Hot plate forming using a cell-typed die is a process for forming a large thick plate with a spherical shape for the manufacture of a large spherical LNG tank.Cell-typed upper and lower dies made of a framework of ste...Hot plate forming using a cell-typed die is a process for forming a large thick plate with a spherical shape for the manufacture of a large spherical LNG tank.Cell-typed upper and lower dies made of a framework of steel plates fitted to make a grid pattern are used in this process,and an air-cooling device is separately installed inside the lower die.A finite element analysis (FEA) technique was developed,which included hot forming,air flow,cooling and thermal deformation analysis for the hot plate forming process using the cell-typed die.Further,the convective and interface heat transfer coefficients were used to reproduce analytically the effects of the cooling device in the hot plate forming analysis.A small-scale model test of the process was conducted to verify the FEA technique.The analysis results show that the curvature of the final plate agrees well with that of the designed experiment within a maximum relative error of 0.03% at the corner of the plate.展开更多
In this study,objective differences between the Cold(Han)and Hot(Re)nature of traditional Chinese medicines,e.g.Strobal and Rhubarb,are determined by using a cold/hot plate differentiation technology.A novel,self-desi...In this study,objective differences between the Cold(Han)and Hot(Re)nature of traditional Chinese medicines,e.g.Strobal and Rhubarb,are determined by using a cold/hot plate differentiation technology.A novel,self-designed cold/hot plate differentiating instrument,with methodological study,was used to investigate the intervention of Strobal and Rhubarb on the temperature tropism of mice.Compared with the ICR and BALB/c mice,it was found that KM mice on the cold/hot plate were more sensitive to the change of temperature,within the tolerant temperature range of 15-40℃.The temperature tropism behavior of mice is influenced by treatment with Rhubarb and Strobal,as is the activity of ATPase in liver tissue.These trends are consistent with the definition of the Cold/Hot nature of Chinese medicines based on traditional Chinese medicinal theory.This study showed that the differences of the Cold/Hot nature of traditional Chinese medicines.might be objectively represented by the temperature tropism of animal by means of cold/hot differentiating assay.展开更多
Objective:To investigate the effect of internal heat acupuncture on the tolerance time of plantar hot plate and the pain threshold of gastrocnemius in rats with chronic myofascial pain syndrome(MPS).Methods:A total of...Objective:To investigate the effect of internal heat acupuncture on the tolerance time of plantar hot plate and the pain threshold of gastrocnemius in rats with chronic myofascial pain syndrome(MPS).Methods:A total of 80 adult Wistar rats were randomly selected to establish chronic MPS rat models,and randomly divided into four groups:control group,acupuncture group,internal heat acupuncture group A,and internal heat acupuncture group B,with 20 rats in each group.The rats in the control group were not given any treatment,and the rats in the acupuncture group were only given acupuncture treatment.The rats in group A were treated with internal heat acupuncture(needle heating up to 42℃),and the rats in group B were treated with internal heat acupuncture(needle heating up to 44℃).The tolerance time of plantar hot plate,the pain threshold of gastrocnemius muscle and the level of tumor necrosis factor-α(TNF-α)were observed and compared before modeling,1 d before treatment,and 1,7 and 14 d after treatment.Results:There were significant differences in hot plate tolerance time,time and interaction among the four groups(P<0.05),as well as in gastrocnemius tenderness threshold,time and interaction among the four groups(P<0.05),and there were also significant differences in TNF-αlevel among the three groups(P>0.05).There were significant differences in the number of electric shocks,time and interaction among the four groups(P<0.05).Conclusion:In contrast to conventional acupuncture treatment,internal heat acupuncture demonstrates greater efficacy in extending the tolerance duration of hot plate exposure and enhancing the pain threshold of the gastrocnemius muscle in rats afflicted with myofascial pain syndrome.Additionally,it accelerates the amelioration of inflammatory markers and motor function.However,it is important to note that the therapeutic impact of internal heat acupuncture may be influenced by its temperature,with 44℃being the most effective in this research.展开更多
Rolling force and temperature field are important parameters in the hot rolling process of plate steel.Most researchers use ANSYS/LS-DYNA and MSC.Marc to simulate the hot rolling process,however,software DEFORM-3D is ...Rolling force and temperature field are important parameters in the hot rolling process of plate steel.Most researchers use ANSYS/LS-DYNA and MSC.Marc to simulate the hot rolling process,however,software DEFORM-3D is not used widely in this field.Therefore,in this study,the commercially available finite element analysis software DEFORM-3D is used to simulate the distribution of rolling force,stress-effective,strain-effective and temperature field during the hot rolling process of plate steel with the size of 0.220 m×2.070 m×1.904 m.Both the simulated rolling force and temperature of the multi-pass are compared with the measured results.It is shown that the simulated values by the finite element method are approximate to the measured values in the hot rolling of plate steel.So the simulation can provide an important reference and optimization to make rolling process and parameters in steel factory.展开更多
Hot deformation behavior of a novel Ni-Cr-Mo-B heavy plate steel was studied by hot compression tests,which were conducted on a Gleeble-3800thermo-mechanical simulator corresponding to the temperature range of850-1 15...Hot deformation behavior of a novel Ni-Cr-Mo-B heavy plate steel was studied by hot compression tests,which were conducted on a Gleeble-3800thermo-mechanical simulator corresponding to the temperature range of850-1 150℃ with the strain rates of 0.01-10s-1 and the true strain of 0.8.The results suggest that the majority of flow curves exhibit a typical dynamic recrystallization（DRX）behavior with an apparent single peak stress followed by agradual fall towards a steady-state stress.Important characteristic parameters of flow behavior as critical stress/strain for initiation of DRX and peak and steady-state stress/strain were derived from curves of strain hardening rate versus stress and stress versus strain,respectively.Material constants of the investigated steel were determined based on Arrhenius-type constitutive equation,and then the peak stress was predicted by the equation with the hot deformation activation energy of 379 139J/mol,and the predicted values agree well with the experimental values.Furthermore,the effect of Zener-Hollomon parameter on the characteristic points of flow curves was studied using the power law relation,and the ratio of critical stress and strain to peak stress and strain were found to be 0.91and0.46,respectively.展开更多
Wear-resistant cladding plates consisting of a substrate（Q345 R） and a clad layer（BTW1） were bonded through hot rolling at the temperature of 1 200 ℃ and a rolling speed of 0.5 m/s. The microhardness of the cladd...Wear-resistant cladding plates consisting of a substrate（Q345 R） and a clad layer（BTW1） were bonded through hot rolling at the temperature of 1 200 ℃ and a rolling speed of 0.5 m/s. The microhardness of the cladding plate was also tested after being heat treated. The microstructure evolution on the interface of BTW1/Q345 R sheets under various reduction rates was investigated with a scanning electron microscope（SEM） and EBSD. It is found that the micro-cracks and oxide films on the interface disappear when the reduction is 80%, whereas the maximum uniform diffusion distance reaches 10 μm. As a result, a wide range of metallurgical bonding layers forms, which indicates an improved combination between the BTW1 and the Q345 R. Additionally, it is discovered that the unbroken oxide films on the interface are composed of Mn, Si or Cr at the reductions of 50% and 65%. The SEM fractography of tensile specimen demonstrates that the BTW1 has significant dimple characteristics and possesses lower-sized dimples with the increment in reduction, suggesting that the toughness and bonding strength of the cladding plates would be improved by the increase of reduction. The results reveal that a high rolling reduction causes the interfacial oxide film broken and further forms a higher-sized composite metallurgical bonding interface. The peak microhardness is achieved near the interface.展开更多
Natural convection flow of unsteady Maxwell fluid with the effects of constant magnetic force in the course of a porous media is investigated in this research work. Fluid motion between a channel of parallel plates is...Natural convection flow of unsteady Maxwell fluid with the effects of constant magnetic force in the course of a porous media is investigated in this research work. Fluid motion between a channel of parallel plates is tempted by time dependent shear stress applied on one plate. The governing partial differential equations of a model under consideration are transformed into ordinary differential equations by Laplace transform method and then solved for temperature and velocity fields. The obtained results for temperature fields are expressed in terms of complementary error function. The influences of involved parameters likes Hartmann number, Grashf number, Prandlt number and porosity parameter, on temperature and velocity profiles are shown graphically. There is no such result regarding Maxwell fluid in the existing literature.展开更多
A stainless steel clad plate composed of stainless steel and carbon steel was prepared by vacuum hot rolling process, and its microstructure, especially the bonding interface, was evaluated using an optical microscope...A stainless steel clad plate composed of stainless steel and carbon steel was prepared by vacuum hot rolling process, and its microstructure, especially the bonding interface, was evaluated using an optical microscope, a scanning electron micro- scope and a transmission electron microscope （TEM）. The corresponding mechanical properties were also assessed by means of hardness and shear tests. The results showed a bonding interface formed between stainless steel and carbon steel, which was relatively straight in macroscope but serrated in microscope. Decarburization layer and carbon-enriched layer were distinguished at the side of carbon steel and stainless steel near the interface, respectively, which should be related to diffusion of carbon and alloying elements. The carbon-enriched layer could also be identified as a recombination region, whose microstructure was mainly recognized as martensite by TEM. Consequently, the hardness was the highest at this region. Furthermore, the result of shear test at the bonding interface showed that the shear strength was 395 MPa and the fracture mode was dominated as ductile fracture, indicating the bonding interface with good quality.展开更多
In order to study the bending behavior of aluminum alloy 7050 thick plate during snake hot rolling, several coupled thermo-mechanical finite element(FE) models were established. Effects of different initial thicknesse...In order to study the bending behavior of aluminum alloy 7050 thick plate during snake hot rolling, several coupled thermo-mechanical finite element(FE) models were established. Effects of different initial thicknesses, pass reductions, speed ratios and offset distances on the bending value of the plate were analyzed. ‘Quasi smooth plate' and optimum offset distance were defined and quasi smooth plate could be acquired by adjusting offset distance, and then bending control equation was fitted. The results show that bending value of the plate as well as the extent of the increase grows with the increase of pass reduction and decrease of initial thickness; the bending value firstly increases and then keeps steady with the ascending speed ratio; the bending value can be reduced by enlarging the offset distance. The optimum offset distance varies for different rolling parameters and it is augmented with the increase of pass reduction and speed ratio and the decrease of initial thickness. A proper offset distance for different rolling parameters can be calculated by the bending control equation and this equation can be a guidance to acquire a quasi smooth plate. The FEM results agree well with experimental results.展开更多
Vacuum hot roll bonding （VHRB） was used to bond pure titanium （Ti） plate to a 304 stainless steel （SS） plate with a niobium （Nb） interlayer, with the aim of producing a high-quality Ti-SS clad plate. The roll-...Vacuum hot roll bonding （VHRB） was used to bond pure titanium （Ti） plate to a 304 stainless steel （SS） plate with a niobium （Nb） interlayer, with the aim of producing a high-quality Ti-SS clad plate. The roll-bonding process was performed at different temperatures in the range of 850-1000℃, followed by characterization of microstructure and mechanical properties. The study demonstrates that the interfaces are free from cracks and discontinuities, and interdiffusion between the stainless steel and the titanium is effectively prevented by inserting a layer of pure Nb foil. No intermetallic reaction layer occurred at the Nb-Ti interface at any of the investigated temperatures. An intermetallic FeNb phase was formed at the Nb-SS interface when bonding was performed at 950 ℃ and above. The presence of the FeNb layer was confirmed by x-ray diffraction. The maximum shear strength of -396 MPa was obtained when bonding is carried out at 900 ℃. However, the formation of the FeNb layer at roll bonding temperature greater than 900 ℃ led to decrease in shear strength. Ductile fracture occurred through the Ti-Nb interface for roll-bonded temperatures of up to 900 ℃. On the other hand, at temperature of 950℃ and above, failure occurred through the Nb-SS interface, with brittle fracture characteristics.展开更多
As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufact...As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufacturing, transportation and/or storage of the plates. General corrosion often takes place on the surface of a plate in the exterior part of a package, and only reduces the thickness of the plate and slightly increases the roughness of the surface; however, localized corrosion on the surface of a plate inside the package is likely to result in the formation of pit-like defects on the substrate of the plate, which cannot be removed thoroughly by normal acid pickling or sand blasting, and affects the application of the plate. This research report analyzes the phenomena and characteristics of the rusting behavior of hot- rolled steel plates for automobile applications, and the influencing factors are summaried. The corresponding preventative measures are proposed.展开更多
To study the effect of free radical photocurable passivation film modified by titanate coupling agent for hot-plated aluminum-zinc plate,trimethylpropane triacrylate(TMPTA)and 2-phenoxyethyl acrylate were used as acti...To study the effect of free radical photocurable passivation film modified by titanate coupling agent for hot-plated aluminum-zinc plate,trimethylpropane triacrylate(TMPTA)and 2-phenoxyethyl acrylate were used as active diluents,a mixture of modified epoxy acrylate and modified polyester acrylate in a certain proportion was used as an oligomer,2-methyl-1-[4-(methylothyl)benzene]-2-morpholine acetone(907)was used as a free radical photoinitiator,isopropyl thioxanthone(ITX)was used as sensitizer,and bis(dioctyl phosphate acyl)titanate ethyltitanate acrylamide chelate(FD-812)was used as corrosion inhibitor modifier.After UV-curing,the passivation film was characterized by neutral salt spray test,electrochemical testing and other methods.The general performance of the passivation film may meet the requirements of downstream users of hot aluminum-zinc steel plate.The neutral salt spray test,electrochemical testing and microscopic surface morphology analysis of passivation film are in agreement.The introduction of titanate components may effectively promote the photocuring of free radicals.There have been few reports on the titanate coupling which is added to UV-curing coating formula.The titanate coupling agent contains acrylamide groups and terminal amine groups,acrylamide group has oligomer and crosslinking monomer,the terminal tertiary amine groups can provide hydrogen protons,reduce oxygen polymerization,and a phosphating film is formed on the surface of the metal substrate to improve the adhesion and corrosion resistance of the coating.展开更多
The basic formulation of Al2O3- C slide plates was65%（ in mass,the same hereinafter） white fused corundum particles,25% white fused corundum fines,6% active α-Al2O3 micropowder,4% carbon black and flake graphite, a...The basic formulation of Al2O3- C slide plates was65%（ in mass,the same hereinafter） white fused corundum particles,25% white fused corundum fines,6% active α-Al2O3 micropowder,4% carbon black and flake graphite, and additional 4% phenolic resin.Based on this formulation,3% Al powder,3% Si powder,and 3% Al ＋ 3% Si powder were used to substitute equivalent white corundum fines to improve the hot mechanical properties of Al2O3- C slide plates. The specimens with dimensions of 140 mm × 25 mm × 25 mm were pressed at 150 MPa,dried at 200 ℃ for 24 h,and hot treated at 1 400 ℃ for 3 h in carbon embedded condition. Then hot modulus of rupture and thermal shock resistance of the specimens were tested and the phase compositions and microstructure were analyzed. The results show that specimen with 3% Al powder has the higher hot modulus of rupture but lower residual modulus of rupture after thermal shock than the specimen with3% Si powder; the specimen with 3% Al ＋ 3% Si powders exhibits the highest hot modulus of rupture and the best thermal shock resistance; the change of mechanical property is closely related with the in-situ formed nonoxides： AlN in the form of bars is formed in specimens with Al powder; fibrous SiC whiskers are formed in specimens with Si powder; in the specimens with both Al and Sipowders,besides AlN and SiC whiskers,hexagonal tabular SiAlON is in-situ synthesized,which interlocks with each other.展开更多
The composition and production technology of the type of hot-rolled steel plate used in two-sided enameling were briefly described. The microstructure and mechanical properties before and after enameling were contrast...The composition and production technology of the type of hot-rolled steel plate used in two-sided enameling were briefly described. The microstructure and mechanical properties before and after enameling were contrastively investigated,and the precipitates in the samples were analyzed using transmission electron microscope and energy dispersive spectrometer. The results show the ferrite grain size of the steel plate after high-temperature enamel firing to be fine,with a large number of TiC and Ti;C;S;precipitates dispersed throughout the ferrite matrix. After two rounds of enamel firing at a temperature range of 800-890 ℃,its yield strength can still reach342 MPa. The results of a hydrogen permeation test show that the hydrogen storage properties of the steel plate are much better than those of ordinary structural carbon steel. A better bubble structure in the enamel layer can be obtained by this steel plate,with no fish-scale defects on the enameled steel-plate surface.展开更多
The surface treatment technology of hot aluminum-zinc steel plate and UV curing technology may be effectively combined in the present research. According to different light curing mechanisms, different formulations fr...The surface treatment technology of hot aluminum-zinc steel plate and UV curing technology may be effectively combined in the present research. According to different light curing mechanisms, different formulations from UV curing surface treatment agents can be applied to the surface treatment of hot aluminum-zinc steel plate, mainly including 3-ethyl-3-benzoxy-methyl oxacyclobutane (TCM 104) and 3,4-epoxy-cyclohexylformic acid -3',4'-epoxy-cyclohexyl methyl ester (UVR 6110) as active diluents, high molecular weight polyfunctional oxacyclobutane as oligomer, triaryl sulfonium salt as a cationic photoinitiator, and an anthracene compound as a sensitizer. 385 nm LED lamp used as a radiation resource, the effects of the proportion of active diluent, the type and amount of photoinitiator, the amount of sensitizer, the curing temperature, and the amount of nano-SiO<sub>2</sub> on the photocuring rate were investigated by photoper-scanning differential calorimetry (Photo-DSC). The experimental results show that the system has the fastest photocuring rate under the conditions of 8:2 ratio of TCM 104 to UVR 6110, 2.5% photoinitiator, 0.6% sensitizer, 0.2% nano-SiO<sub>2</sub> additive, and 80˚C curing temperature. Based on addition of the appropriate number of various additives, the cationic photocuring surface treatment solution was prepared and further coated on the hot-dip galvalume steel plates. After curing, the passivation films were characterized by neutral salt spray test (NSST), Fourier transform infrared spectroscopy (FT-IR), electrochemical testing and other methods. The results show that the formulations could be cured at an energy of 150 mJ/cm<sup>2</sup>, and the overall performance of the passivation film could meet with the requirements of the downstream users.展开更多
基金Project(2010-0008-277)supported by the NCRC(National Core Research Center)Program through the National Research Foundation of Korea,funded by the Ministry of Education,Science,and TechnologyProject supported by R&D for Technology Development Program of Ministry of Knowledge Economy,Korea
文摘Hot plate forming using a cell-typed die is a process for forming a large thick plate with a spherical shape for the manufacture of a large spherical LNG tank.Cell-typed upper and lower dies made of a framework of steel plates fitted to make a grid pattern are used in this process,and an air-cooling device is separately installed inside the lower die.A finite element analysis (FEA) technique was developed,which included hot forming,air flow,cooling and thermal deformation analysis for the hot plate forming process using the cell-typed die.Further,the convective and interface heat transfer coefficients were used to reproduce analytically the effects of the cooling device in the hot plate forming analysis.A small-scale model test of the process was conducted to verify the FEA technique.The analysis results show that the curvature of the final plate agrees well with that of the designed experiment within a maximum relative error of 0.03% at the corner of the plate.
基金Supported by the National Basic Research and Development Program of China(Grant No.2007CB512607)
文摘In this study,objective differences between the Cold(Han)and Hot(Re)nature of traditional Chinese medicines,e.g.Strobal and Rhubarb,are determined by using a cold/hot plate differentiation technology.A novel,self-designed cold/hot plate differentiating instrument,with methodological study,was used to investigate the intervention of Strobal and Rhubarb on the temperature tropism of mice.Compared with the ICR and BALB/c mice,it was found that KM mice on the cold/hot plate were more sensitive to the change of temperature,within the tolerant temperature range of 15-40℃.The temperature tropism behavior of mice is influenced by treatment with Rhubarb and Strobal,as is the activity of ATPase in liver tissue.These trends are consistent with the definition of the Cold/Hot nature of Chinese medicines based on traditional Chinese medicinal theory.This study showed that the differences of the Cold/Hot nature of traditional Chinese medicines.might be objectively represented by the temperature tropism of animal by means of cold/hot differentiating assay.
文摘Objective:To investigate the effect of internal heat acupuncture on the tolerance time of plantar hot plate and the pain threshold of gastrocnemius in rats with chronic myofascial pain syndrome(MPS).Methods:A total of 80 adult Wistar rats were randomly selected to establish chronic MPS rat models,and randomly divided into four groups:control group,acupuncture group,internal heat acupuncture group A,and internal heat acupuncture group B,with 20 rats in each group.The rats in the control group were not given any treatment,and the rats in the acupuncture group were only given acupuncture treatment.The rats in group A were treated with internal heat acupuncture(needle heating up to 42℃),and the rats in group B were treated with internal heat acupuncture(needle heating up to 44℃).The tolerance time of plantar hot plate,the pain threshold of gastrocnemius muscle and the level of tumor necrosis factor-α(TNF-α)were observed and compared before modeling,1 d before treatment,and 1,7 and 14 d after treatment.Results:There were significant differences in hot plate tolerance time,time and interaction among the four groups(P<0.05),as well as in gastrocnemius tenderness threshold,time and interaction among the four groups(P<0.05),and there were also significant differences in TNF-αlevel among the three groups(P>0.05).There were significant differences in the number of electric shocks,time and interaction among the four groups(P<0.05).Conclusion:In contrast to conventional acupuncture treatment,internal heat acupuncture demonstrates greater efficacy in extending the tolerance duration of hot plate exposure and enhancing the pain threshold of the gastrocnemius muscle in rats afflicted with myofascial pain syndrome.Additionally,it accelerates the amelioration of inflammatory markers and motor function.However,it is important to note that the therapeutic impact of internal heat acupuncture may be influenced by its temperature,with 44℃being the most effective in this research.
文摘Rolling force and temperature field are important parameters in the hot rolling process of plate steel.Most researchers use ANSYS/LS-DYNA and MSC.Marc to simulate the hot rolling process,however,software DEFORM-3D is not used widely in this field.Therefore,in this study,the commercially available finite element analysis software DEFORM-3D is used to simulate the distribution of rolling force,stress-effective,strain-effective and temperature field during the hot rolling process of plate steel with the size of 0.220 m×2.070 m×1.904 m.Both the simulated rolling force and temperature of the multi-pass are compared with the measured results.It is shown that the simulated values by the finite element method are approximate to the measured values in the hot rolling of plate steel.So the simulation can provide an important reference and optimization to make rolling process and parameters in steel factory.
基金Sponsored by National Natural Science Foundation of China(51071019,51371030)National High Technology Research and Development Program of China(2013AA031601)National Key Technology Research and Development Program of the Ministry of Science and Technology of China(2011BAE25B01)
文摘Hot deformation behavior of a novel Ni-Cr-Mo-B heavy plate steel was studied by hot compression tests,which were conducted on a Gleeble-3800thermo-mechanical simulator corresponding to the temperature range of850-1 150℃ with the strain rates of 0.01-10s-1 and the true strain of 0.8.The results suggest that the majority of flow curves exhibit a typical dynamic recrystallization（DRX）behavior with an apparent single peak stress followed by agradual fall towards a steady-state stress.Important characteristic parameters of flow behavior as critical stress/strain for initiation of DRX and peak and steady-state stress/strain were derived from curves of strain hardening rate versus stress and stress versus strain,respectively.Material constants of the investigated steel were determined based on Arrhenius-type constitutive equation,and then the peak stress was predicted by the equation with the hot deformation activation energy of 379 139J/mol,and the predicted values agree well with the experimental values.Furthermore,the effect of Zener-Hollomon parameter on the characteristic points of flow curves was studied using the power law relation,and the ratio of critical stress and strain to peak stress and strain were found to be 0.91and0.46,respectively.
基金the National Natural Science Foundation of China(No.U151013)the Key Research and Development Program of Shanxi Province(Nos.201603D111004 and 201603D121010)+1 种基金the Natural Science Foundation of Shanxi Province of Chinathe Provincial Special Fund for Coordinative Innovation Center of Taiyuan Heavy Machinery Equipmen(No.20171003)
文摘Wear-resistant cladding plates consisting of a substrate（Q345 R） and a clad layer（BTW1） were bonded through hot rolling at the temperature of 1 200 ℃ and a rolling speed of 0.5 m/s. The microhardness of the cladding plate was also tested after being heat treated. The microstructure evolution on the interface of BTW1/Q345 R sheets under various reduction rates was investigated with a scanning electron microscope（SEM） and EBSD. It is found that the micro-cracks and oxide films on the interface disappear when the reduction is 80%, whereas the maximum uniform diffusion distance reaches 10 μm. As a result, a wide range of metallurgical bonding layers forms, which indicates an improved combination between the BTW1 and the Q345 R. Additionally, it is discovered that the unbroken oxide films on the interface are composed of Mn, Si or Cr at the reductions of 50% and 65%. The SEM fractography of tensile specimen demonstrates that the BTW1 has significant dimple characteristics and possesses lower-sized dimples with the increment in reduction, suggesting that the toughness and bonding strength of the cladding plates would be improved by the increase of reduction. The results reveal that a high rolling reduction causes the interfacial oxide film broken and further forms a higher-sized composite metallurgical bonding interface. The peak microhardness is achieved near the interface.
文摘Natural convection flow of unsteady Maxwell fluid with the effects of constant magnetic force in the course of a porous media is investigated in this research work. Fluid motion between a channel of parallel plates is tempted by time dependent shear stress applied on one plate. The governing partial differential equations of a model under consideration are transformed into ordinary differential equations by Laplace transform method and then solved for temperature and velocity fields. The obtained results for temperature fields are expressed in terms of complementary error function. The influences of involved parameters likes Hartmann number, Grashf number, Prandlt number and porosity parameter, on temperature and velocity profiles are shown graphically. There is no such result regarding Maxwell fluid in the existing literature.
文摘A stainless steel clad plate composed of stainless steel and carbon steel was prepared by vacuum hot rolling process, and its microstructure, especially the bonding interface, was evaluated using an optical microscope, a scanning electron micro- scope and a transmission electron microscope （TEM）. The corresponding mechanical properties were also assessed by means of hardness and shear tests. The results showed a bonding interface formed between stainless steel and carbon steel, which was relatively straight in macroscope but serrated in microscope. Decarburization layer and carbon-enriched layer were distinguished at the side of carbon steel and stainless steel near the interface, respectively, which should be related to diffusion of carbon and alloying elements. The carbon-enriched layer could also be identified as a recombination region, whose microstructure was mainly recognized as martensite by TEM. Consequently, the hardness was the highest at this region. Furthermore, the result of shear test at the bonding interface showed that the shear strength was 395 MPa and the fracture mode was dominated as ductile fracture, indicating the bonding interface with good quality.
基金Projects(2012CB619505,2010CB731703)supported by the National Basic Research Program of ChinaProject(CX2013B065)supported by Hunan Provincial Innovation Foundation for Postgraduate,China+1 种基金Project(51405520)supported by the National Natural Science Foundation of ChinaProject(zzyjkt2013-06B)supported by the State Key Laboratory of High Performance Complex Manufacturing(Central South University),China
文摘In order to study the bending behavior of aluminum alloy 7050 thick plate during snake hot rolling, several coupled thermo-mechanical finite element(FE) models were established. Effects of different initial thicknesses, pass reductions, speed ratios and offset distances on the bending value of the plate were analyzed. ‘Quasi smooth plate' and optimum offset distance were defined and quasi smooth plate could be acquired by adjusting offset distance, and then bending control equation was fitted. The results show that bending value of the plate as well as the extent of the increase grows with the increase of pass reduction and decrease of initial thickness; the bending value firstly increases and then keeps steady with the ascending speed ratio; the bending value can be reduced by enlarging the offset distance. The optimum offset distance varies for different rolling parameters and it is augmented with the increase of pass reduction and speed ratio and the decrease of initial thickness. A proper offset distance for different rolling parameters can be calculated by the bending control equation and this equation can be a guidance to acquire a quasi smooth plate. The FEM results agree well with experimental results.
基金financially supported by the Fundamental Research Funds for Chinese Central Universities(No.N110607001)National High Technical Research and Development Programme of China(No.2013AA031302)
文摘Vacuum hot roll bonding （VHRB） was used to bond pure titanium （Ti） plate to a 304 stainless steel （SS） plate with a niobium （Nb） interlayer, with the aim of producing a high-quality Ti-SS clad plate. The roll-bonding process was performed at different temperatures in the range of 850-1000℃, followed by characterization of microstructure and mechanical properties. The study demonstrates that the interfaces are free from cracks and discontinuities, and interdiffusion between the stainless steel and the titanium is effectively prevented by inserting a layer of pure Nb foil. No intermetallic reaction layer occurred at the Nb-Ti interface at any of the investigated temperatures. An intermetallic FeNb phase was formed at the Nb-SS interface when bonding was performed at 950 ℃ and above. The presence of the FeNb layer was confirmed by x-ray diffraction. The maximum shear strength of -396 MPa was obtained when bonding is carried out at 900 ℃. However, the formation of the FeNb layer at roll bonding temperature greater than 900 ℃ led to decrease in shear strength. Ductile fracture occurred through the Ti-Nb interface for roll-bonded temperatures of up to 900 ℃. On the other hand, at temperature of 950℃ and above, failure occurred through the Nb-SS interface, with brittle fracture characteristics.
文摘As one of the important categories of hot-rolled products, hot-rolled steel plates for automobile applications generally undergo uniform corrosion or localized corrosion according to different environments of manufacturing, transportation and/or storage of the plates. General corrosion often takes place on the surface of a plate in the exterior part of a package, and only reduces the thickness of the plate and slightly increases the roughness of the surface; however, localized corrosion on the surface of a plate inside the package is likely to result in the formation of pit-like defects on the substrate of the plate, which cannot be removed thoroughly by normal acid pickling or sand blasting, and affects the application of the plate. This research report analyzes the phenomena and characteristics of the rusting behavior of hot- rolled steel plates for automobile applications, and the influencing factors are summaried. The corresponding preventative measures are proposed.
基金by the National Basic Research Program of China(2009AA03Z529)。
文摘To study the effect of free radical photocurable passivation film modified by titanate coupling agent for hot-plated aluminum-zinc plate,trimethylpropane triacrylate(TMPTA)and 2-phenoxyethyl acrylate were used as active diluents,a mixture of modified epoxy acrylate and modified polyester acrylate in a certain proportion was used as an oligomer,2-methyl-1-[4-(methylothyl)benzene]-2-morpholine acetone(907)was used as a free radical photoinitiator,isopropyl thioxanthone(ITX)was used as sensitizer,and bis(dioctyl phosphate acyl)titanate ethyltitanate acrylamide chelate(FD-812)was used as corrosion inhibitor modifier.After UV-curing,the passivation film was characterized by neutral salt spray test,electrochemical testing and other methods.The general performance of the passivation film may meet the requirements of downstream users of hot aluminum-zinc steel plate.The neutral salt spray test,electrochemical testing and microscopic surface morphology analysis of passivation film are in agreement.The introduction of titanate components may effectively promote the photocuring of free radicals.There have been few reports on the titanate coupling which is added to UV-curing coating formula.The titanate coupling agent contains acrylamide groups and terminal amine groups,acrylamide group has oligomer and crosslinking monomer,the terminal tertiary amine groups can provide hydrogen protons,reduce oxygen polymerization,and a phosphating film is formed on the surface of the metal substrate to improve the adhesion and corrosion resistance of the coating.
文摘The basic formulation of Al2O3- C slide plates was65%（ in mass,the same hereinafter） white fused corundum particles,25% white fused corundum fines,6% active α-Al2O3 micropowder,4% carbon black and flake graphite, and additional 4% phenolic resin.Based on this formulation,3% Al powder,3% Si powder,and 3% Al ＋ 3% Si powder were used to substitute equivalent white corundum fines to improve the hot mechanical properties of Al2O3- C slide plates. The specimens with dimensions of 140 mm × 25 mm × 25 mm were pressed at 150 MPa,dried at 200 ℃ for 24 h,and hot treated at 1 400 ℃ for 3 h in carbon embedded condition. Then hot modulus of rupture and thermal shock resistance of the specimens were tested and the phase compositions and microstructure were analyzed. The results show that specimen with 3% Al powder has the higher hot modulus of rupture but lower residual modulus of rupture after thermal shock than the specimen with3% Si powder; the specimen with 3% Al ＋ 3% Si powders exhibits the highest hot modulus of rupture and the best thermal shock resistance; the change of mechanical property is closely related with the in-situ formed nonoxides： AlN in the form of bars is formed in specimens with Al powder; fibrous SiC whiskers are formed in specimens with Si powder; in the specimens with both Al and Sipowders,besides AlN and SiC whiskers,hexagonal tabular SiAlON is in-situ synthesized,which interlocks with each other.
文摘The composition and production technology of the type of hot-rolled steel plate used in two-sided enameling were briefly described. The microstructure and mechanical properties before and after enameling were contrastively investigated,and the precipitates in the samples were analyzed using transmission electron microscope and energy dispersive spectrometer. The results show the ferrite grain size of the steel plate after high-temperature enamel firing to be fine,with a large number of TiC and Ti;C;S;precipitates dispersed throughout the ferrite matrix. After two rounds of enamel firing at a temperature range of 800-890 ℃,its yield strength can still reach342 MPa. The results of a hydrogen permeation test show that the hydrogen storage properties of the steel plate are much better than those of ordinary structural carbon steel. A better bubble structure in the enamel layer can be obtained by this steel plate,with no fish-scale defects on the enameled steel-plate surface.
文摘The surface treatment technology of hot aluminum-zinc steel plate and UV curing technology may be effectively combined in the present research. According to different light curing mechanisms, different formulations from UV curing surface treatment agents can be applied to the surface treatment of hot aluminum-zinc steel plate, mainly including 3-ethyl-3-benzoxy-methyl oxacyclobutane (TCM 104) and 3,4-epoxy-cyclohexylformic acid -3',4'-epoxy-cyclohexyl methyl ester (UVR 6110) as active diluents, high molecular weight polyfunctional oxacyclobutane as oligomer, triaryl sulfonium salt as a cationic photoinitiator, and an anthracene compound as a sensitizer. 385 nm LED lamp used as a radiation resource, the effects of the proportion of active diluent, the type and amount of photoinitiator, the amount of sensitizer, the curing temperature, and the amount of nano-SiO<sub>2</sub> on the photocuring rate were investigated by photoper-scanning differential calorimetry (Photo-DSC). The experimental results show that the system has the fastest photocuring rate under the conditions of 8:2 ratio of TCM 104 to UVR 6110, 2.5% photoinitiator, 0.6% sensitizer, 0.2% nano-SiO<sub>2</sub> additive, and 80˚C curing temperature. Based on addition of the appropriate number of various additives, the cationic photocuring surface treatment solution was prepared and further coated on the hot-dip galvalume steel plates. After curing, the passivation films were characterized by neutral salt spray test (NSST), Fourier transform infrared spectroscopy (FT-IR), electrochemical testing and other methods. The results show that the formulations could be cured at an energy of 150 mJ/cm<sup>2</sup>, and the overall performance of the passivation film could meet with the requirements of the downstream users.
