5-（Hydroxymethyl） isophthalic acid （H2HIA） as a novel organic ligand was prepared from 3,5-bis（methoxycarbonyl）benzoic acid by a two-step method. And then, a 3D helical coor- dination polymer with a 3-fold inter...5-（Hydroxymethyl） isophthalic acid （H2HIA） as a novel organic ligand was prepared from 3,5-bis（methoxycarbonyl）benzoic acid by a two-step method. And then, a 3D helical coor- dination polymer with a 3-fold interpenetration structure, namely [Zn1/2（HIA）1/2（DPEE）1/2]n （1）, was hydrothermally synthesized at 160 ℃, using H2HIA ligands to assemble with DPEE ligands and Zn2＋ ions. Complex 1 crystalizes in orthorhombic system, space group Pnna, with a = 8.2118（5）, b = 17.1698（7）, c =14.9922（7） ？, V = 2113.82（18） ？3, μ = 1.194 mm-1, Z = 4 and S = 0.967. Moreover, some physical characteristics of complex 1, such as powder X-ray diffraction （PXRD）, thermogravimetry analyses （TGA） and photoluminescent properties, were also investigated.展开更多
Three indium metal-organic frameworks （In-MOFs）, [In（BTB）（2,2＇-bipy）]？NMP （1）, [In（BTB）（2,2＇-bipy）]？NMP？2H2O （2）, and [In（BTB）（NMP）]·0.5NMP （3）, have been constructed by the solvothermal ...Three indium metal-organic frameworks （In-MOFs）, [In（BTB）（2,2＇-bipy）]？NMP （1）, [In（BTB）（2,2＇-bipy）]？NMP？2H2O （2）, and [In（BTB）（NMP）]·0.5NMP （3）, have been constructed by the solvothermal reaction of In（NO3）3·5H2O and 1,3,5-benzenetribenzoic acid （H3BTB） in similar reaction conditions, and characterized by single-crystal X-ray crystallography, power X-ray diffraction （PXRD）, infrared spectroscopy （IR）, elemental analysis （EA） and thermogravimetry analysis （TGA）. Complex 1 bears a two-dimensional （2D） layered structure of 6,3-connected hcb net topology, and complexes 2 and 3 have 2-fold interpenetrating structures based on 6,3-connected layer, which display the same net topologies with the C3-symmetric H3BTB ligands as 3-connected linkers and the In（Ⅲ） ions as 6-connected nodes. Moreover, the fluorescent properties of 1～3 have also been studied.展开更多
The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only prov...The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only provide indirectly the information of the degree of entanglement in a relatively large scale （several to tens of nanometer）. In this article, we report ^1H-NMR spectroscopy with dipolar filters under fast magic angle spinning for probing chain interpenetration of polymer glasses at the molecular level.展开更多
The effects of atomic-level rnixing are systemically investigated in a multifluid interpenetration mix model ,and results are compared with the single-fluid model＇s simulations and experimental data. It is shown that...The effects of atomic-level rnixing are systemically investigated in a multifluid interpenetration mix model ,and results are compared with the single-fluid model＇s simulations and experimental data. It is shown that increasing the model free parameter α, shock Mach number, and the initial density discontinuity makes the mix length and fraction of mixing particle increase, resulting in the lower shock temperatures compared with the results of single-fluid model without mixing. Recent high-compressibility direct-drive spherical implosions on OMEGA are simulated by the interpenetration mix modal. The calculations with atomic mixing between fuel and shell match quite well with the observations. Without considering any mixing, the calculated neutron yields and ion temperatures are overpredicted; while inclusion of the interpenetration mix model with the adjustable parameter α could fit the simulated neutron yields and ion temperatures well with experimental data.展开更多
Two new azo-based coordination compounds with a flexible second ligand, crystal 1 （composed with [Zn（adc）（eda）],-1） and crystal 2 （composed with {[Zn（adc）]0.9568（eda）}n-1＇ and {[Zn（adc）]0.0414},） have b...Two new azo-based coordination compounds with a flexible second ligand, crystal 1 （composed with [Zn（adc）（eda）],-1） and crystal 2 （composed with {[Zn（adc）]0.9568（eda）}n-1＇ and {[Zn（adc）]0.0414},） have been synthe- sized as a couple of isomers with different reaction temperature. Adc2- and eda represent azobenzene-4,4＇-dicar- boxylic ion and 1,2-ethanediamine, respectively. Single crystal X-ray diffraction measurement indicates the inter- penetration of the above crystals could be suppressed by simply tuning the reaction temperature, that is, the 5-fold interpenetration which leads to no free volume left in lower temperature synthesized compound [Zn（adc）（eda）]n-1 could be reduced to a 4-fold interpenetration in higher temperature synthesized {[Zn（adc）]o.9568（eda）},-l＇ which re- sults in free volume accounting for 3.6% （3 1.6 A3 per unit cell volume） in crystal 2. The synthesis, crystal structure and fluorescence spectra of crystals 1 and 2 have been discussed, together with the data of elemental analysis and X-ray powder diffraction.展开更多
Hydrogen-bonded organic frameworks(HOFs)are an emerging class of porous materials that hold promise for the adsorptive separation of industrially relevant gas mixtures.However,developing HOFs with high thermal stabili...Hydrogen-bonded organic frameworks(HOFs)are an emerging class of porous materials that hold promise for the adsorptive separation of industrially relevant gas mixtures.However,developing HOFs with high thermal stability and resistance to water remains a daunting challenge.We report here a microporous HOF(HIAM-103)assembled from a hexacarboxylate linker(2,4,6-trimethylbenzene-1,3,5-triylisophthalic acid,H6TMBTI).The compound crystallizes in the trigonal crystal system,and its structure is a four-fold interpenetrated network.Upon thermal activation,the single crystals remain intact,allowing for precise determination of the activated structure.HIAM-103 exhibits remarkable thermal and hydrothermal stability.Its microporous channels demonstrate selective adsorption of C_(2)H_(6)over C_(2)H_(4)and Xe over Kr,and its separation capability toward mixed gases has been validated by column breakthrough experiments under dry and humid conditions.The preferential gas adsorption sites and separation mechanisms have been uncovered through DFT analysis,which suggests that the methyl group decorated 1D channels are the primary reason for the selective adsorption.展开更多
Carbon nanotubes(CNTs)reinforced copper(CNTs/Cu)is one of the most promising and extensively researched materials for replacing traditional Cu-based materials in high-load and high-current applications,particularly wi...Carbon nanotubes(CNTs)reinforced copper(CNTs/Cu)is one of the most promising and extensively researched materials for replacing traditional Cu-based materials in high-load and high-current applications,particularly within the aerospace industry.Amorphous carbon nanotubes(aCNTs)are a type of carbon nanotubes characterized by the presence of mesopores distributed across their amorphous sidewalls,facilitating connectivity between the hollow core and the external environment.Therefore,we propose utilizing aCNTs as a reinforcing agent for Cu.The mesoporous structure of aCNTs facilitates the interpenetration of Cu into the aCNTs,thereby maintaining the continuity of the matrix properties.Experimental results demonstrate that Cu effectively penetrates the mesoporous sidewalls of aCNTs.Both pure Cu and aCNTs-reinforced Cu exhibit comparable electrical conductivity,while the hardness of the aCNTs/Cu composite is significantly enhanced.Additionally,both the density and porosity of aCNTs/Cu are lower than those of pure Cu,and the introduction of aCNTs helps to reduce the sintering temperature.展开更多
Matter conductivities are crucial physical properties that directly determine the engineering application value of materials.In reality,the majority of materials are multiphase composites.However,there is currently a ...Matter conductivities are crucial physical properties that directly determine the engineering application value of materials.In reality,the majority of materials are multiphase composites.However,there is currently a lack of theoretical models to accurately predict the conductivities of composite materials.In this study,we develop a unified mixed conductivity(UMC)model,achieving unity in three aspects:(1)a unified description and prediction for different conductivities,including elastic modulus,thermal conductivity,electrical conductivity,magnetic permeability,liquid permeability coefficient,and gas diffusion coefficient;(2)a unified-form governing equation for mixed conductivities of various composite structures,conforming to the Riccati equation;(3)a unified-form composite structure,i.e.,a three-dimensional multiphase interpenetrating cuboid structure,encompassing over a dozen of typical composite structures as its specific cases.The UMC model is applicable for predicting the conductivity across six different types of physical fields and over a dozen different composite structures,providing a broad range of applications.Therefore,the current study deepens our understanding of the conduction phenomena and offers a powerful theoretical tool for predicting the conductivities of composite materials and optimizing their structures,which holds significant scientific and engineering implications.展开更多
Weibel instability is a promising candidate mechanism for collisionless shock formation in astrophysical systems.Capturing the underlying physics of Weibel instability will help us to understand the astrophysical shoc...Weibel instability is a promising candidate mechanism for collisionless shock formation in astrophysical systems.Capturing the underlying physics of Weibel instability will help us to understand the astrophysical shock formation,magnetic field generation and amplification,particle acceleration,and so on.Laboratory astrophysics,provides a new way to study these microphysics in controlled conditions.At Shenguang-Ⅱlaser facility,the interpenetrating plasma flows are generated by eight laser beams irradiating a pair of opposing foils to mimic the supernova explosion and the ejecta sweeping up the surrounding medium.Evolution of collisionless interpenetrating plasma flows is observed using optical diagnostics.Filamentary structures appear in the interaction region and the associated magnetic strength is measured about 40 T.Theoretical analysis and simulations indicate that these characteristics are induced by nonlinear Weibel instability.展开更多
Customized design of well-defined cathode structures with abundant adsorption sites and rapid diffusion dynamics,holds great promise in filling capacity gap of carbonaceous cathodes towards high-performance Zn-ion hyb...Customized design of well-defined cathode structures with abundant adsorption sites and rapid diffusion dynamics,holds great promise in filling capacity gap of carbonaceous cathodes towards high-performance Zn-ion hybrid supercapacitors(ZHC).Herein,we fabricate a series of dynamics-oriented hierarchical porous carbons derived from the unique organic-inorganic interpenetrating polymer networks.The interpenetrating polymer networks are obtained through physically knitting polyferric chloride(PFC)network into the highly crosslinked resorcinol-formaldehyde(RF)network.Instead of covalent bonding,physical interpenetrating force in such RF-PFC networks efficiently relieves the RF skeleton shrinkage upon pyrolysis.Meanwhile,the in-situ PFC network sacrifices as a structure-directing agent to suppress the macrophase separation,and correspondingly 3D hierarchical porous structure with plentiful ion-diffusion channels(pore volume of 1.35 cm^(3)/g)is generated in the representative HPC_(4) via nanospace occupation and swelling effect.Further removal of Fe fillers leaves behind a large accessible specific surface area of 1550 m^(2)/g for enhanced Zn-ion adsorption.When used as the cathode for ZHC,HPC_(4) demonstrates a remarkable electrochemical performance with a specific capacity of 215.1 mAh/g at 0.5 A/g and a high Zn^(2+)ion diffusion coefficient of 11.1×10^(-18)cm^(2)/s.The ZHC device yields 117.0 Wh/kg energy output at a power density of 272.1 W/kg,coupled with good cycle lifespan(100,000 cycles@10 A/g).This work inspires innovative insights to accelerate Zn diffusion dynamics by structure elaboration towards high-capacity cathode materials.展开更多
Mg alloys have the defects of low stiffness,low strength,and high coefficient of thermal expansion(CTE).The composites strategy and its architecture design are effective approaches to improve the comprehensive perform...Mg alloys have the defects of low stiffness,low strength,and high coefficient of thermal expansion(CTE).The composites strategy and its architecture design are effective approaches to improve the comprehensive performance of materials,but the processing difficulty,especially in ceramics forming,limits the control and innovation of material architecture.Here,combined with 3D printing and squeeze infiltration technology,two precisely controllable architectures of AZ91/Al_(2)O_(3)interpenetrating phase composites(IPC)with ceramic scaffold were prepared.The interface,properties and impact of different architecture on IPC performance were studied by experiments and finite element simulation.The metallurgical bonding of the interface was realized with the formation of MgAl_(2)O_(4)reaction layer.The IPC with 1 mm circular hole scaffold(1C-IPC)exhibited significantly improved elastic modulus of 164 GPa,high compressive strength of 680 MPa,and good CTE of 12.91×10^(-6)K^(−1),which were 3.64 times,1.98 times and 55%of the Mg matrix,respectively.Their elastic modulus,compressive strength,and CTE were superior to the vast majority of Mg alloys and Mg based composites.The reinforcement and matrix were bicontinuous and interpenetrating each other,which played a critical role in ensuring the potent strengthening effect of the Al_(2)O_(3)reinforcement by efficient load transfer.Under the same volume fraction of reinforcements,compared to IPC with 1 mm hexagonal hole scaffold(1H-IPC),the elastic modulus and compressive strength of 1C-IPC increased by 15%and 28%,respectively,which was due to the reduced stress concentration and more uniform stress distribution of 1C-IPC.It shows great potential of architecture design in improving the performance of composites.This study provides architectural design strategy and feasible preparation method for the development of high performance materials.展开更多
This paper shows a didactic model (PGM), and not only, but representative of the Hadrons described in the Standard Model (SM). In this model, particles are represented by structures corresponding to geometric shapes o...This paper shows a didactic model (PGM), and not only, but representative of the Hadrons described in the Standard Model (SM). In this model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (IQuO). By the properties of IQuO one can define the electric charge and that of color of quarks. Showing the “aurea” (golden) triangular shape of all quarks, we manage to represent the geometric combinations of the nucleons, light mesons, and K-mesons. By the geometric shape of W-bosons, we represent the weak decay of pions and charged Kaons and neutral, highlighting in geometric terms the possibilities of decay in two and three pions of neutral Kaon and the transition to anti-Kaon. In conclusion, from this didactic representation, an in-depth and exhaustive phenomenology of hadrons emerges, which even manages to resolve some problematic aspects of the SM.展开更多
This work shows a didactic model representative of the quarks described in the Standard Model (SM). In the model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillator...This work shows a didactic model representative of the quarks described in the Standard Model (SM). In the model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (GMP). From these didactic hypotheses emerges an in-depth phenomenology of particles (quarks) fully compatible with that of SM, showing, besides, that the number of possible quarks is six.展开更多
Benefiting from excellent mechanical properties and low density,cellular ceramic structures(CCSs)are competitive candidates as structural components.However,inherent brittleness from strong chemical bonds among atoms ...Benefiting from excellent mechanical properties and low density,cellular ceramic structures(CCSs)are competitive candidates as structural components.However,inherent brittleness from strong chemical bonds among atoms extremely impeded CCSs'application.Natural materials occupied outstanding strength and toughness simultaneously due to the dual-phase interpenetrated structure.Inspired by natural materials,it was proposed to fabricate coating covered and fulfilled polyurea/CCS interpenetrated composites(C/CCSs and B/CCSs)to circumvent the brittleness of 3D-printed Al_(2)O_(3)CCSs.It was demonstrated that polyurea coating had less effect on the compressive strength of C/CCSs but tremendously improved their energy-absorbing ability.The energy-absorbing ability of C/CCSs was improved from26.48-52.57 kJ·m^(-3)of CCSs to 1.04-1.89 MJ·m^(-3)because of the extended plateau stage.Furthermore,compressive strength and energy-absorbing ability of B/CCSs were strengthened to 1.33-1.36 and 2.84-4.61 times of C/CCSs,respectively.Besides,failure mode of C/CCSs changed from localized deformation to fracturing entirely with the increase in relative density of CCSs inside,which was the same as that of CCSs.However,with the help of polyurea coating,C/CCSs were still intact at strains up to60%,which would neve r fail catastrophically as CCSs at low strains.B/CCSs tended to fracture as a whole,which was not influenced by relative density of pristine CCSs.It was believed that this work provided a creative way to circumvent the brittleness of CCSs and improve their mechanical performances.展开更多
The title coordination polymer including two crystallographically independent Co2＋ ions is hydrothermally synthesized, in which the Co（1） 2＋ ion is four-coordinated by two carboxylate oxygen atoms from two differe...The title coordination polymer including two crystallographically independent Co2＋ ions is hydrothermally synthesized, in which the Co（1） 2＋ ion is four-coordinated by two carboxylate oxygen atoms from two different 5-（benzoic acid-4-yldiazenyl）isophthalate （byip3-） anions and two nitrogen atoms from two distinct 1,4-bis（imidazol-1-ylmethyl） benzene （bix） ligands displaying a tetrahedral geometry. The Co（2） 2＋ ion is six-coordinated by two water molecules at the apical positions, and two carboxylate oxygen atoms and two nitrogen atoms at the equatorial positions, affording a slightly distorted octahedron. Two Co（1）2＋ and two Co（2）2＋ ions are linked together by four byip3- anions forming a 44-membered motif and these motifs are further arranged into a three-dimensional framework through bix ligands along the a axis with a larger channel （ca. 22.70×11.01）. Each individual network interpenetrates with the other identical network in a parallel fashion to generate a 2-fold interpenetrating array with the {62.84}{63}2{64.82}2 topology.展开更多
A three-dimensional coordination polymer,[Ni（Hbyip2-）（bix）0.5（H2O）]n,has been hydrothermally synthesized.Each Ni2＋ ion is five-coordinated by three carboxylate O atoms from three different 5-（benzoic acid-4-yl...A three-dimensional coordination polymer,[Ni（Hbyip2-）（bix）0.5（H2O）]n,has been hydrothermally synthesized.Each Ni2＋ ion is five-coordinated by three carboxylate O atoms from three different 5-（benzoic acid-4-yldiazenyl）isophthalate（Hbyip2-） anions,one N atom from one 1,4-bis（imidazol-1-ylmethyl）benzene（bix） ligand and one O atom from an aqua ligand displaying a distorted square-pyramid.Each Ni atom is defined by three Hbyip2-anions and each Hbyip2-anion adopts a tris（mono-dentate） ligand coordinating to three Ni2＋ ions affording a 36-membered inorganic ring.These rings are further arranged into an undulated two-dimensional layer parallel to the（101） plane.Adjacent two-dimensional networks are linked by bix ligands into a three-dimensional {63,83}{63} framework with a large channel（ca.26.3 × 13.6） along the [100] direction.Each individual {63,83}{63} network interpenetrates with two others in a parallel fashion to generate a 3-fold interpenetrating network.展开更多
A new Co（Ⅱ）-based coordination polymer, namely [Co（L）0.5（4,4?-bipy）0.5（H2 O）2]n（1,H4 L = 1,3-di（3?,5?-dicarboxylphenyl）benzene, 4,4?-bipy = 4,4?-bipyridine）, has been hydrothermally synthesized using the ...A new Co（Ⅱ）-based coordination polymer, namely [Co（L）0.5（4,4?-bipy）0.5（H2 O）2]n（1,H4 L = 1,3-di（3?,5?-dicarboxylphenyl）benzene, 4,4?-bipy = 4,4?-bipyridine）, has been hydrothermally synthesized using the mixed-ligands self-assembly strategy and further fully characterized. The crystal structure is of monoclinic, space group C2/c with a = 18.9124（10）, b = 11.6150（5）, c =15.4380（6） ?, β = 110.989（5）°, V = 3166.2（2） ?3, C16 H13 CoNO6, Mr = 374.20, Z = 8, Dc = 1.570 g·cm–3, F（000） = 1496, μ = 1.116 mm–1, R = 0.0461 and wR = 0.1312 for 2328 observed reflections（I > 2s（I））. The crystal structure analysis revealed that 1 is a 4-fold interpenetrated three-dimensional（3D） framework with（3,4）-connected dmd-type topology. Moreover, the thermal stability and magnetic property of 1 were also investigated.展开更多
Two new 2 D → 2 D zinc(II) coordination polymers, [Zn(btre)0.5(nbdc)(H2 O)]n(1) and {[Zn(btre)0.5(Me Oip)(H2 O)2]·H2 O}n(2)(btre = 1,2-bis(1,2,4-triazol-4-yl)ethane, nbdc=3-nitro-1, 2-benzenedicarboxylate, Me Oi...Two new 2 D → 2 D zinc(II) coordination polymers, [Zn(btre)0.5(nbdc)(H2 O)]n(1) and {[Zn(btre)0.5(Me Oip)(H2 O)2]·H2 O}n(2)(btre = 1,2-bis(1,2,4-triazol-4-yl)ethane, nbdc=3-nitro-1, 2-benzenedicarboxylate, Me Oip=4-methoxybenzene-1, 3-dicarboxylate) were synthesized at room temperature condition and characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffractions. Three sets of equivalent 2 D(6, 3) networks parallel polycatenated with each other to give a 2 D → 2 D network in 1 and 2. There are strong π-π interactions and hydrogen bonding interactions between adjacent parallel polycatenated 2 D(6, 3) network in 1. Only hydrogen bonding interactions exist in 2. Thermal stabilities and luminescence of 1 and 2 were investigated.展开更多
Highlighting a golden triangular form in <em>u</em> and <em>d </em>quarks (Quark Geometric Model), we build the geometric structures of light meson <em>η</em> and individualize its...Highlighting a golden triangular form in <em>u</em> and <em>d </em>quarks (Quark Geometric Model), we build the geometric structures of light meson <em>η</em> and individualize its decays and spin. By the structure equations describing mesons, we determine a mathematic procedure to calculate the theoretical value of the mass of light mesons <em>η</em>.展开更多
In previous articles (Guido) we demonstrated that Quarks (u, d) are represented by golden geometric structures of coupled quantum oscillators. In this article we show the geometric structure of the pion triplet and, i...In previous articles (Guido) we demonstrated that Quarks (u, d) are represented by golden geometric structures of coupled quantum oscillators. In this article we show the geometric structure of the pion triplet and, in particular, via the structure equation of neutral pion, we identify its decays and we solve the spin question in hadrons thanks also to introduction of algebraic operations [?, ⊕] on geometric structure. Moreover by means of the golden ratio between (u, d), we determine the values of bare masses of quarks (3.51 MeV for u-quark and 5.67 MeV for d-quark) and those ones bounded in a pion (53.31 MeV for u-quark and 85.26 MeV for d-quark). Finally, using algebraic operations [?, ⊕] we point out a new way to represent the processes of pions’ decay.展开更多
基金supported by the Natural Science Foundation of Guizhou Province(20122344)125 program of Guizhou Education Department(2012015)the Doctoral Scientific Fund of Zunyi Normal College(2012BSJJ12)
文摘5-（Hydroxymethyl） isophthalic acid （H2HIA） as a novel organic ligand was prepared from 3,5-bis（methoxycarbonyl）benzoic acid by a two-step method. And then, a 3D helical coor- dination polymer with a 3-fold interpenetration structure, namely [Zn1/2（HIA）1/2（DPEE）1/2]n （1）, was hydrothermally synthesized at 160 ℃, using H2HIA ligands to assemble with DPEE ligands and Zn2＋ ions. Complex 1 crystalizes in orthorhombic system, space group Pnna, with a = 8.2118（5）, b = 17.1698（7）, c =14.9922（7） ？, V = 2113.82（18） ？3, μ = 1.194 mm-1, Z = 4 and S = 0.967. Moreover, some physical characteristics of complex 1, such as powder X-ray diffraction （PXRD）, thermogravimetry analyses （TGA） and photoluminescent properties, were also investigated.
基金Supported by the National Natural Science Foundation of China(No.21371179,21201179)the Fundamental Research Funds for the Central Universities(14CX02213A,16CX05015A)the Foundation of State Key Laboratory of Structural Chemistry(20150026,20160006)
文摘Three indium metal-organic frameworks （In-MOFs）, [In（BTB）（2,2＇-bipy）]？NMP （1）, [In（BTB）（2,2＇-bipy）]？NMP？2H2O （2）, and [In（BTB）（NMP）]·0.5NMP （3）, have been constructed by the solvothermal reaction of In（NO3）3·5H2O and 1,3,5-benzenetribenzoic acid （H3BTB） in similar reaction conditions, and characterized by single-crystal X-ray crystallography, power X-ray diffraction （PXRD）, infrared spectroscopy （IR）, elemental analysis （EA） and thermogravimetry analysis （TGA）. Complex 1 bears a two-dimensional （2D） layered structure of 6,3-connected hcb net topology, and complexes 2 and 3 have 2-fold interpenetrating structures based on 6,3-connected layer, which display the same net topologies with the C3-symmetric H3BTB ligands as 3-connected linkers and the In（Ⅲ） ions as 6-connected nodes. Moreover, the fluorescent properties of 1～3 have also been studied.
文摘The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only provide indirectly the information of the degree of entanglement in a relatively large scale （several to tens of nanometer）. In this article, we report ^1H-NMR spectroscopy with dipolar filters under fast magic angle spinning for probing chain interpenetration of polymer glasses at the molecular level.
基金Supported by the National Basic Research Program of China under Grant No.2007CB815100the National Natural Science Foundation of China under Grant Nos.10775020 and 10935003
文摘The effects of atomic-level rnixing are systemically investigated in a multifluid interpenetration mix model ,and results are compared with the single-fluid model＇s simulations and experimental data. It is shown that increasing the model free parameter α, shock Mach number, and the initial density discontinuity makes the mix length and fraction of mixing particle increase, resulting in the lower shock temperatures compared with the results of single-fluid model without mixing. Recent high-compressibility direct-drive spherical implosions on OMEGA are simulated by the interpenetration mix modal. The calculations with atomic mixing between fuel and shell match quite well with the observations. Without considering any mixing, the calculated neutron yields and ion temperatures are overpredicted; while inclusion of the interpenetration mix model with the adjustable parameter α could fit the simulated neutron yields and ion temperatures well with experimental data.
文摘Two new azo-based coordination compounds with a flexible second ligand, crystal 1 （composed with [Zn（adc）（eda）],-1） and crystal 2 （composed with {[Zn（adc）]0.9568（eda）}n-1＇ and {[Zn（adc）]0.0414},） have been synthe- sized as a couple of isomers with different reaction temperature. Adc2- and eda represent azobenzene-4,4＇-dicar- boxylic ion and 1,2-ethanediamine, respectively. Single crystal X-ray diffraction measurement indicates the inter- penetration of the above crystals could be suppressed by simply tuning the reaction temperature, that is, the 5-fold interpenetration which leads to no free volume left in lower temperature synthesized compound [Zn（adc）（eda）]n-1 could be reduced to a 4-fold interpenetration in higher temperature synthesized {[Zn（adc）]o.9568（eda）},-l＇ which re- sults in free volume accounting for 3.6% （3 1.6 A3 per unit cell volume） in crystal 2. The synthesis, crystal structure and fluorescence spectra of crystals 1 and 2 have been discussed, together with the data of elemental analysis and X-ray powder diffraction.
基金Shenzhen Science and Technology Program(No.RCYX20200714114539243,KCXFZ20211020163818026)the U.S.Department of Energy,Office of Science,Office of Basic Energy Sciences,under Award No.DE-SC0019902.
文摘Hydrogen-bonded organic frameworks(HOFs)are an emerging class of porous materials that hold promise for the adsorptive separation of industrially relevant gas mixtures.However,developing HOFs with high thermal stability and resistance to water remains a daunting challenge.We report here a microporous HOF(HIAM-103)assembled from a hexacarboxylate linker(2,4,6-trimethylbenzene-1,3,5-triylisophthalic acid,H6TMBTI).The compound crystallizes in the trigonal crystal system,and its structure is a four-fold interpenetrated network.Upon thermal activation,the single crystals remain intact,allowing for precise determination of the activated structure.HIAM-103 exhibits remarkable thermal and hydrothermal stability.Its microporous channels demonstrate selective adsorption of C_(2)H_(6)over C_(2)H_(4)and Xe over Kr,and its separation capability toward mixed gases has been validated by column breakthrough experiments under dry and humid conditions.The preferential gas adsorption sites and separation mechanisms have been uncovered through DFT analysis,which suggests that the methyl group decorated 1D channels are the primary reason for the selective adsorption.
文摘Carbon nanotubes(CNTs)reinforced copper(CNTs/Cu)is one of the most promising and extensively researched materials for replacing traditional Cu-based materials in high-load and high-current applications,particularly within the aerospace industry.Amorphous carbon nanotubes(aCNTs)are a type of carbon nanotubes characterized by the presence of mesopores distributed across their amorphous sidewalls,facilitating connectivity between the hollow core and the external environment.Therefore,we propose utilizing aCNTs as a reinforcing agent for Cu.The mesoporous structure of aCNTs facilitates the interpenetration of Cu into the aCNTs,thereby maintaining the continuity of the matrix properties.Experimental results demonstrate that Cu effectively penetrates the mesoporous sidewalls of aCNTs.Both pure Cu and aCNTs-reinforced Cu exhibit comparable electrical conductivity,while the hardness of the aCNTs/Cu composite is significantly enhanced.Additionally,both the density and porosity of aCNTs/Cu are lower than those of pure Cu,and the introduction of aCNTs helps to reduce the sintering temperature.
基金supported by the National Natural Science Foundation of China(NSFC)(Nos.52322105,52321001,52130002,U22A20114,and 52371084)the Youth Innovation Promotion Association CAS(No.2021192)+1 种基金the IMR Innovation Fund(No.2023-ZD01)the IMR Outstanding Scholar Position(No.E451A804).
文摘Matter conductivities are crucial physical properties that directly determine the engineering application value of materials.In reality,the majority of materials are multiphase composites.However,there is currently a lack of theoretical models to accurately predict the conductivities of composite materials.In this study,we develop a unified mixed conductivity(UMC)model,achieving unity in three aspects:(1)a unified description and prediction for different conductivities,including elastic modulus,thermal conductivity,electrical conductivity,magnetic permeability,liquid permeability coefficient,and gas diffusion coefficient;(2)a unified-form governing equation for mixed conductivities of various composite structures,conforming to the Riccati equation;(3)a unified-form composite structure,i.e.,a three-dimensional multiphase interpenetrating cuboid structure,encompassing over a dozen of typical composite structures as its specific cases.The UMC model is applicable for predicting the conductivity across six different types of physical fields and over a dozen different composite structures,providing a broad range of applications.Therefore,the current study deepens our understanding of the conduction phenomena and offers a powerful theoretical tool for predicting the conductivities of composite materials and optimizing their structures,which holds significant scientific and engineering implications.
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2022YFA1603200 and 2022YFA1603204)the Fund from the Chinese Academy of Sciences Youth Interdisciplinary Team(Grant No.JCTD2022-05)+1 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences,the National Natural Science Foundation of China(Grant Nos.11873061 and 12473099)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDA25030500,XDA25010100,and XDA25030200)。
文摘Weibel instability is a promising candidate mechanism for collisionless shock formation in astrophysical systems.Capturing the underlying physics of Weibel instability will help us to understand the astrophysical shock formation,magnetic field generation and amplification,particle acceleration,and so on.Laboratory astrophysics,provides a new way to study these microphysics in controlled conditions.At Shenguang-Ⅱlaser facility,the interpenetrating plasma flows are generated by eight laser beams irradiating a pair of opposing foils to mimic the supernova explosion and the ejecta sweeping up the surrounding medium.Evolution of collisionless interpenetrating plasma flows is observed using optical diagnostics.Filamentary structures appear in the interaction region and the associated magnetic strength is measured about 40 T.Theoretical analysis and simulations indicate that these characteristics are induced by nonlinear Weibel instability.
基金financially supported by the National Natural Science Foundation of China(Nos.22272118,22172111,21905207,and 22309134)the Science and Technology Commission of Shanghai Municipality(Nos.22ZR1464100,20ZR1460300,and 19DZ2271500)+3 种基金China Postdoctoral Science Foundation(No.2022M712402)Shanghai Rising-Star Program(No.23YF1449200)Zhejiang Provincial Science and Technology Project(No.2022C01182)the Fundamental Research Funds for the Central Universities(Nos.22120210529 and 2023-3-YB-07)。
文摘Customized design of well-defined cathode structures with abundant adsorption sites and rapid diffusion dynamics,holds great promise in filling capacity gap of carbonaceous cathodes towards high-performance Zn-ion hybrid supercapacitors(ZHC).Herein,we fabricate a series of dynamics-oriented hierarchical porous carbons derived from the unique organic-inorganic interpenetrating polymer networks.The interpenetrating polymer networks are obtained through physically knitting polyferric chloride(PFC)network into the highly crosslinked resorcinol-formaldehyde(RF)network.Instead of covalent bonding,physical interpenetrating force in such RF-PFC networks efficiently relieves the RF skeleton shrinkage upon pyrolysis.Meanwhile,the in-situ PFC network sacrifices as a structure-directing agent to suppress the macrophase separation,and correspondingly 3D hierarchical porous structure with plentiful ion-diffusion channels(pore volume of 1.35 cm^(3)/g)is generated in the representative HPC_(4) via nanospace occupation and swelling effect.Further removal of Fe fillers leaves behind a large accessible specific surface area of 1550 m^(2)/g for enhanced Zn-ion adsorption.When used as the cathode for ZHC,HPC_(4) demonstrates a remarkable electrochemical performance with a specific capacity of 215.1 mAh/g at 0.5 A/g and a high Zn^(2+)ion diffusion coefficient of 11.1×10^(-18)cm^(2)/s.The ZHC device yields 117.0 Wh/kg energy output at a power density of 272.1 W/kg,coupled with good cycle lifespan(100,000 cycles@10 A/g).This work inspires innovative insights to accelerate Zn diffusion dynamics by structure elaboration towards high-capacity cathode materials.
基金supported by the National Key Research and Development Program of China(No.2022YFB3708400)the National Natural Science Foundation of China(No.52305158)+1 种基金the Young Elite Scientists Sponsorship Program by CAST(No.2022QNRC001)the Science Innovation Foundation of Shanghai Academy of Spaceflight Technology(No.USCAST2021-18).
文摘Mg alloys have the defects of low stiffness,low strength,and high coefficient of thermal expansion(CTE).The composites strategy and its architecture design are effective approaches to improve the comprehensive performance of materials,but the processing difficulty,especially in ceramics forming,limits the control and innovation of material architecture.Here,combined with 3D printing and squeeze infiltration technology,two precisely controllable architectures of AZ91/Al_(2)O_(3)interpenetrating phase composites(IPC)with ceramic scaffold were prepared.The interface,properties and impact of different architecture on IPC performance were studied by experiments and finite element simulation.The metallurgical bonding of the interface was realized with the formation of MgAl_(2)O_(4)reaction layer.The IPC with 1 mm circular hole scaffold(1C-IPC)exhibited significantly improved elastic modulus of 164 GPa,high compressive strength of 680 MPa,and good CTE of 12.91×10^(-6)K^(−1),which were 3.64 times,1.98 times and 55%of the Mg matrix,respectively.Their elastic modulus,compressive strength,and CTE were superior to the vast majority of Mg alloys and Mg based composites.The reinforcement and matrix were bicontinuous and interpenetrating each other,which played a critical role in ensuring the potent strengthening effect of the Al_(2)O_(3)reinforcement by efficient load transfer.Under the same volume fraction of reinforcements,compared to IPC with 1 mm hexagonal hole scaffold(1H-IPC),the elastic modulus and compressive strength of 1C-IPC increased by 15%and 28%,respectively,which was due to the reduced stress concentration and more uniform stress distribution of 1C-IPC.It shows great potential of architecture design in improving the performance of composites.This study provides architectural design strategy and feasible preparation method for the development of high performance materials.
文摘This paper shows a didactic model (PGM), and not only, but representative of the Hadrons described in the Standard Model (SM). In this model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (IQuO). By the properties of IQuO one can define the electric charge and that of color of quarks. Showing the “aurea” (golden) triangular shape of all quarks, we manage to represent the geometric combinations of the nucleons, light mesons, and K-mesons. By the geometric shape of W-bosons, we represent the weak decay of pions and charged Kaons and neutral, highlighting in geometric terms the possibilities of decay in two and three pions of neutral Kaon and the transition to anti-Kaon. In conclusion, from this didactic representation, an in-depth and exhaustive phenomenology of hadrons emerges, which even manages to resolve some problematic aspects of the SM.
文摘This work shows a didactic model representative of the quarks described in the Standard Model (SM). In the model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (GMP). From these didactic hypotheses emerges an in-depth phenomenology of particles (quarks) fully compatible with that of SM, showing, besides, that the number of possible quarks is six.
基金financially supported by the National Natural Science Foundation of China(No.52275310)the Open Project of State Key Laboratory of Explosion Science and Technology(No.QNKT22-15)the BIT Research and Innovation Promoting Project(No.2022YCX020)。
文摘Benefiting from excellent mechanical properties and low density,cellular ceramic structures(CCSs)are competitive candidates as structural components.However,inherent brittleness from strong chemical bonds among atoms extremely impeded CCSs'application.Natural materials occupied outstanding strength and toughness simultaneously due to the dual-phase interpenetrated structure.Inspired by natural materials,it was proposed to fabricate coating covered and fulfilled polyurea/CCS interpenetrated composites(C/CCSs and B/CCSs)to circumvent the brittleness of 3D-printed Al_(2)O_(3)CCSs.It was demonstrated that polyurea coating had less effect on the compressive strength of C/CCSs but tremendously improved their energy-absorbing ability.The energy-absorbing ability of C/CCSs was improved from26.48-52.57 kJ·m^(-3)of CCSs to 1.04-1.89 MJ·m^(-3)because of the extended plateau stage.Furthermore,compressive strength and energy-absorbing ability of B/CCSs were strengthened to 1.33-1.36 and 2.84-4.61 times of C/CCSs,respectively.Besides,failure mode of C/CCSs changed from localized deformation to fracturing entirely with the increase in relative density of CCSs inside,which was the same as that of CCSs.However,with the help of polyurea coating,C/CCSs were still intact at strains up to60%,which would neve r fail catastrophically as CCSs at low strains.B/CCSs tended to fracture as a whole,which was not influenced by relative density of pristine CCSs.It was believed that this work provided a creative way to circumvent the brittleness of CCSs and improve their mechanical performances.
基金Supported by the Natural Science Foundation of Henan Province (No. 102300410021 and 102300410093)
文摘The title coordination polymer including two crystallographically independent Co2＋ ions is hydrothermally synthesized, in which the Co（1） 2＋ ion is four-coordinated by two carboxylate oxygen atoms from two different 5-（benzoic acid-4-yldiazenyl）isophthalate （byip3-） anions and two nitrogen atoms from two distinct 1,4-bis（imidazol-1-ylmethyl） benzene （bix） ligands displaying a tetrahedral geometry. The Co（2） 2＋ ion is six-coordinated by two water molecules at the apical positions, and two carboxylate oxygen atoms and two nitrogen atoms at the equatorial positions, affording a slightly distorted octahedron. Two Co（1）2＋ and two Co（2）2＋ ions are linked together by four byip3- anions forming a 44-membered motif and these motifs are further arranged into a three-dimensional framework through bix ligands along the a axis with a larger channel （ca. 22.70×11.01）. Each individual network interpenetrates with the other identical network in a parallel fashion to generate a 2-fold interpenetrating array with the {62.84}{63}2{64.82}2 topology.
基金Supported by the Natural Science Foundation of Henan Province(No.092300410119 and 102300410093)
文摘A three-dimensional coordination polymer,[Ni（Hbyip2-）（bix）0.5（H2O）]n,has been hydrothermally synthesized.Each Ni2＋ ion is five-coordinated by three carboxylate O atoms from three different 5-（benzoic acid-4-yldiazenyl）isophthalate（Hbyip2-） anions,one N atom from one 1,4-bis（imidazol-1-ylmethyl）benzene（bix） ligand and one O atom from an aqua ligand displaying a distorted square-pyramid.Each Ni atom is defined by three Hbyip2-anions and each Hbyip2-anion adopts a tris（mono-dentate） ligand coordinating to three Ni2＋ ions affording a 36-membered inorganic ring.These rings are further arranged into an undulated two-dimensional layer parallel to the（101） plane.Adjacent two-dimensional networks are linked by bix ligands into a three-dimensional {63,83}{63} framework with a large channel（ca.26.3 × 13.6） along the [100] direction.Each individual {63,83}{63} network interpenetrates with two others in a parallel fashion to generate a 3-fold interpenetrating network.
基金supported by the grants from Guangdong University of Petrochemical Technology
文摘A new Co（Ⅱ）-based coordination polymer, namely [Co（L）0.5（4,4?-bipy）0.5（H2 O）2]n（1,H4 L = 1,3-di（3?,5?-dicarboxylphenyl）benzene, 4,4?-bipy = 4,4?-bipyridine）, has been hydrothermally synthesized using the mixed-ligands self-assembly strategy and further fully characterized. The crystal structure is of monoclinic, space group C2/c with a = 18.9124（10）, b = 11.6150（5）, c =15.4380（6） ?, β = 110.989（5）°, V = 3166.2（2） ?3, C16 H13 CoNO6, Mr = 374.20, Z = 8, Dc = 1.570 g·cm–3, F（000） = 1496, μ = 1.116 mm–1, R = 0.0461 and wR = 0.1312 for 2328 observed reflections（I > 2s（I））. The crystal structure analysis revealed that 1 is a 4-fold interpenetrated three-dimensional（3D） framework with（3,4）-connected dmd-type topology. Moreover, the thermal stability and magnetic property of 1 were also investigated.
基金Supported by the National Natural Science Foundation of China(21271035)the Natural Science Foundation of Anhui Province(KJ2016A512)the Key Projects of Anhui Province University Outstanding Youth Talent Support Program(gxyqZD2016372)
文摘Two new 2 D → 2 D zinc(II) coordination polymers, [Zn(btre)0.5(nbdc)(H2 O)]n(1) and {[Zn(btre)0.5(Me Oip)(H2 O)2]·H2 O}n(2)(btre = 1,2-bis(1,2,4-triazol-4-yl)ethane, nbdc=3-nitro-1, 2-benzenedicarboxylate, Me Oip=4-methoxybenzene-1, 3-dicarboxylate) were synthesized at room temperature condition and characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffractions. Three sets of equivalent 2 D(6, 3) networks parallel polycatenated with each other to give a 2 D → 2 D network in 1 and 2. There are strong π-π interactions and hydrogen bonding interactions between adjacent parallel polycatenated 2 D(6, 3) network in 1. Only hydrogen bonding interactions exist in 2. Thermal stabilities and luminescence of 1 and 2 were investigated.
文摘Highlighting a golden triangular form in <em>u</em> and <em>d </em>quarks (Quark Geometric Model), we build the geometric structures of light meson <em>η</em> and individualize its decays and spin. By the structure equations describing mesons, we determine a mathematic procedure to calculate the theoretical value of the mass of light mesons <em>η</em>.
文摘In previous articles (Guido) we demonstrated that Quarks (u, d) are represented by golden geometric structures of coupled quantum oscillators. In this article we show the geometric structure of the pion triplet and, in particular, via the structure equation of neutral pion, we identify its decays and we solve the spin question in hadrons thanks also to introduction of algebraic operations [?, ⊕] on geometric structure. Moreover by means of the golden ratio between (u, d), we determine the values of bare masses of quarks (3.51 MeV for u-quark and 5.67 MeV for d-quark) and those ones bounded in a pion (53.31 MeV for u-quark and 85.26 MeV for d-quark). Finally, using algebraic operations [?, ⊕] we point out a new way to represent the processes of pions’ decay.
