In this study,high-performance D18:L8-BO bulk heterojunction organic solar cells(OSCs)were prepared by employing a hot-solution strategy to optimize the active layer morphology during the film solidification process.B...In this study,high-performance D18:L8-BO bulk heterojunction organic solar cells(OSCs)were prepared by employing a hot-solution strategy to optimize the active layer morphology during the film solidification process.By heating the chloroform(CF)solution to 70℃(slightly above the boiling point of CF,~61.2℃),an optimal balance between solvent evaporation and molecular self-assembly was achieved,resulting in enhanced crystallinity,favorable π-π stacking,and ideal nanoscale phase separation.These improvements significantly boost the power conversion efficiency from 17.74%(for the device processed at a room temperature of 30℃)to 19.56%.Moreover,the in-situ grazing-incidence wide-angle X-ray scattering technology was utilized to monitor the crystallization and morphology evolution of the active layer,offering real-time insights into molecule self-assembly and phase separation dynamics during active layer solidification.This work not only provides a simple and scalable approach for fabricating high-efficiency OSCs but also offers fundamental insights into the influence of solution temperature on active layer morphology evolution dynamics,paving the way for large-scale industrial production of organic solar cells.展开更多
基金financially supported by the National Natural Science Foundation of China(61705003)。
文摘In this study,high-performance D18:L8-BO bulk heterojunction organic solar cells(OSCs)were prepared by employing a hot-solution strategy to optimize the active layer morphology during the film solidification process.By heating the chloroform(CF)solution to 70℃(slightly above the boiling point of CF,~61.2℃),an optimal balance between solvent evaporation and molecular self-assembly was achieved,resulting in enhanced crystallinity,favorable π-π stacking,and ideal nanoscale phase separation.These improvements significantly boost the power conversion efficiency from 17.74%(for the device processed at a room temperature of 30℃)to 19.56%.Moreover,the in-situ grazing-incidence wide-angle X-ray scattering technology was utilized to monitor the crystallization and morphology evolution of the active layer,offering real-time insights into molecule self-assembly and phase separation dynamics during active layer solidification.This work not only provides a simple and scalable approach for fabricating high-efficiency OSCs but also offers fundamental insights into the influence of solution temperature on active layer morphology evolution dynamics,paving the way for large-scale industrial production of organic solar cells.
