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On-line monitoring of dissolved gas-in-oil with FTIR spectra 被引量:1
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作者 XianyongLiu YunluoLiu LiYue 《Journal of University of Science and Technology Beijing》 CSCD 2003年第4期65-68,共4页
To overcome the disadvantages of conventional DGA (dissolved gas-in-oil)analysis using gas chromatography and other electrochemical sensors, initial researches werecompleted to realize on-line monitoring of dissolved ... To overcome the disadvantages of conventional DGA (dissolved gas-in-oil)analysis using gas chromatography and other electrochemical sensors, initial researches werecompleted to realize on-line monitoring of dissolved gas-in-oil of power transformers using FTIR(Fourier Transform InfraRed) spectroscopy. Gas cell method is used to determine the characteristicabsorption peaks of each diagnostic gas; simple and novel devices and procedures were designed inorder to get measurable samples and spectra of mixed diagnostic gases with known concentration aretaken using long optical path gas cell. The range of wavelength is estimated to be 3.0-13.9 mum fromexperimental spectra data. Hence the corresponding sampling frequency range should be in 536-4288Hz and usable optical materials are suggested. It is concluded that a resolution of 10 cm^(-1) maywell satisfy the monitoring of all diagnostic gases and water content except hydrogen, and thelowest detection limit may be as low as 2Xl0^(-8) to acetylene with a 2.4-meter-long optical length. 展开更多
关键词 FTIR power transformer dissolved gas-in-oil on-line monitoring infraredspectra
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苄基硫代半卡巴腙的IR及1HNMR
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作者 江炎兰 梁小蕊 吴世永 《光谱实验室》 CAS 2013年第5期2188-2191,共4页
采用Gaussian09软件,用密度泛函理论的B3LYP方法,在6-31G基组水平上优化了苄基硫代半卡巴腙的分子结构,得到了其稳定构型及其能量。在优化结构的基础上用Hartr ee-Fock(HF)/6-31G方法计算了该分子的红外光谱振动频率并绘制了红外光谱图... 采用Gaussian09软件,用密度泛函理论的B3LYP方法,在6-31G基组水平上优化了苄基硫代半卡巴腙的分子结构,得到了其稳定构型及其能量。在优化结构的基础上用Hartr ee-Fock(HF)/6-31G方法计算了该分子的红外光谱振动频率并绘制了红外光谱图,对图中各峰位进行了分析探讨,用同样的方法计算了该分子的核磁共振氢谱。 展开更多
关键词 苄基硫代半卡巴腙 红外光谱 核磁共振氢谱
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