All-solid-state lithium batteries(ASSLBs)are strongly considered as the next-generation energy storage devices for their high energy density and intrinsic safety.The solid-solid contact between lithium metal and solid...All-solid-state lithium batteries(ASSLBs)are strongly considered as the next-generation energy storage devices for their high energy density and intrinsic safety.The solid-solid contact between lithium metal and solid electrolyte plays a vital role in the performance of working ASSLBs,which is challenging to investigate quantitatively by experimental approach.This work proposed a quantitative model based on the finite element method for electrochemical impedance spectroscopy simulation of different solid-solid contact states in ASSLBs.With the assistance of an equivalent circuit model and distribution of relaxation times,it is discovered that as the number of voids and the sharpness of cracks increase,the contact resistance Rcgrows and ultimately dominates the battery impedance.Through accurate fitting,inverse proportional relations between contact resistance Rcand(1-porosity)as well as crack angle was disclosed.This contribution affords a fresh insight into clarifying solid-solid contact states in ASSLBs.展开更多
The trade-off between mechanistic interpretability,operational convenience,and predictive accuracy is challenging for predicting the lifetime of lithium-ion batteries.To resolve this contradiction,we propose a damage ...The trade-off between mechanistic interpretability,operational convenience,and predictive accuracy is challenging for predicting the lifetime of lithium-ion batteries.To resolve this contradiction,we propose a damage model based on fatigue damage theory and electrochemical impedance spectroscopy.The causal relationship of“fatigue damage→resistance increase→capacity fading”is revealed to describe the underlying mechanism.Charge transfer resistance is chosen as the variable to ensure the convenience of data acquisition.To verify the accuracy of the model,the electrochemical impedance spectrum and capacity of a graphene-coated silicon electrode at two charging rates are collected and analyzed.50% and 75% of the measured data are utilized as inputs to compare the prediction capabilities of the proposed damage model and the existing empirical model.The particle filter algorithm is adopted to train the parameters of both models.The maximum prediction error of the damage model is less than 3%,showing better prediction accuracy and medium-term prediction stability than the empirical model.Our work demonstrates that the proposed damage model is an effective way to resolve contradictions in lifetime prediction.展开更多
Quantum well infrared photodetectors(QWIPs) based on intersubband transitions hold significant potential for high bandwidth operation. In this work, we establish a carrier transport optimization model incorporating el...Quantum well infrared photodetectors(QWIPs) based on intersubband transitions hold significant potential for high bandwidth operation. In this work, we establish a carrier transport optimization model incorporating electron injection at the emitter to investigate the carrier dynamics time and impedance spectroscopy in GaAs/AlGaAs QWIPs. Our findings provide novel evidence that the escape time of electrons is the key limiting factor for the 3-dB bandwidth of QWIPs. Moreover, to characterize the impact of carrier dynamics time and non-equilibrium space charge region on impedance, we developed an equivalent circuit model where depletion region resistance and capacitance are employed to describe non-equilibrium space charge region. Using this model, we discovered that under illumination, both net charge accumulation caused by variations in carrier dynamics times within quantum wells and changes in width of non-equilibrium space charge region exert different dominant influences on depletion region capacitance at various doping concentrations.展开更多
Electrochemical impedance spectroscopy(EIS)was used to examine the electrical properties of metakaolin(MK)cement-based materials at elevated temperatures.We utilized a new equivalent circuit to investigate the EIS res...Electrochemical impedance spectroscopy(EIS)was used to examine the electrical properties of metakaolin(MK)cement-based materials at elevated temperatures.We utilized a new equivalent circuit to investigate the EIS results of cementitious materials blended with MK at these temperatures.A new evaluation method to high temperature damage is proposed.The findings show that both elevated temperatures and MK contents in cement mortar can impact the impedance spectra’s form properties.However,the residual compressive strength of the MK-blended cementitious material at elevated temperatures does not improve with the addition of MK.A quantitative relationship between the electrochemical parameters of the new equivalent circuit and the residual compressive strength is determined.The degree of high-temperature damage to cementitious materials can be evaluated based on these electrochemical parameters,providing a new approach for evaluating the high-temperature damage of MK-blend cementitious materials.展开更多
Erratum to:International Journal of Minerals,Metallurgy and Materials Volume 31,Number 1,January 2024,Page 186 https://doi.org/10.1007/s12613-023-2744-0 The original version of this article unfortunately contained thr...Erratum to:International Journal of Minerals,Metallurgy and Materials Volume 31,Number 1,January 2024,Page 186 https://doi.org/10.1007/s12613-023-2744-0 The original version of this article unfortunately contained three mistakes.The presentation of Fig.8 in original version was incorrect.The correct version is given below.展开更多
One of the core works of analyzing Electrochemical Impedance Spectroscopy(EIS)data is to select an appropriate equivalent circuit model to quantify the parameters of the electrochemical reaction process.However,this p...One of the core works of analyzing Electrochemical Impedance Spectroscopy(EIS)data is to select an appropriate equivalent circuit model to quantify the parameters of the electrochemical reaction process.However,this process often relies on human experience and judgment,which will introduce subjectivity and error.In this paper,an intelligent approach is proposed for matching EIS data to their equivalent circuits based on the Random Forest algorithm.It can automatically select the most suitable equivalent circuit model based on the characteristics and patterns of EIS data.Addressing the typical scenario of metal corrosion,an atmospheric corrosion EIS dataset of low-carbon steel is constructed in this paper,which includes five different corrosion scenarios.This dataset was used to validate and evaluate the pro-posed method in this paper.The contributions of this paper can be summarized in three aspects:(1)This paper proposes a method for selecting equivalent circuit models for EIS data based on the Random Forest algorithm.(2)Using authentic EIS data collected from metal atmospheric corrosion,the paper es-tablishes a dataset encompassing five categories of metal corrosion scenarios.(3)The superiority of the proposed method is validated through the utilization of the established authentic EIS dataset.The ex-periment results demonstrate that,in terms of equivalent circuit matching,this method surpasses other machine learning algorithms in both precision and robustness.Furthermore,it shows strong applicability in the analysis of EIS data.展开更多
3Gd2O3-3Yb2O3-4Y2O3 （mole fraction, %） co-doped ZrO2 （GY-YSZ） thermal barrier coatings （TBCs） were produced by electron beam physical vapor deposition （EB-PVD）. The oxidation behavior of GY-YSZ at 1 050 ℃ was...3Gd2O3-3Yb2O3-4Y2O3 （mole fraction, %） co-doped ZrO2 （GY-YSZ） thermal barrier coatings （TBCs） were produced by electron beam physical vapor deposition （EB-PVD）. The oxidation behavior of GY-YSZ at 1 050 ℃ was investigated using impedance spectroscopy （IS） combined with scanning electron microscopy （SEM）, Raman spectroscopy and X-ray diffractometry （XRD）. Various electrical responses observed in the impedance spectra corresponding to GY-YSZ grains and grain boundaries were explained using circuit modeling. The change in the conduction mechanism of GY-YSZ was found to be related to the O^2- vacancy and lattice distortion due to the stabilizer diffusion during the oxidation. The results also suggested that the specific oxidation information about the GY-YSZ grains and grain boundaries should be acquired at a moderate measurement temperature, which was related to the resistance value in the impedance spectra. The resistance values of the GY-YSZ grains and grain boundaries should be measured at 200 ℃ and 300 ℃, respectively.展开更多
The passive film formed on 2205 duplex stainless steel（DSS） in 0.5 M NaHCO3＋0.5 M NaCl aqueous solution was characterized by electrochemical measurements,including potentiodynamic anodic polarization and dynamic el...The passive film formed on 2205 duplex stainless steel（DSS） in 0.5 M NaHCO3＋0.5 M NaCl aqueous solution was characterized by electrochemical measurements,including potentiodynamic anodic polarization and dynamic electrochemical impedance spectroscopy（DEIS）.The results demonstrate that there is a great difference between the passive film evolutions of ferrite and austenite.The impedance values of ferrite are higher than those of austenite.The impedance peaks of ferritic and austenitic phases correspond to the potential of 0.15 and 0.25 V in the low potential range and correspond to 0.8 and 0.75 V in the high potential range.The evolutions of the capacitance of both phases are reverse compared to the evolutions of impedance.The thickness variations obtained from capacitance agree well with those of impedance analysis.The results can be used to explain why pitting corrosion occurs more easily in austenite phase than in ferrite phase.展开更多
The corrosion behaviors of the isolated short and vertical long scale Q235B steel in a simulated tidal zone were studied by electrochemical impedance spectroscopy （EIS） monitoring and corrosion weight loss calculati...The corrosion behaviors of the isolated short and vertical long scale Q235B steel in a simulated tidal zone were studied by electrochemical impedance spectroscopy （EIS） monitoring and corrosion weight loss calculation in an experimental indoor simulating trough. The results show that the corrosion rate of the isolated short scale Q235B steel in the tidal zone acquired by the EIS agrees with the corrosion weight loss result. The corrosion rates of the short scale steel are in the order of middle tidal zone 〉 the central zone between the middle tidal zone and low tidal zone 〉 high tidal zone 〉 low tidal zone. The fastest corrosion rate in the middle tidal zone is attributed to the longest wet time in a tidal cycle. According to the comparison of corrosion weight loss between the vertical long scale and isolated short scale specimens, the corrosion rate of vertical long scale specimens of Q235B steel is lower than that of the isolated short scale specimens in the tidal zone, but the result is contrary in the immersion zone.展开更多
The welded joints of 3Cr pipeline steel were fabricated with commercial welding wire using the gas tungsten arc welding （GTAW） technique. Potentiodynamic polarization curves, linear polarization resistance （LPR）, ...The welded joints of 3Cr pipeline steel were fabricated with commercial welding wire using the gas tungsten arc welding （GTAW） technique. Potentiodynamic polarization curves, linear polarization resistance （LPR）, electrochemical impedance spectroscopy （EIS）, scan- ning electron microscopy （SEM）, and energy-dispersive spectrometry （EDS） were used to investigate the corrosion resistance and the growth of a corrosion film on the weld zone （WZ）. The changes in electrochemical characteristics of the film were obtained through fitting of the EIS data. The results showed that the average corrosion rate of the WZ in CO2 environments first increased, then fluctuated, and finally de- creased gradually. The formation of the film on the WZ was divided into three stages： dynamic adsorption, incomplete-coverage layer forma- tion, and integral layer formation.展开更多
The degradation coefficient is proposed to evaluate the degradation degree of organic coatings by directly anaIyzing the Bode plots of the electrochemical impedance spectroscopy （EIS） data. This paper investigated t...The degradation coefficient is proposed to evaluate the degradation degree of organic coatings by directly anaIyzing the Bode plots of the electrochemical impedance spectroscopy （EIS） data. This paper investigated the degradation of phenolic epoxy coating/tinplate system by EIS and the degradation coefficient value, which correlates well with the results of breakpoint frequency and variation of phase angle at 10 Hz. Furthermore, the degradation process was confirmed by scanning electron microscope （SEM） and scanning probe microscopy （SPM）. It is concluded that degradation coefficient can be used for the fast evaluation of degradation degree of organic coatings in practical appli- cations.展开更多
Pitting corrosion of 316L stainless steel in NaCl solution was investigated by means of staircase potential electrochemical impedance spectroscopy（SPEIS）.The investigation focused on the transition of stainless stee...Pitting corrosion of 316L stainless steel in NaCl solution was investigated by means of staircase potential electrochemical impedance spectroscopy（SPEIS）.The investigation focused on the transition of stainless steel from the passive state to pitting corrosion.Based on the evolution of electrical parameters of the equivalent electrical circuit,it is suggested that the most probable mechanism of pit creation is the film breaking model.The result demonstrates that staircase potential electrochemical impedance spectroscopy is an effective method for the investigation of pitting corrosion.展开更多
In this investigation, impedance spectroscopy （IS） is used, as a non-destructive tool, to examine the hot corrosion behavior of thermal barrier coatings （TBCs） exposed to a mixture of 25wt% NaCl and 75wt% Na2SO4. ...In this investigation, impedance spectroscopy （IS） is used, as a non-destructive tool, to examine the hot corrosion behavior of thermal barrier coatings （TBCs） exposed to a mixture of 25wt% NaCl and 75wt% Na2SO4. The results show that the thermally grown oxide （TGO） formed along the top coat/bond coat interface is a mixed oxide layer, i.e. Cr2O3, （Ni, Co）（Cr, Al）2O4 spinel and NiO. The growth of TGO layer appears to follow the parabolic law. The resistance of TGO increases due to the increase of thickness when the number of cycles is less than 110. While for more than 110 cycles, the resistance of TGO decreases with the increase of porosity of TGO layer, even though the thickness of TGO layer increases. The nucleation and propagation of cracks within top coat increase the electrical resistance of top coat. The parameters in equivalent circuit could be used to characterize the degradation of TBCs.展开更多
Machine learning-based methods have emerged as a promising solution to accurate battery capacity estimation for battery management systems.However,they are generally developed in a supervised manner which requires a c...Machine learning-based methods have emerged as a promising solution to accurate battery capacity estimation for battery management systems.However,they are generally developed in a supervised manner which requires a considerable number of input features and corresponding capacities,leading to prohibitive costs and efforts for data collection.In response to this issue,this study proposes a convolutional neural network(CNN)based method to perform end-to-end capacity estimation by taking only raw impedance spectra as input.More importantly,an input reconstruction module is devised to effectively exploit impedance spectra without corresponding capacities in the training process,thereby significantly alleviating the cost of collecting training data.Two large battery degradation datasets encompassing over 4700 impedance spectra are developed to validate the proposed method.The results show that accurate capacity estimation can be achieved when substantial training samples with measured capacities are given.However,the estimation performance of supervised machine learning algorithms sharply deteriorates when fewer samples with measured capacities are available.In this case,the proposed method outperforms supervised benchmarks and can reduce the root mean square error by up to 50.66%.A further validation under different current rates and states of charge confirms the effectiveness of the proposed method.Our method provides a flexible approach to take advantage of unlabelled samples for developing data-driven models and is promising to be generalised to other battery management tasks.展开更多
The corrosion inhibition for carbon steel in circulating cooling water by modified lignosulphonate has been investigated using electrochemical impedance spectroscopy technique. Results show that the inhibition efficie...The corrosion inhibition for carbon steel in circulating cooling water by modified lignosulphonate has been investigated using electrochemical impedance spectroscopy technique. Results show that the inhibition efficiency of modified lignosulphonate GCL2 is a great improvement on that of lignosulphonate. The maximum inhibition efficiency of GCL2 reaches 99.21% at the concentration of 400mg·L^-1 at 303K. The corrosion inhibition of GCL2 is attributed to forming adsorption film on the metal surface for the electrochemical impedance spectroscopy in GCL2 solution shows more than one time-constant.Moreover,results also indicate that it is more efficient in stirring solution than in still solution for GCL2 because the constant of adsorption in stirring solution is much larger than that in still solution. The adsorption of inhibitor GCL2 follows Langmuir＇s adsorption isotherm.展开更多
The corrosion behaviors of Fe-Cr alloy under three different pH values solutions with C1- and SO42- were investigated by localized electrochemical impedance spectroscopy （LEIS） measurements and the corrosion product...The corrosion behaviors of Fe-Cr alloy under three different pH values solutions with C1- and SO42- were investigated by localized electrochemical impedance spectroscopy （LEIS） measurements and the corrosion products were analyzed by laser Raman spectrometry. The results show that the high corrosion resistance of Fe-Cr Alloy is attributed to a passive film which is formed more easily when the alloy contains a large quantity of Cr element. However, its corrosion resistance varies in the solutions with different pH values, especially in the initial corrosion. The average impedance values in neutral and alkaline solution are much higher than that in acidic solution because the passive film is more likely to dissolve in the acidic condition. Moreover, the destructive effect of C1- and SO42 ions on the passive film is also demonstrated in corrosion process through the change of the impedance value with the steeping time.展开更多
Metal-based nanomaterials have a wide range of applications in energy conversion,catalysis,bioimaging,and sensors.In our review,we mainly introduce metal nanomaterials-based electrochemical impedance spectroscopy(EIS)...Metal-based nanomaterials have a wide range of applications in energy conversion,catalysis,bioimaging,and sensors.In our review,we mainly introduce metal nanomaterials-based electrochemical impedance spectroscopy(EIS)biosensors in medical healthcare,environmental monitoring,and food safety instructively,with collecting and analyzing the current achievement of predecessors.In general,metal nanomaterials-based EIS biosensors can be divided into four components,in which bioreceptors and metal nanomaterials transducers are vital for designs.Bioreceptors and metal nanomaterials determine the feasibility,specificity,sensitivity and simplicity of manufacturing and operations.With the demonstration and discussion of bioreceptors and metal nanomaterials of biosensors in different fields,our review aims to assist brief acknowledgement of current state-of-the-art achievement and provide our insights for the future development.展开更多
BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sin...BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sintering technique. The temperature dependence of resistivity shows that the phase transition of the PTC thermistor ceramic occurs at the Curie temperature, Tc = 155℃, which is higher than that of BaTiO3 （≤ 130 ℃）. Analysis of ac impedance data using complex impedance spectroscopy gives the alternate current （AC） resistance of the PTCR ceramic. By additional use of the complex electric modulus formalism to analyse the same data, the inhomogeneous nature of the ceramic may be unveiled. The impedance spectra reveal that the grain resistance of the BB-BT sample is slightly influenced by the increase of temperature, indicating that the increase in overall resistivity is entirely due to a grain-boundary effect. Based on the dependence of the extent to which the peaks of the imaginary part of electric modulus and impedance are matched on frequency, the conduction mechanism is also discussed for a BB-BT ceramic system.展开更多
The electrochemical characteristics of 1Cr18Ni9Ti in sulphate-reducing bacteria （SRB） solutions and the biofilm of SRB on the surface of the 1Cr18Ni9Ti electrode were studied by electrochemical, microbiological, and...The electrochemical characteristics of 1Cr18Ni9Ti in sulphate-reducing bacteria （SRB） solutions and the biofilm of SRB on the surface of the 1Cr18Ni9Ti electrode were studied by electrochemical, microbiological, and surface analysis methods. Electrochemical impedance spectroscopy （EIS） of 1Cr18Ni9Ti was measured in the solutions with and without SRB at the culture time of 2, 4, 8 d, respectively. The measurement used two test methods, the nonimmersion electrode method and the immersion electrode method. It was found that the polarization resistance （Rp） of 1Cr18Ni9Ti in the solutions without SRB is the greatest for each test method. When using the nonimmersion electrode method, Rp shifts negatively at first and then positively, and the time constant is only one. Although using the immersion electrode method, the Rp shifts positively at first and then negatively, and the time constant also changes when the biofilm forms. The biofilm observed through SEM is with pores. It was demonstrated that SRB has accelerated corrosion action on 1Cr18Ni9Ti. The protection effect of the biofilm on the electrode depends on the compact degree of the film.展开更多
Despite great progress in lithium-sulfur(Li-S) batteries, the electrochemical reactions in the cell are not yet fully understood. Electrode processes, complex interfaces and internal resistance may be characterized by...Despite great progress in lithium-sulfur(Li-S) batteries, the electrochemical reactions in the cell are not yet fully understood. Electrode processes, complex interfaces and internal resistance may be characterized by electrochemical impedance spectroscopy(EIS). EIS is a non-destructive technique and easy to apply, though there are challenges in ensuring the reproducibility of measurements and the interpretation of impedance data. Here, we present the impedance behavior of a 3.4 Ah Li-S pouch cell characterized by EIS. The impedance changes were analyzed over the entire depth-of-discharge, depth-of-charge,and at various temperatures. Based on the formation of intermediates during(dis)charging, the changes of resistances are observed. Overall, the increase in temperature causes a decrease in electrolyte viscosity,lowering the surface energy which can improve the penetration of the electrolyte into the electrode pores. Moreover, the effect of superimposed AC current during EIS measurement was analyzed, and the results show the dependence of the charge transfer resistance on superimposed AC current which was lower compared to steady-state conditions and consents with theory.展开更多
基金supported by the Beijing Natural Science Foundation(Z200011,L233004)the National Key Research and Development Program(2021YFB2500300)+3 种基金the National Natural Science Foundation of China(52394170,52394171,22109011,22393900,and 22108151)the Tsinghua-Jiangyin Innovation Special Fund(TJISF)(2022JYTH0101)the S&T Program of Hebei(22344402D)the Tsinghua University Initiative Scientific Research Program.
文摘All-solid-state lithium batteries(ASSLBs)are strongly considered as the next-generation energy storage devices for their high energy density and intrinsic safety.The solid-solid contact between lithium metal and solid electrolyte plays a vital role in the performance of working ASSLBs,which is challenging to investigate quantitatively by experimental approach.This work proposed a quantitative model based on the finite element method for electrochemical impedance spectroscopy simulation of different solid-solid contact states in ASSLBs.With the assistance of an equivalent circuit model and distribution of relaxation times,it is discovered that as the number of voids and the sharpness of cracks increase,the contact resistance Rcgrows and ultimately dominates the battery impedance.Through accurate fitting,inverse proportional relations between contact resistance Rcand(1-porosity)as well as crack angle was disclosed.This contribution affords a fresh insight into clarifying solid-solid contact states in ASSLBs.
基金supported by the National Natural Science Foundation of China(12021002,12472183,and 12041201).
文摘The trade-off between mechanistic interpretability,operational convenience,and predictive accuracy is challenging for predicting the lifetime of lithium-ion batteries.To resolve this contradiction,we propose a damage model based on fatigue damage theory and electrochemical impedance spectroscopy.The causal relationship of“fatigue damage→resistance increase→capacity fading”is revealed to describe the underlying mechanism.Charge transfer resistance is chosen as the variable to ensure the convenience of data acquisition.To verify the accuracy of the model,the electrochemical impedance spectrum and capacity of a graphene-coated silicon electrode at two charging rates are collected and analyzed.50% and 75% of the measured data are utilized as inputs to compare the prediction capabilities of the proposed damage model and the existing empirical model.The particle filter algorithm is adopted to train the parameters of both models.The maximum prediction error of the damage model is less than 3%,showing better prediction accuracy and medium-term prediction stability than the empirical model.Our work demonstrates that the proposed damage model is an effective way to resolve contradictions in lifetime prediction.
基金financially supported by the National Natural Science Foundation of China (Grant No. 61991442)。
文摘Quantum well infrared photodetectors(QWIPs) based on intersubband transitions hold significant potential for high bandwidth operation. In this work, we establish a carrier transport optimization model incorporating electron injection at the emitter to investigate the carrier dynamics time and impedance spectroscopy in GaAs/AlGaAs QWIPs. Our findings provide novel evidence that the escape time of electrons is the key limiting factor for the 3-dB bandwidth of QWIPs. Moreover, to characterize the impact of carrier dynamics time and non-equilibrium space charge region on impedance, we developed an equivalent circuit model where depletion region resistance and capacitance are employed to describe non-equilibrium space charge region. Using this model, we discovered that under illumination, both net charge accumulation caused by variations in carrier dynamics times within quantum wells and changes in width of non-equilibrium space charge region exert different dominant influences on depletion region capacitance at various doping concentrations.
基金Funded by the Natural Science Foundation of Inner Mongolia Autonomous Region(No.2024QN05023)High Level Talent Research Launch Foundation of Inner Mongolia University(No.10000-22311201/008)。
文摘Electrochemical impedance spectroscopy(EIS)was used to examine the electrical properties of metakaolin(MK)cement-based materials at elevated temperatures.We utilized a new equivalent circuit to investigate the EIS results of cementitious materials blended with MK at these temperatures.A new evaluation method to high temperature damage is proposed.The findings show that both elevated temperatures and MK contents in cement mortar can impact the impedance spectra’s form properties.However,the residual compressive strength of the MK-blended cementitious material at elevated temperatures does not improve with the addition of MK.A quantitative relationship between the electrochemical parameters of the new equivalent circuit and the residual compressive strength is determined.The degree of high-temperature damage to cementitious materials can be evaluated based on these electrochemical parameters,providing a new approach for evaluating the high-temperature damage of MK-blend cementitious materials.
文摘Erratum to:International Journal of Minerals,Metallurgy and Materials Volume 31,Number 1,January 2024,Page 186 https://doi.org/10.1007/s12613-023-2744-0 The original version of this article unfortunately contained three mistakes.The presentation of Fig.8 in original version was incorrect.The correct version is given below.
基金support of the project from the National Key R&D Program of China,Research and Application of Sensing System for Cross-regional Complex Oil&Gas Pipeline Network Safe and Efficiency Operational Status Monitoring(Grant No.2022YFB3207603).
文摘One of the core works of analyzing Electrochemical Impedance Spectroscopy(EIS)data is to select an appropriate equivalent circuit model to quantify the parameters of the electrochemical reaction process.However,this process often relies on human experience and judgment,which will introduce subjectivity and error.In this paper,an intelligent approach is proposed for matching EIS data to their equivalent circuits based on the Random Forest algorithm.It can automatically select the most suitable equivalent circuit model based on the characteristics and patterns of EIS data.Addressing the typical scenario of metal corrosion,an atmospheric corrosion EIS dataset of low-carbon steel is constructed in this paper,which includes five different corrosion scenarios.This dataset was used to validate and evaluate the pro-posed method in this paper.The contributions of this paper can be summarized in three aspects:(1)This paper proposes a method for selecting equivalent circuit models for EIS data based on the Random Forest algorithm.(2)Using authentic EIS data collected from metal atmospheric corrosion,the paper es-tablishes a dataset encompassing five categories of metal corrosion scenarios.(3)The superiority of the proposed method is validated through the utilization of the established authentic EIS dataset.The ex-periment results demonstrate that,in terms of equivalent circuit matching,this method surpasses other machine learning algorithms in both precision and robustness.Furthermore,it shows strong applicability in the analysis of EIS data.
基金Projects (50771009, 50731001 and 51071013) supported by the National Natural Science Foundations of China Project (2010CB631200) supported by the National Basic Research Program of China
文摘3Gd2O3-3Yb2O3-4Y2O3 （mole fraction, %） co-doped ZrO2 （GY-YSZ） thermal barrier coatings （TBCs） were produced by electron beam physical vapor deposition （EB-PVD）. The oxidation behavior of GY-YSZ at 1 050 ℃ was investigated using impedance spectroscopy （IS） combined with scanning electron microscopy （SEM）, Raman spectroscopy and X-ray diffractometry （XRD）. Various electrical responses observed in the impedance spectra corresponding to GY-YSZ grains and grain boundaries were explained using circuit modeling. The change in the conduction mechanism of GY-YSZ was found to be related to the O^2- vacancy and lattice distortion due to the stabilizer diffusion during the oxidation. The results also suggested that the specific oxidation information about the GY-YSZ grains and grain boundaries should be acquired at a moderate measurement temperature, which was related to the resistance value in the impedance spectra. The resistance values of the GY-YSZ grains and grain boundaries should be measured at 200 ℃ and 300 ℃, respectively.
基金supported by the National Natural Science Foundation of China(No.50871020)
文摘The passive film formed on 2205 duplex stainless steel（DSS） in 0.5 M NaHCO3＋0.5 M NaCl aqueous solution was characterized by electrochemical measurements,including potentiodynamic anodic polarization and dynamic electrochemical impedance spectroscopy（DEIS）.The results demonstrate that there is a great difference between the passive film evolutions of ferrite and austenite.The impedance values of ferrite are higher than those of austenite.The impedance peaks of ferritic and austenitic phases correspond to the potential of 0.15 and 0.25 V in the low potential range and correspond to 0.8 and 0.75 V in the high potential range.The evolutions of the capacitance of both phases are reverse compared to the evolutions of impedance.The thickness variations obtained from capacitance agree well with those of impedance analysis.The results can be used to explain why pitting corrosion occurs more easily in austenite phase than in ferrite phase.
基金supported finically by the National Natural Science Foundation of China(Nos.51201170,51131007 and 50971120)
文摘The corrosion behaviors of the isolated short and vertical long scale Q235B steel in a simulated tidal zone were studied by electrochemical impedance spectroscopy （EIS） monitoring and corrosion weight loss calculation in an experimental indoor simulating trough. The results show that the corrosion rate of the isolated short scale Q235B steel in the tidal zone acquired by the EIS agrees with the corrosion weight loss result. The corrosion rates of the short scale steel are in the order of middle tidal zone 〉 the central zone between the middle tidal zone and low tidal zone 〉 high tidal zone 〉 low tidal zone. The fastest corrosion rate in the middle tidal zone is attributed to the longest wet time in a tidal cycle. According to the comparison of corrosion weight loss between the vertical long scale and isolated short scale specimens, the corrosion rate of vertical long scale specimens of Q235B steel is lower than that of the isolated short scale specimens in the tidal zone, but the result is contrary in the immersion zone.
基金financial support from the Natural Science Foundation of China (No. 51371034)
文摘The welded joints of 3Cr pipeline steel were fabricated with commercial welding wire using the gas tungsten arc welding （GTAW） technique. Potentiodynamic polarization curves, linear polarization resistance （LPR）, electrochemical impedance spectroscopy （EIS）, scan- ning electron microscopy （SEM）, and energy-dispersive spectrometry （EDS） were used to investigate the corrosion resistance and the growth of a corrosion film on the weld zone （WZ）. The changes in electrochemical characteristics of the film were obtained through fitting of the EIS data. The results showed that the average corrosion rate of the WZ in CO2 environments first increased, then fluctuated, and finally de- creased gradually. The formation of the film on the WZ was divided into three stages： dynamic adsorption, incomplete-coverage layer forma- tion, and integral layer formation.
基金Supported by Major State Basic Research Program of China ("973"Program,No. 2011CB610500)
文摘The degradation coefficient is proposed to evaluate the degradation degree of organic coatings by directly anaIyzing the Bode plots of the electrochemical impedance spectroscopy （EIS） data. This paper investigated the degradation of phenolic epoxy coating/tinplate system by EIS and the degradation coefficient value, which correlates well with the results of breakpoint frequency and variation of phase angle at 10 Hz. Furthermore, the degradation process was confirmed by scanning electron microscope （SEM） and scanning probe microscopy （SPM）. It is concluded that degradation coefficient can be used for the fast evaluation of degradation degree of organic coatings in practical appli- cations.
文摘Pitting corrosion of 316L stainless steel in NaCl solution was investigated by means of staircase potential electrochemical impedance spectroscopy（SPEIS）.The investigation focused on the transition of stainless steel from the passive state to pitting corrosion.Based on the evolution of electrical parameters of the equivalent electrical circuit,it is suggested that the most probable mechanism of pit creation is the film breaking model.The result demonstrates that staircase potential electrochemical impedance spectroscopy is an effective method for the investigation of pitting corrosion.
文摘In this investigation, impedance spectroscopy （IS） is used, as a non-destructive tool, to examine the hot corrosion behavior of thermal barrier coatings （TBCs） exposed to a mixture of 25wt% NaCl and 75wt% Na2SO4. The results show that the thermally grown oxide （TGO） formed along the top coat/bond coat interface is a mixed oxide layer, i.e. Cr2O3, （Ni, Co）（Cr, Al）2O4 spinel and NiO. The growth of TGO layer appears to follow the parabolic law. The resistance of TGO increases due to the increase of thickness when the number of cycles is less than 110. While for more than 110 cycles, the resistance of TGO decreases with the increase of porosity of TGO layer, even though the thickness of TGO layer increases. The nucleation and propagation of cracks within top coat increase the electrical resistance of top coat. The parameters in equivalent circuit could be used to characterize the degradation of TBCs.
基金supported by the National Key R&D Program of China(2021YFB2402002)the National Natural Science Foundation of China(51922006 and 51877009)+1 种基金the China Postdoctoral Science Foundation(BX2021035 and 2022M710379)the Beijing Natural Science Foundation(Grant No.L223013)。
文摘Machine learning-based methods have emerged as a promising solution to accurate battery capacity estimation for battery management systems.However,they are generally developed in a supervised manner which requires a considerable number of input features and corresponding capacities,leading to prohibitive costs and efforts for data collection.In response to this issue,this study proposes a convolutional neural network(CNN)based method to perform end-to-end capacity estimation by taking only raw impedance spectra as input.More importantly,an input reconstruction module is devised to effectively exploit impedance spectra without corresponding capacities in the training process,thereby significantly alleviating the cost of collecting training data.Two large battery degradation datasets encompassing over 4700 impedance spectra are developed to validate the proposed method.The results show that accurate capacity estimation can be achieved when substantial training samples with measured capacities are given.However,the estimation performance of supervised machine learning algorithms sharply deteriorates when fewer samples with measured capacities are available.In this case,the proposed method outperforms supervised benchmarks and can reduce the root mean square error by up to 50.66%.A further validation under different current rates and states of charge confirms the effectiveness of the proposed method.Our method provides a flexible approach to take advantage of unlabelled samples for developing data-driven models and is promising to be generalised to other battery management tasks.
基金supported by the National Natural Science Foundation of China(No.20276024)the Guangdong Provincial Laboratory of Green Chemical Technology
文摘The corrosion inhibition for carbon steel in circulating cooling water by modified lignosulphonate has been investigated using electrochemical impedance spectroscopy technique. Results show that the inhibition efficiency of modified lignosulphonate GCL2 is a great improvement on that of lignosulphonate. The maximum inhibition efficiency of GCL2 reaches 99.21% at the concentration of 400mg·L^-1 at 303K. The corrosion inhibition of GCL2 is attributed to forming adsorption film on the metal surface for the electrochemical impedance spectroscopy in GCL2 solution shows more than one time-constant.Moreover,results also indicate that it is more efficient in stirring solution than in still solution for GCL2 because the constant of adsorption in stirring solution is much larger than that in still solution. The adsorption of inhibitor GCL2 follows Langmuir＇s adsorption isotherm.
基金National Natural Science Foundation of China (No. 50871021)
文摘The corrosion behaviors of Fe-Cr alloy under three different pH values solutions with C1- and SO42- were investigated by localized electrochemical impedance spectroscopy （LEIS） measurements and the corrosion products were analyzed by laser Raman spectrometry. The results show that the high corrosion resistance of Fe-Cr Alloy is attributed to a passive film which is formed more easily when the alloy contains a large quantity of Cr element. However, its corrosion resistance varies in the solutions with different pH values, especially in the initial corrosion. The average impedance values in neutral and alkaline solution are much higher than that in acidic solution because the passive film is more likely to dissolve in the acidic condition. Moreover, the destructive effect of C1- and SO42 ions on the passive film is also demonstrated in corrosion process through the change of the impedance value with the steeping time.
基金financially sponsored by the National Natural Science Foundation of China(Nos.51672204 and 22102128)UK NERC Fellowship Grant(No.NE/R013349/2)。
文摘Metal-based nanomaterials have a wide range of applications in energy conversion,catalysis,bioimaging,and sensors.In our review,we mainly introduce metal nanomaterials-based electrochemical impedance spectroscopy(EIS)biosensors in medical healthcare,environmental monitoring,and food safety instructively,with collecting and analyzing the current achievement of predecessors.In general,metal nanomaterials-based EIS biosensors can be divided into four components,in which bioreceptors and metal nanomaterials transducers are vital for designs.Bioreceptors and metal nanomaterials determine the feasibility,specificity,sensitivity and simplicity of manufacturing and operations.With the demonstration and discussion of bioreceptors and metal nanomaterials of biosensors in different fields,our review aims to assist brief acknowledgement of current state-of-the-art achievement and provide our insights for the future development.
基金supported by the Research Funds of the Guangxi Key Laboratory of Information Materials at the School of Material Science and Engineering,China (Grant No. 0710908-07-Z)
文摘BaBiO3-doped BaTiO3 （BB-BT） ceramic, as a candidate for lead-free positive temperature coefficient of resistivity （PTCR） materials with a higher Curie temperature, has been synthesized in air by a conventional sintering technique. The temperature dependence of resistivity shows that the phase transition of the PTC thermistor ceramic occurs at the Curie temperature, Tc = 155℃, which is higher than that of BaTiO3 （≤ 130 ℃）. Analysis of ac impedance data using complex impedance spectroscopy gives the alternate current （AC） resistance of the PTCR ceramic. By additional use of the complex electric modulus formalism to analyse the same data, the inhomogeneous nature of the ceramic may be unveiled. The impedance spectra reveal that the grain resistance of the BB-BT sample is slightly influenced by the increase of temperature, indicating that the increase in overall resistivity is entirely due to a grain-boundary effect. Based on the dependence of the extent to which the peaks of the imaginary part of electric modulus and impedance are matched on frequency, the conduction mechanism is also discussed for a BB-BT ceramic system.
文摘The electrochemical characteristics of 1Cr18Ni9Ti in sulphate-reducing bacteria （SRB） solutions and the biofilm of SRB on the surface of the 1Cr18Ni9Ti electrode were studied by electrochemical, microbiological, and surface analysis methods. Electrochemical impedance spectroscopy （EIS） of 1Cr18Ni9Ti was measured in the solutions with and without SRB at the culture time of 2, 4, 8 d, respectively. The measurement used two test methods, the nonimmersion electrode method and the immersion electrode method. It was found that the polarization resistance （Rp） of 1Cr18Ni9Ti in the solutions without SRB is the greatest for each test method. When using the nonimmersion electrode method, Rp shifts negatively at first and then positively, and the time constant is only one. Although using the immersion electrode method, the Rp shifts positively at first and then negatively, and the time constant also changes when the biofilm forms. The biofilm observed through SEM is with pores. It was demonstrated that SRB has accelerated corrosion action on 1Cr18Ni9Ti. The protection effect of the biofilm on the electrode depends on the compact degree of the film.
基金supported by the Ministry of Education,Science,Research and Sport of the Slovak Republic under project No.313011V334,Innovative Solutions for Propulsion,Power and Safety Components of Transport Vehicles。
文摘Despite great progress in lithium-sulfur(Li-S) batteries, the electrochemical reactions in the cell are not yet fully understood. Electrode processes, complex interfaces and internal resistance may be characterized by electrochemical impedance spectroscopy(EIS). EIS is a non-destructive technique and easy to apply, though there are challenges in ensuring the reproducibility of measurements and the interpretation of impedance data. Here, we present the impedance behavior of a 3.4 Ah Li-S pouch cell characterized by EIS. The impedance changes were analyzed over the entire depth-of-discharge, depth-of-charge,and at various temperatures. Based on the formation of intermediates during(dis)charging, the changes of resistances are observed. Overall, the increase in temperature causes a decrease in electrolyte viscosity,lowering the surface energy which can improve the penetration of the electrolyte into the electrode pores. Moreover, the effect of superimposed AC current during EIS measurement was analyzed, and the results show the dependence of the charge transfer resistance on superimposed AC current which was lower compared to steady-state conditions and consents with theory.
