that the evolution of microstructure and texture during in-plane shear is closely related to the failure behavior of materials. Therefore, this review is focused on techniques for in-plane shear testing that have been reported thus far, on the effect of in-plane shear on the microstructure development of Mg alloy sheets, and on the usefulness of in-plane shear testing to evaluate the formability of Mg alloy sheets.展开更多
As the continuation study on amplification of in-plane seismic ground motion by underground group cavities in layered half-space, this study extends to the case of poroelastic half-space with dry poroelastic and satur...As the continuation study on amplification of in-plane seismic ground motion by underground group cavities in layered half-space, this study extends to the case of poroelastic half-space with dry poroelastic and saturated poroelastic soil layers. The influence of poroelastic layers on the amplification of seismic ground motion is studied both in frequency domain and time domain using indirect boundary element method （IBEM）. It is shown that for the example of a saturated poroelastic site in Tianjin under the excitation of Taft wave and E1 Centro wave, the amplification of seismic ground motion in poroelastic case is slightly smaller than that in the elastic case, and the amplification of PGA （peak ground acceleration） and its PRS （peak response spectrum）.. can be increased up to 38.8% and 64.6%; the predominant period of response spectra in poroelastic case becomes shorter to some extent compared with that in the elastic case. It is suggested that the effect of underground group cavities in poroelastic half-space on design seismic ground motion should be considered.展开更多
As an effort to minimize material utilization, seismic steel dampers designed to deform inelastically in an in-plane flexural mode have attracted serious attention recently. This paper presents a new type of metallic ...As an effort to minimize material utilization, seismic steel dampers designed to deform inelastically in an in-plane flexural mode have attracted serious attention recently. This paper presents a new type of metallic yielding damper referred to as the in-plane arch-shaped damper modified from its portal frame-shaped counterpart by replacing the straight beam with a circular arch to minimize the effects of stress concentration and warping, and therefore to avoid premature failure. Component tests of both the portal frame-shaped and arch-shaped in-plane dampers were conducted for comparison. Hysteresis loops obtained from the component tests under cyclic loads indicate substantial improvement on the energydissipative characteristics of the proposed damper. Moreover, seismic performance assessment of the proposed damper was carried out further via shaking table tests of a five-story model frame. Encouraging results have been achieved in terms of acceleration reduction, damping enhancement and peak suppression of the frequency response functions, suggesting the potential of the proposed device to be used in earthquake-resisting systems.展开更多
Amplification of in-plane seismic ground motion by underground group cavities in layered half-space is studied both in frequency domain and time domain by using indirect boundary element method （IBEM）, and the effec...Amplification of in-plane seismic ground motion by underground group cavities in layered half-space is studied both in frequency domain and time domain by using indirect boundary element method （IBEM）, and the effect of cavity interval and spectrum of incident waves on the amplification are studied by numerical examples. It is shown that there may be large interaction between cavities, and group cavities with certain intervals may have significant amplification to seismic ground motion. The amplification of PGA （peak ground acceleration） and its PRS （peak response spectrum） can be increased up to 45.2% and 84.4%, for an example site in Tianjin, under the excitation of Taft wave and E1 Centro wave; and group cavities may also affect the spectra of the seismic ground motion. It is suggested that the effect of underground group cavities on design seismic ground motion should be considered.展开更多
文摘The evolution of microstructure and texture in Mg-3Al-1Zn-1Ca alloy sheets subjected to in-plane shear(IPS)loading was investigated using experimental techniques and viscoplastic self-consistent(VPSC)modeling.The specimens were deformed under varying degrees of IPS strain(γ12=0.05,0.10,and 0.15)using a customized jig.Electron backscatter diffraction(EBSD)observations revealed profuse tensile twinning(TTW)even at an IPS strain of 0.05,with its intensity continuously increased as the IPS strain increased.The TTWs progressively engulfed parent grains with increasing shear strain,evolving into an unusual deformation twin morphology.Furthermore,VPSC model predictions confirmed basal slip as the dominant deformation mode at low IPS strains,transitioning to prismatic slip dominance at higher IPS strains.The activity of the TTW mode was significantly higher during the initial stages of IPS strain and saturated to lower values at higher strains.VPSC simulation results also indicated preferential shear accumulation on a single twin system,explaining the phenomenon of a single twin variant engulfing a parent grain.Additionally,the influence of individual slip and twin modes on texture evolution was evaluated through orientation tracking of representative grains at various shear strain increments using VPSC simulation.The simulation results quantitatively highlighted the activities of basal slip,prismatic slip,and tensile twinning,establishing a correlation between texture evolution and the underlying deformation mechanisms.
基金supported by the National Natural Science Foundation of China(Nos.22175060 and 22376062)JSPS Grant-in-Aid for Scientific Research(Nos.JP21H05235,JP22H05478 and JP22F22358)+1 种基金China Postdoctoral Science Foundation(No.2022M722867)the Key Research Project of Higher Education Institutions in Henan Province(No.23A530001).
文摘Exploring earth-abundant,highly active bifunctional electrocatalysts for efficient hydrogen and oxygen evolution is crucial for water splitting.However,due to their distinct free energies and conducting behaviors(electron/hole),balancing the catalytic efficiency between hydrogen and oxygen evolution remains challenging for achieving bifunctional electrocatalysts.Here,we report a locally-doped MoS_(2)monolayer with an in-plane heterostructure acting as a bifunctional electrocatalyst and apply it to the overall water splitting.In this heterostructure,the core region contains Mo/S vacancies,while the ring region was doped by Fe atoms(in two substitution configurations:1FeMo and 3FeMo-VS clusters)with a p-type conductive characteristic.Our micro-cell measurements,combined with density functional theory(DFT)calculations,reveal that the vacancies-rich core region presents remarkable hydrogen evolution reaction(HER)activity while the Fe-doped ring gives an excellent oxygen evolution reaction(OER)activity,thus forming an in-plane bifunctional electrocatalyst.Finally,as a proof-of-concept for overall water splitting,we constructed a full-cell configuration based on a locally-doped MoS_(2)monolayer,which achieved a cell voltage of 1.87 V at 10 mA·cm^(-2),demonstrating outstanding performance in strong acid electrolytes.Our work provides insight into the hetero-integration of bifunctional electrocatalysts at the atomic level,paving the way for designing transition metal dichalcogenide catalysts with activity-manipulated regions capable of multiple reactions.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.62488201 and 1240041502)the Ministry of Science and Technology of China(Grant No.2022YFA1204100)+1 种基金the Chinese Academy of Sciences(Grant No.XDB33030100)the Innovation Program of Quantum Science and Technology(Grant No.2021ZD0302700)。
文摘Two-dimensional van der Waals(vdW)magnetic materials,characterized by their tunable magnetism,spin transport properties,and remarkable quantum effects,provide significant promise for the development of efficient,low-power spintronic devices.Intriguingly,the rare earth tritelluride(RTe3)materials have attracted great attention due to their unique magnetic structure,exotic electronic properties,multiple charge density wave(CDW),and superconductivity under pressure.Here,we report the successful synthesis of high-quality DyTe_(3)single crystals using a self-flux method.DyTe_(3)shows an antiferromagnetic transition at 4.5 K and demonstrates the magnetic field-induced ferromagnetism.The high-quality DyTe_(3)single crystal demonstrates outstanding transport properties,featuring a high carrier mobility of approximately1.4×10^(4)cm^(2)·V^(-1)·s^(-1)and large linear magnetoresistance of 1300%.Furthermore,distinct Shubnikov-de Haas(SdH)oscillations are observed in DyTe_(3),revealing a small Fermi pocket and an effective mass of 0.24 me.Remarkably,the unconventional in-plane negative magnetoresistances appear along the a-axis below 2 T and c-axis until 9 T from 2 K to17 K,which are attributed to the complex helimagnetic structures caused by CDW coupling and weak single-ion anisotropy.Our findings offer a significant platform for understanding the complex magnetoresistance behavior and quantum transport effects in RTe3-type materials,holding great promise for advancing applications in electronic and spintronic devices.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 62074036, 61674038, and 11574302)Foreign Cooperation Project of Fujian Province (Grant No. 2023I0005)+2 种基金Open Research Fund Program of the State Key Laboratory of Low-Dimensional Quantum Physics (Grant No. KF202108)the National Key Research and Development Program (Grant No. 2016YFB0402303)the Foundation of Fujian Provincial Department of Industry and Information Technology of China (Grant No. 82318075)。
文摘The in-plane optical anisotropy(IPOA) of c-plane In Ga N/Ga N quantum disks(Qdisks) in nanowires grown on MoS_(2)/Mo and Ti/Mo substrates is investigated using reflectance difference spectroscopy(RDS) at room temperature. A large IPOA related to defect or impurity states is observed. The IPOA of samples grown on MoS_(2)/Mo is approximately one order of magnitude larger than that of samples grown on Ti/Mo substrates. Numerical calculations based on the envelope function approximation have been performed to analyze the origin of the IPOA. It is found that the IPOA primarily results from the segregation of indium atoms in the In Ga N/Ga N Qdisks. This work highlights the significant influence of substrate materials on the IPOA of semiconductor heterostructures.
基金supports from The National Natural Science Foundation of China(nos.52222409,52074132,and U19A2084)The National Key Research and Development Program(no.2022YFE0122000)are greatly acknowledgedsupport from The Science and Technology Development Program of Jilin Province(no.20210301025GX).
文摘Texture regulation is a prominent method to modify the mechanical properties and anisotropy of magnesium alloy.In this work,the Mg-1Al-0.3Ca-0.5Mn-0.2Gd(wt.%)alloy sheet with TD-tilted and circular texture was fabricated by unidirectional rolling(UR)and multidirectional rolling(MR)method,respectively.Unlike generating a strong in-plane mechanical anisotropy in conventional TD-tilted texture,the novel circular texture sample possessed a weak in-plane yield anisotropy.This can be rationalized by the similar proportion of soft grains with favorable orientation for basalslip and{10.12}tensile twinning during the uniaxial tension of circular-texture sample along different directions.Moreover,compared with the TD-tilted texture,the circular texture improved the elongation to failure both along the rolling direction(RD)and transverse direction(TD).By quasi-in-situ EBSD-assisted slip trace analysis,higher activation of basal slip was observed in the circular-texture sample during RD tension,contributing to its excellent ductility.When loading along the TD,the TD-tilted texture promoted the activation of{10.12}tensile twins significantly,thus providing nucleation sites for cracks and deteriorating the ductility.This research may shed new insights into the development of formable and ductile Mg alloy sheets by texture modification.
基金financially supported by the National Natural Science Foundation of China (51704324, 52374027)Natural Science Foundation of Shandong Province (ZR2023ME158, ZR2022ME025)Open Fund of Key Laboratory of Tectonics and Petroleum Resources (TPR-2020-14)。
文摘Tri-axial fracturing studies were carried out to understand the impact of lateral mechanical parameters on fracture propagation from multiple in-plane perforations in horizontal wells. Additionally, the discussion covered the effects of geology, treatment, and perforation characteristics on the non-planar propagation behavior. According to experimental findings, two parallel transverse fractures can be successfully initiated from in-plane perforation clusters in the horizontal well because of the in-plane perforation, the guide nonuniform fishbone structure fracture propagation still can be exhibited. The emergence of transverse fractures and axial fractures combined as complex fractures under low horizontal principal stress difference and large pump rate conditions. The injection pressure was also investigated, and the largest breakdown pressure can be also found for samples under these conditions.The increase in perforation number or decrease in the cluster spacing could provide more chances to increase the complexity of the target stimulated zone, thus affecting the pressure fluctuation. In a contrast, the increase in fracturing fluid viscosity can reduce the multiple fracture complexity. The fracture propagation is significantly affected by the change in the rock mechanical properties. The fracture geometry in the high brittle zone seems to be complicated and tends to induce fracture reorientation from the weak-brittle zone. The stress shadow effect can be used to explain the fracture attraction, branch, connection, and repulsion in the multiple perforation clusters for the horizontal well.The increase in the rock heterogeneity can enhance the stress shadow effect, resulting in more complex fracture geometry. In addition, the variable density perforation and temporary plugging fracturing were also conducted, demonstrating higher likelihood for non-uniform multiple fracture propagation. Thus, to increase the perforation efficiency along the horizontal well, it is necessary to consider the lateral fracability of the horizontal well on target formation.
基金Project supported by the Excellent Young Teachers Program of the Ministry of Education of Chinathe Shu-Guang Program of the City of Shanghai+1 种基金the National Natural Sciences Foundation of China(No.10372120)Shanghai Leading Academic Discipline Project(No.Y0103).
文摘This contribution attempts to model the alteration of the in-plane elastic properties in laminates caused by stitching, and to predict the in-plane effective tensile strength of the stitched composite laminates. The distortion of in-plane fibers is considered to be the main cause that affects the in-plane mechanical properties. A fiber distortion model is proposed to characterize the fiber misalignment and the fiber content concentration due to stitching. The undistorted region, the fiber distortion region, the resin-rich pocket and the through-thickness reinforcement section are taken into account. The fiber misalignment and inhomogeneous fiber content due to stitching have been formulated by introducing two parameters, the distortion width and maximum misalignment. It has been found that the ply stress concentration in stitched laminates is influenced by the two concurrent factors, the stitch hole and inhomogeneous fiber content. The stitch hole brings about the stress concentration whereas the higher fiber content at the local region induced by stitching restrains the local deformation of the composite. The model is used to predict the tensile strength of the [0/45/0/-45/90/45/0/-45]58 T300/QY9512 composite laminate stitched by Kevlar 29 yarn with different stitching configurations, showing an acceptable agreement with experimental data.
基金financially supported by National Basic Research Program of China(No.2014CB643604)
文摘The thermal and mechanical properties of the chemically imidized polyimide(CIPI) films and thermally imidized polyimide(TIPI) films were investigated systematically. Experimental results indicated that the CIPI films show dramatically enhanced tensile strength and modulus with obviously reduced coefficient of thermal expansion(CTE) in comparison with TIPI films. These enhancements results from the high in-plane orientation and close packing of the CIPI backbones. Compared with thermal imidization which starts at about 140 °C, the chemical imidization activated by acetic anhydride and isoquinoline initiates the cyclization even at room temperature.The resulting imide rings restrict the mobility of polymer chains and lead to the in-plane orientation with solvent evaporation.Additionally, fewer small molecules remain in the films after treated at 120 °C by chemical imidization than by thermal imidization. The polymer chain plasticization caused by the evaporation of small molecules at high temperature is obviously restricted. Moreover, the partially imidized polymer inhibits the decomposition of mainchains that occurs at subsequent high temperature process, being beneficial to the formation of high molecular weight PI films. Hence, chemical imidization pathway shows apparent advantage to produce PI films with great combined properties, including high modulus, strength and toughness, as well as high thermal dimension stability etc.
基金the National Natural Science Foundation of China(50478014)the National 973 Program(2007CB714200)the Beijing Natural Science Foundation(8061003).
文摘A 1D finite element method in time domain is developed in this paper and applied to calculate in-plane wave motions of free field exited by SV or P wave oblique incidence in an elastic layered half-space. First, the layered half-space is discretized on the basis of the propagation characteristic of elastic wave according to the Snell law. Then, the finite element method with lumped mass and the central difference method are incorporated to establish 2D wave motion equations, which can be transformed into 1D equations by discretization principle and explicit finite element method. By solving the 1D equations, the displacements of nodes in any vertical line can be obtained, and the wave motions in layered half-space are finally determined based on the characteristic of traveling wave. Both the theoretical analysis and the numerical results demonstrate that the proposed method has high accuracy and good stability.
基金This work was supported by the National Natural Science Foundation of China(22078063,21825801).
文摘Electrochemical nitrogen reduction reaction (eNRR) is an alternative promising manner for sustainable N2 fixation with low-emission. The major challenge for developing an efficient electrocatalyst is the cleaving of the stable Ntriple bondN triple bonds. Herein, we design a new MoS_(2) with in-plane defect cluster through a bottom-up approach for the first time, where the defect cluster is composed of three adjacent S vacancies. The well-defined in-plane defect clusters could contribute to the strong chemical adsorption and activation towards inert nitrogen, achieving an excellent eNRR performance with an ammonia yield rate of 43.4 ± 3 μg h^(−1) mgcat.^(−1) and a Faradaic efficiency of 16.8 ± 2% at −0.3 V (vs. RHE). The performance is much higher than that of MoS_(2) with the edge defect. Isotopic labeling confirms that N atoms of produced NH4+ originate from N2. Furthermore, the in-plane defect clusters realized the alternate hydrogenation of nitrogen in a side-on way to synthesize ammonia. This work provides a prospecting strategy for fine-tuning in-plane defects in a catalyst, and also promotes the progress of eNRR.
基金supported by the National Natural Science Foundation of China(Grant No.51605292)the Natural Science Foundation of Shanghai(Grant No.15ZR1429000)the Youth Foundation of Shanghai(Grant No.ZZslg15013)
文摘In this work, a set of GTN （Gurson-Tvergaard-Needleman） parameters of the Alloy52M dissimilar metal welded joint （DMWJ） have been calibrated, and a micromechanical analysis of in-plane constraint effects on the local fracture behavior of two cracks, which located in the weakest regions of the DMWJ, has been investigated by the local approach based on the GTN damage model. The results show that the partition of the material and the variation of the q2 parameter make the J-resistance curves obtained by numerical simulations close to the experimental values. The numerical J-resistance curves and crack growth paths are consistent with the experiment results, which show that the GTN damage model can incorporate the in-plane constraint effect. Furthermore, after the stress, strain and damage fields at the crack tip during the crack propagation process have been calculated, and the change of the J-resistance curves, crack growth paths and fracture mechanism with in-plane constraint have been analyzed.
基金Project supported by the National Science and Technology Major Project(NMP)of China(No.2013ZX04011-011)
文摘The Green function method （GFM） is utilized to analyze the in-plane forced vibration of curved pipe conveying fluid, where the randomicity and distribution of the external excitation and the added mass and damping ratio are considered. The Laplace transform is used, and the Green functions with various boundary conditions are obtained subsequently. Numerical calculations are performed to validate the present solutions, and the effects of some key parameters on both tangential and radial displacements are further investigated. The forced vibration problems with linear and nonlinear motion constraints are also discussed briefly. The method can be radiated to study other forms of forced vibration problems related with pipes or more extensive issues.
基金This work was financially supported by the National Key Fundamental Research Development Program(No.G1999064911).
文摘The Al-Mg-Mn alloy sheets with and without trace Sc and Zr were investigated by means of tensile test,X-ray diffraction,optical microscope,and transmission electron microscope.The indexes of in-plane anisotropy(IIPA)of their tensile mechanical properties were calculated and their inverse pole figures were obtained by Harris method.The two alloy sheets have the same law of in-plane anisotropy and remarkable in-plane anisotropy of mechanical properties,and the IIPA of the alloy sheet with Sc and Zr is bigger than that of the alloy sheet without Sc and Zr.The relationships of the in-plane anisotropy and the anisotropy of the crystallographic texture were analyzed based on the model of monocrystal.It is the common action of the anisotropy of crystallography and microstructures that causes the in-plane anisotropy of their mechanical properties,but the major cause is the{110}〈112〉crystallographic texture.The trace Sc and Zr can promote the formation and stabilization of the{110}〈112〉texture,inhibit the formation of the{100}〈001〉texture,and increase the in-plane anisotropy of the alloy sheet containing trace Sc and Zr.
基金Project supported by the National Natural Science Foundation of China(Grant No.61705066)the Open Fund of State Key Laboratory of Information Photonics and Optical Communications(Beijing University of Posts and Telecommunications),China(Grant No.IPOC2018B004)the National Key Research and Development Program,China(Grant No.2016YFA0202401)
文摘Bi2O2Se thin film could be one of the promising material candidates for the next-generation electronic and optoelectronic applications. However, the performance of Bi2O2Se thin film-based device is not fully explored in the photodetecting area. Considering the fact that the electrical properties such as carrier mobility, work function, and energy band structure of Bi2O2Se are thickness-dependent, the in-plane Bi2O2Se homojunctions consisting of layers with different thicknesses are successfully synthesized by the chemical vapor deposition(CVD) method across the terraces on the mica substrates,where terraces are created in the mica surface layer peeling off process. In this way, effective internal electrical fields are built up along the Bi2O2Se homojunctions, exhibiting diode-like rectification behavior with an on/off ratio of 102, what is more, thus obtained photodetectors possess highly sensitive and ultrafast features, with a maximum photoresponsivity of 2.5 A/W and a lifetime of 4.8 μs. Comparing with the Bi2O2Se uniform thin films, the photo-electric conversion efficiency is greatly improved for the in-plane homojunctions.
基金supported by the National Natural Science Foundation of China (Nos. 51205203, 51275228, 51075212, and 91123020)Nanjing University of Aeronautics and Astronautics (Nos. 56YAH12015, 56XZA12044, and S0896-013)+1 种基金Innovation and Entrepreneurship Program of Jiangsu, the 111 Project (No. B12021)PAPD
文摘Ultrasonic motors have the merits of high ratio of torque to volume, high positioning precision, intrinsic holding torque, etc., compared to the conventional electromagnetic motors. There have been several potential applications for this type of motor in aerospace exploration, but bearings and bonding mechanism of the piezoelectric ring in the motors limit the performance of them in the space operation conditions. It is known that the Langevin type transducer has excel- lent energy efficiency and reliability. Hence using the Langevin type transducer in ultrasonic motors may improve the reliability of piezoelectric motors for space applications. In this study, a novel in-plane mode rotary ultrasonic motor is designed, fabricated, and characterized. The proposed motor operates in in-plane vibration mode which is excited by four Langevin-type bending vibra- tors separately placed around a ring-shaped stator. Two tapered rotors are assembled to the inner ring of the stator and clamped together by a screw nut. In order to make the motor more stable and convenient to fix, a thin cylindrical support is placed under the stator ring. Due to its no-bearing structure and Langevin transducer excitation, the prototype ultrasonic motor may operate well in aeronautic and astronautic environments.
基金The project sponsored by the Earthquake Science Foundation under Contract No. 90141
文摘The analysis method of lattice dynamics in classical physics is extended to study the properties of in-plane wave motion in the hybrid-mass finite element model in this paper. The dispersion equations of P and SV waves in the discrete model are first obtained by means of separating the characteristic equation of the motion equation, and then used to analyse the properties of P-and SV-homogeneous, inhomogeneous waves and other types of motion in the model. The dispersion characters, cut-off frequencies of P and SV waves, the polarization drift and appendent anisotropic property of wave motion caused by the discretization are finally discussed.
基金financially supported by the Science and Engineering Research Board (SERB)a statutory body of the Department of Science&Technology (DST)+1 种基金Government of India through the Start-up Research Grant (SRG) scheme (File No. SRG/2020/000341)National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT)(NRF-2020R1A2C1010134)。
文摘Sheet-metal products are integral parts of engineering industries and academia research. Various testing techniques have revealed the deformation behaviors of sheet metals under complex stress states. Information obtained from tensile and compression tests, however, are insufficient for the identification of material parameters relevant to modern constitutive laws, which require experimental setups capable of generating various loading conditions and applying great amounts of strain to sheet metals. In-plane shear testing has emerged as an important method to overcome the challenges associated with tension and compression tests and can provide additional information about deformation behaviors under large plastic strains. Materials such as Mg alloys with poor levels of both ductility and formability cannot accommodate large plastic strains. Therefore, tension and compression tests have limitations in explaining the material behaviors that occur during sheet metal forming where large plastic strains are introduced. Many studies have been conducted to explain the deformation behaviors of Mg alloys under shear deformation techniques. These include severe plastic deformation(SPD), especially the equal channel angular pressing(ECAP)and equal channel angular extrusion, rolling combined with shear deformation i.e. differential speed rolling(DSR), and also in-plane shear for sheet metals, particularly under large levels of plastic strain. These in-plane shear technique involves the Miyauchi shear test, ASTM shear test, and twin bridge shear tests. Moreover, many experimental results have revealed that the evolution of microstructure and texture during in-plane shear is closely related to the failure behavior of materials. Therefore, this review is focused on techniques for in-plane shear testing that have been reported thus far, on the effect of in-plane shear on the microstructure development of Mg alloy sheets, and on the usefulness of in-plane shear testing to evaluate the formability of Mg alloy sheets.
基金supported by National Natural Science Foundation of China under grant No. 50978183Key Project for Applied Basic Research of Tianjin Municipality under Grant No. 12JCZDJC29000
文摘As the continuation study on amplification of in-plane seismic ground motion by underground group cavities in layered half-space, this study extends to the case of poroelastic half-space with dry poroelastic and saturated poroelastic soil layers. The influence of poroelastic layers on the amplification of seismic ground motion is studied both in frequency domain and time domain using indirect boundary element method （IBEM）. It is shown that for the example of a saturated poroelastic site in Tianjin under the excitation of Taft wave and E1 Centro wave, the amplification of seismic ground motion in poroelastic case is slightly smaller than that in the elastic case, and the amplification of PGA （peak ground acceleration） and its PRS （peak response spectrum）.. can be increased up to 38.8% and 64.6%; the predominant period of response spectra in poroelastic case becomes shorter to some extent compared with that in the elastic case. It is suggested that the effect of underground group cavities in poroelastic half-space on design seismic ground motion should be considered.
基金TSC under contract MOST 103-2625-M-009-014the Science&Technology of Fujian Province,China under Project No.2017J01495
文摘As an effort to minimize material utilization, seismic steel dampers designed to deform inelastically in an in-plane flexural mode have attracted serious attention recently. This paper presents a new type of metallic yielding damper referred to as the in-plane arch-shaped damper modified from its portal frame-shaped counterpart by replacing the straight beam with a circular arch to minimize the effects of stress concentration and warping, and therefore to avoid premature failure. Component tests of both the portal frame-shaped and arch-shaped in-plane dampers were conducted for comparison. Hysteresis loops obtained from the component tests under cyclic loads indicate substantial improvement on the energydissipative characteristics of the proposed damper. Moreover, seismic performance assessment of the proposed damper was carried out further via shaking table tests of a five-story model frame. Encouraging results have been achieved in terms of acceleration reduction, damping enhancement and peak suppression of the frequency response functions, suggesting the potential of the proposed device to be used in earthquake-resisting systems.
基金supported by National Natural Science Foundation of China under grant No. 50978183Tianjin Key Project for Applied Basic Research under grant No. 12JCZDJC29000
文摘Amplification of in-plane seismic ground motion by underground group cavities in layered half-space is studied both in frequency domain and time domain by using indirect boundary element method （IBEM）, and the effect of cavity interval and spectrum of incident waves on the amplification are studied by numerical examples. It is shown that there may be large interaction between cavities, and group cavities with certain intervals may have significant amplification to seismic ground motion. The amplification of PGA （peak ground acceleration） and its PRS （peak response spectrum） can be increased up to 45.2% and 84.4%, for an example site in Tianjin, under the excitation of Taft wave and E1 Centro wave; and group cavities may also affect the spectra of the seismic ground motion. It is suggested that the effect of underground group cavities on design seismic ground motion should be considered.
