This paper describes the geographical distribution, utilization, cultural value and ex-situ conservation of bamboo resources in Xishuangbanna, Yunan Province, China. Sixty species of bamboo in 19 genera are recorded i...This paper describes the geographical distribution, utilization, cultural value and ex-situ conservation of bamboo resources in Xishuangbanna, Yunan Province, China. Sixty species of bamboo in 19 genera are recorded in Xishuangbanna. The area of natural bamboo forest is 14319 ha, accounting for 5.92% of whole area of Xishuangbanna. The abundant resource of bamboo plays an important role in the economics and culture of national minorities in Xishuangbanna. Xishuangbanna Tropic Botanic Garden, Chinese Academy of Sciences （CAS）, started to introduce bamboo species in 1961 and established the ex-situ conservation reserve （8 ha） of bamboo in 1981. Up to now, 211 species in 27 genera collected from tropic and sub-tropic of China and South-east Asia have been planted in the bamboo reserve, of which 11 species have bloomed and seeded, and their seeds were cultivated in Xishuangbanna Tropical Botanic Gardens, CAS, China.展开更多
This paper reviewed a large scale conservation work of rare and endangered plants currently conducted in main botanical gardens in China, and the existed, predictable and neglected problems on plant growth and reprodu...This paper reviewed a large scale conservation work of rare and endangered plants currently conducted in main botanical gardens in China, and the existed, predictable and neglected problems on plant growth and reproduction in ex-situ conservation process. Considered the status quo in plant ex conservation, a nutritional strategy on the plant conservation was proposed based on ＇Ecological Similarity＇. Its main idea was that the ex-situ conservation plants coming from natural ecosystem were compulsively allocated in the agro-ecosystems and would return to natural ecosystem ultimately. Therefore, research on plant nutrition of the ex-situ conservation plants should neither just pursue yield and quality as that in agro-ecosystems nor merely stay on intrinsic natures without human intervening. We should give attentions to both of their attributes as in natural ecosystems and in agro-ecosystems, i.e., taking full advantage of plant nutritional measures as in agro-ecosystems to solve actual survival problems of the ex-conservation plants, and ensuring the final goal of returning to nature and playing its ecological role.展开更多
Aconitum heterophyllum Wall.ex Royle,an endangered Ayurvedic medicinal plant,is predominantly found in the alpine and subalpine zones of the Himalayas.This study aimed to enhance seed germination under various soil co...Aconitum heterophyllum Wall.ex Royle,an endangered Ayurvedic medicinal plant,is predominantly found in the alpine and subalpine zones of the Himalayas.This study aimed to enhance seed germination under various soil conditions,to facilitate conservation and provide opportunities for income generation through large-scale cultivation.The selection of soil treatments was based on their contrasting physicochemical properties and known influence on seed germination in related high altitude species.The study was conducted in a mist chamber at the Deoban nursery in Dehradun,India,using five soil conditions:normal forest soil(NS),vermiculite(Vc),vermiculite+normal forest soil(Vc+NS),normal forest soil+sand(NS+S),and a mixture of soil,sand,vermiculite,and vermicompost(NS+S+Vc+VCo).All the soil treatments were replicated ten times under the controlled environmental conditions.These substrates were selected to represent a gradient of water retention,aeration,nutrient content,and organic matter composition,which are known to affect seed germination and early seedling development.Results showed significant different among treatments in terms of physical and chemical soil properties in sand,silt,clay,pH,organic carbon,organic matter,total nitrogen,total phosphorus,as well as growth parameters such as,seed vigor index,root length,plant length,and leaf number across soil conditions.Among all treatments,vermiculite alone showed the highest germination rate(73.33%),peak germination value(0.719),and seed vigor index(24.02),along with superior growth parameters and the lowest seed mortality index(2.45).These findings in addition to its low seed mortality underscore vermiculite's potential as a suitable growth medium for the ex-situ cultivation of A.heterophyllum offering a promising alternative to wild harvesting while supporting conservation and sustainable use of this valuable Himalayan species.展开更多
This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the L...This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the Life Cycle Assessment(LCA)methodology.The treatments are either in-situ or exsitu,the latter requiring an initial dredging to transport the contaminated sediments to the management site.More in detail,four ex-situ remediation technologies based on landfilling,bioremediation,electrokinetic technique and soil washing were identified.These technologies are compared to an in-situ strategy currently under validation for enhancing bioremediation of the polluted sediments of the Bagnoli-Coroglio site.Our results indicate that the disposal in landfilling site is the worst option in most categories(e.g.,650 kg CO_(2) eq./t of treated sediment,considering the nearest landfilling site),followed by the bioremediation,mainly due to the high energy demand.Electrokinetic remediation,soil washing,and innovative in-situ technology represent the most sustainable options.In particular,the new in-situ technology appears to be the least impacting in all categories(e.g.,54 kg CO_(2) eq./t of treated sediment),although it is expected to require longer treatment time(estimated up to 12 months based on its potential efficiency).It can reduce the impact on climate change more than 12 times compared to the disposal and 7 times compared to bioremediation in addition to the possibility to avoid/reduce the dredging operations and the consequent dispersion of pollutants.The results open relevant perspectives towards more eco-sustainable and costly effective actions for the reclamation of contaminated marine sediments.展开更多
AIM:To evaluate the results of hepatic resection with ex-situ hypothermic perfusion and without veno-venous bypass.METHODS:In 3 patients with liver tumor,the degree of the inferior vena cava and/or main hepatic vein i...AIM:To evaluate the results of hepatic resection with ex-situ hypothermic perfusion and without veno-venous bypass.METHODS:In 3 patients with liver tumor,the degree of the inferior vena cava and/or main hepatic vein involvement was verified when the liver was dissociated in the operation.It was impossible to resect the tumors by the routine hepatectomy,so the patients underwent ex-situ liver surgery,vein cava replacement and hepatic autotransplantation without veno-venous bypass.All surgical procedures were carried out or supervised by a senior surgeon.A retrospective analysis was performed for the prospectively collected data from patients with liver tumor undergoing ex-situ liver surgery,vein cava replacement and hepatic autotransplantation without veno-venous bypass.We also compared our data with the 9 cases of Pichlmayr's group.RESULTS:Three patients with liver tumor were analysed.The first case was a 60-year-old female with a huge haemangioma located in S1,S4,S5,S6,S7 and S8 of liver;the second was a 64-year-old man with cholangiocarcinoma in S1,S2,S3 and S4 and the third one was a 55-year-old man with a huge cholangiocarcinoma in S1,S5,S7 and S8.The operation time for the three patients were 6.6,6.4 and 7.3 h,respectively.The anhepatic phases were 3.8,2.8 and 4.0 h.The volume of blood loss during operation were 1200,3100,2000 mL in the three patients,respectively.The survival periods without recurrence were 22 and 17 mo in the first two cases.As for the third case complicated with postoperative hepatic vein outflow obstruction,emergency hepatic vein outflow extending operation and assistant living donor liver transplantation were performed the next day,and finally died of liver and renal failure on the third day.Operation time(6.7 ± 0.47 h vs 13.7 ± 2.6 h) and anhepatic phase(3.5 ± 0.64 h vs 5.7 ± 1.7 h) were compared between Pichlmayr's group and our series(P = 0.78).CONCLUSION:Ex-situ liver resection and liver autotransplantation has shown a potential for treatment of complicated hepatic neoplasms that are unresectable by traditional procedures.展开更多
The 2018 Joint International Congress of ILTS,ELITA and LICAGE were held in Lisbon,Portugal on May 23–26,2018.The exciting and innovative program brought together 1144 experts in liver transplantation(LT)such as surg...The 2018 Joint International Congress of ILTS,ELITA and LICAGE were held in Lisbon,Portugal on May 23–26,2018.The exciting and innovative program brought together 1144 experts in liver transplantation(LT)such as surgeons,physicians or basic scientists from 61 countries.The presentations included 110 invited speakers,181 oral presentations,and 545 posters.This editorial highlights some of the most innovative and impactful presentations in展开更多
Conservation programs require rigorous evaluation to ensure the preservation of genetic diversity and viability of conservation populations. In this study, we conducted a comparative analysis of two indigenous Chinese...Conservation programs require rigorous evaluation to ensure the preservation of genetic diversity and viability of conservation populations. In this study, we conducted a comparative analysis of two indigenous Chinese chicken breeds, Gushi and Xichuan black-bone, using whole-genome SNPs to understand their genetic diversity, track changes over time and population structure. The breeds were divided into five conservation populations(GS1, 2010, ex-situ;GS2, 2019, ex-situ;GS3, 2019, in-situ;XB1, 2010, in-situ;and XB2, 2019, in-situ) based on conservation methods and generations. The genetic diversity indices of three conservation populations of Gushi chicken showed consistent trends, with the GS3 population under in-situ strategy having the highest diversity and GS2 under ex-situ strategy having the lowest. The degree of inbreeding of GS2 was higher than that of GS1 and GS3. Conserved populations of Xichuan black-bone chicken showed no obvious changes in genetic diversity between XB1 and XB2. In terms of population structure, the GS3 population were stratified relative to GS1 and GS2. According to the conservation priority, GS3 had the highest contribution to the total gene and allelic diversity in GS breed, whereas the contribution of XB1 and XB2 were similar. We also observed that the genetic diversity of GS2 was lower than GS3, which were from the same generation but under different conservation programs(in-situ and ex-situ). While XB1 and XB2 had similar levels of genetic diversity. Overall, our findings suggested that the conservation programs performed in ex-situ could slow down the occurrence of inbreeding events, but could not entirely prevent the loss of genetic diversity when the conserved population size was small, while in-situ conservation populations with large population size could maintain a relative high level of genetic diversity.展开更多
High-performance bismaleimdes (BMI) matrix composites reinforced by graphite fibers were prepared and toughened with a thermoplastic component (PAEK) by using the Ex-situ concept. Experimental matrix was designed for ...High-performance bismaleimdes (BMI) matrix composites reinforced by graphite fibers were prepared and toughened with a thermoplastic component (PAEK) by using the Ex-situ concept. Experimental matrix was designed for overall toughening of the base resin, periodically interleaving thermoplastic films into each plies (Ex-situ concept) and for varying the film compositions. The highest impact damage resistance characterized by compression after impact (CAI) was obtained for the laminates toughened on the Ex-situ concept, especially, when two-component cast films of a special ration of PAEK/BMI 60∶40 were interleaved though the thermoplastic concentration for the overall toughening, interleaving the pure thermoplastic films and the two-component films was comparable. There were two peaks found in the DSC trace of the laminates toughened implying a phase separation process occurred. The glass transition temperature of the laminates toughened was slightly reduced due to the low-temperature PAEK. Morphological study revealed a typical granular structure just in the interplay region as a result of spinodal decomposition and coarsening process. This was in agreement of the result of DSC investigation.展开更多
The present work concerns with ex-situ Conservation issues study of the three economical species Cyclamen vernum Sweet is a synonym of Cyclamen coum subsp.caucasicum(K.Koch)O.Schwarz(Primulaceae)Helleborus caucasicus ...The present work concerns with ex-situ Conservation issues study of the three economical species Cyclamen vernum Sweet is a synonym of Cyclamen coum subsp.caucasicum(K.Koch)O.Schwarz(Primulaceae)Helleborus caucasicus A.Braun(Ranuculaceae)and Paeonia caucasica Schipcz)Schipcz.Is synonym of Paeonia dauricasubsp.Coriifolia(Rupr.)D.Y.Hong distribution in Georgia.These species are under strong anthropogenic stress,Its populations are collected in nature as a decorative and traditional medicinal properties.It is of urgent necessity to take conservation measures for these species through both ex-situ and in-situ protection methods.For this purpose it is of critical importance to collect data on the distribution of the above species and vitality and fertility of their populations.Processes of seed production and seed multiplication have been studied.The ex-situ base of the seed and live collection bank was created.The work is done in Great Britain within the framework of the“Millennium”Seed Bank Partnership of Kew Botanical Garden.The seeds are placed in the National Seed Bank,duplicates together with Herbarium sample are sent in the millennium seed bank.The live collection obtained from seeds is placed on the collection plot of Plant Conservation Department of the National Botanical Garden of Georgia.展开更多
Composites were prepared with polysulfone through ex-situ toughening technique. The dynamic parameters of cyanate/epoxy resin were studied by differential scanning calorimetric（DSC） analysis and dynamic mechanical a...Composites were prepared with polysulfone through ex-situ toughening technique. The dynamic parameters of cyanate/epoxy resin were studied by differential scanning calorimetric（DSC） analysis and dynamic mechanical analysis（DMA）. Microstructual toughening mechanism was studied through scanning electron microscopy（SEM）. The particle microstructure in interlaminar region of composites toughened through ex-situ toughening technique revealed that a reaction induced phase decomposition and phase inversion happened in the interlaminar region. The thermosetting particles were surrounded by the PS phase, which could signifi cantly improve the delamination resistance of composites. The compression after impact（CAI） can be signifi cantly improved from 180 MPa to 260 MPa by using ex-situ toughening while the mechanical properties are not affected.展开更多
Solid-state battery(SSB)with lithium metal anode(LMA)is considered as one of the most promising storage devices for the next generation.To simultaneously address two critical issues in lithium metal batteries:the nega...Solid-state battery(SSB)with lithium metal anode(LMA)is considered as one of the most promising storage devices for the next generation.To simultaneously address two critical issues in lithium metal batteries:the negative impact of interfacial compatibility on the electrochemical performance and the safety risks associated with Li dendrite growth-we propose a dual in-situ strategy for fabricating SSBs.Herein,the excellent cycling performance and improved safety of polymer SSB under dual in-situ strategy was confirmed.The lower Li nucleation barrier of Sn leads to uniform Li deposition on the modified-Li(ModLi)/solid-state electrolyte(SSE)interface.LiF-enriched layer on LMA contributes to capacity retention of 92%after 550 cycles in LiFePO_(4)SSB.The modified layer provides outstanding dendrite suppression ability under an overcharge condition of 5.5 V.The higher thermal stability of SSE than liquid electrolyte was investigated through in-situ heat and gas generation analysis,with ModLi+SSE generating only 9.9%of Li+SSE.Higher cycling stability of SSB was demonstrated through in-situ cycling heat generation analysis,and lower temperature sensitivity of SSB with 31%of heat production decrease from 30 to 70℃,while LIBs show a 54%reduction.Excellent high-temperature stability was proved by a 92%capacity retention at 60℃after 50 cycles.Ultimately,pouch cells with SSE of higher thermal stability and modifications on LMA achieved a higher self-heating onset temperature(Tonset)of 180℃and a lower thermal runaway maximum temperature(T_(max))of 401℃,The impacts of dual in-situ strategy for materials,interfaces,coin cells and pouch cells aid in further understanding on thermal runaway mechanism of SSB.展开更多
Extracorporeal liver surgery(ELS), also known as liver autotransplantation, is a hybrid(cross-fertilized) surgery incorporating the technical knowledge from extreme liver and transplant liver surgeries, and recently b...Extracorporeal liver surgery(ELS), also known as liver autotransplantation, is a hybrid(cross-fertilized) surgery incorporating the technical knowledge from extreme liver and transplant liver surgeries, and recently became more embraced and popularized among leading centers. ELS could be summarized into three major categories, namely, ex-situ liver resection and autotransplantation(ELRA), ante-situm liver resection and autotransplantation(ALRA) and auxiliary partial liver autotransplantation(APLA). The successful development of ELS during the past 37 years is definitely inseparable from continuous effort s done by Chinese surgeons and researchers. Especially, the precision liver surgery paradigm has allowed to transform ELS into a modularized, more simplified, and standardized surgery, to upgrade surgical skills, to improve peri-operative outcome and long-term survival, to increase the capability of surgeons to select more complex diseases and to expand the level of medical service to the population. This review highlights the Chinese contributions to the field of ELS, focusing thereby on features of different surgical types, technical innovations, disease selection and surgical indication, patient prognosis and future perspectives.展开更多
This study compares the crude oil removal efficiency of free and biosurfactant-producing bacterial consortia(Bacillus tequilensis NR_104919 and Bacillus axarquiensis NR_115929)entrapped in chitosan(CH),chitosan/glutar...This study compares the crude oil removal efficiency of free and biosurfactant-producing bacterial consortia(Bacillus tequilensis NR_104919 and Bacillus axarquiensis NR_115929)entrapped in chitosan(CH),chitosan/glutaraldehyde(CH/GA),and chitosan/Na-bentonite(CH/BNT)matrices.Additionally,the mechanical and thermal stability,swelling capacity,surface morphology,and chemical bonding of these composites were evaluated.Initially,the biosurfactant produced by the consortium was identified using screening methods,and its lipopeptide structure was confirmed through TLC and 1H NMR analyses,with a yield of 0.2 g/L.Following characterization,the biosurfactant-producing bacterial consortium was immobilized onto CH,CH/GA,and CH/BNT beads for further assessment.When comparing the oil removal capacities of the composites,the consortium immobilized in the CH/BNT matrix exhibited significantly higher crude oil removal efficiency than those entrapped in CH,CH/GA,and the free consortium.The maximum oil removal by the CH/BNT-entrapped consortium was achieved under optimized conditions:0.5 mL crude oil,0.1 g Na-bentonite,pH=6.0,at 35℃,over a 7-day incubation period.However,a decline in oil remediation performance was observed from the fourth reuse cycle onward.These laboratory-scale findings were further validated through ex-situ simulation and long-term experiments,confirming the potential of the CH/BNT composite for effective and sustainable petroleum pollutant remediation.The swelling capacity of inactivated CH was comparable to that of the CH/BNT composite,with both exhibiting greater swelling than CH/GA beads.Additionally,CH/BNT beads demonstrated superior mechanical stability relative to CH and CH/GA,which showed similar stability profiles.Thermal stability,surface morphology,and chemical bonding of the CH,CH/GA,and CH/BNT composites were characterized using TGA,FT-IR,and SEM analyses.CH/BNT composite represents an effective,economical,and environmentally benign alternative to costly synthetic materials for the remediation of oil pollution in aquatic environments.This study highlights the potential of chitosan/Na-bentonite-based composites as sustainable solutions for petroleum pollutant removal,while recommending pilot-scale investigations to assess their feasibility and performance under real-world conditions.展开更多
The Yangtze finless porpoise(Neophocaena asiaeorientalis asiaeorientalis)is distributed in the main stream of the middle and lower reaches of the Yangtze River,as well as in Dongting and Poyang lakes.Currently,the mos...The Yangtze finless porpoise(Neophocaena asiaeorientalis asiaeorientalis)is distributed in the main stream of the middle and lower reaches of the Yangtze River,as well as in Dongting and Poyang lakes.Currently,the most crucial conservation approach involves the establishment and management of both in-situ and ex-situ nature reserves.Since the 1990s,seven nature reserves have been established in the middle and lower reaches of the Yangtze River,covering nearly one-third of its main stream.Additionally,two nature reserves,one in the Dongting Lake and another in the Poyang Lake,have been set up;and three ex-situ nature reserves have been established in three oxbows respectively in Hunan,Hubei,and Anhui provinces.Through measures such as improving the ecological environment quality within the reserves,regulating human activities,and conducting continuous monitoring,the finless porpoise population showed a slight increase in 2022 for the first time.The ex-situ population has continued to grow,with four individuals being released back into the main stream of the Yangtze River after undergoing reintroduction training in 2023.Based on the population development lasting for over three decades,and predictions of future ecological changes,orderly establishment and scientific management of nature reserves have played a key role in and will remain an important basis for the sustaining growth of the finless porpoise population.展开更多
The microstructure property relationships have been studied in terms of glass transition behavior,phase morphology,and fracture toughness on thermoplastic polyetherketone with a phenolphthalein side group (PAEK) tough...The microstructure property relationships have been studied in terms of glass transition behavior,phase morphology,and fracture toughness on thermoplastic polyetherketone with a phenolphthalein side group (PAEK) toughened bismaleimdes (BMI) resins,and in terms of interlaminar morphology and compression after impact (CAI) on the graphite fiber (T700SC),the rein-forced BMI matrix composites that are toughened with a so-called ex-situ concept,respectively. The characteristic morphology spectrum has been found ...展开更多
Transition metal nitrides(TMN)have recently grabbed immensely appealing as ideal active materials in energy storage and catalysis fields on account of their remarkable electrical conductivity,excellent chemical stabil...Transition metal nitrides(TMN)have recently grabbed immensely appealing as ideal active materials in energy storage and catalysis fields on account of their remarkable electrical conductivity,excellent chemical stability,wide band gap and tunable morphology.Both pure TMN and TMN-based materials have been extensively studied concerned with their preparation approaches,nanostructures,and favored performance in various applications.However,the processes towards synthesis of TMN are numerous and complex.Choosing appropriate method to obtain target TMN with desired structure is crucial,which further affects its practical application performance.Herein,this review offers a timely and comprehensive summary of the synthetic ways to TMN and their application in energy related domains.The synthesis section is categorized into in-situ and ex-situ based on where the N element in TMN origins from.Then,overviews on the energy related applications including energy storage,electrocatalysis and photocatalysis are discussed.In the end,the problems to be solved and the development trend of the synthesis and application of transition metal nitrides are prospected.展开更多
Problems associated with organochlorine pesticide （OCP）-contaminated sites in China have received wide attention. To solve such problems, innovative ex-situ methods of site remediation are urgently needed. We invest...Problems associated with organochlorine pesticide （OCP）-contaminated sites in China have received wide attention. To solve such problems, innovative ex-situ methods of site remediation are urgently needed. We investigated the feasibility of the extraction method with different organic solvents, ethanol, 1-propanol, and three fractions of petroleum ether, using a soil collected from Wujiang （W J）, China, a region with long-term contamination of dichlorodiphenyltrichloroethanes （DDTs）. We evaluated different influential factors, including organic solvent concentration, washing time, mixing speed, solutiomto-soil ratio, and washing temperature, on the removal of DDTs from the WJ soil. A set of relatively better parameters were selected for extraction with 100 mL L-1 petroleum ether （60-90 ℃）： washing time of 180 min, mixing speed of 100 r min-I, solution-to-soil ratio of 10：1, and washing temperature of 50 ℃. These selected parameters were also applied on three other seriously OCP-polluted soils. Results demonstrated their broad-spectrum effectiveness and excellent OCP extraction performance on the contaminated soils with different characteristics.展开更多
Sustainable transformation and efficient utilization of biomasses and their derived materials are environ-mentally as well as economically compliant strategies.Biomass seaweed-derived nitrogen self-doped porous carbon...Sustainable transformation and efficient utilization of biomasses and their derived materials are environ-mentally as well as economically compliant strategies.Biomass seaweed-derived nitrogen self-doped porous carbon with tailored surface area and pore structures are prepared through carb on izatio n and activation.The in fluence of carb on ization temperature on morphology,surface area,and heteroatom dopants are investigated to optimize sodium-ion storage capability.Seaweed-derived nitrogen selfdoped activated carbon(SAC)as anode materials for sodium-ion batteries exhibits remarkable reversible capacity of 303/192 mAh g^(-1) after 100/500 cycles at current densities of 100/200 mA g^(-1) respectively,and a good rate capability.The interconnected and porous conducting nature along with the heteroatom dopant role in creating defective sites and charge stabilization are favorable for ion storage and diffusion and electron transport,indicating the electrodes can offer improved electrochemical performances.In addition,post-mortem analysis of the cycled carbon electrodes through ex-situ tools demonstrates the sodium-ion storage mechanism.展开更多
Metal selenides owing to their high theoretical capacity and good conductivity are considered as one of the potential candidates for the anode materials of sodium-ion batteries(SIBs).However,their practical applicatio...Metal selenides owing to their high theoretical capacity and good conductivity are considered as one of the potential candidates for the anode materials of sodium-ion batteries(SIBs).However,their practical applications are greatly restricted by the poor cycling performances and complicated synthesis methods.In this work,a sandwich-like Sn Se2/reduced graphene oxide(r GO)composite with a small amount of r GO(7.3%)is synthesized by a simple one-pot solvothermal technique.The as-synthesized Sn Se2/r GO shows improved initial coulombic efficiency(ICE)of 73.7%,high capacity of 402.0 m Ah g-1 after 150 cycles at 0.1 A g-1 with a retention of 86.2%and outstanding rate performances.The abundant Sn-O-C bonds of synthesized material not only accelerate the charge transfer at the interface but also enhance the mechanical strength to accommodate volume variation and prevent active material loss during cycling.Moreover,the compact structure leads to thin solid electrolyte interface(SEI)so that high initial coulombic efficiency was obtained.Furthermore,full cells are assembled to test its potential application.This work offers a simple method to synthesize Sn Se2/r GO as a candidate anode for SIBs.展开更多
基金The Ministry of Science and Technology of the People’s Republic of China (2004DKA30400-05-01-02)
文摘This paper describes the geographical distribution, utilization, cultural value and ex-situ conservation of bamboo resources in Xishuangbanna, Yunan Province, China. Sixty species of bamboo in 19 genera are recorded in Xishuangbanna. The area of natural bamboo forest is 14319 ha, accounting for 5.92% of whole area of Xishuangbanna. The abundant resource of bamboo plays an important role in the economics and culture of national minorities in Xishuangbanna. Xishuangbanna Tropic Botanic Garden, Chinese Academy of Sciences （CAS）, started to introduce bamboo species in 1961 and established the ex-situ conservation reserve （8 ha） of bamboo in 1981. Up to now, 211 species in 27 genera collected from tropic and sub-tropic of China and South-east Asia have been planted in the bamboo reserve, of which 11 species have bloomed and seeded, and their seeds were cultivated in Xishuangbanna Tropical Botanic Gardens, CAS, China.
基金supported by National Key Technology R & D Program,China (2008BADA4B08,2007BAD87B09)the International Plant Nutrition Institute (IPNI-Hubei 200501).
文摘This paper reviewed a large scale conservation work of rare and endangered plants currently conducted in main botanical gardens in China, and the existed, predictable and neglected problems on plant growth and reproduction in ex-situ conservation process. Considered the status quo in plant ex conservation, a nutritional strategy on the plant conservation was proposed based on ＇Ecological Similarity＇. Its main idea was that the ex-situ conservation plants coming from natural ecosystem were compulsively allocated in the agro-ecosystems and would return to natural ecosystem ultimately. Therefore, research on plant nutrition of the ex-situ conservation plants should neither just pursue yield and quality as that in agro-ecosystems nor merely stay on intrinsic natures without human intervening. We should give attentions to both of their attributes as in natural ecosystems and in agro-ecosystems, i.e., taking full advantage of plant nutritional measures as in agro-ecosystems to solve actual survival problems of the ex-conservation plants, and ensuring the final goal of returning to nature and playing its ecological role.
文摘Aconitum heterophyllum Wall.ex Royle,an endangered Ayurvedic medicinal plant,is predominantly found in the alpine and subalpine zones of the Himalayas.This study aimed to enhance seed germination under various soil conditions,to facilitate conservation and provide opportunities for income generation through large-scale cultivation.The selection of soil treatments was based on their contrasting physicochemical properties and known influence on seed germination in related high altitude species.The study was conducted in a mist chamber at the Deoban nursery in Dehradun,India,using five soil conditions:normal forest soil(NS),vermiculite(Vc),vermiculite+normal forest soil(Vc+NS),normal forest soil+sand(NS+S),and a mixture of soil,sand,vermiculite,and vermicompost(NS+S+Vc+VCo).All the soil treatments were replicated ten times under the controlled environmental conditions.These substrates were selected to represent a gradient of water retention,aeration,nutrient content,and organic matter composition,which are known to affect seed germination and early seedling development.Results showed significant different among treatments in terms of physical and chemical soil properties in sand,silt,clay,pH,organic carbon,organic matter,total nitrogen,total phosphorus,as well as growth parameters such as,seed vigor index,root length,plant length,and leaf number across soil conditions.Among all treatments,vermiculite alone showed the highest germination rate(73.33%),peak germination value(0.719),and seed vigor index(24.02),along with superior growth parameters and the lowest seed mortality index(2.45).These findings in addition to its low seed mortality underscore vermiculite's potential as a suitable growth medium for the ex-situ cultivation of A.heterophyllum offering a promising alternative to wild harvesting while supporting conservation and sustainable use of this valuable Himalayan species.
基金support in the literature analysis.This study has been carried out in the framework of the project funded by EU entitled“Bioremediation of contaminated sediments in coastal areas of exindustrial sites-LIFE SEDREMED”(No.LIFE20 ENV/IT/000572).
文摘This study compares the environmental sustainability of five alternatives for the remediation of marine sediments of one of the most polluted coastal sites in Europe(Bagnoli-Coroglio bay,Mediterranean Sea),using the Life Cycle Assessment(LCA)methodology.The treatments are either in-situ or exsitu,the latter requiring an initial dredging to transport the contaminated sediments to the management site.More in detail,four ex-situ remediation technologies based on landfilling,bioremediation,electrokinetic technique and soil washing were identified.These technologies are compared to an in-situ strategy currently under validation for enhancing bioremediation of the polluted sediments of the Bagnoli-Coroglio site.Our results indicate that the disposal in landfilling site is the worst option in most categories(e.g.,650 kg CO_(2) eq./t of treated sediment,considering the nearest landfilling site),followed by the bioremediation,mainly due to the high energy demand.Electrokinetic remediation,soil washing,and innovative in-situ technology represent the most sustainable options.In particular,the new in-situ technology appears to be the least impacting in all categories(e.g.,54 kg CO_(2) eq./t of treated sediment),although it is expected to require longer treatment time(estimated up to 12 months based on its potential efficiency).It can reduce the impact on climate change more than 12 times compared to the disposal and 7 times compared to bioremediation in addition to the possibility to avoid/reduce the dredging operations and the consequent dispersion of pollutants.The results open relevant perspectives towards more eco-sustainable and costly effective actions for the reclamation of contaminated marine sediments.
文摘AIM:To evaluate the results of hepatic resection with ex-situ hypothermic perfusion and without veno-venous bypass.METHODS:In 3 patients with liver tumor,the degree of the inferior vena cava and/or main hepatic vein involvement was verified when the liver was dissociated in the operation.It was impossible to resect the tumors by the routine hepatectomy,so the patients underwent ex-situ liver surgery,vein cava replacement and hepatic autotransplantation without veno-venous bypass.All surgical procedures were carried out or supervised by a senior surgeon.A retrospective analysis was performed for the prospectively collected data from patients with liver tumor undergoing ex-situ liver surgery,vein cava replacement and hepatic autotransplantation without veno-venous bypass.We also compared our data with the 9 cases of Pichlmayr's group.RESULTS:Three patients with liver tumor were analysed.The first case was a 60-year-old female with a huge haemangioma located in S1,S4,S5,S6,S7 and S8 of liver;the second was a 64-year-old man with cholangiocarcinoma in S1,S2,S3 and S4 and the third one was a 55-year-old man with a huge cholangiocarcinoma in S1,S5,S7 and S8.The operation time for the three patients were 6.6,6.4 and 7.3 h,respectively.The anhepatic phases were 3.8,2.8 and 4.0 h.The volume of blood loss during operation were 1200,3100,2000 mL in the three patients,respectively.The survival periods without recurrence were 22 and 17 mo in the first two cases.As for the third case complicated with postoperative hepatic vein outflow obstruction,emergency hepatic vein outflow extending operation and assistant living donor liver transplantation were performed the next day,and finally died of liver and renal failure on the third day.Operation time(6.7 ± 0.47 h vs 13.7 ± 2.6 h) and anhepatic phase(3.5 ± 0.64 h vs 5.7 ± 1.7 h) were compared between Pichlmayr's group and our series(P = 0.78).CONCLUSION:Ex-situ liver resection and liver autotransplantation has shown a potential for treatment of complicated hepatic neoplasms that are unresectable by traditional procedures.
基金supported by grants from China Postdoctoral Science Foundation(2017M610374)National Natural Science Foundation of China(81470891)+2 种基金Science and Technology Bureau of Zhejiang Province,China(2016C33145)Innovative Research Groups of the National Natural Science Foundation of China(81421062)the Fundamental Research Funds for the Central Universities(2018FZA7003)
文摘The 2018 Joint International Congress of ILTS,ELITA and LICAGE were held in Lisbon,Portugal on May 23–26,2018.The exciting and innovative program brought together 1144 experts in liver transplantation(LT)such as surgeons,physicians or basic scientists from 61 countries.The presentations included 110 invited speakers,181 oral presentations,and 545 posters.This editorial highlights some of the most innovative and impactful presentations in
基金supported by the Key Research Project of the Shennong Laboratory,Henan Province,China(SN012022-05)the National Natural Science Foundation of China(32272866)+1 种基金the Young Elite Scientists Sponsorship Program by CAST(2021QNRC001)the Starting Foundation for Outstanding Young Scientists of Henan Agricultural University,China(30500664&30501280)。
文摘Conservation programs require rigorous evaluation to ensure the preservation of genetic diversity and viability of conservation populations. In this study, we conducted a comparative analysis of two indigenous Chinese chicken breeds, Gushi and Xichuan black-bone, using whole-genome SNPs to understand their genetic diversity, track changes over time and population structure. The breeds were divided into five conservation populations(GS1, 2010, ex-situ;GS2, 2019, ex-situ;GS3, 2019, in-situ;XB1, 2010, in-situ;and XB2, 2019, in-situ) based on conservation methods and generations. The genetic diversity indices of three conservation populations of Gushi chicken showed consistent trends, with the GS3 population under in-situ strategy having the highest diversity and GS2 under ex-situ strategy having the lowest. The degree of inbreeding of GS2 was higher than that of GS1 and GS3. Conserved populations of Xichuan black-bone chicken showed no obvious changes in genetic diversity between XB1 and XB2. In terms of population structure, the GS3 population were stratified relative to GS1 and GS2. According to the conservation priority, GS3 had the highest contribution to the total gene and allelic diversity in GS breed, whereas the contribution of XB1 and XB2 were similar. We also observed that the genetic diversity of GS2 was lower than GS3, which were from the same generation but under different conservation programs(in-situ and ex-situ). While XB1 and XB2 had similar levels of genetic diversity. Overall, our findings suggested that the conservation programs performed in ex-situ could slow down the occurrence of inbreeding events, but could not entirely prevent the loss of genetic diversity when the conserved population size was small, while in-situ conservation populations with large population size could maintain a relative high level of genetic diversity.
文摘High-performance bismaleimdes (BMI) matrix composites reinforced by graphite fibers were prepared and toughened with a thermoplastic component (PAEK) by using the Ex-situ concept. Experimental matrix was designed for overall toughening of the base resin, periodically interleaving thermoplastic films into each plies (Ex-situ concept) and for varying the film compositions. The highest impact damage resistance characterized by compression after impact (CAI) was obtained for the laminates toughened on the Ex-situ concept, especially, when two-component cast films of a special ration of PAEK/BMI 60∶40 were interleaved though the thermoplastic concentration for the overall toughening, interleaving the pure thermoplastic films and the two-component films was comparable. There were two peaks found in the DSC trace of the laminates toughened implying a phase separation process occurred. The glass transition temperature of the laminates toughened was slightly reduced due to the low-temperature PAEK. Morphological study revealed a typical granular structure just in the interplay region as a result of spinodal decomposition and coarsening process. This was in agreement of the result of DSC investigation.
文摘The present work concerns with ex-situ Conservation issues study of the three economical species Cyclamen vernum Sweet is a synonym of Cyclamen coum subsp.caucasicum(K.Koch)O.Schwarz(Primulaceae)Helleborus caucasicus A.Braun(Ranuculaceae)and Paeonia caucasica Schipcz)Schipcz.Is synonym of Paeonia dauricasubsp.Coriifolia(Rupr.)D.Y.Hong distribution in Georgia.These species are under strong anthropogenic stress,Its populations are collected in nature as a decorative and traditional medicinal properties.It is of urgent necessity to take conservation measures for these species through both ex-situ and in-situ protection methods.For this purpose it is of critical importance to collect data on the distribution of the above species and vitality and fertility of their populations.Processes of seed production and seed multiplication have been studied.The ex-situ base of the seed and live collection bank was created.The work is done in Great Britain within the framework of the“Millennium”Seed Bank Partnership of Kew Botanical Garden.The seeds are placed in the National Seed Bank,duplicates together with Herbarium sample are sent in the millennium seed bank.The live collection obtained from seeds is placed on the collection plot of Plant Conservation Department of the National Botanical Garden of Georgia.
基金Funded by the National Natural Science Foundation of China(51373137)
文摘Composites were prepared with polysulfone through ex-situ toughening technique. The dynamic parameters of cyanate/epoxy resin were studied by differential scanning calorimetric（DSC） analysis and dynamic mechanical analysis（DMA）. Microstructual toughening mechanism was studied through scanning electron microscopy（SEM）. The particle microstructure in interlaminar region of composites toughened through ex-situ toughening technique revealed that a reaction induced phase decomposition and phase inversion happened in the interlaminar region. The thermosetting particles were surrounded by the PS phase, which could signifi cantly improve the delamination resistance of composites. The compression after impact（CAI） can be signifi cantly improved from 180 MPa to 260 MPa by using ex-situ toughening while the mechanical properties are not affected.
基金supported by the Key-Area Research and Development Program of Guangdong Province(2024B1111080001)the National Natural Science Foundation of China(52204248 and 52474258)Youth Innovation Promotion Association CAS(Y201768)。
文摘Solid-state battery(SSB)with lithium metal anode(LMA)is considered as one of the most promising storage devices for the next generation.To simultaneously address two critical issues in lithium metal batteries:the negative impact of interfacial compatibility on the electrochemical performance and the safety risks associated with Li dendrite growth-we propose a dual in-situ strategy for fabricating SSBs.Herein,the excellent cycling performance and improved safety of polymer SSB under dual in-situ strategy was confirmed.The lower Li nucleation barrier of Sn leads to uniform Li deposition on the modified-Li(ModLi)/solid-state electrolyte(SSE)interface.LiF-enriched layer on LMA contributes to capacity retention of 92%after 550 cycles in LiFePO_(4)SSB.The modified layer provides outstanding dendrite suppression ability under an overcharge condition of 5.5 V.The higher thermal stability of SSE than liquid electrolyte was investigated through in-situ heat and gas generation analysis,with ModLi+SSE generating only 9.9%of Li+SSE.Higher cycling stability of SSB was demonstrated through in-situ cycling heat generation analysis,and lower temperature sensitivity of SSB with 31%of heat production decrease from 30 to 70℃,while LIBs show a 54%reduction.Excellent high-temperature stability was proved by a 92%capacity retention at 60℃after 50 cycles.Ultimately,pouch cells with SSE of higher thermal stability and modifications on LMA achieved a higher self-heating onset temperature(Tonset)of 180℃and a lower thermal runaway maximum temperature(T_(max))of 401℃,The impacts of dual in-situ strategy for materials,interfaces,coin cells and pouch cells aid in further understanding on thermal runaway mechanism of SSB.
基金supported by grants from the Beijing Hospitals Authority Youth Program (12022B4010)BTCH Young Talent En-lightenment Program (2024QMRC24)CAMS Innovation Fund for Medical Sciences (2019-I2M-5–056)。
文摘Extracorporeal liver surgery(ELS), also known as liver autotransplantation, is a hybrid(cross-fertilized) surgery incorporating the technical knowledge from extreme liver and transplant liver surgeries, and recently became more embraced and popularized among leading centers. ELS could be summarized into three major categories, namely, ex-situ liver resection and autotransplantation(ELRA), ante-situm liver resection and autotransplantation(ALRA) and auxiliary partial liver autotransplantation(APLA). The successful development of ELS during the past 37 years is definitely inseparable from continuous effort s done by Chinese surgeons and researchers. Especially, the precision liver surgery paradigm has allowed to transform ELS into a modularized, more simplified, and standardized surgery, to upgrade surgical skills, to improve peri-operative outcome and long-term survival, to increase the capability of surgeons to select more complex diseases and to expand the level of medical service to the population. This review highlights the Chinese contributions to the field of ELS, focusing thereby on features of different surgical types, technical innovations, disease selection and surgical indication, patient prognosis and future perspectives.
文摘This study compares the crude oil removal efficiency of free and biosurfactant-producing bacterial consortia(Bacillus tequilensis NR_104919 and Bacillus axarquiensis NR_115929)entrapped in chitosan(CH),chitosan/glutaraldehyde(CH/GA),and chitosan/Na-bentonite(CH/BNT)matrices.Additionally,the mechanical and thermal stability,swelling capacity,surface morphology,and chemical bonding of these composites were evaluated.Initially,the biosurfactant produced by the consortium was identified using screening methods,and its lipopeptide structure was confirmed through TLC and 1H NMR analyses,with a yield of 0.2 g/L.Following characterization,the biosurfactant-producing bacterial consortium was immobilized onto CH,CH/GA,and CH/BNT beads for further assessment.When comparing the oil removal capacities of the composites,the consortium immobilized in the CH/BNT matrix exhibited significantly higher crude oil removal efficiency than those entrapped in CH,CH/GA,and the free consortium.The maximum oil removal by the CH/BNT-entrapped consortium was achieved under optimized conditions:0.5 mL crude oil,0.1 g Na-bentonite,pH=6.0,at 35℃,over a 7-day incubation period.However,a decline in oil remediation performance was observed from the fourth reuse cycle onward.These laboratory-scale findings were further validated through ex-situ simulation and long-term experiments,confirming the potential of the CH/BNT composite for effective and sustainable petroleum pollutant remediation.The swelling capacity of inactivated CH was comparable to that of the CH/BNT composite,with both exhibiting greater swelling than CH/GA beads.Additionally,CH/BNT beads demonstrated superior mechanical stability relative to CH and CH/GA,which showed similar stability profiles.Thermal stability,surface morphology,and chemical bonding of the CH,CH/GA,and CH/BNT composites were characterized using TGA,FT-IR,and SEM analyses.CH/BNT composite represents an effective,economical,and environmentally benign alternative to costly synthetic materials for the remediation of oil pollution in aquatic environments.This study highlights the potential of chitosan/Na-bentonite-based composites as sustainable solutions for petroleum pollutant removal,while recommending pilot-scale investigations to assess their feasibility and performance under real-world conditions.
基金supported by the National Natural Science Foundation of China(42225604,31500456,31430080)the 2023 Strategic Consultation Project of the Chinese National Committee for Man and the Biosphere,the National Key Programme of Research and Development of Ministry of Science and Technology of China(2022YFF1301603)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA23040403).
文摘The Yangtze finless porpoise(Neophocaena asiaeorientalis asiaeorientalis)is distributed in the main stream of the middle and lower reaches of the Yangtze River,as well as in Dongting and Poyang lakes.Currently,the most crucial conservation approach involves the establishment and management of both in-situ and ex-situ nature reserves.Since the 1990s,seven nature reserves have been established in the middle and lower reaches of the Yangtze River,covering nearly one-third of its main stream.Additionally,two nature reserves,one in the Dongting Lake and another in the Poyang Lake,have been set up;and three ex-situ nature reserves have been established in three oxbows respectively in Hunan,Hubei,and Anhui provinces.Through measures such as improving the ecological environment quality within the reserves,regulating human activities,and conducting continuous monitoring,the finless porpoise population showed a slight increase in 2022 for the first time.The ex-situ population has continued to grow,with four individuals being released back into the main stream of the Yangtze River after undergoing reintroduction training in 2023.Based on the population development lasting for over three decades,and predictions of future ecological changes,orderly establishment and scientific management of nature reserves have played a key role in and will remain an important basis for the sustaining growth of the finless porpoise population.
基金National Basic Research Programs of China (2003CB615604973)
文摘The microstructure property relationships have been studied in terms of glass transition behavior,phase morphology,and fracture toughness on thermoplastic polyetherketone with a phenolphthalein side group (PAEK) toughened bismaleimdes (BMI) resins,and in terms of interlaminar morphology and compression after impact (CAI) on the graphite fiber (T700SC),the rein-forced BMI matrix composites that are toughened with a so-called ex-situ concept,respectively. The characteristic morphology spectrum has been found ...
基金support offered by National Natural Science Foundation of China(NSFC,Grant No.21403091)。
文摘Transition metal nitrides(TMN)have recently grabbed immensely appealing as ideal active materials in energy storage and catalysis fields on account of their remarkable electrical conductivity,excellent chemical stability,wide band gap and tunable morphology.Both pure TMN and TMN-based materials have been extensively studied concerned with their preparation approaches,nanostructures,and favored performance in various applications.However,the processes towards synthesis of TMN are numerous and complex.Choosing appropriate method to obtain target TMN with desired structure is crucial,which further affects its practical application performance.Herein,this review offers a timely and comprehensive summary of the synthetic ways to TMN and their application in energy related domains.The synthesis section is categorized into in-situ and ex-situ based on where the N element in TMN origins from.Then,overviews on the energy related applications including energy storage,electrocatalysis and photocatalysis are discussed.In the end,the problems to be solved and the development trend of the synthesis and application of transition metal nitrides are prospected.
基金Supported by the National High Technology Research and Development Program of China (No. 2009AA063103)the National Natural Science Foundation of China (No. 41030531)
文摘Problems associated with organochlorine pesticide （OCP）-contaminated sites in China have received wide attention. To solve such problems, innovative ex-situ methods of site remediation are urgently needed. We investigated the feasibility of the extraction method with different organic solvents, ethanol, 1-propanol, and three fractions of petroleum ether, using a soil collected from Wujiang （W J）, China, a region with long-term contamination of dichlorodiphenyltrichloroethanes （DDTs）. We evaluated different influential factors, including organic solvent concentration, washing time, mixing speed, solutiomto-soil ratio, and washing temperature, on the removal of DDTs from the WJ soil. A set of relatively better parameters were selected for extraction with 100 mL L-1 petroleum ether （60-90 ℃）： washing time of 180 min, mixing speed of 100 r min-I, solution-to-soil ratio of 10：1, and washing temperature of 50 ℃. These selected parameters were also applied on three other seriously OCP-polluted soils. Results demonstrated their broad-spectrum effectiveness and excellent OCP extraction performance on the contaminated soils with different characteristics.
基金supported by the Next Generation Engineering Researcher Program of National Research Foundation of Korea(NRF)funded by the Ministry of Science and ICT(2017H1D8A2031138).
文摘Sustainable transformation and efficient utilization of biomasses and their derived materials are environ-mentally as well as economically compliant strategies.Biomass seaweed-derived nitrogen self-doped porous carbon with tailored surface area and pore structures are prepared through carb on izatio n and activation.The in fluence of carb on ization temperature on morphology,surface area,and heteroatom dopants are investigated to optimize sodium-ion storage capability.Seaweed-derived nitrogen selfdoped activated carbon(SAC)as anode materials for sodium-ion batteries exhibits remarkable reversible capacity of 303/192 mAh g^(-1) after 100/500 cycles at current densities of 100/200 mA g^(-1) respectively,and a good rate capability.The interconnected and porous conducting nature along with the heteroatom dopant role in creating defective sites and charge stabilization are favorable for ion storage and diffusion and electron transport,indicating the electrodes can offer improved electrochemical performances.In addition,post-mortem analysis of the cycled carbon electrodes through ex-situ tools demonstrates the sodium-ion storage mechanism.
基金supported by the National Natural Science Foundation of China(Nos.21771164,U1804129,21773215)。
文摘Metal selenides owing to their high theoretical capacity and good conductivity are considered as one of the potential candidates for the anode materials of sodium-ion batteries(SIBs).However,their practical applications are greatly restricted by the poor cycling performances and complicated synthesis methods.In this work,a sandwich-like Sn Se2/reduced graphene oxide(r GO)composite with a small amount of r GO(7.3%)is synthesized by a simple one-pot solvothermal technique.The as-synthesized Sn Se2/r GO shows improved initial coulombic efficiency(ICE)of 73.7%,high capacity of 402.0 m Ah g-1 after 150 cycles at 0.1 A g-1 with a retention of 86.2%and outstanding rate performances.The abundant Sn-O-C bonds of synthesized material not only accelerate the charge transfer at the interface but also enhance the mechanical strength to accommodate volume variation and prevent active material loss during cycling.Moreover,the compact structure leads to thin solid electrolyte interface(SEI)so that high initial coulombic efficiency was obtained.Furthermore,full cells are assembled to test its potential application.This work offers a simple method to synthesize Sn Se2/r GO as a candidate anode for SIBs.
