The intramolecular process of Mg ( Ⅱ ) - , Sc ( Ⅲ ) - , Y ( Ⅲ ) - , In(Ⅲ)-and Pb ( Ⅱ )-trans-1,2-cyclohexanediaminetetraacetic acid (CyDTA) complexes was studied by the method of proton dynamic NMR(DNMR). The top...The intramolecular process of Mg ( Ⅱ ) - , Sc ( Ⅲ ) - , Y ( Ⅲ ) - , In(Ⅲ)-and Pb ( Ⅱ )-trans-1,2-cyclohexanediaminetetraacetic acid (CyDTA) complexes was studied by the method of proton dynamic NMR(DNMR). The top limit of. the experimental temperature range of deuterium oxide solutions was extended from 100℃ to 167 ℃ instead of the previous 100 ℃ by using sealed, thick-walled tubes to observe experimental phenomena further. It was found that another intramolecular process, i. e. B, R (Bonded State, Rotational State) conversion, exists in these complexes formed by polyaminepolycarboxylic ligands in addition to △,A conversion and nitrogen inversion. A quantitative treatment was proposed to estimate the relative populations of acetate groups in B and R states.展开更多
Direct-conversion transceivers are gaining increasing attention due to their low power consumption. However, they suffer from a serious in- and quadrature-phase （I/Q） imbalance problem. The I/Q imbalance can severel...Direct-conversion transceivers are gaining increasing attention due to their low power consumption. However, they suffer from a serious in- and quadrature-phase （I/Q） imbalance problem. The I/Q imbalance can severely limit the achievable operating signal-to-noise ratio （SNR） at the receiver and, consequently, the supported constellation sizes and data rates. In this paper, we first investigate the effects of I/Q imbalance on orthogonal frequency division multiplexing （OFDM） receivers, and then propose a new I/Q imbalance compensation scheme. In the proposed method, a new statistic, which is robust against channel distortion, is used to estimate the I/Q imbalance parameters, and then the I/Q imbalance is corrected in the frequency domain. Simulations are performed to verify the effectiveness of the proposed method for I/Q imbalance compensation. The results show that the proposed I/Q imbalance compensation method can achieve bit error rate （BER） performance close to that in the ideal case without I/Q imbalance in additive white Gaussian noise （AWGN） or multipath environments. Furthermore, because no pilot information is required, this method can be applied in various standard communication systems.展开更多
基金Supported by the National Natural Science Foundation of China
文摘The intramolecular process of Mg ( Ⅱ ) - , Sc ( Ⅲ ) - , Y ( Ⅲ ) - , In(Ⅲ)-and Pb ( Ⅱ )-trans-1,2-cyclohexanediaminetetraacetic acid (CyDTA) complexes was studied by the method of proton dynamic NMR(DNMR). The top limit of. the experimental temperature range of deuterium oxide solutions was extended from 100℃ to 167 ℃ instead of the previous 100 ℃ by using sealed, thick-walled tubes to observe experimental phenomena further. It was found that another intramolecular process, i. e. B, R (Bonded State, Rotational State) conversion, exists in these complexes formed by polyaminepolycarboxylic ligands in addition to △,A conversion and nitrogen inversion. A quantitative treatment was proposed to estimate the relative populations of acetate groups in B and R states.
基金Project supported by the National Natural Science Foundation of China(No.61601477)
文摘Direct-conversion transceivers are gaining increasing attention due to their low power consumption. However, they suffer from a serious in- and quadrature-phase （I/Q） imbalance problem. The I/Q imbalance can severely limit the achievable operating signal-to-noise ratio （SNR） at the receiver and, consequently, the supported constellation sizes and data rates. In this paper, we first investigate the effects of I/Q imbalance on orthogonal frequency division multiplexing （OFDM） receivers, and then propose a new I/Q imbalance compensation scheme. In the proposed method, a new statistic, which is robust against channel distortion, is used to estimate the I/Q imbalance parameters, and then the I/Q imbalance is corrected in the frequency domain. Simulations are performed to verify the effectiveness of the proposed method for I/Q imbalance compensation. The results show that the proposed I/Q imbalance compensation method can achieve bit error rate （BER） performance close to that in the ideal case without I/Q imbalance in additive white Gaussian noise （AWGN） or multipath environments. Furthermore, because no pilot information is required, this method can be applied in various standard communication systems.
