The dissolved organic matter(DOM)with high mobility and reactivity plays a crucial role in soil.In this study,the characteristics and phytotoxicity ofDOMreleased fromthe hydrochars prepared from different feedstocks(c...The dissolved organic matter(DOM)with high mobility and reactivity plays a crucial role in soil.In this study,the characteristics and phytotoxicity ofDOMreleased fromthe hydrochars prepared from different feedstocks(cowmanure,corn stalk and Myriophyllum aquaticum)under three hydrothermal carbonization(HTC)temperatures(180,200 and 220°C)were evaluated.The results showed that the hydrochars had high dissolved organic carbon content(20.15 to 37.65 mg/g)and its content showed a gradual reduction as HTC temperature increased.Three fluorescent components including mixed substance of fulvic acid-like and humic acid-like substances(C1,30.92%-58.32%),UVA humic acid-like substance(C2,25.27%-29.94%)and protein-like substance(C3,11.74%-41.92%)were identified in hydrochar DOM by excitation emission matrix spectra coupled with parallel factor analysis.High HTC temperature increased the relative proportion of aromatic substances(C1+C2)and humification degree of hydrochar DOM from cow manure,while it presented adverse effects on the hydrochar DOM from corn stalk and Myriophyllum.aquaticum.The principal component analysis suggested that feedstock type and HTC temperature posed significant effects on the characteristics of hydrochar DOM.Additionally,seed germination test of all hydrochar DOM demonstrated that the root length was reduced by 8.88%-26.43%in contrast with control,and the germination index values were 73.57%-91.12%.These findings provided new insights into the potential environmental effects for hydrochar application in soil.展开更多
The copper complexing of dissolved organic matter released from hydrochar(HDOM)affects the former’s environmental behavior.In this study,how hydrothermal temperatures(180,220 and 260℃)influence the molecular-level c...The copper complexing of dissolved organic matter released from hydrochar(HDOM)affects the former’s environmental behavior.In this study,how hydrothermal temperatures(180,220 and 260℃)influence the molecular-level constitutions and Cu(II)binding features of HDOM were elucidated via fourier transform ion cyclotron resonance mass spectrometry and multi-spectroscopic analysis.The findings demonstrated that the almost HDOM molecules had the traits of lower polarity and higher hydrophobicity.As the hydrothermal temperature increased,the molecules with particularly high relative strength gradually disappeared,average molecular weight,percentages of CHON and aliphatic compounds of HDOM reduced while the percentages of CHO and aromatic compounds increased.In general,the fluorescence quenching of Cu(II)weakened as hydrothermal temperature rose and the Cu(II)binding stability constants of fluorophores in HDOM were 4.50–5.31.In addition,the Cu(II) binding order of fluorophores in HDOM showed temperature heterogeneities, andpolysaccharides or aromatic rings of non-fluorescent substances had the fastest responsesto Cu(II) binding. Generally, fluorescent components tend to bind Cu(II) at relatively traceconcentrations (0–40 μmol/L), whereas non-fluorescent substances tend to the bind Cu(II)at relatively higher concentrations (50–100 μmol/L). This study contributed to the predictionof the potential environmental behaviors and risks of Cu(II) at the molecular level afterhydrochar application.展开更多
The effectiveness of using vegetation to stabilise shallow soil slopes heavily depends on the survival of vegetation,yet the amplification of extreme events induced by climate change threatens the health of plants cov...The effectiveness of using vegetation to stabilise shallow soil slopes heavily depends on the survival of vegetation,yet the amplification of extreme events induced by climate change threatens the health of plants covering slopes.Hydrochar is an environmentally friendly soil amender that can achieve the potential benefits of promoting plant growth for slope stabilisation and facilitation of waste upcycling.The mechanism underlying the hydrochar effects on the mechanical behaviour of unsaturated soils remains unclear.This study investigated the influence of grass-derived hydrochar on the water retention,compressibility,and shear strength of a compacted siltyeclay sand.Soil microstructural changes due to hydrochar amendment were measured to explain the soilehydrochar hydromechanical interaction.The increase in suction resulted in a less significant increase in yield stress and a negligible reduction in compressibility of the hydrochar-amended soil compared with the unamended case.This phenomenon was observed because hydrochar addition reduced the large pores with diameters greater than the macropore peak of 60 mm due to pore filling by hydrochar particles,resulting in a less substantial volume contraction during drying.Hydrochar introduced more significant effects on the soil’s shear strength in an unsaturated state compared to a saturated case.Despite the similarity of the unsaturated amended soil with the critical-state friction angle to the saturated case,the former exhibited a greater shear strength because the hydrochar addition improved water retention capability.As a result,the degree of saturation and,hence,Bishop’s effective stress were higher than those for the unamended case for a given suction.展开更多
Innovative measure is a urgent requirement for managing the huge volume of municipal sewage sludge. The hydrothermal carbonation （HTC） shows some potential advantages for using hydrochar as a soil conditioner. The a...Innovative measure is a urgent requirement for managing the huge volume of municipal sewage sludge. The hydrothermal carbonation （HTC） shows some potential advantages for using hydrochar as a soil conditioner. The aim of this work was to investigate the properties of hydrochars, by means of the HTC of municipal sewage sludge under different temperatures （190 and 260~C） and reaction hours （1, 6, 12, 18 and 24 h）. The HTC led to the decreases of N, O and H contents by more than 54.6, 37.9 and 10.0%, respectively, and slight changes of C content. The Py-GC-MS analysis showed that a large proportion of fatty acids, in particular hexadecanoic acid, transferred into alkenes, olefins and aromatic compounds. The 13C-NMR and fourier transform infrared spectra （FTIR） confirmed the transformation and changes in chemical structure in which hydrochar contained lower oxygen-containing organic C of O-alkyl, carboxylic and carbonyl C and aliphaticity, but higher aromatic C and aromaticity. The rich hydrophobic functions induced in high positive charges in the charred sludge. The HTC facilitated the pore structure development, proved by higher specific surface area and specific pore volume, with a maximum of 17.30 and 0.83 cm^3 g^-1, respectively. The availabilities of N, P and K markedly reduced during HTC treatment. The activities of most heavy metals were depressed though they accumulated in the hydrochar. Further work is required to investigate the values and risk of the charred sludge amended to soil.展开更多
In this paper,a novel compound was developed by mixing H_(3)PO_(4)-modified cauliflower leaves hydrochar(CLH)and coal gangue-based Na-X zeolite(ZL).An alkaline soil contaminated with cadmium(Cd)and lead(Pb)was amended...In this paper,a novel compound was developed by mixing H_(3)PO_(4)-modified cauliflower leaves hydrochar(CLH)and coal gangue-based Na-X zeolite(ZL).An alkaline soil contaminated with cadmium(Cd)and lead(Pb)was amended through the individual and synergistic application of CLH and ZL(1%CLH,2%CLH,1%ZL,2%ZL and 1%CLH+1%ZL),and Chinese cabbage was grown on it.Individual application of CLH was superior to ZL on decreasing the pH of alkaline soil and increasing soil available phosphorus(Olsen-P)and soil organic matter(SOM).In contrast,their combined application significantly improved the soil cation exchange capacity(CEC).Besides,the 1%CLH+1%ZL was the most efficient treatment in decreasing diethylenetriamine pentaacetate(DTPA)-extractable Cd/Pb and concentrations of these two metals in cabbage root and shoot.Their synergistic application could better increase Cd and Pb immobilization and cabbage yield than their alone application.Furthermore,the immobilization of Pb for all treatments was higher than that of Cd.The synergistic immobilization mechanism of CLH and ZL reflected that the CLH precipitated and complexed with these two metals,which may block the pores of hydrochar or wrap on the surface of hydrochar.So the continuous adsorption and complexation were prevented.Nevertheless,ZL could probably alleviate this obstacle.This finding provides helpful information about using CLH combined with ZL as a soil stabilizer to immobilize heavy metals in contaminated alkaline soil.展开更多
A rising global population and aspirational higher living standards has driven a step change in resource utilization and concomitant anthropogenic pollution across the biosphere.Low-cost and scalable technologies for ...A rising global population and aspirational higher living standards has driven a step change in resource utilization and concomitant anthropogenic pollution across the biosphere.Low-cost and scalable technologies for environmental remediation are therefore urgently sought,with an emphasis on trash-to-treasure strategies that exploit abundant but underutilized waste by-products of existing sectors.Biochars are carbon-rich,porous solids produced by biomass pyrolysis under anaerobic or oxygen-scarce conditions at high temperature(350–700°C),while hydrochars are produced by hydrothermal biomass carbonization at lower temperature(130–250°C)and high autogenous pressures(0.3–4.0 MPa).Bio/hydrochars possess unique physicochemical properties,notably high surface areas(100–1500 m2 g-1)and porosity(0.25–2.5 cm^(3)g^(-1))and rich surface chemistry featuring carboxylic,phenolic,hydroxyl,and carbonyl functions,amenable to chemical,physical,or biochemical modification,rendering them ideal sorbents for pollutants such as heavy metals(e.g.As and Cr),and toxic organic(e.g.,dyes and xenobiotics)and inorganic(e.g.,SO_(2))molecules.Bio/hydrochars are attractive for environmental remediation of pollutant mixtures by surface complexation,redox chemistry,electrostatic interactions/ion exchange,or coprecipitation.This review discusses recent opportunities and challenges in creating bio/hydrochar sorbents and their nanocomposites through grafting,doping,and chemical/physical activation,for the depollution of aquatic and atmospheric environments.展开更多
The function-led design of porous hydrochar from mineral-rich biowaste for environmental applications inevitably suffers from carbon-ash recalcitrance.However,a method to alter the original carbon skeleton with ash re...The function-led design of porous hydrochar from mineral-rich biowaste for environmental applications inevitably suffers from carbon-ash recalcitrance.However,a method to alter the original carbon skeleton with ash remains elusive and hinders the availability of hydrochar.Herein,we propose a facile strategy for breaking the rigid structure of carbon-ash coupled hydrochar using phase-tunable molten carbonates.A case system was designed in which livestock manure and NaHCO3 were used to prepare the activated hydrochar,and NH3 served as the target contaminant.Due to the redox effect,we found that organic fractions significantly advanced the melting temperature of Na2CO3 below 800℃.The Na species steadily broke the carbon-ash interaction as the thermal intensity increased and transformed inorganic constituents to facilitate ash dissolution,rebuilding the hydrochar skeleton with abundant hierarchical channels and active defect edges.The surface polarity and mesopore distribution collectively governed the five cycles NH3 adsorption attenuation process.Manure hydrochar delivered favorable potential for application with a maximum overall adsorption capacity of 100.49 mg·g^(-1).Integrated spectroscopic characterization and theoretical computations revealed that incorporating NH3 on the carbon surface could transfer electrons to chemisorbed oxygen,which promoted the oxidation of pyridine-N during adsorption.This work offers deep insight into the structure function correlation of hydrochar and inspires a more rational design of engineered hydrochar from high-ash biowaste.展开更多
The corncob hydrochar is prepared by using a stainless autoclave at 230?C for 8 h.The products are characterized by elemental analyzer,Fourier Transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and scanning ...The corncob hydrochar is prepared by using a stainless autoclave at 230?C for 8 h.The products are characterized by elemental analyzer,Fourier Transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and scanning electron microscope(SEM).The effects of hydrochar dosage,pH,adsorption time and phenol concentration on the adsorption performance of hydrochar are investigated by means of single-factor experimental analysis.Based on the experiments the adsorption thermodynamic and kinetics are tentatively discussed.The results show that abundant oxygen-containing functional groups are scattered on the surface of the corncob hydrochar.The adsorption kinetics of phenol on the hydrochar corresponds well with pseudo-second-order kinetic model.Thermodynamic studies indicate that Freundlich adsorption isotherm model is much better than Langmuir model in describing the adsorption of phenol on the corncob hydrochar at 25?C-45?C.This study provides scientific basis for the development of cheap and efficient adsorbents for the removal of phenols derived from oilfield wastewater.展开更多
Hydrothermal carbonization is highly applicable to high moisture biomass upgrading due to the fact that moist-ure involved can be directly used as reaction media under the subcritical-water region.With this,value-adde...Hydrothermal carbonization is highly applicable to high moisture biomass upgrading due to the fact that moist-ure involved can be directly used as reaction media under the subcritical-water region.With this,value-added utilization of hydrochar as solid fuel with high carbon and energy density is one of the important pathways for biomass conversion.In this review,the dewatering properties of hydrochar after the hydrothermal carbonization of biowaste,coalification degree with elemental composition and evolution,pelletization of hydrochar to enhance the mechanical properties and density,coupled with the combustion properties of hydrochar biofuel were discussed with various biomass and carbonization parameters.Potential applications for the co-combustion with coal,cleaner properties and energy balance for biowaste hydrothermal carbonization were presented as well as the challenges.展开更多
Hydrochar prepared with four typical biowastes,pine wood,food waste,digested sewage sludge,and Chlorella were applied for the promotion of anaerobic digestion.The gas production and substrate composition were analyzed...Hydrochar prepared with four typical biowastes,pine wood,food waste,digested sewage sludge,and Chlorella were applied for the promotion of anaerobic digestion.The gas production and substrate composition were analyzed associated with the hydrochar characteristics.The results suggested that Chlorella hydrochar(C-C)showed the highest cumulative yield of methane(approximately 345 mL)with high total organic carbon(TOC)removal efficiency and low volatile fatty acids(VAFs)concentration.Especially,food waste hydrochar(F-C)showed a poor effect on anaerobic digestion and aroused 1.4–1.6 g/L accumulation of VAFs,in which the toxic components may account for the low efficiency.The C-C and sludge hydrochar(S-C)may develop direct interspecific electron transport(DIET)to facilitate the generation of methane by both surface groups and conductivity of the body structure,unlike pinewood hydrochar(P-C),which mainly depended on the aromatic matrix structure of hydrochar body.This work suggested that C-C can be the best candidate for the facilitation of anaerobic digestion,and N-containing biowaste like algae and lignocellulose like pine wood may establish different DIET pathways based on the physicochemical characteristics of hydrochar.展开更多
The Response Surface Methodology (RSM) was used to optimise the conditions of preparation of activated hydrochar from tannery solid waste by hydrothermal carbonisation (HTC). The main factors such as residence time, m...The Response Surface Methodology (RSM) was used to optimise the conditions of preparation of activated hydrochar from tannery solid waste by hydrothermal carbonisation (HTC). The main factors such as residence time, moisture content and final carbonisation temperature were investigated during the optimisation of hydrochar preparation conditions. The three responses investigated are hydrochar yield, iodine and methylene blue indices. The results of experimental analyses showed that the yield of hydrochar decreases with increasing final temperature, leading to the formation of micropores inside the carbonaceous solid. The optimum conditions for preparing the following hydrochar were obtained: 83.10%, 390.44 mg∙g−1 and 259.63 mg∙g−1 respectively for the hydrochar yield, the iodine and methylene blue indices. The specific surface area of prepared hydrochar is 849.160 m2/g, SEM micrographs showed a porous heterogeneous surface and particularly, the hydrochar surface also revealed external pores on the hydrochar surface which acted as a pathway to the micropores. Fourier transform infrared (FTIR), however, showed a predominance of acid functions on the surface of the carbonaceous solids. Tests were carried out to eliminate indigo carmine in aqueous media. Activated hydrochar showed a high level of activity, with the Langmuir and Freundlich isotherms giving an adsorption quantity of 354.610 mol/g and a KF constant of 468.2489, respectively. The findings of the research revealed that hydrochar produced is well adapted for dyes removal.展开更多
Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of...Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of biomass plays a significant role in promoting the development of clean energy,alleviating environmental pressures,and achieving carbon neutrality goals.Among the numerous processing technologies of biomass,hydrothermal carbonization(HTC)is a promising thermochemical process that can decompose and convert biomass into hydrochar under relatively mild conditions of approximately 180℃–300℃,thereby enabling its efficient resource utilization.In addition,HTC can directly process feedstocks with high moisture content without the need for high-temperature drying,resulting in lower energy consumption.Based on a systematic analysis of the critical articles mainly published in 2011-2025 related to biomass,HTC,and hydrochar applications,in this review,the category of biomass was first classified and the chemical compositions were summarized.Then,the main chemical reaction pathways involved in biomass decomposition and transformation during the HTC process were introduced.Meanwhile,the roles of key process parameters,including reaction temperature,residence time,pH,feedstock type,pressure,mass ratio of biomass to water,and the use of catalysts on HTC,were carefully discussed.Finally,the applications of hydrochar in energy utilization,environmental remediation,soil improvement,adsorbent,microbial fermentation,and phosphorus recovery fields were highlighted.The future directions of the HTC process were also provided,which would respond to climate change by promoting the development of the sustainable carbon materials field.展开更多
Applications of artificial intelligence(AI)-and machine learning(ML)-based methodologies for predicting optimal conditions in sustainable and effective management of biowastes and natural resources are of great concer...Applications of artificial intelligence(AI)-and machine learning(ML)-based methodologies for predicting optimal conditions in sustainable and effective management of biowastes and natural resources are of great concern.However,the AI-applications for optimizing the hydrothermal treatment(HT)of organic solid biowastes and prediction of nutrients fate during the HT process have not yet been investigated.Therefore,this study explores the application of different ML models(e.g.,XGBoost,Decision Tree,and Random Forest)for optimizing HT of swine manure,focusing on the role of calcium(Ca)and iron(Fe)ions in phosphorus(P)distribution in the produced liquid and solid phases(hydrochar).Specifically,we investigated the fate of total P(TPS)in the hydrochar and inorganic P(IPL)in the liquid phase during HT.Experimental validation was conducted alongside the ML predictions,with XGBoost outperforming the other models,showing strong predictive accuracy for TPS(R^(2)=0.77)and IPL(R^(2)=1.0).Key factors influencing model accuracy included feedstock composition,reaction temperature,duration,solid–liquid ratio,and Ca and Fe concentrations.We found that the impact of time on TPS and IPL was minimal when the reaction time was less than 200 min,while pH showed a positive correlation with TPS and IPL.NMR and XRD analyses indicated that as the reaction severity increased,the organic P content in the hydrochar became more uniform.These findings highlight the potential of AI-based methodologies for optimizing HT processes,contributing to more sustainable and effective solutions for safe recycling,management,and development of bioresources.展开更多
Tetracycline(TC),which is widely employed in agriculture,constitutes a serious source of environmental pollution.In this study,mechanical ball-milling(B)treated iron/manganese-nitrogen(Fe/Mn-N)doped hydrochars(Fe/Mn-B...Tetracycline(TC),which is widely employed in agriculture,constitutes a serious source of environmental pollution.In this study,mechanical ball-milling(B)treated iron/manganese-nitrogen(Fe/Mn-N)doped hydrochars(Fe/Mn-BNHT)synthesized using saponin-containing seed meal(T)as a carbon source,showed excellent removal ability of tetracycline with a removal efficiency 95%.The Fe/Mn-BNHT showed superior performance in batch experiments with solution pH(3-9),coexisting ions,and after 5 cycles of application.Further analysis showed that Fe/Mn-BNHT mediated the degradation of adsorbed tetracycline with a degradation efficiency 87%.Surface complexation,electrostatic interactions,and hydrogen bonding facilitated the adsorption of tetracycline.・OH induced by oxygen vacancy(O_(V))was identified as the main reactive oxidation species in tetracycline degradation.Fe(III)-tetracycline complexes gained electrons through graphitic N,leading to tetracycline degradation and Fe(III)reduction.The degradation pathways for tetracycline are shown through density functional theory calculation and intermediate identification,and the ecological toxicity risk of 10 degradation intermediates is evaluated.This research provides a new perspective on the development of environmentally friendly materials that can simultaneously adsorb and degrade pollutants.展开更多
Char amendment is an option to lower climatic impact of agricultural soils.However,their effect can vary depending on char and soil properties,vegetation type and their interactions.Nutrient poor and acidic soils of b...Char amendment is an option to lower climatic impact of agricultural soils.However,their effect can vary depending on char and soil properties,vegetation type and their interactions.Nutrient poor and acidic soils of boreal region could benefit from char amendment.We conducted a three-month long mesocosm study representing a typical boreal forage-legume grassland to understand the effects of char application on greenhouse gas(GHG)emissions,soil organic carbon(SOC)pools and biomass yield.We examined biochar and hydrochar for changes in soil properties,gross nitrogen transformation rates,SOC and its fractions,biomass yield and all three major GHG fluxes.We assessed our results from two different perspectives;one,when chars were added at a uniform rate with fertilizer nitrogen(N)following the farmer’s practice and two,when chars were added based on the char C amount without fertilizer N.We show that only N_(2)O emissions(not CO_(2)and CH_(4))were affected when chars were added at a uniform rate with fertilizer N.Biochar increased N_(2)O emissions significantly compared to control whereas hydrochar restricted N_(2)O relative to control and lowered significantly compared to biochar treatments.Biochar with N amendment significantly increased gross NO_(3)−production(gross nitrification)and N_(2)O emissions,indicating a linkage between increased nitrifier activity and N_(2)O emissions.Hydrochar with N amendment showed lower gross nitrification rates and N_(2)O emissions,indicating a reduced nitrifier activity and N_(2)O emissions compared to biochar.Interestingly,hydrochar without N amendment showed lowest N_(2)O emissions with few N_(2)O uptake events and similar gross NO_(3)−consumption and production rates,hinting an enhanced soil N_(2)O reduction/sink mechanism,especially with actively photosynthesizing vegetation.Both chars increased soil particulate organic C(POC)significantly mainly owing to both chars themselves being carbon.The mineral associated organic C(MAOC)remained unaltered.Interestingly,we found significantly lower soil MAOC per unit of char C with biochar than with hydochar amendment,especially when endpoint soil MAOC was compared with initial soil MAOC.Our results suggest that destabilization of MAOC increased more with biochar than with hydrochar,especially with N fertilization and in the presence of actively photosynthesizing vegetation.This was further supported by a significantly greater rise in microbial biomass carbon with hydrochar than with biochar amendment.The total biomass yield remained unaffected.However,biochar with the applied N reduced the timothy grass yield compared to control,implying a reduced uptake of applied N by timothy.Our results shed light on the complex interactions among chars,soil,vegetation and N management.Therefore,future studies should focus on assessing the char amendment impacts including both plant and soil and at the whole agricultural field scale.Chars manufactured from diverse feedstocks need to be investigated for their impacts in diverse agricultural ecosystems,paving the way for their large-scale use.展开更多
Application of advanced techniques and machine learning(ML)for designing and predicting the properties of engineered hydrochar/biochar is of great agro-environmental concern.Carbon(C)stability and phosphorus(P)availab...Application of advanced techniques and machine learning(ML)for designing and predicting the properties of engineered hydrochar/biochar is of great agro-environmental concern.Carbon(C)stability and phosphorus(P)availability in hydrochar(HC)are among the key limitations as they cannot be accurately predicted by traditional one-factor tests and might be overcome by engineering the pristine HC.Therefore,the aims of this study were(1)to determine the optimal production conditions of engineered swine manure HC with high C stability and P availability,and(2)to develop the best ML models to predict the properties of HC derived from different feedstocks.Pristine-(HC)and FeCl_(3)impregnated swine manure-derived HC(HC-Fe)were produced by hydrothermal carbonization under different pH(4,7,and 10),reaction temperature(180,220,and 260℃),and residence time(60,120,and 180 min)and characterized using thermo-gravimetric,microscopic,and spectroscopic analyses.Also,different ML algorithms were used to model and predict the hydrochar solid yield,properties,and nutrients content.FeCl_(3)impregnation increased Fe-phosphate content,while it reduced H/C and O/C ratios and hydroxyapatite P content,and therefore improved C stability and P availability in the HC-Fe as compared to HC,particularly under lower pH(4),temperature of 220℃,and at 120 min.The generalized additive ML model outperformed the other models for predicting the HC properties with a correlation coefficient of 0.86.The ML analysis showed that the most influential features on the hydrochar C stability were the H and O contents in the biomass,while P availability in HC was more dependent on the C,N and O contents in biomass.These results provided optimal production conditions for Fe-engineered manure hydrochar and identified the best performing ML model for predicting hydrochar properties.The main implication of this study is that it offers a high potential to improve the utilization of biowastes and produce biowastederived engineered hydrochar with high C stability and P availability on a large scale.展开更多
Hydrothermal treatment(HTT)can efficiently valorize the digestate after anaerobic digestion.However,the disposal of the HTT liquid is challenging.This paper proposes a method to recover energy through the anaerobic co...Hydrothermal treatment(HTT)can efficiently valorize the digestate after anaerobic digestion.However,the disposal of the HTT liquid is challenging.This paper proposes a method to recover energy through the anaerobic co-digestion of food waste and HTT liquid fraction.The effect of HTT liquid recirculation on anaerobic co-digestion performance was investigated.This study focused on the self-generated hydrochars that remained in the HTT supernatant after centrifugation.The effect of the self-generated hydrochars on the methane(CH_(4))yield and microbial communities were discussed.After adding HTT liquids treated at 140 and 180C,the maximum CH4 production increased to 309.36 and 331.61 mL per g COD,respectively.The HTT liquid exhibited a pH buffering effect and kept a favorable pH for the anaerobic co-digestion.In addition,the self-generated hydrochars with higher carbon content and large oxygen-containing functional groups remained in HTT liquid.They increased the electron transferring rate of the anaerobic co-digestion.The increased relative abundance of Methanosarcina,Syntrophomonadaceae,and Synergistota was observed with adding HTT liquid.The results of the principal component analysis indicate that the electron transferring rate constant had positive correlationships with the relative abundance of Methanosarcina,Syntrophomonadaceae,and Synergistota.This study can provide a good reference for the disposal of the HTT liquid and a novel insight regarding the mechanism for the anaerobic co-digestion.展开更多
The hydrothermal carbonization(HTC)of biogas digestate alters the raw materials inherent characteristics to produce a carbon(C)-rich hydrochar(HC),with an improved suitability for soil amelioration.Numerous studies re...The hydrothermal carbonization(HTC)of biogas digestate alters the raw materials inherent characteristics to produce a carbon(C)-rich hydrochar(HC),with an improved suitability for soil amelioration.Numerous studies report conflicting impacts of various HC application rates on soil properties and plant growth.In this study,the influence of HC application rate on soil improvement and plant growth aspects was investigated in three diverse soils(Chernozem,Podzol,and Gleysol).Pot trials were conducted in which all soils were amended with 5,10,20 and 30%(w/w)HC in quintuplicate,with two controls of pure soil(with and without plants,respectively)also included.Prior to potting,soil samples were collected from all HC-amended soils and controls and analyzed for soil pH,plant available nutrients(PO4-P and K),and microbial activity using standard laboratory and statistical methods.Immediately after potting,a 6-week seed germination experiment using Chinese cabbage was conducted to determine germination success,followed by a plant growth experiment of equal duration and plant species to determine biomass success.At the end of the study(after a total plant growth period of 12 weeks),each pot was sampled and comparatively analyzed for the same soil properties as at the beginning of the study.Soil pH shifted toward the pH of the HC(6.6)in all soils over the course of the study,but was most expressed in the 20%and 30%application rates,confirming the well-documented liming effect of HC.The addition of HC increased the PO4-P and K contents,particularly with 20%and 30%HC amendments.These results are proposedly due to the large labile C fraction of the HC,which is easily degradable by microorganisms.The rapid decomposition of this C fraction prompted the quick release of the HCs inherently high PO4-P and K content into the soil,and in turn,further stimulated microbial activity,until this fraction was essentially depleted.HC addition did not inhibit seed germination at any rate,presumably due to a lack of phytotoxic compounds in the HC from aging and microbial processes,and furthermore,showed no significant impact(positive or negative)on plant growth in any soil,despite improved soil conditions.In conclusion,although less pronounced,soil improvements were still achievable and maintainable at lower application rates(5%and 10%),whereas higher rates did not ensure greater benefits for plant growth.While the addition of high rates of HC did not detrimentally effect soil quality or plant growth,it could lead to leaching if the nutrient supply exceeds plant requirements and the soil’s nutrient retention capacity.Therefore,this study validates the previous study in the effectiveness of the biogas digestate HC for soil amelioration and suggests that smaller regularly repeated HC applications may be recommendable for soil improvement.展开更多
Hydrochar(HC),produced by hydrothermal carbonization,offers technical advantages over biochar(BC)produced by pyrolysis,and is suitable for soil amelioration,carbon sequestration,and enhanced plant growth.BC grain size...Hydrochar(HC),produced by hydrothermal carbonization,offers technical advantages over biochar(BC)produced by pyrolysis,and is suitable for soil amelioration,carbon sequestration,and enhanced plant growth.BC grain size has been shown to influence nutrient retention,microbial colonization and aggregate formation;however,similar research for HC is lacking.Pot trials were conducted to investigate the influence of HC grain size[coarse(6.3-2 mm),medium(2-0.63 mm)and fine(<0.63 mm)],produced from biogas digestate,for soil improvement in three soils:loamy Chernozem,sandy Podzol,and clayey Gleysol,at a 5%HC application rate(w/w).All soils including two controls(with and without plants)were analysed for water holding capacity(WHC),cation exchange capacity(CEC),wet aggregate stability,pH,plant available nutrients(PO_(4)-P,K and N_(min))and germination and biomass success using standard laboratory and statistical methods.Soil pH showed a compensatory shift toward the HC pH(7.2)in all soils over the course of the study.For example,the pH of the medium grained HC treatment for the Chernozem decreased from 7.9 to 7.2 and increased in the Podzol and Gleysol from 5.9 to 6.1 and 4.9 to 5.5,respectively.The nutrient-rich HC(2034±38.3 mg kg^(−1) PO_(4)-P and 2612.5±268.7 mg kg^(−1) K content)provided only a short-term supply of nutrients,due to the relatively easily mineralized fraction of HC,which allowed for quick nutrient release.The pH and PO_(4)-P effects were most pronounced in the fine grained HC treatments,with a~87%,~308%and~2500%increase in PO_(4)-P content in the Chernozem,Podzol and Gleysol,respectively,compared to the controls at the beginning of the study.The same trend was observed for the K and NH_(4)^(+)content in the fine and medium grained HC treatments in all soils.No seed germination inhibition of Chinese cabbage was observed,with average germina-tion rates>50%in all soils.An effect on NO_(3)^(−)content was indeterminable,while there was little to no effect on biomass production,WHC,CEC and aggregate stability.In conclusion,the application of 5%fine grained HC significantly influenced the nutrient content over a short-term.However,the application rate was insufficient to substantially improve plant growth,nor to sustain a longer-term nutrients supply,regardless of grain size.展开更多
基金supported by the Director Fund Project provided by the Institute of Plant Nutrition,Resources and Environment,Beijing Academy of Agriculture and Forestry Sciences(No.YZS202101)the Youth Fund Project provided by Beijing Academy of Agriculture and Forestry Sciences(No.QNJJ202125)China Agriculture Research System of MOF and MARA.
文摘The dissolved organic matter(DOM)with high mobility and reactivity plays a crucial role in soil.In this study,the characteristics and phytotoxicity ofDOMreleased fromthe hydrochars prepared from different feedstocks(cowmanure,corn stalk and Myriophyllum aquaticum)under three hydrothermal carbonization(HTC)temperatures(180,200 and 220°C)were evaluated.The results showed that the hydrochars had high dissolved organic carbon content(20.15 to 37.65 mg/g)and its content showed a gradual reduction as HTC temperature increased.Three fluorescent components including mixed substance of fulvic acid-like and humic acid-like substances(C1,30.92%-58.32%),UVA humic acid-like substance(C2,25.27%-29.94%)and protein-like substance(C3,11.74%-41.92%)were identified in hydrochar DOM by excitation emission matrix spectra coupled with parallel factor analysis.High HTC temperature increased the relative proportion of aromatic substances(C1+C2)and humification degree of hydrochar DOM from cow manure,while it presented adverse effects on the hydrochar DOM from corn stalk and Myriophyllum.aquaticum.The principal component analysis suggested that feedstock type and HTC temperature posed significant effects on the characteristics of hydrochar DOM.Additionally,seed germination test of all hydrochar DOM demonstrated that the root length was reduced by 8.88%-26.43%in contrast with control,and the germination index values were 73.57%-91.12%.These findings provided new insights into the potential environmental effects for hydrochar application in soil.
基金supported by the National Natural Science Foundation of China(No.42307090)the Open Subject from State Environmental Protection Key Laboratory of Aquatic Ecosystem Health in theMiddle and Lower Reaches of Yangtze River(No.AEHKF2023008).
文摘The copper complexing of dissolved organic matter released from hydrochar(HDOM)affects the former’s environmental behavior.In this study,how hydrothermal temperatures(180,220 and 260℃)influence the molecular-level constitutions and Cu(II)binding features of HDOM were elucidated via fourier transform ion cyclotron resonance mass spectrometry and multi-spectroscopic analysis.The findings demonstrated that the almost HDOM molecules had the traits of lower polarity and higher hydrophobicity.As the hydrothermal temperature increased,the molecules with particularly high relative strength gradually disappeared,average molecular weight,percentages of CHON and aliphatic compounds of HDOM reduced while the percentages of CHO and aromatic compounds increased.In general,the fluorescence quenching of Cu(II)weakened as hydrothermal temperature rose and the Cu(II)binding stability constants of fluorophores in HDOM were 4.50–5.31.In addition,the Cu(II) binding order of fluorophores in HDOM showed temperature heterogeneities, andpolysaccharides or aromatic rings of non-fluorescent substances had the fastest responsesto Cu(II) binding. Generally, fluorescent components tend to bind Cu(II) at relatively traceconcentrations (0–40 μmol/L), whereas non-fluorescent substances tend to the bind Cu(II)at relatively higher concentrations (50–100 μmol/L). This study contributed to the predictionof the potential environmental behaviors and risks of Cu(II) at the molecular level afterhydrochar application.
基金supported by grants funded by the Hong Kong Research Grants Council(Grant No.CRF/C6006-20G)a grant provided by the Joint NSFC/RGC Joint Research Scheme(Grant No.N_HKUST603/22)the Fundamental Research Funds for the Central Universities(Grant No.Z1090125018).
文摘The effectiveness of using vegetation to stabilise shallow soil slopes heavily depends on the survival of vegetation,yet the amplification of extreme events induced by climate change threatens the health of plants covering slopes.Hydrochar is an environmentally friendly soil amender that can achieve the potential benefits of promoting plant growth for slope stabilisation and facilitation of waste upcycling.The mechanism underlying the hydrochar effects on the mechanical behaviour of unsaturated soils remains unclear.This study investigated the influence of grass-derived hydrochar on the water retention,compressibility,and shear strength of a compacted siltyeclay sand.Soil microstructural changes due to hydrochar amendment were measured to explain the soilehydrochar hydromechanical interaction.The increase in suction resulted in a less significant increase in yield stress and a negligible reduction in compressibility of the hydrochar-amended soil compared with the unamended case.This phenomenon was observed because hydrochar addition reduced the large pores with diameters greater than the macropore peak of 60 mm due to pore filling by hydrochar particles,resulting in a less substantial volume contraction during drying.Hydrochar introduced more significant effects on the soil’s shear strength in an unsaturated state compared to a saturated case.Despite the similarity of the unsaturated amended soil with the critical-state friction angle to the saturated case,the former exhibited a greater shear strength because the hydrochar addition improved water retention capability.As a result,the degree of saturation and,hence,Bishop’s effective stress were higher than those for the unamended case for a given suction.
基金financially supported by the National Natural Science Foundation of China (41071206)
文摘Innovative measure is a urgent requirement for managing the huge volume of municipal sewage sludge. The hydrothermal carbonation （HTC） shows some potential advantages for using hydrochar as a soil conditioner. The aim of this work was to investigate the properties of hydrochars, by means of the HTC of municipal sewage sludge under different temperatures （190 and 260~C） and reaction hours （1, 6, 12, 18 and 24 h）. The HTC led to the decreases of N, O and H contents by more than 54.6, 37.9 and 10.0%, respectively, and slight changes of C content. The Py-GC-MS analysis showed that a large proportion of fatty acids, in particular hexadecanoic acid, transferred into alkenes, olefins and aromatic compounds. The 13C-NMR and fourier transform infrared spectra （FTIR） confirmed the transformation and changes in chemical structure in which hydrochar contained lower oxygen-containing organic C of O-alkyl, carboxylic and carbonyl C and aliphaticity, but higher aromatic C and aromaticity. The rich hydrophobic functions induced in high positive charges in the charred sludge. The HTC facilitated the pore structure development, proved by higher specific surface area and specific pore volume, with a maximum of 17.30 and 0.83 cm^3 g^-1, respectively. The availabilities of N, P and K markedly reduced during HTC treatment. The activities of most heavy metals were depressed though they accumulated in the hydrochar. Further work is required to investigate the values and risk of the charred sludge amended to soil.
基金This work was financially supported by the National Natural Science Foundation of China(No.21701099)the Science and Technology Innovation Project of Colleges and Universities of Shanxi Province in 2020(No.2020L0721)the Basic Research Project of Shanxi Province,China(No.201801D121267).
文摘In this paper,a novel compound was developed by mixing H_(3)PO_(4)-modified cauliflower leaves hydrochar(CLH)and coal gangue-based Na-X zeolite(ZL).An alkaline soil contaminated with cadmium(Cd)and lead(Pb)was amended through the individual and synergistic application of CLH and ZL(1%CLH,2%CLH,1%ZL,2%ZL and 1%CLH+1%ZL),and Chinese cabbage was grown on it.Individual application of CLH was superior to ZL on decreasing the pH of alkaline soil and increasing soil available phosphorus(Olsen-P)and soil organic matter(SOM).In contrast,their combined application significantly improved the soil cation exchange capacity(CEC).Besides,the 1%CLH+1%ZL was the most efficient treatment in decreasing diethylenetriamine pentaacetate(DTPA)-extractable Cd/Pb and concentrations of these two metals in cabbage root and shoot.Their synergistic application could better increase Cd and Pb immobilization and cabbage yield than their alone application.Furthermore,the immobilization of Pb for all treatments was higher than that of Cd.The synergistic immobilization mechanism of CLH and ZL reflected that the CLH precipitated and complexed with these two metals,which may block the pores of hydrochar or wrap on the surface of hydrochar.So the continuous adsorption and complexation were prevented.Nevertheless,ZL could probably alleviate this obstacle.This finding provides helpful information about using CLH combined with ZL as a soil stabilizer to immobilize heavy metals in contaminated alkaline soil.
基金the National Natural Science Foundation of China(NNSFC21706134)the Young Natural Science Foundation of Jiangsu Province(BK20170918)for financial supportsupport from the“Advanced analysis and testing center of Nanjing Forestry University.”
文摘A rising global population and aspirational higher living standards has driven a step change in resource utilization and concomitant anthropogenic pollution across the biosphere.Low-cost and scalable technologies for environmental remediation are therefore urgently sought,with an emphasis on trash-to-treasure strategies that exploit abundant but underutilized waste by-products of existing sectors.Biochars are carbon-rich,porous solids produced by biomass pyrolysis under anaerobic or oxygen-scarce conditions at high temperature(350–700°C),while hydrochars are produced by hydrothermal biomass carbonization at lower temperature(130–250°C)and high autogenous pressures(0.3–4.0 MPa).Bio/hydrochars possess unique physicochemical properties,notably high surface areas(100–1500 m2 g-1)and porosity(0.25–2.5 cm^(3)g^(-1))and rich surface chemistry featuring carboxylic,phenolic,hydroxyl,and carbonyl functions,amenable to chemical,physical,or biochemical modification,rendering them ideal sorbents for pollutants such as heavy metals(e.g.As and Cr),and toxic organic(e.g.,dyes and xenobiotics)and inorganic(e.g.,SO_(2))molecules.Bio/hydrochars are attractive for environmental remediation of pollutant mixtures by surface complexation,redox chemistry,electrostatic interactions/ion exchange,or coprecipitation.This review discusses recent opportunities and challenges in creating bio/hydrochar sorbents and their nanocomposites through grafting,doping,and chemical/physical activation,for the depollution of aquatic and atmospheric environments.
基金supported by the National Natural Science Foundation of China(52261145701 and U21A20162)the 2115 Talent Development Program of China Agricultural University.
文摘The function-led design of porous hydrochar from mineral-rich biowaste for environmental applications inevitably suffers from carbon-ash recalcitrance.However,a method to alter the original carbon skeleton with ash remains elusive and hinders the availability of hydrochar.Herein,we propose a facile strategy for breaking the rigid structure of carbon-ash coupled hydrochar using phase-tunable molten carbonates.A case system was designed in which livestock manure and NaHCO3 were used to prepare the activated hydrochar,and NH3 served as the target contaminant.Due to the redox effect,we found that organic fractions significantly advanced the melting temperature of Na2CO3 below 800℃.The Na species steadily broke the carbon-ash interaction as the thermal intensity increased and transformed inorganic constituents to facilitate ash dissolution,rebuilding the hydrochar skeleton with abundant hierarchical channels and active defect edges.The surface polarity and mesopore distribution collectively governed the five cycles NH3 adsorption attenuation process.Manure hydrochar delivered favorable potential for application with a maximum overall adsorption capacity of 100.49 mg·g^(-1).Integrated spectroscopic characterization and theoretical computations revealed that incorporating NH3 on the carbon surface could transfer electrons to chemisorbed oxygen,which promoted the oxidation of pyridine-N during adsorption.This work offers deep insight into the structure function correlation of hydrochar and inspires a more rational design of engineered hydrochar from high-ash biowaste.
基金financial support by the National Natural Science Foundation of China(No.41472095)the Open Fund of Key Laboratory of Exploration Technologies for Oil and Gas Resources(Yangtze University)+1 种基金Ministry of Education(No.K2018-05)the Foundation of Shandong Provincial Key Laboratory of Depositional Mineralization and Sedimentary Minerals,Shandong University of Science and Technology(Grant No.DMSM2018041).
文摘The corncob hydrochar is prepared by using a stainless autoclave at 230?C for 8 h.The products are characterized by elemental analyzer,Fourier Transform infrared spectroscopy(FT-IR),X-ray diffraction(XRD)and scanning electron microscope(SEM).The effects of hydrochar dosage,pH,adsorption time and phenol concentration on the adsorption performance of hydrochar are investigated by means of single-factor experimental analysis.Based on the experiments the adsorption thermodynamic and kinetics are tentatively discussed.The results show that abundant oxygen-containing functional groups are scattered on the surface of the corncob hydrochar.The adsorption kinetics of phenol on the hydrochar corresponds well with pseudo-second-order kinetic model.Thermodynamic studies indicate that Freundlich adsorption isotherm model is much better than Langmuir model in describing the adsorption of phenol on the corncob hydrochar at 25?C-45?C.This study provides scientific basis for the development of cheap and efficient adsorbents for the removal of phenols derived from oilfield wastewater.
基金supported by the Fundamental Research Funds for the Central Universities of Southwest Jiaotong University,supported by Sichuan Science and Technology Program(2021YFS0284).
文摘Hydrothermal carbonization is highly applicable to high moisture biomass upgrading due to the fact that moist-ure involved can be directly used as reaction media under the subcritical-water region.With this,value-added utilization of hydrochar as solid fuel with high carbon and energy density is one of the important pathways for biomass conversion.In this review,the dewatering properties of hydrochar after the hydrothermal carbonization of biowaste,coalification degree with elemental composition and evolution,pelletization of hydrochar to enhance the mechanical properties and density,coupled with the combustion properties of hydrochar biofuel were discussed with various biomass and carbonization parameters.Potential applications for the co-combustion with coal,cleaner properties and energy balance for biowaste hydrothermal carbonization were presented as well as the challenges.
基金supported by the Opening Project of Key Laboratory of Agricultural Renewable Resource Utilization Technology (No.HLJHDNY2104)Funding for the National Natural Science Foundation of China (NSFC U21A20162)+2 种基金Heilongjiang Postdoctoral Financial Assistance (LBH-Z21042)University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province (UNPYSCT-2020106)Sichuan Science and Technology Program (2022NSFSC1162).
文摘Hydrochar prepared with four typical biowastes,pine wood,food waste,digested sewage sludge,and Chlorella were applied for the promotion of anaerobic digestion.The gas production and substrate composition were analyzed associated with the hydrochar characteristics.The results suggested that Chlorella hydrochar(C-C)showed the highest cumulative yield of methane(approximately 345 mL)with high total organic carbon(TOC)removal efficiency and low volatile fatty acids(VAFs)concentration.Especially,food waste hydrochar(F-C)showed a poor effect on anaerobic digestion and aroused 1.4–1.6 g/L accumulation of VAFs,in which the toxic components may account for the low efficiency.The C-C and sludge hydrochar(S-C)may develop direct interspecific electron transport(DIET)to facilitate the generation of methane by both surface groups and conductivity of the body structure,unlike pinewood hydrochar(P-C),which mainly depended on the aromatic matrix structure of hydrochar body.This work suggested that C-C can be the best candidate for the facilitation of anaerobic digestion,and N-containing biowaste like algae and lignocellulose like pine wood may establish different DIET pathways based on the physicochemical characteristics of hydrochar.
文摘The Response Surface Methodology (RSM) was used to optimise the conditions of preparation of activated hydrochar from tannery solid waste by hydrothermal carbonisation (HTC). The main factors such as residence time, moisture content and final carbonisation temperature were investigated during the optimisation of hydrochar preparation conditions. The three responses investigated are hydrochar yield, iodine and methylene blue indices. The results of experimental analyses showed that the yield of hydrochar decreases with increasing final temperature, leading to the formation of micropores inside the carbonaceous solid. The optimum conditions for preparing the following hydrochar were obtained: 83.10%, 390.44 mg∙g−1 and 259.63 mg∙g−1 respectively for the hydrochar yield, the iodine and methylene blue indices. The specific surface area of prepared hydrochar is 849.160 m2/g, SEM micrographs showed a porous heterogeneous surface and particularly, the hydrochar surface also revealed external pores on the hydrochar surface which acted as a pathway to the micropores. Fourier transform infrared (FTIR), however, showed a predominance of acid functions on the surface of the carbonaceous solids. Tests were carried out to eliminate indigo carmine in aqueous media. Activated hydrochar showed a high level of activity, with the Langmuir and Freundlich isotherms giving an adsorption quantity of 354.610 mol/g and a KF constant of 468.2489, respectively. The findings of the research revealed that hydrochar produced is well adapted for dyes removal.
基金supported by National Natural Science Foundation of China(22578155,22478147)the Natural Science Foundation of Huaian City(HAB2024051).
文摘Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of biomass plays a significant role in promoting the development of clean energy,alleviating environmental pressures,and achieving carbon neutrality goals.Among the numerous processing technologies of biomass,hydrothermal carbonization(HTC)is a promising thermochemical process that can decompose and convert biomass into hydrochar under relatively mild conditions of approximately 180℃–300℃,thereby enabling its efficient resource utilization.In addition,HTC can directly process feedstocks with high moisture content without the need for high-temperature drying,resulting in lower energy consumption.Based on a systematic analysis of the critical articles mainly published in 2011-2025 related to biomass,HTC,and hydrochar applications,in this review,the category of biomass was first classified and the chemical compositions were summarized.Then,the main chemical reaction pathways involved in biomass decomposition and transformation during the HTC process were introduced.Meanwhile,the roles of key process parameters,including reaction temperature,residence time,pH,feedstock type,pressure,mass ratio of biomass to water,and the use of catalysts on HTC,were carefully discussed.Finally,the applications of hydrochar in energy utilization,environmental remediation,soil improvement,adsorbent,microbial fermentation,and phosphorus recovery fields were highlighted.The future directions of the HTC process were also provided,which would respond to climate change by promoting the development of the sustainable carbon materials field.
基金sustained by a grant from the National Key Research and Development Program of China"Intergovernmental Cooperation in International Science and Technology Innovation"[Grant number 2023YFE0104700]the National Natural Science Foundation of China[Grant Number 31401944]funded by Taif University,Saudi Arabia through project number(TU-DSPP-2024-27),which is appreciated by the author Esmat F.Ali.
文摘Applications of artificial intelligence(AI)-and machine learning(ML)-based methodologies for predicting optimal conditions in sustainable and effective management of biowastes and natural resources are of great concern.However,the AI-applications for optimizing the hydrothermal treatment(HT)of organic solid biowastes and prediction of nutrients fate during the HT process have not yet been investigated.Therefore,this study explores the application of different ML models(e.g.,XGBoost,Decision Tree,and Random Forest)for optimizing HT of swine manure,focusing on the role of calcium(Ca)and iron(Fe)ions in phosphorus(P)distribution in the produced liquid and solid phases(hydrochar).Specifically,we investigated the fate of total P(TPS)in the hydrochar and inorganic P(IPL)in the liquid phase during HT.Experimental validation was conducted alongside the ML predictions,with XGBoost outperforming the other models,showing strong predictive accuracy for TPS(R^(2)=0.77)and IPL(R^(2)=1.0).Key factors influencing model accuracy included feedstock composition,reaction temperature,duration,solid–liquid ratio,and Ca and Fe concentrations.We found that the impact of time on TPS and IPL was minimal when the reaction time was less than 200 min,while pH showed a positive correlation with TPS and IPL.NMR and XRD analyses indicated that as the reaction severity increased,the organic P content in the hydrochar became more uniform.These findings highlight the potential of AI-based methodologies for optimizing HT processes,contributing to more sustainable and effective solutions for safe recycling,management,and development of bioresources.
基金supported by the National Key Research and Development Program of China(2023YFD1701403,2022YFD1601103)the Central Public-interest Scientific Institution Basal Research Fund(Y2024QC28)+1 种基金Basic Research Foundation of Yunnan Province of China(202401AT070304)the Science&Technology Innovation Program of the Chinese Academy of Agricultural Sciences.
文摘Tetracycline(TC),which is widely employed in agriculture,constitutes a serious source of environmental pollution.In this study,mechanical ball-milling(B)treated iron/manganese-nitrogen(Fe/Mn-N)doped hydrochars(Fe/Mn-BNHT)synthesized using saponin-containing seed meal(T)as a carbon source,showed excellent removal ability of tetracycline with a removal efficiency 95%.The Fe/Mn-BNHT showed superior performance in batch experiments with solution pH(3-9),coexisting ions,and after 5 cycles of application.Further analysis showed that Fe/Mn-BNHT mediated the degradation of adsorbed tetracycline with a degradation efficiency 87%.Surface complexation,electrostatic interactions,and hydrogen bonding facilitated the adsorption of tetracycline.・OH induced by oxygen vacancy(O_(V))was identified as the main reactive oxidation species in tetracycline degradation.Fe(III)-tetracycline complexes gained electrons through graphitic N,leading to tetracycline degradation and Fe(III)reduction.The degradation pathways for tetracycline are shown through density functional theory calculation and intermediate identification,and the ecological toxicity risk of 10 degradation intermediates is evaluated.This research provides a new perspective on the development of environmentally friendly materials that can simultaneously adsorb and degrade pollutants.
基金supported by Finnish Ministry of Agriculture and Forestry and Walter Ahlstrom Foundation(Woodpro:Grant No:VN/17097/2022)the Research Council of Finland through project,“Mechanism of nitrous oxide(N_(2)O)uptake in different cropping systems in different climate zones(ENSINK,Grant No.334422).
文摘Char amendment is an option to lower climatic impact of agricultural soils.However,their effect can vary depending on char and soil properties,vegetation type and their interactions.Nutrient poor and acidic soils of boreal region could benefit from char amendment.We conducted a three-month long mesocosm study representing a typical boreal forage-legume grassland to understand the effects of char application on greenhouse gas(GHG)emissions,soil organic carbon(SOC)pools and biomass yield.We examined biochar and hydrochar for changes in soil properties,gross nitrogen transformation rates,SOC and its fractions,biomass yield and all three major GHG fluxes.We assessed our results from two different perspectives;one,when chars were added at a uniform rate with fertilizer nitrogen(N)following the farmer’s practice and two,when chars were added based on the char C amount without fertilizer N.We show that only N_(2)O emissions(not CO_(2)and CH_(4))were affected when chars were added at a uniform rate with fertilizer N.Biochar increased N_(2)O emissions significantly compared to control whereas hydrochar restricted N_(2)O relative to control and lowered significantly compared to biochar treatments.Biochar with N amendment significantly increased gross NO_(3)−production(gross nitrification)and N_(2)O emissions,indicating a linkage between increased nitrifier activity and N_(2)O emissions.Hydrochar with N amendment showed lower gross nitrification rates and N_(2)O emissions,indicating a reduced nitrifier activity and N_(2)O emissions compared to biochar.Interestingly,hydrochar without N amendment showed lowest N_(2)O emissions with few N_(2)O uptake events and similar gross NO_(3)−consumption and production rates,hinting an enhanced soil N_(2)O reduction/sink mechanism,especially with actively photosynthesizing vegetation.Both chars increased soil particulate organic C(POC)significantly mainly owing to both chars themselves being carbon.The mineral associated organic C(MAOC)remained unaltered.Interestingly,we found significantly lower soil MAOC per unit of char C with biochar than with hydochar amendment,especially when endpoint soil MAOC was compared with initial soil MAOC.Our results suggest that destabilization of MAOC increased more with biochar than with hydrochar,especially with N fertilization and in the presence of actively photosynthesizing vegetation.This was further supported by a significantly greater rise in microbial biomass carbon with hydrochar than with biochar amendment.The total biomass yield remained unaffected.However,biochar with the applied N reduced the timothy grass yield compared to control,implying a reduced uptake of applied N by timothy.Our results shed light on the complex interactions among chars,soil,vegetation and N management.Therefore,future studies should focus on assessing the char amendment impacts including both plant and soil and at the whole agricultural field scale.Chars manufactured from diverse feedstocks need to be investigated for their impacts in diverse agricultural ecosystems,paving the way for their large-scale use.
基金sustained by a grant from the National Key Research and Development Program of China“Intergovernmental Cooperation in International Science and Technology Innovation”[Grant number 2023YFE0104700]the National Natural Science Foundation of China[Grant Number 31401944]The author Esmat F.Ali extends his appreciation to Taif University,Saudi Arabia for supporting this work through project number(TU-DSPP-2024-27).
文摘Application of advanced techniques and machine learning(ML)for designing and predicting the properties of engineered hydrochar/biochar is of great agro-environmental concern.Carbon(C)stability and phosphorus(P)availability in hydrochar(HC)are among the key limitations as they cannot be accurately predicted by traditional one-factor tests and might be overcome by engineering the pristine HC.Therefore,the aims of this study were(1)to determine the optimal production conditions of engineered swine manure HC with high C stability and P availability,and(2)to develop the best ML models to predict the properties of HC derived from different feedstocks.Pristine-(HC)and FeCl_(3)impregnated swine manure-derived HC(HC-Fe)were produced by hydrothermal carbonization under different pH(4,7,and 10),reaction temperature(180,220,and 260℃),and residence time(60,120,and 180 min)and characterized using thermo-gravimetric,microscopic,and spectroscopic analyses.Also,different ML algorithms were used to model and predict the hydrochar solid yield,properties,and nutrients content.FeCl_(3)impregnation increased Fe-phosphate content,while it reduced H/C and O/C ratios and hydroxyapatite P content,and therefore improved C stability and P availability in the HC-Fe as compared to HC,particularly under lower pH(4),temperature of 220℃,and at 120 min.The generalized additive ML model outperformed the other models for predicting the HC properties with a correlation coefficient of 0.86.The ML analysis showed that the most influential features on the hydrochar C stability were the H and O contents in the biomass,while P availability in HC was more dependent on the C,N and O contents in biomass.These results provided optimal production conditions for Fe-engineered manure hydrochar and identified the best performing ML model for predicting hydrochar properties.The main implication of this study is that it offers a high potential to improve the utilization of biowastes and produce biowastederived engineered hydrochar with high C stability and P availability on a large scale.
基金supported by the Shenzhen Fundamental Research Program(No.GXWD20201231165807007-20220724202837001).
文摘Hydrothermal treatment(HTT)can efficiently valorize the digestate after anaerobic digestion.However,the disposal of the HTT liquid is challenging.This paper proposes a method to recover energy through the anaerobic co-digestion of food waste and HTT liquid fraction.The effect of HTT liquid recirculation on anaerobic co-digestion performance was investigated.This study focused on the self-generated hydrochars that remained in the HTT supernatant after centrifugation.The effect of the self-generated hydrochars on the methane(CH_(4))yield and microbial communities were discussed.After adding HTT liquids treated at 140 and 180C,the maximum CH4 production increased to 309.36 and 331.61 mL per g COD,respectively.The HTT liquid exhibited a pH buffering effect and kept a favorable pH for the anaerobic co-digestion.In addition,the self-generated hydrochars with higher carbon content and large oxygen-containing functional groups remained in HTT liquid.They increased the electron transferring rate of the anaerobic co-digestion.The increased relative abundance of Methanosarcina,Syntrophomonadaceae,and Synergistota was observed with adding HTT liquid.The results of the principal component analysis indicate that the electron transferring rate constant had positive correlationships with the relative abundance of Methanosarcina,Syntrophomonadaceae,and Synergistota.This study can provide a good reference for the disposal of the HTT liquid and a novel insight regarding the mechanism for the anaerobic co-digestion.
基金This study was conducted under the auspices of the‘BIOCAS,circular BIOmass CAScade to 100%’project,which is funded by the European Union Interreg North Sea Region Project 38-2-4-17The funders played no role in the design of the study,the collection and analyses of data or the preparation of the manuscript.
文摘The hydrothermal carbonization(HTC)of biogas digestate alters the raw materials inherent characteristics to produce a carbon(C)-rich hydrochar(HC),with an improved suitability for soil amelioration.Numerous studies report conflicting impacts of various HC application rates on soil properties and plant growth.In this study,the influence of HC application rate on soil improvement and plant growth aspects was investigated in three diverse soils(Chernozem,Podzol,and Gleysol).Pot trials were conducted in which all soils were amended with 5,10,20 and 30%(w/w)HC in quintuplicate,with two controls of pure soil(with and without plants,respectively)also included.Prior to potting,soil samples were collected from all HC-amended soils and controls and analyzed for soil pH,plant available nutrients(PO4-P and K),and microbial activity using standard laboratory and statistical methods.Immediately after potting,a 6-week seed germination experiment using Chinese cabbage was conducted to determine germination success,followed by a plant growth experiment of equal duration and plant species to determine biomass success.At the end of the study(after a total plant growth period of 12 weeks),each pot was sampled and comparatively analyzed for the same soil properties as at the beginning of the study.Soil pH shifted toward the pH of the HC(6.6)in all soils over the course of the study,but was most expressed in the 20%and 30%application rates,confirming the well-documented liming effect of HC.The addition of HC increased the PO4-P and K contents,particularly with 20%and 30%HC amendments.These results are proposedly due to the large labile C fraction of the HC,which is easily degradable by microorganisms.The rapid decomposition of this C fraction prompted the quick release of the HCs inherently high PO4-P and K content into the soil,and in turn,further stimulated microbial activity,until this fraction was essentially depleted.HC addition did not inhibit seed germination at any rate,presumably due to a lack of phytotoxic compounds in the HC from aging and microbial processes,and furthermore,showed no significant impact(positive or negative)on plant growth in any soil,despite improved soil conditions.In conclusion,although less pronounced,soil improvements were still achievable and maintainable at lower application rates(5%and 10%),whereas higher rates did not ensure greater benefits for plant growth.While the addition of high rates of HC did not detrimentally effect soil quality or plant growth,it could lead to leaching if the nutrient supply exceeds plant requirements and the soil’s nutrient retention capacity.Therefore,this study validates the previous study in the effectiveness of the biogas digestate HC for soil amelioration and suggests that smaller regularly repeated HC applications may be recommendable for soil improvement.
基金Open Access funding provided by Projekt DEAL.This study was conducted under the auspices of the Circular BIOmass CAScade to 100%(BIOCAS)project,which is funded by the European Union Interreg North Sea Region Project 38-2-4-17.
文摘Hydrochar(HC),produced by hydrothermal carbonization,offers technical advantages over biochar(BC)produced by pyrolysis,and is suitable for soil amelioration,carbon sequestration,and enhanced plant growth.BC grain size has been shown to influence nutrient retention,microbial colonization and aggregate formation;however,similar research for HC is lacking.Pot trials were conducted to investigate the influence of HC grain size[coarse(6.3-2 mm),medium(2-0.63 mm)and fine(<0.63 mm)],produced from biogas digestate,for soil improvement in three soils:loamy Chernozem,sandy Podzol,and clayey Gleysol,at a 5%HC application rate(w/w).All soils including two controls(with and without plants)were analysed for water holding capacity(WHC),cation exchange capacity(CEC),wet aggregate stability,pH,plant available nutrients(PO_(4)-P,K and N_(min))and germination and biomass success using standard laboratory and statistical methods.Soil pH showed a compensatory shift toward the HC pH(7.2)in all soils over the course of the study.For example,the pH of the medium grained HC treatment for the Chernozem decreased from 7.9 to 7.2 and increased in the Podzol and Gleysol from 5.9 to 6.1 and 4.9 to 5.5,respectively.The nutrient-rich HC(2034±38.3 mg kg^(−1) PO_(4)-P and 2612.5±268.7 mg kg^(−1) K content)provided only a short-term supply of nutrients,due to the relatively easily mineralized fraction of HC,which allowed for quick nutrient release.The pH and PO_(4)-P effects were most pronounced in the fine grained HC treatments,with a~87%,~308%and~2500%increase in PO_(4)-P content in the Chernozem,Podzol and Gleysol,respectively,compared to the controls at the beginning of the study.The same trend was observed for the K and NH_(4)^(+)content in the fine and medium grained HC treatments in all soils.No seed germination inhibition of Chinese cabbage was observed,with average germina-tion rates>50%in all soils.An effect on NO_(3)^(−)content was indeterminable,while there was little to no effect on biomass production,WHC,CEC and aggregate stability.In conclusion,the application of 5%fine grained HC significantly influenced the nutrient content over a short-term.However,the application rate was insufficient to substantially improve plant growth,nor to sustain a longer-term nutrients supply,regardless of grain size.
