The 3d34p, 3d35p and 3d24s4p odd configurations of the V II spectrum have been reanalysed and three 3d24s4p triplets are assigned higher energies than previously proposed. We have determined the fine structure paramet...The 3d34p, 3d35p and 3d24s4p odd configurations of the V II spectrum have been reanalysed and three 3d24s4p triplets are assigned higher energies than previously proposed. We have determined the fine structure parameters, the largest and next largest eigenvector percentages of levels, their calculated Landé gJ-factors and predicted positions for missing experimental levels up to 100,000 cm-1 for the 3d24s4p configuration. Furthermore for the first time a hyperfine structure (HFS) parametric treatment, involving levels of these two configurations has been carried out. The deduced single-electron HFS parameter values are successfully checked with those obtained by means of ab initio calculations.展开更多
Using a linked-parameter technique of level-fitting calculations in a multi configuration basis, a parametric analysis of fine structure (fs) for even-parity levels of V II, involving six configurations, has been perf...Using a linked-parameter technique of level-fitting calculations in a multi configuration basis, a parametric analysis of fine structure (fs) for even-parity levels of V II, involving six configurations, has been performed. This led us to exchange the assignments of two triplets, 3d3(2F)4s c 3F and 3d4 d 3F, reported in earlier analyses as being located at 30,300 cm-1 and 30,600 cm-1, respectively. This is confirmed by experimental hyperfine structure (hfs) A constants, used as fingerprints. Moreover, the current singlet 3d24s2 1D2 position is likely too high. The fs parameters, magnetic Landé g-factors, and the percentage of leading eigenvectors of levels are calculated. We present also predicted singlet, triplet and quintet positions for missing experimental levels up to 100,000 cm-1. The single-electron hfs parameters are determined in their entirety for 51V II for the model space (3d + 4s)4 with good accuracy. For the model space (3d + 4s)4 of 51V II the single-electron hfs parameters are computed;furthermore, our achieved theoretical evaluations of the single-electron hfs parameters, thanks to the use of ab initio calculations, reinforce the validity of these hfs parameter values, deduced from experimental data.展开更多
<strong>Background:</strong> Since bleedings in surgery are infrequent and inexperienced, we always try to proceed with surgery assuming a crisis situation, adhere to routine procedures and its standardiza...<strong>Background:</strong> Since bleedings in surgery are infrequent and inexperienced, we always try to proceed with surgery assuming a crisis situation, adhere to routine procedures and its standardization. We focus on the bleeding accidents and reveal how to implement a resilient healthcare theory. By clarifying the Safety-I and Safety-II, we developed a system to support surgical safety based on the surgeon’s individual, team, and organization. <strong>Material and Methods:</strong> We searched 25 cases of bleeding incidents in thoracic surgery, which were obtained from the database of the Project to Collect Medical Near-Miss/Adverse Event Information of the Japan Council of Quality Health Care in April 2018. Retrospectively, we analyzed 13 hemorrhage cases in our department between July 2002 and March 2020. We studied their surgical factors such as procedures, sites and causes of bleeding, response, treatment, and outcomes. <strong>Results:</strong> The causes of bleeding included damage of the adhesion detachment, insertions of automatic sutures and forceps, detachment of ultrasonic scalpel, vascular taping, removal of resected lung, lymph node dissection, exfoliation of the infiltrated adventitia of vessels, pull-out of vessel, gauze attachment with staple cut-line of vessel, thoracoscopic collision, infectious vascular rupture, detachment of vascular ligature, and suction tube hit. We summarized the variation in the usual controllable and unexpected uncontrollable bleeding and learned how to respond and treat them. We built up the balanced combination of Safety-I and Safety-II in the daily routine work in normal surgery, the patient’s individual factors, the massive bleeding, and its life-threatening crisis. <strong>Conclusions:</strong> We can learn how to prevent and respond to bleeding accidents by developing a system to support surgical safety (Safety-I and Safety-II). We can flexibly respond to unexpected bleeding disturbances under constraints by adjusting the surgeon’s individuals, team, and organization.展开更多
Objective: To find out whether 14 16 year old reading and writing impaired pu pils have atypical EEG activation patterns during reading. Methods: EEG correlat ion indices (EEGCIs), based on the waveform characteristic...Objective: To find out whether 14 16 year old reading and writing impaired pu pils have atypical EEG activation patterns during reading. Methods: EEG correlat ion indices (EEGCIs), based on the waveform characteristics of twoEEG signals, w ere used as measurers of slow joint activation of cortical regions during readin g in pupils with reading and writing impairment. Results: Reading was associated with high EEGCIs within the right hemisphere in reading and writing impaired pu pils. The finding is analogous to the results of an earlier study [Byring, Elec t roencephalogr. Clin. Neurophysiol. 63 (1986) 1] in boys with spelling disabilit i es. The activation in the right hemisphere might represent a compensation for a left hemisphere dysfunction in pupils with reading and writing impairment during reading, as suggested by a number of functional neuroimaging studies. T his interpretation was corroborated by high EEGCIs especially in those impaired pupils who had a good occupational outcome. Conclusions: EEGCIs during reading a re high within the right hemisphere in pupils with reading and writing impairmen t. Significance: High EEGCIs within the right hemisphere during reading might be considered neurophysiological markers for reading and writing impairment.展开更多
Dynamic mixed-mode I/II crack growth under various engineering disturbances can result in rock failure and even catastrophic events.Nevertheless,the dynamic cracking behaviour of rock and fracture criterion for mixed-...Dynamic mixed-mode I/II crack growth under various engineering disturbances can result in rock failure and even catastrophic events.Nevertheless,the dynamic cracking behaviour of rock and fracture criterion for mixed-mode I/II remain poorly understood.Cracked straight-through Brazilian disc tests were performed on sandstone specimens to examine the effects of strain rate(ε˙)and loading angle(β)on the dynamic fracture behaviour of mixed-mode I/II using a split Hopkinson pressure bar system.The generalized maximum tangential stress(GMTS)criterion was modified by considering the influence ofβand crack propagation velocity(CPV)to estimate the dynamic fracture parameters.The results indicate that the CPV increases with increasingε˙,while remaining nearly independent ofβ.βandε˙strongly affect the dynamic mixed-mode fracturing process.The crack initiation angle changes slightly with increasingε˙,and it first increases and then stabilizes asβincreases.Whenβexceeds 60°andε˙is lower than approximately 10^(2)s^(−1),the crack initiation location transitions from the crack tip to the centre region of the crack.Whenε˙is greater than approximately 10^(2)s^(−1),the non-tip cracking disappears gradually.The dynamic failure characteristics of specimens can be divided into four main types,which occur successively with increasingβandε˙.Additionally,the dynamic stress intensity factors and crack initiation angles predicted by the modified GMTS criterion are generally consistent with the experimental results for different CPVs.This study provides valuable insights into the detailed dynamic mixed-mode cracking behaviour and fracture criterion of rock.展开更多
文摘The 3d34p, 3d35p and 3d24s4p odd configurations of the V II spectrum have been reanalysed and three 3d24s4p triplets are assigned higher energies than previously proposed. We have determined the fine structure parameters, the largest and next largest eigenvector percentages of levels, their calculated Landé gJ-factors and predicted positions for missing experimental levels up to 100,000 cm-1 for the 3d24s4p configuration. Furthermore for the first time a hyperfine structure (HFS) parametric treatment, involving levels of these two configurations has been carried out. The deduced single-electron HFS parameter values are successfully checked with those obtained by means of ab initio calculations.
文摘Using a linked-parameter technique of level-fitting calculations in a multi configuration basis, a parametric analysis of fine structure (fs) for even-parity levels of V II, involving six configurations, has been performed. This led us to exchange the assignments of two triplets, 3d3(2F)4s c 3F and 3d4 d 3F, reported in earlier analyses as being located at 30,300 cm-1 and 30,600 cm-1, respectively. This is confirmed by experimental hyperfine structure (hfs) A constants, used as fingerprints. Moreover, the current singlet 3d24s2 1D2 position is likely too high. The fs parameters, magnetic Landé g-factors, and the percentage of leading eigenvectors of levels are calculated. We present also predicted singlet, triplet and quintet positions for missing experimental levels up to 100,000 cm-1. The single-electron hfs parameters are determined in their entirety for 51V II for the model space (3d + 4s)4 with good accuracy. For the model space (3d + 4s)4 of 51V II the single-electron hfs parameters are computed;furthermore, our achieved theoretical evaluations of the single-electron hfs parameters, thanks to the use of ab initio calculations, reinforce the validity of these hfs parameter values, deduced from experimental data.
文摘<strong>Background:</strong> Since bleedings in surgery are infrequent and inexperienced, we always try to proceed with surgery assuming a crisis situation, adhere to routine procedures and its standardization. We focus on the bleeding accidents and reveal how to implement a resilient healthcare theory. By clarifying the Safety-I and Safety-II, we developed a system to support surgical safety based on the surgeon’s individual, team, and organization. <strong>Material and Methods:</strong> We searched 25 cases of bleeding incidents in thoracic surgery, which were obtained from the database of the Project to Collect Medical Near-Miss/Adverse Event Information of the Japan Council of Quality Health Care in April 2018. Retrospectively, we analyzed 13 hemorrhage cases in our department between July 2002 and March 2020. We studied their surgical factors such as procedures, sites and causes of bleeding, response, treatment, and outcomes. <strong>Results:</strong> The causes of bleeding included damage of the adhesion detachment, insertions of automatic sutures and forceps, detachment of ultrasonic scalpel, vascular taping, removal of resected lung, lymph node dissection, exfoliation of the infiltrated adventitia of vessels, pull-out of vessel, gauze attachment with staple cut-line of vessel, thoracoscopic collision, infectious vascular rupture, detachment of vascular ligature, and suction tube hit. We summarized the variation in the usual controllable and unexpected uncontrollable bleeding and learned how to respond and treat them. We built up the balanced combination of Safety-I and Safety-II in the daily routine work in normal surgery, the patient’s individual factors, the massive bleeding, and its life-threatening crisis. <strong>Conclusions:</strong> We can learn how to prevent and respond to bleeding accidents by developing a system to support surgical safety (Safety-I and Safety-II). We can flexibly respond to unexpected bleeding disturbances under constraints by adjusting the surgeon’s individuals, team, and organization.
文摘Objective: To find out whether 14 16 year old reading and writing impaired pu pils have atypical EEG activation patterns during reading. Methods: EEG correlat ion indices (EEGCIs), based on the waveform characteristics of twoEEG signals, w ere used as measurers of slow joint activation of cortical regions during readin g in pupils with reading and writing impairment. Results: Reading was associated with high EEGCIs within the right hemisphere in reading and writing impaired pu pils. The finding is analogous to the results of an earlier study [Byring, Elec t roencephalogr. Clin. Neurophysiol. 63 (1986) 1] in boys with spelling disabilit i es. The activation in the right hemisphere might represent a compensation for a left hemisphere dysfunction in pupils with reading and writing impairment during reading, as suggested by a number of functional neuroimaging studies. T his interpretation was corroborated by high EEGCIs especially in those impaired pupils who had a good occupational outcome. Conclusions: EEGCIs during reading a re high within the right hemisphere in pupils with reading and writing impairmen t. Significance: High EEGCIs within the right hemisphere during reading might be considered neurophysiological markers for reading and writing impairment.
基金funded by the National Natural Science Foundation of China(Grant Nos.52325404 and 52504094)Shenzhen University 2035 Initiative(Grant No.2022B001).
文摘Dynamic mixed-mode I/II crack growth under various engineering disturbances can result in rock failure and even catastrophic events.Nevertheless,the dynamic cracking behaviour of rock and fracture criterion for mixed-mode I/II remain poorly understood.Cracked straight-through Brazilian disc tests were performed on sandstone specimens to examine the effects of strain rate(ε˙)and loading angle(β)on the dynamic fracture behaviour of mixed-mode I/II using a split Hopkinson pressure bar system.The generalized maximum tangential stress(GMTS)criterion was modified by considering the influence ofβand crack propagation velocity(CPV)to estimate the dynamic fracture parameters.The results indicate that the CPV increases with increasingε˙,while remaining nearly independent ofβ.βandε˙strongly affect the dynamic mixed-mode fracturing process.The crack initiation angle changes slightly with increasingε˙,and it first increases and then stabilizes asβincreases.Whenβexceeds 60°andε˙is lower than approximately 10^(2)s^(−1),the crack initiation location transitions from the crack tip to the centre region of the crack.Whenε˙is greater than approximately 10^(2)s^(−1),the non-tip cracking disappears gradually.The dynamic failure characteristics of specimens can be divided into four main types,which occur successively with increasingβandε˙.Additionally,the dynamic stress intensity factors and crack initiation angles predicted by the modified GMTS criterion are generally consistent with the experimental results for different CPVs.This study provides valuable insights into the detailed dynamic mixed-mode cracking behaviour and fracture criterion of rock.
