It is known that the first lanthanide （Ln） catalyst used for stereospecific polymeriza-tion of conjugated diene is composed of LnCl3 and R3Al.It initiates stereospecific polymeri-zation of butadiene with a very high...It is known that the first lanthanide （Ln） catalyst used for stereospecific polymeriza-tion of conjugated diene is composed of LnCl3 and R3Al.It initiates stereospecific polymeri-zation of butadiene with a very high cis-1, 4 content（98%）, yet owns poor activity. This paper presents the new results obtained in our laboratory. By adding alcohol tothis binary system （LnCl3-R3Al）, the catalytic activity is greatly enhanced without any losson its high stereospecificity. It is shown that the catalytic activity is dependent on the ratioof its components and their order of addition. Furthermore, we have ascertained that itis the alcohol complex of LnCl3 with a definite composition LnCl3.R3OH, that turns out tobe an active catalyst when treated with R3Al.展开更多
文摘It is known that the first lanthanide （Ln） catalyst used for stereospecific polymeriza-tion of conjugated diene is composed of LnCl3 and R3Al.It initiates stereospecific polymeri-zation of butadiene with a very high cis-1, 4 content（98%）, yet owns poor activity. This paper presents the new results obtained in our laboratory. By adding alcohol tothis binary system （LnCl3-R3Al）, the catalytic activity is greatly enhanced without any losson its high stereospecificity. It is shown that the catalytic activity is dependent on the ratioof its components and their order of addition. Furthermore, we have ascertained that itis the alcohol complex of LnCl3 with a definite composition LnCl3.R3OH, that turns out tobe an active catalyst when treated with R3Al.
