Quantum dynamical calculations for the IR-multiphoton excitation of H_2O,D_2O and T_2O are presented using a generalized Hamiltonian for XY_2 molecules.The energy spectra obtained from this Hamiltonian are in good agr...Quantum dynamical calculations for the IR-multiphoton excitation of H_2O,D_2O and T_2O are presented using a generalized Hamiltonian for XY_2 molecules.The energy spectra obtained from this Hamiltonian are in good agreement with those of the experiments.The long time average of the transition probabilities and the isotopic effects are discussed in detail,展开更多
文摘Quantum dynamical calculations for the IR-multiphoton excitation of H_2O,D_2O and T_2O are presented using a generalized Hamiltonian for XY_2 molecules.The energy spectra obtained from this Hamiltonian are in good agreement with those of the experiments.The long time average of the transition probabilities and the isotopic effects are discussed in detail,
