In this study,complete tetracycline(TTC)and above 50%of total organic carbon(TOC)were removed by Fe S/PS after 30 min under optimized conditions.Although free radicals and high-valent iron ions were identified to gene...In this study,complete tetracycline(TTC)and above 50%of total organic carbon(TOC)were removed by Fe S/PS after 30 min under optimized conditions.Although free radicals and high-valent iron ions were identified to generate in the process,the apparent similarity between intermediate products of Fe S/PS,Fe/PS,and UV/PS systems demonstrated that the degradation of TTC was due to sulfate radicals(SO_(4)·^(-))and hydroxyl radicals(·OH).Based on the reaction between free radicals and organic matter,we speculated that TTC in the Fe S/PS system was decomposed and mineralized by dehydration,dehydrogenation,hydroxyl addition,demethylation,substitution,E-transfer,and ring-opening.Furthermore,a new understanding of Fe S-mediated PS activation based on stoichiometry and kinetic analysis showed that there were both homogeneous and heterogeneous reactions that occurred in the entire progress.However,due to the effect of p H on the dissolution of iron ions,the homogeneous reaction became the principal process with iron ions concentration exceeding 1.35 mg/L.This work provides a theoretical basis for the study of the degradation of TTC-containing wastewater by the iron-based advanced oxidation process.展开更多
The present article provides mathematical modeling for melting heat and thermal radiation in stagnationpoint flow of carbon nanotubes towards a nonlinear stretchable surface of variable thickness. The process of homog...The present article provides mathematical modeling for melting heat and thermal radiation in stagnationpoint flow of carbon nanotubes towards a nonlinear stretchable surface of variable thickness. The process of homogeneousheterogeneous reactions is considered. Diffusion coefficients are considered equal for both reactant and autocatalyst.Water and gasoline oil are taken as base fluids. The conversion of partial differential system to ordinary differential system is done by suitable transformations. Optimal homotopy technique is employed for the solutions development of velocity, temperature, concentration, skin friction and local Nusselt number. Graphical results for various values of pertinent parameters are displayed and discussed. Our results indicate that the skin friction coefficient and local Nusselt number are enhanced for larger values of nanoparticles volume fraction.展开更多
This article addresses melting heat transfer in magnetohydrodynamics(MHD)nanofluid flows by a rotating disk. The analysis is performed in Cu-water and Ag-water nanofluids. Thermal radiation, viscous dissipation, and c...This article addresses melting heat transfer in magnetohydrodynamics(MHD)nanofluid flows by a rotating disk. The analysis is performed in Cu-water and Ag-water nanofluids. Thermal radiation, viscous dissipation, and chemical reactions impacts are added in the nanofluid model. Appropriate transformations lead to the nondimensionalized boundary layer equations. Series solutions for the resulting equations are computed.The role of pertinent parameters on the velocity, temperature, and concentration is analyzed in the outputs. It is revealed that the larger melting parameter enhances the velocity profile while the temperature profile decreases. The surface drag force and heat transfer rate are computed under the influence of pertinent parameters. Furthermore, the homogeneous reaction parameter serves to decrease the surface concentration.展开更多
This study presents the effect of non-uniform heat source on the magneto-hydrodynamic flow of nanofluid across an expanding plate with consideration of the homogeneous-heterogeneous reactions and thermal radiation eff...This study presents the effect of non-uniform heat source on the magneto-hydrodynamic flow of nanofluid across an expanding plate with consideration of the homogeneous-heterogeneous reactions and thermal radiation effects.A nanofluid’s dynamic viscosity and effective thermal conductivity are specified with Corcione correlation.According to this correlation,the thermal conductivity is carried out by the Brownian motion.Similarity transformations reduce the governing equations concerned with energy,momentum,and concentration of nanofluid and then numerically solved.The influences of the effective parameters,e.g.,the internal heat source parameters,the volume fraction of nanofluid,the radiation parameter,the homogeneous reaction parameter,the magnetic parameter,the heterogeneous parameter and the Schmidt number are studied on the heat and flow transfer features.Further,regarding the effective parameters of the present work,the correlation for the Nusselt number has been developed.The outcomes illustrate that with the raising of the heterogeneous parameter and the homogeneous reaction parameter,the concentration profile diminishes.In addition,the outcomes point to a reverse relationship between the Nusselt number and the internal heat source parameters.展开更多
The steady two-dimensional flow of Powell-Eyring fluid is investigated. The flow is caused by a stretching surface with homogeneous-heterogeneous reactions. The governing nonlinear differential equations are reduced t...The steady two-dimensional flow of Powell-Eyring fluid is investigated. The flow is caused by a stretching surface with homogeneous-heterogeneous reactions. The governing nonlinear differential equations are reduced to the ordinary differential equations by similarity transformations. The analytic solutions are presented in series forms by homotopy analysis method(HAM). Convergence of the obtained series solutions is explicitly discussed. The physical significance of different parameters on the velocity and concentration profiles is discussed through graphical illustrations. It is noticed that the boundary layer thickness increases by increasing the Powell-Eyring fluid material parameter(ε) whereas it decreases by increasing the fluid material parameter(δ). Further, the concentration profile increases when Powell-Eyring fluid material parameters increase. The concentration is also an increasing function of Schmidt number and decreasing function of strength of homogeneous reaction. Also mass transfer rate increases for larger rate of heterogeneous reaction.展开更多
This study examines the stagnation point flow over a stretching/shrinking sheet in a hybrid nanofluid with homogeneous-heterogeneous reactions.The hybrid nanofluid consists of copper(Cu)and alumina(Al2O3)nanoparticles...This study examines the stagnation point flow over a stretching/shrinking sheet in a hybrid nanofluid with homogeneous-heterogeneous reactions.The hybrid nanofluid consists of copper(Cu)and alumina(Al2O3)nanoparticles which are added into water to form Cu-Al2O3/water hybrid nanofluid.The similarity equations are obtained using a similarity transformation.Then,the function bvp4c in MATLAB is utilised to obtain the numerical results.The dual solutions are found for limited values of the stretching/shrinking parameter.Also,the turning point arises in the shrinking region(λ<0).Besides,the presence of hybrid nanoparticles enhances the heat transfer rate,skin friction coefficient,and the concentration gradient.In addition,the concentration gradient is intensified with the heterogeneous reaction but the effect is opposite for the homogeneous reaction.Furthermore,the velocity and the concentration increase,whereas the temperature decreases for higher compositions of hybrid nanoparticles.Moreover,the concentration decreases for larger values of homogeneous and heterogeneous reactions.It is consistent with the fact that higher reaction rate cause a reduction in the rate of diffusion.However,the velocity and the temperature are not affected by these parameters.From these observations,it can be concluded that the effect of the homogeneous and heterogeneous reactions is dominant on the concentration profiles.Two solutions are obtained for a single value of parameter.The temporal stability analysis shows that only one of these solutions is stable and thus physically reliable over time.展开更多
This letter describes the characteristics of homogeneous-heterogeneous re- action in the boundary layer flow of a Jeffrey fluid due to an impermeable horizontal stretching sheet. An analysis is carried out through the...This letter describes the characteristics of homogeneous-heterogeneous re- action in the boundary layer flow of a Jeffrey fluid due to an impermeable horizontal stretching sheet. An analysis is carried out through the similar values of reactant and auto catalyst diffusion coefficients. Heat released by the reaction is not accounted. The exact solution for the flow of the Jeffrey fluid is constructed. The series solution for the concentration equation is derived. The velocity and concentration fields reflecting the impact of interesting parameters are plotted and examined.展开更多
1 Results Significant progress has been made in recent years in developing efficient, atom economical catalytic reactions of potential applicability to the pharmaceutical, petrochemical, and commodity chemical busines...1 Results Significant progress has been made in recent years in developing efficient, atom economical catalytic reactions of potential applicability to the pharmaceutical, petrochemical, and commodity chemical business sectors. In some cases, homogeneous catalytic processes offer advantages, but in others the use of heterogenized homogeneous catalysis provides a competitive advantage concerning recyclability and catalyst recovery. This presentation will consider new approaches to cyclization reactions a...展开更多
A new mathematical model is presented to study the heat and mass transfer characteristics of magnetohydrodynamic(MHD) Maxwell fluid flow over a convectively heated stretchable rotating disk. To regulate the fluid temp...A new mathematical model is presented to study the heat and mass transfer characteristics of magnetohydrodynamic(MHD) Maxwell fluid flow over a convectively heated stretchable rotating disk. To regulate the fluid temperature at the surface, a simple isothermal model of homogeneous-heterogeneous reactions is employed. The impact of nonlinear thermal radiative heat flux on thermal transport features is studied. The transformed nonlinear system of ordinary differential equations is solved numerically with an efficient method, namely, the Runge-Kutta-Felberg fourth-order and fifth-order(RKF45)integration scheme using the MAPLE software. Achieved results are validated with previous studies in an excellent way. Major outcomes reveal that the magnetic flux reduces the velocity components in the radial, angular, and axial directions, and enhances the fluid temperature. Also, the presence of radiative heat flux is to raise the temperature of fluid. Further, the strength of homogeneous-heterogeneous reactions is useful to diminish the concentration of reaction.展开更多
This study deals with the stagnation point flow of ferrofluid over a flat plate with non-linear slip boundary condition in the presence of homogeneous-heterogeneous reactions.Three kinds of ferroparticles,namely,magne...This study deals with the stagnation point flow of ferrofluid over a flat plate with non-linear slip boundary condition in the presence of homogeneous-heterogeneous reactions.Three kinds of ferroparticles,namely,magnetite(Fe_3O_4),cobalt ferrite(CoFe_2O_4) and manganese zinc ferrite(Mn-ZnFe_2O_4) are taken into account with water and kerosene as conventional base fluids.The developed model of homogeneous-heterogeneous reactions in boundary layer flow with equal and unequal diffusivities for reactant and autocatalysis is considered.The governing partial differential equations are converted into system of non-linear ordinary differential equations by mean of similarity transformations.These ordinary differential equations are integrated numerically using shooting method.The effects of pertinent parameters on velocity and concentration profiles are presented graphically and discussed.We found that in the presence of Fe_3O_4-kerosene and CoFe_2O_4-kerosene,velocity profiles increase for large values of α and β whereas there is a decrement in concentration profiles with increasing values of if and K_s.Furthermore,the comparison between non-magnetic(A1_2O_3) and magnetic Fe_3O_4 nanoparticles is given in tabular form.展开更多
This research delves into an intricate exploration offluid dynamics within heat transfer systems,with a specific focus on enhancing our understanding and improving system efficiency.Employing a sophisticated mathemati...This research delves into an intricate exploration offluid dynamics within heat transfer systems,with a specific focus on enhancing our understanding and improving system efficiency.Employing a sophisticated mathematical model,the study incorporates micropolarfluid dynamics,micro rotational effects,laminarflow characterized by the Darcy-Forchheimer model,inertia effects,and chemical reactions within a heat transfer system featuring boundary layer complexities.The mathematical framework consists of partial differential equations(PDEs),and the study utilizes advanced numerical techniques,including the(PC4-FDM)Predictor-Corrector Finite Difference Method and the shooting method,to solve these govern-ing equations.The inclusion of quantized mesh points and analysis of convergence using 4th orderfinite difference methods enhances the precision of the obtained solutions.Various param-eters are scrutinized to draw meaningful insights.The heterogeneous parameter reveals an increasing trend influid concentration,while the homogeneous parameter indicates a collision effect leading to a decrease influid concentration.The Eckert number,associated with viscous dissipation,exhibits a correlation with decreasedfluid temperature and increasedfluid velocity.Micro rotation parameters suggest a parallel increase influid velocity and a marginal decrease influid temperature.Notably,the Darcy-Forchheimer parameter,reflective of inertial effects,showcases an increase influid temperature and decrease in velocity in the convection system.Highlighting the industrial implications,the study underscores the significance of convection heat transfer systems in the context of industrialization.Thefindings offer valuable insights for optimizing heating and cooling processes in diverse industrial applications,ranging from power plants to waste heat recovery units and pharmaceutical industries.展开更多
Photosensitized heterogeneous CO_(2) reduction(PHCR)has emerged as a promising means to convert CO_(2) into valuable chemicals,however,challenged by the relatively low carbonaceous product selectivity caused by the co...Photosensitized heterogeneous CO_(2) reduction(PHCR)has emerged as a promising means to convert CO_(2) into valuable chemicals,however,challenged by the relatively low carbonaceous product selectivity caused by the competing hydrogen evolution reaction(HER).Here,we report a PHCR system that couples Ru(bpy)32+photosensitizer with{001}faceted LiCoO_(2) nanosheets photocatalyst to simultaneously yield 21.2 and 722μmol·g^(-1)·h^(-1) of CO,and 4.42 and 108μmol·g^(-1)·h^(-1) of CH4 under the visible light and the simulated sunlight irradiations,respectively,with completely suppressed HER.The experimental and theoretical studies reveal that the favored CO_(2) adsorption on the exposed Li sites on{001}faceted LiCoO_(2) surface is responsible for the completely suppressed HER.展开更多
This model is dedicated to visualizing the nature of magnetite-water nanoliquid induced by a permeable plate having variable magnetic effect,non-linear radiation,heterogeneous and homogeneous chemically reactive speci...This model is dedicated to visualizing the nature of magnetite-water nanoliquid induced by a permeable plate having variable magnetic effect,non-linear radiation,heterogeneous and homogeneous chemically reactive species.The system of momentum,thermal and concentration expressions is formulated and transformed from the partial to ordinary differential systems by using the adequate transforms.This highly non-linear system is solved through RKF(Runge-Kutta-Fehlberg)numerical method.Important parameters such as suction/injection,magnetic,and radiation effects as well as other relevant parameters are investigated.The graphs show that the rise in radiation parameter numerically improves the thermal distribution,implying a faster heat transfer rate.Non-linear radiation has greater effect on temperature than the linear radiation.While the volume concentration effect reveals that the friction factor increase with the enhancement of nanoparticle concentration.It is also observed that,plate velocity decreases the skin-friction but increases the wall heat transfer for both suction and blowing cases.The results indicate that the current research has a strong agreement with the relevant data in a limiting approach.展开更多
基金supported by the National Natural Science Foundation of China(No.21876130)Natural Science Foundation of Shanghai(No.18ZR1440800)。
文摘In this study,complete tetracycline(TTC)and above 50%of total organic carbon(TOC)were removed by Fe S/PS after 30 min under optimized conditions.Although free radicals and high-valent iron ions were identified to generate in the process,the apparent similarity between intermediate products of Fe S/PS,Fe/PS,and UV/PS systems demonstrated that the degradation of TTC was due to sulfate radicals(SO_(4)·^(-))and hydroxyl radicals(·OH).Based on the reaction between free radicals and organic matter,we speculated that TTC in the Fe S/PS system was decomposed and mineralized by dehydration,dehydrogenation,hydroxyl addition,demethylation,substitution,E-transfer,and ring-opening.Furthermore,a new understanding of Fe S-mediated PS activation based on stoichiometry and kinetic analysis showed that there were both homogeneous and heterogeneous reactions that occurred in the entire progress.However,due to the effect of p H on the dissolution of iron ions,the homogeneous reaction became the principal process with iron ions concentration exceeding 1.35 mg/L.This work provides a theoretical basis for the study of the degradation of TTC-containing wastewater by the iron-based advanced oxidation process.
文摘The present article provides mathematical modeling for melting heat and thermal radiation in stagnationpoint flow of carbon nanotubes towards a nonlinear stretchable surface of variable thickness. The process of homogeneousheterogeneous reactions is considered. Diffusion coefficients are considered equal for both reactant and autocatalyst.Water and gasoline oil are taken as base fluids. The conversion of partial differential system to ordinary differential system is done by suitable transformations. Optimal homotopy technique is employed for the solutions development of velocity, temperature, concentration, skin friction and local Nusselt number. Graphical results for various values of pertinent parameters are displayed and discussed. Our results indicate that the skin friction coefficient and local Nusselt number are enhanced for larger values of nanoparticles volume fraction.
文摘This article addresses melting heat transfer in magnetohydrodynamics(MHD)nanofluid flows by a rotating disk. The analysis is performed in Cu-water and Ag-water nanofluids. Thermal radiation, viscous dissipation, and chemical reactions impacts are added in the nanofluid model. Appropriate transformations lead to the nondimensionalized boundary layer equations. Series solutions for the resulting equations are computed.The role of pertinent parameters on the velocity, temperature, and concentration is analyzed in the outputs. It is revealed that the larger melting parameter enhances the velocity profile while the temperature profile decreases. The surface drag force and heat transfer rate are computed under the influence of pertinent parameters. Furthermore, the homogeneous reaction parameter serves to decrease the surface concentration.
文摘This study presents the effect of non-uniform heat source on the magneto-hydrodynamic flow of nanofluid across an expanding plate with consideration of the homogeneous-heterogeneous reactions and thermal radiation effects.A nanofluid’s dynamic viscosity and effective thermal conductivity are specified with Corcione correlation.According to this correlation,the thermal conductivity is carried out by the Brownian motion.Similarity transformations reduce the governing equations concerned with energy,momentum,and concentration of nanofluid and then numerically solved.The influences of the effective parameters,e.g.,the internal heat source parameters,the volume fraction of nanofluid,the radiation parameter,the homogeneous reaction parameter,the magnetic parameter,the heterogeneous parameter and the Schmidt number are studied on the heat and flow transfer features.Further,regarding the effective parameters of the present work,the correlation for the Nusselt number has been developed.The outcomes illustrate that with the raising of the heterogeneous parameter and the homogeneous reaction parameter,the concentration profile diminishes.In addition,the outcomes point to a reverse relationship between the Nusselt number and the internal heat source parameters.
文摘The steady two-dimensional flow of Powell-Eyring fluid is investigated. The flow is caused by a stretching surface with homogeneous-heterogeneous reactions. The governing nonlinear differential equations are reduced to the ordinary differential equations by similarity transformations. The analytic solutions are presented in series forms by homotopy analysis method(HAM). Convergence of the obtained series solutions is explicitly discussed. The physical significance of different parameters on the velocity and concentration profiles is discussed through graphical illustrations. It is noticed that the boundary layer thickness increases by increasing the Powell-Eyring fluid material parameter(ε) whereas it decreases by increasing the fluid material parameter(δ). Further, the concentration profile increases when Powell-Eyring fluid material parameters increase. The concentration is also an increasing function of Schmidt number and decreasing function of strength of homogeneous reaction. Also mass transfer rate increases for larger rate of heterogeneous reaction.
基金This research was funded by Universiti Kebangsaan Malaysia(Project Code:DIP-2020-001).
文摘This study examines the stagnation point flow over a stretching/shrinking sheet in a hybrid nanofluid with homogeneous-heterogeneous reactions.The hybrid nanofluid consists of copper(Cu)and alumina(Al2O3)nanoparticles which are added into water to form Cu-Al2O3/water hybrid nanofluid.The similarity equations are obtained using a similarity transformation.Then,the function bvp4c in MATLAB is utilised to obtain the numerical results.The dual solutions are found for limited values of the stretching/shrinking parameter.Also,the turning point arises in the shrinking region(λ<0).Besides,the presence of hybrid nanoparticles enhances the heat transfer rate,skin friction coefficient,and the concentration gradient.In addition,the concentration gradient is intensified with the heterogeneous reaction but the effect is opposite for the homogeneous reaction.Furthermore,the velocity and the concentration increase,whereas the temperature decreases for higher compositions of hybrid nanoparticles.Moreover,the concentration decreases for larger values of homogeneous and heterogeneous reactions.It is consistent with the fact that higher reaction rate cause a reduction in the rate of diffusion.However,the velocity and the temperature are not affected by these parameters.From these observations,it can be concluded that the effect of the homogeneous and heterogeneous reactions is dominant on the concentration profiles.Two solutions are obtained for a single value of parameter.The temporal stability analysis shows that only one of these solutions is stable and thus physically reliable over time.
文摘This letter describes the characteristics of homogeneous-heterogeneous re- action in the boundary layer flow of a Jeffrey fluid due to an impermeable horizontal stretching sheet. An analysis is carried out through the similar values of reactant and auto catalyst diffusion coefficients. Heat released by the reaction is not accounted. The exact solution for the flow of the Jeffrey fluid is constructed. The series solution for the concentration equation is derived. The velocity and concentration fields reflecting the impact of interesting parameters are plotted and examined.
文摘1 Results Significant progress has been made in recent years in developing efficient, atom economical catalytic reactions of potential applicability to the pharmaceutical, petrochemical, and commodity chemical business sectors. In some cases, homogeneous catalytic processes offer advantages, but in others the use of heterogenized homogeneous catalysis provides a competitive advantage concerning recyclability and catalyst recovery. This presentation will consider new approaches to cyclization reactions a...
文摘A new mathematical model is presented to study the heat and mass transfer characteristics of magnetohydrodynamic(MHD) Maxwell fluid flow over a convectively heated stretchable rotating disk. To regulate the fluid temperature at the surface, a simple isothermal model of homogeneous-heterogeneous reactions is employed. The impact of nonlinear thermal radiative heat flux on thermal transport features is studied. The transformed nonlinear system of ordinary differential equations is solved numerically with an efficient method, namely, the Runge-Kutta-Felberg fourth-order and fifth-order(RKF45)integration scheme using the MAPLE software. Achieved results are validated with previous studies in an excellent way. Major outcomes reveal that the magnetic flux reduces the velocity components in the radial, angular, and axial directions, and enhances the fluid temperature. Also, the presence of radiative heat flux is to raise the temperature of fluid. Further, the strength of homogeneous-heterogeneous reactions is useful to diminish the concentration of reaction.
文摘This study deals with the stagnation point flow of ferrofluid over a flat plate with non-linear slip boundary condition in the presence of homogeneous-heterogeneous reactions.Three kinds of ferroparticles,namely,magnetite(Fe_3O_4),cobalt ferrite(CoFe_2O_4) and manganese zinc ferrite(Mn-ZnFe_2O_4) are taken into account with water and kerosene as conventional base fluids.The developed model of homogeneous-heterogeneous reactions in boundary layer flow with equal and unequal diffusivities for reactant and autocatalysis is considered.The governing partial differential equations are converted into system of non-linear ordinary differential equations by mean of similarity transformations.These ordinary differential equations are integrated numerically using shooting method.The effects of pertinent parameters on velocity and concentration profiles are presented graphically and discussed.We found that in the presence of Fe_3O_4-kerosene and CoFe_2O_4-kerosene,velocity profiles increase for large values of α and β whereas there is a decrement in concentration profiles with increasing values of if and K_s.Furthermore,the comparison between non-magnetic(A1_2O_3) and magnetic Fe_3O_4 nanoparticles is given in tabular form.
文摘This research delves into an intricate exploration offluid dynamics within heat transfer systems,with a specific focus on enhancing our understanding and improving system efficiency.Employing a sophisticated mathematical model,the study incorporates micropolarfluid dynamics,micro rotational effects,laminarflow characterized by the Darcy-Forchheimer model,inertia effects,and chemical reactions within a heat transfer system featuring boundary layer complexities.The mathematical framework consists of partial differential equations(PDEs),and the study utilizes advanced numerical techniques,including the(PC4-FDM)Predictor-Corrector Finite Difference Method and the shooting method,to solve these govern-ing equations.The inclusion of quantized mesh points and analysis of convergence using 4th orderfinite difference methods enhances the precision of the obtained solutions.Various param-eters are scrutinized to draw meaningful insights.The heterogeneous parameter reveals an increasing trend influid concentration,while the homogeneous parameter indicates a collision effect leading to a decrease influid concentration.The Eckert number,associated with viscous dissipation,exhibits a correlation with decreasedfluid temperature and increasedfluid velocity.Micro rotation parameters suggest a parallel increase influid velocity and a marginal decrease influid temperature.Notably,the Darcy-Forchheimer parameter,reflective of inertial effects,showcases an increase influid temperature and decrease in velocity in the convection system.Highlighting the industrial implications,the study underscores the significance of convection heat transfer systems in the context of industrialization.Thefindings offer valuable insights for optimizing heating and cooling processes in diverse industrial applications,ranging from power plants to waste heat recovery units and pharmaceutical industries.
基金supported by Australian Research Council Discovery Projects(Nos.DP170104834 and DP200100965)。
文摘Photosensitized heterogeneous CO_(2) reduction(PHCR)has emerged as a promising means to convert CO_(2) into valuable chemicals,however,challenged by the relatively low carbonaceous product selectivity caused by the competing hydrogen evolution reaction(HER).Here,we report a PHCR system that couples Ru(bpy)32+photosensitizer with{001}faceted LiCoO_(2) nanosheets photocatalyst to simultaneously yield 21.2 and 722μmol·g^(-1)·h^(-1) of CO,and 4.42 and 108μmol·g^(-1)·h^(-1) of CH4 under the visible light and the simulated sunlight irradiations,respectively,with completely suppressed HER.The experimental and theoretical studies reveal that the favored CO_(2) adsorption on the exposed Li sites on{001}faceted LiCoO_(2) surface is responsible for the completely suppressed HER.
文摘This model is dedicated to visualizing the nature of magnetite-water nanoliquid induced by a permeable plate having variable magnetic effect,non-linear radiation,heterogeneous and homogeneous chemically reactive species.The system of momentum,thermal and concentration expressions is formulated and transformed from the partial to ordinary differential systems by using the adequate transforms.This highly non-linear system is solved through RKF(Runge-Kutta-Fehlberg)numerical method.Important parameters such as suction/injection,magnetic,and radiation effects as well as other relevant parameters are investigated.The graphs show that the rise in radiation parameter numerically improves the thermal distribution,implying a faster heat transfer rate.Non-linear radiation has greater effect on temperature than the linear radiation.While the volume concentration effect reveals that the friction factor increase with the enhancement of nanoparticle concentration.It is also observed that,plate velocity decreases the skin-friction but increases the wall heat transfer for both suction and blowing cases.The results indicate that the current research has a strong agreement with the relevant data in a limiting approach.
