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Suppressing the hot carrier injection degradation rate in total ionizing dose effect hardened nMOSFETs 被引量:1
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作者 陈建军 陈书明 +3 位作者 梁斌 何益百 池雅庆 邓科峰 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第11期346-352,共7页
Annular gate nMOSFETs are frequently used in spaceborne integrated circuits due to their intrinsic good capability of resisting total ionizing dose (TID) effect. However, their capability of resisting the hot carrie... Annular gate nMOSFETs are frequently used in spaceborne integrated circuits due to their intrinsic good capability of resisting total ionizing dose (TID) effect. However, their capability of resisting the hot carrier effect (HCE) has also been proven to be very weak. In this paper, the reason why the annular gate nMOSFETs have good TID but bad HCE resistance is discussed in detail, and an improved design to locate the source contacts only along one side of the annular gate is used to weaken the HCE degradation. The good TID and HCE hardened capability of the design are verified by the experiments for I/O and core nMOSFETs in a 0.18 μm bulk CMOS technology. In addition, the shortcoming of this design is also discussed and the TID and the HCE characteristics of the replacers (the annular source nMOSFETs) are also studied to provide a possible alternative for the designers. 展开更多
关键词 annular gate nmosFETs total ionizing dose effect hot carrier effect annular sourcenmosFETs
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1/f~γ Noise Characteristics of an n-MOSFET Under DC Hot Carrier Stress
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作者 刘宇安 余晓光 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第7期1263-1267,共5页
The 1/fγ noise characteristic parameter Sfγ model in an n-MOSFET under DC hot carrier stress is studied. A method characterizing the MOSFET abilities of an anti-hot carrier with noise parameter Sfγ is presented. Th... The 1/fγ noise characteristic parameter Sfγ model in an n-MOSFET under DC hot carrier stress is studied. A method characterizing the MOSFET abilities of an anti-hot carrier with noise parameter Sfγ is presented. The hot carrier degradation effect of n-MOSFET in high-,mid-,and low gate stresses and its 1/fγ noise feature are studied. Experimental results agree well with the developed model. 展开更多
关键词 N-mosFET hot carrier 1/fγ noise
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Hot carrier degradation and a new lifetime prediction model in ultra-deep sub-micron pMOSFET
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作者 雷晓艺 刘红侠 +4 位作者 张凯 张月 郑雪峰 马晓华 郝跃 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第4期434-437,共4页
The hot carrier effect (HCE) of an ultra-deep sub-micron p-channel metal–oxide semiconductor field-effect transistor (pMOSFET) is investigated in this paper. Experiments indicate that the generation of positively... The hot carrier effect (HCE) of an ultra-deep sub-micron p-channel metal–oxide semiconductor field-effect transistor (pMOSFET) is investigated in this paper. Experiments indicate that the generation of positively charged interface states is the predominant mechanism in the case of the ultra-deep sub-micron pMOSFET. The relation of the pMOSFET hot carrier degradation to stress time (t), channel width (W ), channel length (L), and stress voltage (Vd ) is then discussed. Based on the relation, a lifetime prediction model is proposed, which can predict the lifetime of the ultra-deep sub-micron pMOSFET accurately and reflect the influence of the factors on hot carrier degradation directly. 展开更多
关键词 PmosFETS hot carrier effect (HCE) DEGRADATION lifetime modeling
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Actions of negative bias temperature instability (NBTI) and hot carriers in ultra-deep submicron p-channel metal-oxide-semiconductor field-effect transistors (PMOSFETs)
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作者 刘红侠 郝跃 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第7期2111-2115,共5页
Hot carrier injection (HCI) at high temperatures and different values of gate bias Vg has been performed in order to study the actions of negative bias temperature instability (NBTI) and hot carriers. Hot-carrier-... Hot carrier injection (HCI) at high temperatures and different values of gate bias Vg has been performed in order to study the actions of negative bias temperature instability (NBTI) and hot carriers. Hot-carrier-stress-induced damage at Vg = Vd, where Vd is the voltage of the transistor drain, increases as temperature rises, contrary to conventional hot carrier behaviour, which is identified as being related to the NBTI. A comparison between the actions of NBTI and hot carriers at low and high gate voltages shows that the damage behaviours are quite different: the low gate voltage stress results in an increase in transconductance, while the NBTI-dominated high gate voltage and high temperature stress causes a decrease in transconductance. It is concluded that this can be a major source of hot carrier damage at elevated temperatures and high gate voltage stressing of p-channel metal-oxide-semiconductor field-effect transistors (PMOSFETs). We demonstrate a novel mode of NBTI-enhanced hot carrier degradation in PMOSFETs. A novel method to decouple the actions of NBTI from that of hot carriers is also presented. 展开更多
关键词 ultra-deep submicron PmosFETs negative bias temperature instability (NBTI) hot carrier injection (HCI) positive fixed oxide charges
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STUDY ON THE RELATION BETWEEN STRUCTURE AND HOT CARRIER EFFECT IMMUNITY FOR DEEP SUB-MICRON GROOVED GATE NMOSFET's
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作者 Ren Hongxia Zhang Xiaoju Hao Yue Xu Donggang(Microelectronics Institute, Xidian University, Xi’an 710071) 《Journal of Electronics(China)》 2003年第3期202-208,共7页
Grooved gate structure Metal-Oxide-Semiconductor (MOS) device is consideredas the most promising candidate used in deep and super-deep sub-micron region, for it cansuppress hot carrier effect and short channel effect ... Grooved gate structure Metal-Oxide-Semiconductor (MOS) device is consideredas the most promising candidate used in deep and super-deep sub-micron region, for it cansuppress hot carrier effect and short channel effect deeply. Based on the hydrodynamic energytransport model, using two-dimensional device simulator Medici, the relation between structureparameters and hot carrier effect immunity for deep-sub-micron N-channel MOSFET's is studiedand compared with that of counterpart conventional planar device in this paper. The examinedstructure parameters include negative junction depth, concave corner and effective channel length.Simulation results show that grooved gate device can suppress hot carrier effect deeply even indeep sub-micron region. The studies also indicate that hot carrier effect is strongly influencedby the concave corner and channel length for grooved gate device. With the increase of concavecorner, the hot carrier effect in grooved gate MOSFET decreases sharply, and with the reducingof effective channel length, the hot carrier effect becomes large. 展开更多
关键词 Grooved gate NmosFET's hot carrier effect Deep sub-micron Structure parameter
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Impact of substrate injected hot electrons on hot carrier degradation in a 180-nm NMOSFET
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作者 梁斌 陈建军 池雅庆 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第11期502-506,共5页
Although hot carriers induced degradation of NMOSFETs has been studied for decades, the role of hot electron in this process is still debated. In this paper, the additional substrate hot electrons have been intentiona... Although hot carriers induced degradation of NMOSFETs has been studied for decades, the role of hot electron in this process is still debated. In this paper, the additional substrate hot electrons have been intentionally injected into the oxide layer to analyze tile role of hot electron in hot carrier degradation. The enhanced degradation and the decreased time exponent appear with the injected hot electrons increasing, the degradation increases from 21.80% to 62.00% and the time exponent decreases from 0.59 to 0.27 with Vb decreasing from 0 V to -4 V, at the same time, the recovery also becomes remarkable and which strongly depends on the post stress gate bias Vg. Based on the experimental results, more unrecovered interface traps are created by the additional injected hot electron from the breaking Si-H bond, but the oxide trapped negative charges do not increase after a rapid recovery. 展开更多
关键词 substrate hot electron injection hot carrier injection (HCI) degradation interface trap oxidetrapped charge
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Unified Degradation Model in Low Gate Voltage Range During Hot-Carrier Stressing of p-MOS Transistors
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作者 胡靖 穆甫臣 +1 位作者 许铭真 谭长华 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第2期124-130,共7页
Hot carrier effects of p MOSFETs with different oxide thicknesses are studied in low gate voltage range.All electrical parameters follow a power law relationship with stress time,but degradation slope is dependent ... Hot carrier effects of p MOSFETs with different oxide thicknesses are studied in low gate voltage range.All electrical parameters follow a power law relationship with stress time,but degradation slope is dependent on gate voltage.For the devices with thicker oxides,saturated drain current degradation has a close relationship with the product of gate current and electron fluence.For small dimensional devices,saturated drain current degradation has a close relationship with the electron fluence.This degradation model is valid for p MOSFETs with 0 25μm channel length and different gate oxide thicknesses. 展开更多
关键词 hot carrier effects p mosFET degradation model electron fluence
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Experimental Evidence of Interface-Trap-Related SILC in Ultrathin (4nm- and 2.5nm-Thick) n-MOSFET and p-MOSFET Under Hot-Carrier Stress
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作者 杨国勇 霍宗亮 +4 位作者 王金延 毛凌锋 王子欧 谭长华 许铭真 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2003年第6期579-585,共7页
Stress-induced leakage current (SILC) of ultrathin gate oxide is investigated by observing the generation of interface traps for n-MOSFET and p-MOSFET under hot-carrier stress.It is found experimentally that there is ... Stress-induced leakage current (SILC) of ultrathin gate oxide is investigated by observing the generation of interface traps for n-MOSFET and p-MOSFET under hot-carrier stress.It is found experimentally that there is linear correlation between the generation of interface traps and SILC for both types of MOSFET with different channel lengths (including 1,0.5,0.275,and 0.135μm) and different gate oxide thickness (4nm and 2.5nm).These experimental evidences show that the SILC has a strong dependence on interface traps. 展开更多
关键词 SILC hot carrier stress ultra-thin gate oxide mosFET
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New Forward Gated-Diode Technique for Separating Front Gate Interface- from Oxide-Traps Induced by Hot-Carrier-Stress in SOI-NMOSFETs
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作者 何进 张兴 +1 位作者 黄如 王阳元 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第1期11-15,共5页
The front gate interface and oxide traps induced by hot carrier stress in SOI NMOSFETs are studied.Based on a new forward gated diode technique,the R G current originating from the front interface traps is me... The front gate interface and oxide traps induced by hot carrier stress in SOI NMOSFETs are studied.Based on a new forward gated diode technique,the R G current originating from the front interface traps is measured,and then the densities of the interface and oxide traps are separated independently.The experimental results show that the hot carrier stress of front channel not only results in the strong generation of the front interface traps,but also in the significant oxide traps.These two kinds of traps have similar characteristic in increasing with the hot carrier stress time.This analysis allows one to obtain a clear physical picture of the effects of the hot carrier stress on the generating of interface and oxide traps,which help to understand the degradation and reliability of the SOI MOSFETs. 展开更多
关键词 SOI Nmos device hot carrier effect interface traps oxide traps gated diode
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Oxide Thickness Effects on n-MOSFETs Under On-State Hot-Carrier Stress
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作者 胡靖 穆甫臣 +1 位作者 许铭真 谭长华 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第3期290-295,共6页
Hot carrier induced (HCI) degradation of surface channel n MOSFETs with different oxide thicknesses is investigated under maximum substrate current condition.Results show that the key parameters m and n of H... Hot carrier induced (HCI) degradation of surface channel n MOSFETs with different oxide thicknesses is investigated under maximum substrate current condition.Results show that the key parameters m and n of Hu's lifetime prediction model have a close relationship with oxide thickness.Furthermore,a linear relationship is found between m and n .Based on this result,the lifetime prediction model can be expended to the device with thinner oxides. 展开更多
关键词 HCI hot carrier effect oxide thickness effect lifetime prediction model device reliability
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Regulation strategies of hot carrier cooling process in perovskite nanocrystals
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作者 Zhenyao Tan Kexin Xu +2 位作者 Yi Chen Can Ren Tingchao He 《Chinese Physics B》 2025年第9期507-517,共11页
Recent breakthroughs in hot carrier(HC)cooling dynamics within halide perovskite nanocrystals(NCs)have positioned them as promising candidates for next-generation optoelectronic applications.Therefore,it is of great i... Recent breakthroughs in hot carrier(HC)cooling dynamics within halide perovskite nanocrystals(NCs)have positioned them as promising candidates for next-generation optoelectronic applications.Therefore,it is of great importance to systematically summarize advances in understanding and controlling HC relaxation mechanisms.Here,we offer an overview of advances in the understanding of the HC cooling process in perovskite NCs,with a focus on influences of excitation energy,excitation intensity,composition,size,dimensionality,doping,and core-shell structure on the HC cooling times.Finally,we propose suggestions for future investigations into the HC cooling process in perovskite NCs. 展开更多
关键词 perovskite nanocrystals hot carrier cooling ultrafast dynamics
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An Improved Method to Extract Generation of Interface Trap in Hot-Carrier-Stressed LDD n-MOSFET
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作者 杨国勇 毛凌锋 +4 位作者 王金延 霍宗亮 王子欧 许铭真 谭长华 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2003年第8期803-808,共6页
A new improved technique,based on the direct current current voltage and charge pumping methods,is proposed for measurements of interface traps density in the channel and the drain region for LDD n MOSFET.This tech... A new improved technique,based on the direct current current voltage and charge pumping methods,is proposed for measurements of interface traps density in the channel and the drain region for LDD n MOSFET.This technique can be applied to virgin samples and those subjected to hot carrier stress,and the latter are known to cause the interface damage in the drain region and the channel region.The generation of interface traps density in the channel region and in the drain region can be clearly distinguished by using this technique. 展开更多
关键词 hot carrier stress LDD ultra thin gate oxide two step degradation
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Hot carrier effects of SOI NMOS
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作者 陈建军 陈书明 +3 位作者 梁斌 刘必慰 刘征 滕浙乾 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2010年第7期36-40,共5页
Hot carrier effect(HCE) is studied on annular NMOS and two-edged NMOS such as H-shape gate NMOS, T-shape gate NMOS and common two-edged NMOS.Based on the chemical reaction equation of HCE degradation and a geometry ... Hot carrier effect(HCE) is studied on annular NMOS and two-edged NMOS such as H-shape gate NMOS, T-shape gate NMOS and common two-edged NMOS.Based on the chemical reaction equation of HCE degradation and a geometry dependent reaction diffusion equation,a HCE degradation model for annular NMOS and two-edged NMOS is proposed.According to this model,we conclude that the time exponent of the threshold voltage degradation depends on the configuration of the gate,and annular NMOS has more serious HCE degradation than two-edged NMOS.The design,fabrication and HCE experiments of these NMOS in a 0.5-μm PD SOI process verify the correctness of the conclusion. 展开更多
关键词 annular Nmos two-edged Nmos hot carrier effects reaction diffusion model
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Layout and process hot carrier optimization of HV-nLEDMOS transistor
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作者 钱钦松 李海松 +1 位作者 孙伟锋 易扬波 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2009年第3期56-58,共3页
Two layout and process key parameters for improving high voltage nLEDMOS (n-type lateral extended drain MOS) transistor hot carrier performance have been identified. Increasing the space between Hv-pwell and n-drift... Two layout and process key parameters for improving high voltage nLEDMOS (n-type lateral extended drain MOS) transistor hot carrier performance have been identified. Increasing the space between Hv-pwell and n-drift region and reducing the n-drift implant dose can dramatically reduce the device hot carder degradations, for the maximum impact ionization rate near the Bird Beak decreases or its location moves away from the Si/SiO2 interface. This conclusion has been analyzed in detail by using the MEDICI simulator and it is also confirmed by the test results. 展开更多
关键词 nLEDmos hot carrier degradation layout PROCESS
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Positive Bias Temperature Instability and Hot Carrier Injection of Back Gate Ultra-thin-body In0.53Ga0.47As-on-Insulator n-Channel Metal-Oxide-Semiconductor Field-Effect Transistor 被引量:1
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作者 唐晓雨 卢继武 +6 位作者 张睿 吴枉然 刘畅 施毅 黄子乾 孔月婵 赵毅 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第11期127-130,共4页
Ultra-thin-body (UTB) In0.53Ga0.47As-on-insulator (In0.53Ga0.47As-OI) structures with thicknesses of 8 and 15nm are realized by transferring epitaxially grown In0.53Ga0.47As layers to silicon substrates with 15-nm... Ultra-thin-body (UTB) In0.53Ga0.47As-on-insulator (In0.53Ga0.47As-OI) structures with thicknesses of 8 and 15nm are realized by transferring epitaxially grown In0.53Ga0.47As layers to silicon substrates with 15-nmthick A12 03 as a buried oxide by using the direct wafer bonding method. Back gate n-channel metal-oxidesemiconductor field-effect transistors (nMOSFETs) are fabricated by using these In0.53Ga0.47As-OI structures with excellent electrical characteristics. Positive bias temperature instability (PBTI) and hot carrier injection (HCI) characterizations are performed for the In0.53Ga0.47As-OI nMOSFETs. It is confirmed that the In0.53Ga0.47 As-OI nMOSFETs with a thinner body thickness suffer from more severe degradations under both PBTI and HCr stresses. Moreover, the different evolutions of the threshold voltage and the saturation current of the UTB In0.53Ga0.47As-OI nMOSFETs may be due to the slow border traps. 展开更多
关键词 As-on-Insulator n-Channel Metal-Oxide-Semiconductor Field-Effect Transistor OI Positive Bias Temperature Instability and hot carrier Injection of Back Gate Ultra-thin-body In Ga
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Characterization of atomic-layer MoS_2 synthesized using a hot filament chemical vapor deposition method 被引量:1
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作者 彭英姿 宋扬 +3 位作者 解晓强 李源 钱正洪 白茹 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第5期423-428,共6页
Atomic-layer MoS_2 ultrathin films are synthesized using a hot filament chemical vapor deposition method. A combination of atomic force microscopy(AFM), x-ray diffraction(XRD), high-resolution transition electron ... Atomic-layer MoS_2 ultrathin films are synthesized using a hot filament chemical vapor deposition method. A combination of atomic force microscopy(AFM), x-ray diffraction(XRD), high-resolution transition electron microscopy(HRTEM), photoluminescence(PL), and x-ray photoelectron spectroscopy(XPS) characterization methods is applied to investigate the crystal structures, valence states, and compositions of the ultrathin film areas. The nucleation particles show irregular morphology, while for a larger size somewhere, the films are granular and the grains have a triangle shape. The films grow in a preferred orientation(002). The HRTEM images present the graphene-like structure of stacked layers with low density of stacking fault, and the interlayer distance of plane is measured to be about 0.63 nm. It shows a clear quasihoneycomb-like structure and 6-fold coordination symmetry. Room-temperature PL spectra for the atomic layer MoS_2 under the condition of right and left circular light show that for both cases, the A1 and B1 direct excitonic transitions can be observed. In the meantime, valley polarization resolved PL spectra are obtained. XPS measurements provide high-purity samples aside from some contaminations from the air, and confirm the presence of pure MoS_2. The stoichiometric mole ratio of S/Mo is about 2.0–2.1, suggesting that sulfur is abundant rather than deficient in the atomic layer MoS_2 under our experimental conditions. 展开更多
关键词 atomic-layer mos2 hot filament chemical vapor deposition high-resolution transition electron microscopy(HRTEM) x-ray photoelectron spectroscopy(XPS)
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Hot carrier injection degradation under dynamic stress
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作者 马晓华 曹艳荣 +1 位作者 郝跃 张月 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第3期402-406,共5页
In this paper, we have studied hot carrier injection (HCI) different degradations are obtained from the experiment results. under alternant stress. Under different stress modes, The different alternate stresses can ... In this paper, we have studied hot carrier injection (HCI) different degradations are obtained from the experiment results. under alternant stress. Under different stress modes, The different alternate stresses can reduce or enhance the HC effect, which mainly depends on the latter condition of the stress cycle. In the stress mode A (DC stress with electron injection), the degradation keeps increasing. In the stress modes B (DC stress and then stress with the smMlest gate injection) and C (DC stress and then stress with hole injection under Vg = 0 V and Vd = 1.8 V), recovery appears in the second stress period. And in the stress mode D (DC stress and then stress with hole injection under Vg = -1.8 V and Vd = 1.8 V), as the traps filled in by holes can be smaller or greater than the generated interface states, the continued degradation or recovery in different stress periods can be obtained. 展开更多
关键词 hot carrier injection alternate stress RECOVERY DEGRADATION
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Ultrafast Dynamics of Defect-Assisted Carrier Capture in MoS2 Nanodots Investigated by Transient Absorption Spectroscopy
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作者 Da Ke Lai-zhi Sui +8 位作者 Dun-li Liu Jian-qiu Cui Yun-feng Zhang Qing-yi Li Su-yu Li Yuan-fei Jiang An-min Chen Jun-ling Song Ming-xing Jin 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2018年第3期277-283,367,共8页
MoS2 nanodots are emerging as promising semiconductor materials for optoelectronic devices. However, most of the recent attention is focused on the fabrication of MoS2 nanodots,and the survey for exciton dynamics of M... MoS2 nanodots are emerging as promising semiconductor materials for optoelectronic devices. However, most of the recent attention is focused on the fabrication of MoS2 nanodots,and the survey for exciton dynamics of MoS2 nanodots remains less explored. Herein, we use femtosecond transient absorption spectroscopy to investigate the carrier dynamics of MoS2 nanodots. Our results show that defect-assisted carrier recombination processes are well consistent with the observed dynamics. The photo-excited carriers are captured by defects with at least two different capture rates via Auger scattering. Four processes are deemed to take part in the carrier relaxation. After photoexcitation, carrier cooling occurs instantly within ~0.5 ps. Then most of carriers are fast captured by the defects, and the corresponding time constant increases from ~4.9 ps to ~9.2 ps with increasing pump fluence, which may be interpreted by saturation of the defect states. Next a small quantity of carriers is captured by the other kinds of defects with a relatively slow carrier capture time within ~65 ps.Finally, the remaining small fraction of carriers relaxes via direct interband electron-hole recombination within~1 ns. Our results may lead to deep insight into the fundamentals of carrier dynamics in MoS2 nanodots, paving the way for their further applications. 展开更多
关键词 mos2 Transient absorption spectroscopy Defect-assisted carrier CAPTURE
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Tuning hot carrier transfer dynamics by perovskite surface modification
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作者 Chenghao Ge Peng Wang +5 位作者 Pei Yuan Tai Wu Rongjun Zhao Rong Huang Lin Xie Yong Hua 《Chinese Chemical Letters》 SCIE CAS CSCD 2024年第10期457-460,共4页
Understanding the role of perovskite surface passivators in hot carriers transfer dynamics is important to develop highly efficient perovskite solar cells(PSCs).In this work,we have designed and synthesized a naphthal... Understanding the role of perovskite surface passivators in hot carriers transfer dynamics is important to develop highly efficient perovskite solar cells(PSCs).In this work,we have designed and synthesized a naphthalimide-based organic small molecule(NCN)for perovskite surface defect passivator.We reveal that the introduction of NCN not only reduces the density of perovskite defect-state,but also promotes hot carriers(HCs)cooling in perovskite through the transient absorption spectroscopy measurements.Fast HCs cooling permits HCs transfer from perovskite layer into NCN layer,thus resulting in the decreased charge-carrier recombination in NCN-treated device.As expected,the power conversion efficiency(PCE)of PSCs with NCN is enhanced to 22.02%from 19.95%for the control device.The findings are relevant for developing highly efficient PSCs. 展开更多
关键词 Perovskite solar cells Interface passivation hot carrier Charge recombination Stability NAPHTHALIMIDE
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Nanoscale visualization of hot carrier generation and transfer at non-noble metal and oxide interface
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作者 Ranveer Singh Qadeer Akbar Sial +3 位作者 Seung-ik Han Sanghee Nah Ji-Yong Park Hyungtak Seo 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第3期151-159,共9页
The conversion efficiency of energy-harvesting devices can be increased by utilizing hot-carriers(HCs).However,due to ultrafast carrier-carrier scattering and the lack of carrier injection dynamics,HC-based devices ha... The conversion efficiency of energy-harvesting devices can be increased by utilizing hot-carriers(HCs).However,due to ultrafast carrier-carrier scattering and the lack of carrier injection dynamics,HC-based devices have low efficiencies.In the present work,we report the effective utilization of HCs at the nanoscale and their transfer dynamics from a non-noble metal to a metal oxide interface by means of real-space photocurrent mapping by using local probe techniques and conducting femtosecond transient absorption(TA)measurements.The photocurrent maps obtained under white light unambiguously show that the HCs are injected into the metal oxide layer from the TiN layer,as also confirmed by conductive atomic force microscopy.In addition,the increased photocurrent in the bilayer structure indicates the injection of HCs from both layers due to the broadband absorption efficiency of TiN layer,passivation of the surface states by the top TiN layer,and smaller barrier height of the interfaces.Furthermore,electrostatic force microscopy and Kelvin probe force microscopy provide direct evidence of charge injection from TiN to the MoO_(x)film at the nanoscale.The TA absorption spectra show a strong photo-bleaching signal over wide spectral range and ultrafast decaying behavior at the picosecond time scale,which indicate efficient electron transfer from TiN to MoO_(x).Thus,our simple and effective approach can facilitate HC collection under white light,thereby achieving high conversion efficiency for optoelectronic devices. 展开更多
关键词 Non-noble metal hot carrier Real-space photocurrent mapping Local-probe force microscopy
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