Novel wet-phase modified expandable graphite(WMEG)particles were developed for in-depth profile control in carbonate reservoirs.The harsh environment of carbonate reservoirs(≥130℃,≥22×10^(4)mg/L)brings signifi...Novel wet-phase modified expandable graphite(WMEG)particles were developed for in-depth profile control in carbonate reservoirs.The harsh environment of carbonate reservoirs(≥130℃,≥22×10^(4)mg/L)brings significant challenges for existing profile control agents.WMEG particles were developed to address this problem.WMEG particles were synthesized via intercalation with ultrasound irradiation and chemical oxidation.The critical expansion temperature of WMEG particles is 130℃,and these particles can effectively expand 3-8 times under high temperature and high salinity water.The core flow experiments show that WMEG particles exhibit a good plugging capacity,profile control capacity,and a better-enhanced oil recovery(EOR)capacity in deep carbonate reservoirs.WMEG particles can be expanded in the formation and form larger particles that bridge the upper and lower end faces of the fracture.Then the high-permeability zones are effectively plugged,and the heterogeneity is improved,resulting in an obvious increase in oil recovery.This research provides a novel insight into future applications of profile control agents for in-depth profile control treatment in carbonate reservoirs.展开更多
CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voir...CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voirs.However,the use of these gels in high-temperature CCUS applications is limited due to their rever-sible swelling behavior at elevated temperatures.In this study,a novel dispersed particle gel(DPG)suspension is developed for high-temperature profile control in CCUS applications.First,we synthesize a double-network hydrogel consisting of a crosslinked polyacrylamide(PAAm)network and a crosslinked sodium alginate(SA)network.The hydrogel is then sheared in water to form a pre-prepared DPG suspen-sion.To enhance its performance,the gel particles are modified by introducing potassium methylsilan-etriolate(PMS)upon CO_(2) exposure.Comparing the particle size distributions of the modified and pre-prepared DPG suspension reveals a significant swelling of gel particles,over twice their original size.Moreover,subjecting the new DPG suspension to a 100℃ environment for 24 h demonstrates that its gel particle sizes do not decrease,confirming irreversible swelling,which is a significant advantage over the traditional CO_(2)-responsive gels.Thermogravimetric analysis further indicates improved thermal sta-bility compared to the pre-prepared DPG particles.Core flooding experiments show that the new DPG suspension achieves a high plugging efficiency of 95.3%in plugging an ultra-high permeability sandpack,whereas the pre-prepared DPG suspension achieves only 82.8%.With its high swelling ratio,irreversible swelling at high temperatures,enhanced thermal stability,and superior plugging performance,the newly developed DPG suspension in this work presents a highly promising solution for profile control in high-temperature CCUS applications.展开更多
A new polymer system, referred to simply as the AP-P4 polymer system, aims at solving the problems of high temperature, high salinity and the poor shearing resistance, all of which are encountered by conventional ...A new polymer system, referred to simply as the AP-P4 polymer system, aims at solving the problems of high temperature, high salinity and the poor shearing resistance, all of which are encountered by conventional polymers (such as polyacrylamide) used in profile control, profile performance improvement and EOR operations in the Zhongyuan Oilfield, Sinopec. This system has been developed on the basis of the specific molecular structure and the better properties of high temperature resistance, high salinity resistance and strong shearing resistance of the new type of AP-P4 association polymer. Acidity modifying agents and cross-linking agents (MZ-YL, MZ-BE, MZ-XS), compatible with the new polymer system, are selected. Results of performance tests have shown that the new polymer system has excellent thickening, high temperature, high salinity and shearing resistance and anti-dehydrating properties. In 2003, it underwent its first pilot test in 26 wells in China, with remarkable effects in increasing oil production and decreasing water production. The newly developed polymer system and its application technology described in this paper may play a guiding role in polymer profile control operations in the oil reservoirs of high temperature and high salinity.展开更多
Profile monitoring is used to check the stability of the quality of a product over time when the product quality is best represented by a function at each time point.However,most previous monitoring approaches have no...Profile monitoring is used to check the stability of the quality of a product over time when the product quality is best represented by a function at each time point.However,most previous monitoring approaches have not considered that the argument values may vary from profile to profile,which is common in practice.A novel nonparametric control scheme based on profile error is proposed for monitoring nonlinear profiles with varied argument values.The proposed scheme uses the metrics of profile error as the statistics to construct the control charts.More details about the design of this nonparametric scheme are also discussed.The monitoring performance of the combined control scheme is compared with that of alternative nonparametric methods via simulation.Simulation studies show that the combined scheme is effective in detecting parameter error and is sensitive to small shifts in the process.In addition,due to the properties of the charting statistics,the out-of-control signal can provide diagnostic information for the users.Finally,the implementation steps of the proposed monitoring scheme are given and applied for monitoring the blade manufacturing process.With the application in blade manufacturing of aircraft engines,the proposed nonparametric control scheme is effective,interpretable,and easy to apply.展开更多
Varying contact-length backup roll and linearly variable crown work roll are provided for improving the mill performance of profile and flatness control. Integrated with theses technologies, relevant profile and flatn...Varying contact-length backup roll and linearly variable crown work roll are provided for improving the mill performance of profile and flatness control. Integrated with theses technologies, relevant profile and flatness control models are developed for hot strip mills on the basis of large amount of finite element calculation. These models include shape setup control model in process control system, bending force feedforward control model, crown feedback control model and flatness feedback control model in basis automation system. Such a profile and flatness control system with full functions is applied in 1 700 mm industrial hot strip mills of Ansteel. Large amount of production data shows that the crown precision with the tolerance of±18 μm is over 90%, the strip percentage which the actual flatness is within ±25 I-unit surpasses 96%, and general roll consume is reduced by 28% by using the profile and fiatness control system. In addition, schedule-free rolling is realized.展开更多
Scaled physical model tests for steam breakthrough were conducted based on the analysis of mechanisms and influence factors of steam breakthrough. Physical simulation results showed that at the initial steam breakthro...Scaled physical model tests for steam breakthrough were conducted based on the analysis of mechanisms and influence factors of steam breakthrough. Physical simulation results showed that at the initial steam breakthrough, preferential flow channels were formed in narrow sand packs and most residual oil left in these channels was immobile. This shortened the steam breakthrough time of follow-up steam flooding and decreased the increment of oil recovery efficiency. Steam breakthrough occurred easily for a smaller producer-injector spacing, and a bigger difference in physical properties between fluids and rock. Steam breakthrough is more likely to occur at a larger formation permeability （k）, greater steam displacement velocity （u） and smaller producer-injector spacing （L）. Steam breakthrough time is a function of the parameter group （uk/L）, i.e. tb=3.2151 （uk/L）^-0.5142. A non piston-like displacement model was built based on steam breakthrough observation for a steam stimulated well in the Jinglou Oilfield, Henan Oilfield Company. The steam volume swept in different directions could be obtained from inter-well permeability capacity and breakthrough angle, and the steam swept pore volume （SSPV） was also determined. Numerical simulation showed that steam sweep efficiency reached its peak value when a slug of profile control agent （slug size 10%-15% SSPV） was set at one half of the inter-well spacing. Field test with 12.5% SSPV of profile control agents in the Jinglou Oilfield achieved success in sealing breakthrough channels and good production performance of adjacent producers.展开更多
The healthy and rapid development of the controlled cooling technology was hampered by the uneven cooling phenomenon. During the process of hot plate production,the homogeneous cooling along the length direction of pl...The healthy and rapid development of the controlled cooling technology was hampered by the uneven cooling phenomenon. During the process of hot plate production,the homogeneous cooling along the length direction of plate was constrained by lots of factors. And because the speed was a flexible control parameter,the calculation method of optimal speed profile was developed based on the measured start cooling temperature and its matrix equation was solved by the Cholesky decomposition method. The optimal speed profile was used in online control system. As a result,the temperature distribution along the plate length direction was relatively uniform,and 95% of measured final cooling temperature difference from the target temperature 700 ℃ was controlled within ±20 ℃.展开更多
The roll contour pattern and variety of work and backup rolls in service and its effect on profile and flatness control performance in 1 700 mm hot strip mill at Wuhan Iron and Steel(Group) Corporation were tested and...The roll contour pattern and variety of work and backup rolls in service and its effect on profile and flatness control performance in 1 700 mm hot strip mill at Wuhan Iron and Steel(Group) Corporation were tested and analyzed by the developed finite element models of different typical roll contours configurations.A rather smooth local work roll contour near strip edges and an increase in rolled length can be obtained by application of long stroke work roll shifting system with conventional work roll contours that is incapable of the crown control.In comparison with the conventional backup and work roll contours configuration,the crown control range by the roll bending force enhances by 12.79% and the roll gap stiffness increases by 25.26% with the developed asymmetry self-compensating work rolls(ASR) and varying contact backup rolls(VCR).A better strip profile and flatness quality,an increase in coil numbers within the rolling campaign and a significant alleviated effect of severe work roll wear contours on performance of edge drop control are achieved by the application of ASR with crown control and wear control ability in downstream stand F5 and VCR in all stands of 1 700 mm hot strip mill.展开更多
When heavy-duty commercial vehicles(HDCVs)must engage in emergency braking,uncertain conditions such as the brake pressure and road profile variations will inevitably affect braking control.To minimize these uncertain...When heavy-duty commercial vehicles(HDCVs)must engage in emergency braking,uncertain conditions such as the brake pressure and road profile variations will inevitably affect braking control.To minimize these uncertainties,we propose a combined longitudinal and lateral controller method based on stochastic model predictive control(SMPC)that is achieved via Chebyshev–Cantelli inequality.In our method,SMPC calculates braking control inputs based on a finite time prediction that is achieved by solving stochastic programming elements,including chance constraints.To accomplish this,SMPC explicitly describes the probabilistic uncertainties to be used when designing a robust control strategy.The main contribution of this paper is the proposal of a braking control formulation that is robust against probabilistic friction circle uncertainty effects.More specifically,the use of Chebyshev–Cantelli inequality suppresses road profile influences,which have characteristics that are different from the Gaussian distribution,thereby improving both braking robustness and control performance against statistical disturbances.Additionally,since the Kalman filtering(KF)algorithm is used to obtain the expectation and covariance used for calculating deterministic transformed chance constraints,the SMPC is reformulated as a KF embedded deterministic MPC.Herein,the effectiveness of our proposed method is verified via a MATLAB/Simulink and TruckSim co-simulation.展开更多
The morphology of the gully longitudinal profile （GLP） is an important topographic index of the gully bottom associated with the evolution of the gullies. This index can be used to predict the development trend and ...The morphology of the gully longitudinal profile （GLP） is an important topographic index of the gully bottom associated with the evolution of the gullies. This index can be used to predict the development trend and evaluate the eroded volumes and soil losses by gullying. To depict the morphology of GLP and understand its controlling factors, the Global Positioning System Real-time Kinematic （GPS RTK） and the total station were used to measure the detail points along the gully bottom of 122 gullies at six sites of the Yuanmou dry-hot Valley. Then, nine parameters including length （Lt）, horizontal distance （Dh）, height （H）, vertical erosional area （A）, vertical curvature （Co）, concavity （Ca）, average gradient （Ga）, gully length-gradient index （GL）, normalized gully length-gradient index （Ngl）, were calculated and mapped using CASS, Excel and SPSS. The results showed that this study area is dominated by slightly concave and medium gradient GLPs, and the lithology of most gullies is sandstone and siltstone. Although different types of GLPs appear at different sites, all parameters present a positively skewed distribution. There are relatively strong correlations between several parameters： namely Lt and H, Dh and H, Lt and A, Dh and A, H and GL. Most GLPs, except three, have a best fit of exponential functions with quasi- straight shapes. Soil properties, vegetation coverage, piping erosion and topography are important factors to affect the GLP morphology. This study provides useful insight into the knowledge of GLP morphology and its influential factors that are of critical importance to prevent and control gully erosion.展开更多
Two sand packs were filled with fine glass beads and quartz sand respectively. The characteristics of crosslinked polymer flowing through the sand packs as well as the influence of shear fracture of porous media on th...Two sand packs were filled with fine glass beads and quartz sand respectively. The characteristics of crosslinked polymer flowing through the sand packs as well as the influence of shear fracture of porous media on the indepth profile modification of the weak gel generated from the crosslinked polymer were investigated. The results indicated that under the dynamic condition crosslinking reaction happened in both sand packs, and the weak gels in these two cases became small gel particles after water flooding. The differences were： the dynamic gelation time in the quartz sand pack was longer than that in the glass bead pack. Residual resistance factor （FRR） caused by the weak gel in the quartz sand pack was smaller than that in the glass bead pack. The weak gel became gel particles after being scoured by subsequent flood water. A weak gel with uniform apparent viscosity and sealing characteristics was generated in every part of the glass bead pack, which could not only move deeply into the sand pack but also seal the high capacity channels again when it reached the deep part. The weak gel performed in-depth profile modification in the glass bead pack, while in the quartz sand pack, the weak gel was concentrated with 100 cm from the entrance of the sand pack. When propelled by the subsequent flood water, the weak gel could move towards the deep part of the sand pack but then became tiny gel particles and could not effectively seal the high capacity channels there. The in-depth profile modification of the weak gel was very weak in the quartz sand pack. It was the shear fracture of porous media that mainly affected the properties and weakened the in-depth profile modification of the weak gel.展开更多
The electromagnetic control roll(ECR)and electromagnetic stick(ES)are the core elements and the main driving parts of roll profile electromagnetic control technology(RPECT).To prolong the service life,it is necessary ...The electromagnetic control roll(ECR)and electromagnetic stick(ES)are the core elements and the main driving parts of roll profile electromagnetic control technology(RPECT).To prolong the service life,it is necessary to treat ECR and ES surfaces.According to the heterogeneous characteristics of surface treatments,the roll profile electromagnetic control characteristics were analyzed for different parameters.An electromagnetic-thermal-force coupled axisymmetric finite element model was built to explore the differences in performance as a result of several treatment strategies,and the model was verified by experimental results measured with a roll profile electromagnetic control experimental platform.This model was used to analyze the influence of the heterogeneity of ECR inner hole and ES on the roll crown,the roll profile,the average contact pressure,and the stress state during RPECT process.The results indicate that the heterogeneous layer at ECR inner hole has a restrictive effect on RPECT and that the heterogeneous layer of ES can enhance the profile control ability of RPECT.A reasonable configuration scheme between the heterogeneity of ECR inner hole and the ES can increase the life of ECR and maintain the control ability of RPECT.展开更多
The profile control hard-gel is composed of polyarylamide (5-6g/L), whose molecular weight is 4,000,000 - 7,000,000 and hydrolysis degree is 17.6%, and cross-linking oxidation-reduction agent (Na2Cr2O7 + NH4Cl), with ...The profile control hard-gel is composed of polyarylamide (5-6g/L), whose molecular weight is 4,000,000 - 7,000,000 and hydrolysis degree is 17.6%, and cross-linking oxidation-reduction agent (Na2Cr2O7 + NH4Cl), with an delayed organic acid crosslinker which contains lactic acid/propionic acid/ethanoic acid and ethylene glycol. After research of the influence factors, such as pH, temperature, salinity and the dosage of delayed crosslinker, the optimum condition(pH 5.2, temperature 55℃, salinity < 7g/L) was found. Gelation time (12-144h) can be controlled by adjusting the dosage of the delayed crosslinker. Deep profile control experiments are carried out on heterogeneous models, which contains three serial high permeable and low permeable cores arranged in a parallel. After water flooding (total recovery, 24.3%), the first, second and third high-permeable cores each are sealed in turn by the profile control agent, and the total displacement recovery increases to 46.8%, 62.2% and 69.1% respectively. So, the greater the sealed depth, the larger the enhancing recovery will be. Finally, the oil displacement mechanisms of deep profile control are discussed.展开更多
Heavy oil will play an important role in future resources exploitation.Factors such as reservoir heterogeneity and adverse oil/steam mobility ratio have led to severe steam channeling and fingering,thereby reduced con...Heavy oil will play an important role in future resources exploitation.Factors such as reservoir heterogeneity and adverse oil/steam mobility ratio have led to severe steam channeling and fingering,thereby reduced conformance efficiency and affected de-velopment response.Therefore,the research on profile control and water shut-off agents becomes increasingly important for thermal recovery wells.The requirements on the performances of profile control and water shut-off agents are discussed in conjunction with the physical properties of heavy oil reservoirs and the technical conditions of steam injection in China.Based on the mechanism of action,research progress and application status,5 agents are summarized including polymer gel,solid particles plugging agent,foam,water-in-oil emulsion and salt precipitation.Problems in each agent are mentioned,and optimization solutions are put for-ward.At last,the development trend of future profile control and water shut-off agents is put forward,i.e.synthesizing agents of low cost and high-temperature resistance,intensifying mechanism research,developing composite system,and researching on new technologies that are less harmful and environmental friendly.展开更多
Most of the mining method of domestic oilfield is waterflood development, thus the water content in the mid and late water flooding would rise faster, and the oil recovery rate would decline relatively more rapid. So ...Most of the mining method of domestic oilfield is waterflood development, thus the water content in the mid and late water flooding would rise faster, and the oil recovery rate would decline relatively more rapid. So it is very important to research profile control agent for stabilizing oil production resin-type profile control agent, and focus on researching the themal stability, shear resistance, gelation time and gelation strength and other properties of this profile control agent?[1]. Finally, the best ratio for synthesizing the high temperature resistant phenolic resin-type profile control agent was obtained.展开更多
Facing problems with oil production decreasing quickly and water content increasing gradually in S103 well area, the Foam Profile Control was studied on the basis of its confirmed agent formula. The facies-controlled ...Facing problems with oil production decreasing quickly and water content increasing gradually in S103 well area, the Foam Profile Control was studied on the basis of its confirmed agent formula. The facies-controlled geological model of S103 well area was generated using random model based on Petrel software and using numerical simulation based on CMG software. Gas liquid alternating injection pattern was optimized as the optimal solution through the simulation optimization. Two months are optimized as the optimal solution through the simulation optimization. The cumulative oil production is 0.933 × 107 kg which is higher than the value of subsequent water flooding and the other three. Finally, it reaches the goals of slowing down the production decline and controlling the water rising.展开更多
Polyacrylamide microspheres have been suc- cessfully used to reduce water production in reservoirs, but it is impossible to distinguish polyacrylamide microspheres from polyacrylamide that is used to enhance oil recov...Polyacrylamide microspheres have been suc- cessfully used to reduce water production in reservoirs, but it is impossible to distinguish polyacrylamide microspheres from polyacrylamide that is used to enhance oil recovery and is already present in production fluids. In order to detect polyacrylamide microspheres in the reservoir pro- duced fluid, fluorescent polyacrylamide microspheres P（AM-BA-AMCO）, which fluoresce under ultraviolet irradiation, were synthesized via an inverse suspension polymerization. In order to keep the particle size distribu- tion in a narrow range, the synthesis conditions of the polymerization were studied, including the stirring speed and the concentrations of initiator, NaaCO3, and dispersant. The bonding characteristics of microspheres were deter- mined by Fourier transform infrared spectroscopy. The surface morphology of these microspheres was observed under ultraviolet irradiation with an inverse fluorescence microscope. A laboratory evaluation test showed that the fluorescent polymer microspheres had good water swelling capability, thus they had the ability to plug and migrate in a sand pack. The plugging rate was 99.8 % and the residual resistance coefficient was 800 after microsphere treatment in the sand pack. Furthermore, the fluorescent microspheres and their fragments were accurately detected under ultra- violet irradiation in the produced fluid, even though theyhad experienced extrusion and deformation in the sand pack.展开更多
Due to long-term water injection,often oilfields enter the so-called medium and high water cut stage,and it is difficult to achieve good oil recovery and water reduction through standard methods(single profile control...Due to long-term water injection,often oilfields enter the so-called medium and high water cut stage,and it is difficult to achieve good oil recovery and water reduction through standard methods(single profile control and flooding measures).Therefore,in this study,a novel method based on“plugging,profile control,and flooding”being implemented at the same time is proposed.To assess the performances of this approach,physical simulations,computer tomography,and nuclear magnetic resonance are used.The results show that the combination of a gel plugging agent,a polymer microsphere flooding agent,and a high-efficiency oil displacement agent leads to better results in terms of oil recovery with respect to the situation in which these approaches are used separately(the oil recovery is increased by 15.37%).Computer tomography scan results show that with the combined approach,a larger sweep volume and higher oil washing efficiency are obtained.The remaining oil in the cluster form can be recovered in the middle and low permeability layer,increasing the proportion of the columnar and blind end states of the oil.The nuclear magnetic resonance test results show that the combined“plugging,profile control,and flooding”treatment can also be used to control more effectively the dominant channels of the high permeability layer and further expand the recovery degree of the remaining oil in the pores of different sizes in the middle and low permeability layers.However,for the low permeability layer(permeability difference of 20),the benefits in terms of oil recovery are limited.展开更多
In this survey paper we first recall the known results on the exact boundary controllability of nodal profile, then give some suggestions on further studies on this subject.
A large amount of residue from the water treatment process has gradually accumulated and thus caused serious environmental pollution in waterflood oilfields. The water treatment residue is a grey suspension, with a de...A large amount of residue from the water treatment process has gradually accumulated and thus caused serious environmental pollution in waterflood oilfields. The water treatment residue is a grey suspension, with a density of 1.08 g/cm^3, and mainly contains over 65% of light CaCO3, MgCO3, CaSO4, Fe2S3 and Ca（OH）2. This paper ascertains the effect of water treatment residue on core permeability and its application in oilfields. Coreflooding tests in laboratory were conducted in two artificial cores and one natural core. Core changes were evaluated by cast model image analysis, mercury injection method and scanning electron microscopy （SEM）. Fresh water was injected into another natural core, which was plugged with water treatment residue, to determine the effective life. The results indicate that the water treatment residue has a strongly plugging capability, a resistance to erosion and a long effective life, and thus it can be used as a cheap raw material for profile control. In the past 8 years, a total of 60,164 m^3 of water treatment residue has been used for profile control of 151 well treatments, with a success ratio of 98% and an effective ratio of 83.2%. In the field tests, the profile control agent increased both starting pressure and injection pressure of injectors, and decreased the apparent water injectivity coefficient, significantly improving intake profiles and lengthening average service life of injectors. 28,381 tons of additional oil were recovered from these corresponding oil wells, with economic benefits of ￥3,069.55×10^4 （RMB） and a remarkable input-output ratio of 8.6：1.展开更多
基金financially supported by the National Natural Science Foundation of China(No.52074335)China University of Petroleum(East China)Independent Innovation Research Program:Oilfield Chemistry and Enhanced Oil Recovery(27RA2302015)+1 种基金Innovation Fund Project for Graduate Student of China University of Petroleum(East China)the Fundamental Research Funds for the Central Universities(No.24CX04003A)。
文摘Novel wet-phase modified expandable graphite(WMEG)particles were developed for in-depth profile control in carbonate reservoirs.The harsh environment of carbonate reservoirs(≥130℃,≥22×10^(4)mg/L)brings significant challenges for existing profile control agents.WMEG particles were developed to address this problem.WMEG particles were synthesized via intercalation with ultrasound irradiation and chemical oxidation.The critical expansion temperature of WMEG particles is 130℃,and these particles can effectively expand 3-8 times under high temperature and high salinity water.The core flow experiments show that WMEG particles exhibit a good plugging capacity,profile control capacity,and a better-enhanced oil recovery(EOR)capacity in deep carbonate reservoirs.WMEG particles can be expanded in the formation and form larger particles that bridge the upper and lower end faces of the fracture.Then the high-permeability zones are effectively plugged,and the heterogeneity is improved,resulting in an obvious increase in oil recovery.This research provides a novel insight into future applications of profile control agents for in-depth profile control treatment in carbonate reservoirs.
基金Lin Du acknowledges the financial support provided by China Scholarship Council(CSC)via a Ph.D.Scholarship(202008510128)supported by Core Technology Project of China National Petroleum Corporation(CNPC)"Research on Thermal Miscible Flooding Technology"(2023ZG18)。
文摘CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voirs.However,the use of these gels in high-temperature CCUS applications is limited due to their rever-sible swelling behavior at elevated temperatures.In this study,a novel dispersed particle gel(DPG)suspension is developed for high-temperature profile control in CCUS applications.First,we synthesize a double-network hydrogel consisting of a crosslinked polyacrylamide(PAAm)network and a crosslinked sodium alginate(SA)network.The hydrogel is then sheared in water to form a pre-prepared DPG suspen-sion.To enhance its performance,the gel particles are modified by introducing potassium methylsilan-etriolate(PMS)upon CO_(2) exposure.Comparing the particle size distributions of the modified and pre-prepared DPG suspension reveals a significant swelling of gel particles,over twice their original size.Moreover,subjecting the new DPG suspension to a 100℃ environment for 24 h demonstrates that its gel particle sizes do not decrease,confirming irreversible swelling,which is a significant advantage over the traditional CO_(2)-responsive gels.Thermogravimetric analysis further indicates improved thermal sta-bility compared to the pre-prepared DPG particles.Core flooding experiments show that the new DPG suspension achieves a high plugging efficiency of 95.3%in plugging an ultra-high permeability sandpack,whereas the pre-prepared DPG suspension achieves only 82.8%.With its high swelling ratio,irreversible swelling at high temperatures,enhanced thermal stability,and superior plugging performance,the newly developed DPG suspension in this work presents a highly promising solution for profile control in high-temperature CCUS applications.
文摘A new polymer system, referred to simply as the AP-P4 polymer system, aims at solving the problems of high temperature, high salinity and the poor shearing resistance, all of which are encountered by conventional polymers (such as polyacrylamide) used in profile control, profile performance improvement and EOR operations in the Zhongyuan Oilfield, Sinopec. This system has been developed on the basis of the specific molecular structure and the better properties of high temperature resistance, high salinity resistance and strong shearing resistance of the new type of AP-P4 association polymer. Acidity modifying agents and cross-linking agents (MZ-YL, MZ-BE, MZ-XS), compatible with the new polymer system, are selected. Results of performance tests have shown that the new polymer system has excellent thickening, high temperature, high salinity and shearing resistance and anti-dehydrating properties. In 2003, it underwent its first pilot test in 26 wells in China, with remarkable effects in increasing oil production and decreasing water production. The newly developed polymer system and its application technology described in this paper may play a guiding role in polymer profile control operations in the oil reservoirs of high temperature and high salinity.
基金supported by National Natural Science Foundation of China (Grant No. 70931004,Grant No. 70802043)
文摘Profile monitoring is used to check the stability of the quality of a product over time when the product quality is best represented by a function at each time point.However,most previous monitoring approaches have not considered that the argument values may vary from profile to profile,which is common in practice.A novel nonparametric control scheme based on profile error is proposed for monitoring nonlinear profiles with varied argument values.The proposed scheme uses the metrics of profile error as the statistics to construct the control charts.More details about the design of this nonparametric scheme are also discussed.The monitoring performance of the combined control scheme is compared with that of alternative nonparametric methods via simulation.Simulation studies show that the combined scheme is effective in detecting parameter error and is sensitive to small shifts in the process.In addition,due to the properties of the charting statistics,the out-of-control signal can provide diagnostic information for the users.Finally,the implementation steps of the proposed monitoring scheme are given and applied for monitoring the blade manufacturing process.With the application in blade manufacturing of aircraft engines,the proposed nonparametric control scheme is effective,interpretable,and easy to apply.
基金National Key Scientific Technological Project of the Ninth Five-year of China(No.97-316-01-01)
文摘Varying contact-length backup roll and linearly variable crown work roll are provided for improving the mill performance of profile and flatness control. Integrated with theses technologies, relevant profile and flatness control models are developed for hot strip mills on the basis of large amount of finite element calculation. These models include shape setup control model in process control system, bending force feedforward control model, crown feedback control model and flatness feedback control model in basis automation system. Such a profile and flatness control system with full functions is applied in 1 700 mm industrial hot strip mills of Ansteel. Large amount of production data shows that the crown precision with the tolerance of±18 μm is over 90%, the strip percentage which the actual flatness is within ±25 I-unit surpasses 96%, and general roll consume is reduced by 28% by using the profile and fiatness control system. In addition, schedule-free rolling is realized.
文摘Scaled physical model tests for steam breakthrough were conducted based on the analysis of mechanisms and influence factors of steam breakthrough. Physical simulation results showed that at the initial steam breakthrough, preferential flow channels were formed in narrow sand packs and most residual oil left in these channels was immobile. This shortened the steam breakthrough time of follow-up steam flooding and decreased the increment of oil recovery efficiency. Steam breakthrough occurred easily for a smaller producer-injector spacing, and a bigger difference in physical properties between fluids and rock. Steam breakthrough is more likely to occur at a larger formation permeability （k）, greater steam displacement velocity （u） and smaller producer-injector spacing （L）. Steam breakthrough time is a function of the parameter group （uk/L）, i.e. tb=3.2151 （uk/L）^-0.5142. A non piston-like displacement model was built based on steam breakthrough observation for a steam stimulated well in the Jinglou Oilfield, Henan Oilfield Company. The steam volume swept in different directions could be obtained from inter-well permeability capacity and breakthrough angle, and the steam swept pore volume （SSPV） was also determined. Numerical simulation showed that steam sweep efficiency reached its peak value when a slug of profile control agent （slug size 10%-15% SSPV） was set at one half of the inter-well spacing. Field test with 12.5% SSPV of profile control agents in the Jinglou Oilfield achieved success in sealing breakthrough channels and good production performance of adjacent producers.
文摘The healthy and rapid development of the controlled cooling technology was hampered by the uneven cooling phenomenon. During the process of hot plate production,the homogeneous cooling along the length direction of plate was constrained by lots of factors. And because the speed was a flexible control parameter,the calculation method of optimal speed profile was developed based on the measured start cooling temperature and its matrix equation was solved by the Cholesky decomposition method. The optimal speed profile was used in online control system. As a result,the temperature distribution along the plate length direction was relatively uniform,and 95% of measured final cooling temperature difference from the target temperature 700 ℃ was controlled within ±20 ℃.
基金Project(20040311890) supported by the Science and Technology Development Foundation of University of Science and Technology Beijing
文摘The roll contour pattern and variety of work and backup rolls in service and its effect on profile and flatness control performance in 1 700 mm hot strip mill at Wuhan Iron and Steel(Group) Corporation were tested and analyzed by the developed finite element models of different typical roll contours configurations.A rather smooth local work roll contour near strip edges and an increase in rolled length can be obtained by application of long stroke work roll shifting system with conventional work roll contours that is incapable of the crown control.In comparison with the conventional backup and work roll contours configuration,the crown control range by the roll bending force enhances by 12.79% and the roll gap stiffness increases by 25.26% with the developed asymmetry self-compensating work rolls(ASR) and varying contact backup rolls(VCR).A better strip profile and flatness quality,an increase in coil numbers within the rolling campaign and a significant alleviated effect of severe work roll wear contours on performance of edge drop control are achieved by the application of ASR with crown control and wear control ability in downstream stand F5 and VCR in all stands of 1 700 mm hot strip mill.
文摘When heavy-duty commercial vehicles(HDCVs)must engage in emergency braking,uncertain conditions such as the brake pressure and road profile variations will inevitably affect braking control.To minimize these uncertainties,we propose a combined longitudinal and lateral controller method based on stochastic model predictive control(SMPC)that is achieved via Chebyshev–Cantelli inequality.In our method,SMPC calculates braking control inputs based on a finite time prediction that is achieved by solving stochastic programming elements,including chance constraints.To accomplish this,SMPC explicitly describes the probabilistic uncertainties to be used when designing a robust control strategy.The main contribution of this paper is the proposal of a braking control formulation that is robust against probabilistic friction circle uncertainty effects.More specifically,the use of Chebyshev–Cantelli inequality suppresses road profile influences,which have characteristics that are different from the Gaussian distribution,thereby improving both braking robustness and control performance against statistical disturbances.Additionally,since the Kalman filtering(KF)algorithm is used to obtain the expectation and covariance used for calculating deterministic transformed chance constraints,the SMPC is reformulated as a KF embedded deterministic MPC.Herein,the effectiveness of our proposed method is verified via a MATLAB/Simulink and TruckSim co-simulation.
基金supported by the"National Natural Science Foundation of China(Grant No.41471232)""the Fundamental Research Funds of China West Normal University"(Grant No.16A001)"Ecological Security Key Laboratory of Sichuan Province"(Grant No.ESP201301)
文摘The morphology of the gully longitudinal profile （GLP） is an important topographic index of the gully bottom associated with the evolution of the gullies. This index can be used to predict the development trend and evaluate the eroded volumes and soil losses by gullying. To depict the morphology of GLP and understand its controlling factors, the Global Positioning System Real-time Kinematic （GPS RTK） and the total station were used to measure the detail points along the gully bottom of 122 gullies at six sites of the Yuanmou dry-hot Valley. Then, nine parameters including length （Lt）, horizontal distance （Dh）, height （H）, vertical erosional area （A）, vertical curvature （Co）, concavity （Ca）, average gradient （Ga）, gully length-gradient index （GL）, normalized gully length-gradient index （Ngl）, were calculated and mapped using CASS, Excel and SPSS. The results showed that this study area is dominated by slightly concave and medium gradient GLPs, and the lithology of most gullies is sandstone and siltstone. Although different types of GLPs appear at different sites, all parameters present a positively skewed distribution. There are relatively strong correlations between several parameters： namely Lt and H, Dh and H, Lt and A, Dh and A, H and GL. Most GLPs, except three, have a best fit of exponential functions with quasi- straight shapes. Soil properties, vegetation coverage, piping erosion and topography are important factors to affect the GLP morphology. This study provides useful insight into the knowledge of GLP morphology and its influential factors that are of critical importance to prevent and control gully erosion.
文摘Two sand packs were filled with fine glass beads and quartz sand respectively. The characteristics of crosslinked polymer flowing through the sand packs as well as the influence of shear fracture of porous media on the indepth profile modification of the weak gel generated from the crosslinked polymer were investigated. The results indicated that under the dynamic condition crosslinking reaction happened in both sand packs, and the weak gels in these two cases became small gel particles after water flooding. The differences were： the dynamic gelation time in the quartz sand pack was longer than that in the glass bead pack. Residual resistance factor （FRR） caused by the weak gel in the quartz sand pack was smaller than that in the glass bead pack. The weak gel became gel particles after being scoured by subsequent flood water. A weak gel with uniform apparent viscosity and sealing characteristics was generated in every part of the glass bead pack, which could not only move deeply into the sand pack but also seal the high capacity channels again when it reached the deep part. The weak gel performed in-depth profile modification in the glass bead pack, while in the quartz sand pack, the weak gel was concentrated with 100 cm from the entrance of the sand pack. When propelled by the subsequent flood water, the weak gel could move towards the deep part of the sand pack but then became tiny gel particles and could not effectively seal the high capacity channels there. The in-depth profile modification of the weak gel was very weak in the quartz sand pack. It was the shear fracture of porous media that mainly affected the properties and weakened the in-depth profile modification of the weak gel.
基金This project is supported by the National Natural Science Foundation of China(Grant Nos.U1560206 and 51975510).
文摘The electromagnetic control roll(ECR)and electromagnetic stick(ES)are the core elements and the main driving parts of roll profile electromagnetic control technology(RPECT).To prolong the service life,it is necessary to treat ECR and ES surfaces.According to the heterogeneous characteristics of surface treatments,the roll profile electromagnetic control characteristics were analyzed for different parameters.An electromagnetic-thermal-force coupled axisymmetric finite element model was built to explore the differences in performance as a result of several treatment strategies,and the model was verified by experimental results measured with a roll profile electromagnetic control experimental platform.This model was used to analyze the influence of the heterogeneity of ECR inner hole and ES on the roll crown,the roll profile,the average contact pressure,and the stress state during RPECT process.The results indicate that the heterogeneous layer at ECR inner hole has a restrictive effect on RPECT and that the heterogeneous layer of ES can enhance the profile control ability of RPECT.A reasonable configuration scheme between the heterogeneity of ECR inner hole and the ES can increase the life of ECR and maintain the control ability of RPECT.
文摘The profile control hard-gel is composed of polyarylamide (5-6g/L), whose molecular weight is 4,000,000 - 7,000,000 and hydrolysis degree is 17.6%, and cross-linking oxidation-reduction agent (Na2Cr2O7 + NH4Cl), with an delayed organic acid crosslinker which contains lactic acid/propionic acid/ethanoic acid and ethylene glycol. After research of the influence factors, such as pH, temperature, salinity and the dosage of delayed crosslinker, the optimum condition(pH 5.2, temperature 55℃, salinity < 7g/L) was found. Gelation time (12-144h) can be controlled by adjusting the dosage of the delayed crosslinker. Deep profile control experiments are carried out on heterogeneous models, which contains three serial high permeable and low permeable cores arranged in a parallel. After water flooding (total recovery, 24.3%), the first, second and third high-permeable cores each are sealed in turn by the profile control agent, and the total displacement recovery increases to 46.8%, 62.2% and 69.1% respectively. So, the greater the sealed depth, the larger the enhancing recovery will be. Finally, the oil displacement mechanisms of deep profile control are discussed.
文摘Heavy oil will play an important role in future resources exploitation.Factors such as reservoir heterogeneity and adverse oil/steam mobility ratio have led to severe steam channeling and fingering,thereby reduced conformance efficiency and affected de-velopment response.Therefore,the research on profile control and water shut-off agents becomes increasingly important for thermal recovery wells.The requirements on the performances of profile control and water shut-off agents are discussed in conjunction with the physical properties of heavy oil reservoirs and the technical conditions of steam injection in China.Based on the mechanism of action,research progress and application status,5 agents are summarized including polymer gel,solid particles plugging agent,foam,water-in-oil emulsion and salt precipitation.Problems in each agent are mentioned,and optimization solutions are put for-ward.At last,the development trend of future profile control and water shut-off agents is put forward,i.e.synthesizing agents of low cost and high-temperature resistance,intensifying mechanism research,developing composite system,and researching on new technologies that are less harmful and environmental friendly.
文摘Most of the mining method of domestic oilfield is waterflood development, thus the water content in the mid and late water flooding would rise faster, and the oil recovery rate would decline relatively more rapid. So it is very important to research profile control agent for stabilizing oil production resin-type profile control agent, and focus on researching the themal stability, shear resistance, gelation time and gelation strength and other properties of this profile control agent?[1]. Finally, the best ratio for synthesizing the high temperature resistant phenolic resin-type profile control agent was obtained.
文摘Facing problems with oil production decreasing quickly and water content increasing gradually in S103 well area, the Foam Profile Control was studied on the basis of its confirmed agent formula. The facies-controlled geological model of S103 well area was generated using random model based on Petrel software and using numerical simulation based on CMG software. Gas liquid alternating injection pattern was optimized as the optimal solution through the simulation optimization. Two months are optimized as the optimal solution through the simulation optimization. The cumulative oil production is 0.933 × 107 kg which is higher than the value of subsequent water flooding and the other three. Finally, it reaches the goals of slowing down the production decline and controlling the water rising.
基金supported by the National Natural Science Foundation of China (No.21273286)Doctoral Program Foundation of the Education Ministry (No.20130133110005)
文摘Polyacrylamide microspheres have been suc- cessfully used to reduce water production in reservoirs, but it is impossible to distinguish polyacrylamide microspheres from polyacrylamide that is used to enhance oil recovery and is already present in production fluids. In order to detect polyacrylamide microspheres in the reservoir pro- duced fluid, fluorescent polyacrylamide microspheres P（AM-BA-AMCO）, which fluoresce under ultraviolet irradiation, were synthesized via an inverse suspension polymerization. In order to keep the particle size distribu- tion in a narrow range, the synthesis conditions of the polymerization were studied, including the stirring speed and the concentrations of initiator, NaaCO3, and dispersant. The bonding characteristics of microspheres were deter- mined by Fourier transform infrared spectroscopy. The surface morphology of these microspheres was observed under ultraviolet irradiation with an inverse fluorescence microscope. A laboratory evaluation test showed that the fluorescent polymer microspheres had good water swelling capability, thus they had the ability to plug and migrate in a sand pack. The plugging rate was 99.8 % and the residual resistance coefficient was 800 after microsphere treatment in the sand pack. Furthermore, the fluorescent microspheres and their fragments were accurately detected under ultra- violet irradiation in the produced fluid, even though theyhad experienced extrusion and deformation in the sand pack.
基金The authors gratefully acknowledge the financial support from the National Science and Technology Major Special Project(2016ZX05058-003).
文摘Due to long-term water injection,often oilfields enter the so-called medium and high water cut stage,and it is difficult to achieve good oil recovery and water reduction through standard methods(single profile control and flooding measures).Therefore,in this study,a novel method based on“plugging,profile control,and flooding”being implemented at the same time is proposed.To assess the performances of this approach,physical simulations,computer tomography,and nuclear magnetic resonance are used.The results show that the combination of a gel plugging agent,a polymer microsphere flooding agent,and a high-efficiency oil displacement agent leads to better results in terms of oil recovery with respect to the situation in which these approaches are used separately(the oil recovery is increased by 15.37%).Computer tomography scan results show that with the combined approach,a larger sweep volume and higher oil washing efficiency are obtained.The remaining oil in the cluster form can be recovered in the middle and low permeability layer,increasing the proportion of the columnar and blind end states of the oil.The nuclear magnetic resonance test results show that the combined“plugging,profile control,and flooding”treatment can also be used to control more effectively the dominant channels of the high permeability layer and further expand the recovery degree of the remaining oil in the pores of different sizes in the middle and low permeability layers.However,for the low permeability layer(permeability difference of 20),the benefits in terms of oil recovery are limited.
基金Supported by the National Natural Science Foundation of China(Grant No.11831011)
文摘In this survey paper we first recall the known results on the exact boundary controllability of nodal profile, then give some suggestions on further studies on this subject.
文摘A large amount of residue from the water treatment process has gradually accumulated and thus caused serious environmental pollution in waterflood oilfields. The water treatment residue is a grey suspension, with a density of 1.08 g/cm^3, and mainly contains over 65% of light CaCO3, MgCO3, CaSO4, Fe2S3 and Ca（OH）2. This paper ascertains the effect of water treatment residue on core permeability and its application in oilfields. Coreflooding tests in laboratory were conducted in two artificial cores and one natural core. Core changes were evaluated by cast model image analysis, mercury injection method and scanning electron microscopy （SEM）. Fresh water was injected into another natural core, which was plugged with water treatment residue, to determine the effective life. The results indicate that the water treatment residue has a strongly plugging capability, a resistance to erosion and a long effective life, and thus it can be used as a cheap raw material for profile control. In the past 8 years, a total of 60,164 m^3 of water treatment residue has been used for profile control of 151 well treatments, with a success ratio of 98% and an effective ratio of 83.2%. In the field tests, the profile control agent increased both starting pressure and injection pressure of injectors, and decreased the apparent water injectivity coefficient, significantly improving intake profiles and lengthening average service life of injectors. 28,381 tons of additional oil were recovered from these corresponding oil wells, with economic benefits of ￥3,069.55×10^4 （RMB） and a remarkable input-output ratio of 8.6：1.
