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Evolutionary Characteristics of Interfacial Defects Inside Vehicle-mounted High-voltage Cable Termination for High-speed Trains
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作者 Dongli Xin Guangning Wu +7 位作者 Kui Chen Kai Liu Yunlong Xie Guoqiang Gao Song Xiao Yujing Tang Chuanming Sun Mu Lin 《CSEE Journal of Power and Energy Systems》 2026年第2期1072-1085,共14页
Partial discharge caused by interfacial defects of cable terminations is an important factor affecting insulating performance,which will seriously threaten operational safety of high-speed trains by causing a breakdow... Partial discharge caused by interfacial defects of cable terminations is an important factor affecting insulating performance,which will seriously threaten operational safety of high-speed trains by causing a breakdown fault of vehicle-mounted cable terminations.Simulation combined with experimentation is adopted to study the evolution characteristic of interfacial defects inside cable termination for high-speed trains.A simulation model and test samples of high-voltage cable terminations with prefabricated air gap and carbon trace defects are constructed.Results show that maximum field strength(MFS)at the defect is always located at the end of it.Evolution of the defects can be significantly divided into three stages based on the variation law of field strength and characteristics of partial discharge.A new feature of stage III is that volume of discharge in the third quadrant is significantly higher than in the first quadrant.PDEV in this stage is 51.41%lower than that of the defect-free cable termination and lower than operating voltage.Therefore,stage III is critical for detection of insulation state.Findings of the new characteristics and conclusions of the study provide strong support for improving operation and maintenance techniques of vehicle-mounted cable terminations. 展开更多
关键词 Air gap cable termination carbon trace evolution characteristics high-speed train interface discharge
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The Partial Discharge Characteristics of Inner Air Gap Inside High-Voltage Cable Termination for High-Speed Trains
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作者 Dongli Xin Guangning Wu +5 位作者 Guoqiang Gao Kui Chen Kai Liu Yunlong Xie Mu Lin Bo Li 《High Voltage》 2025年第5期1110-1124,共15页
The air gap at the interface inside the cable terminations for high-speed trains and the partial discharge caused by it are two important factors affecting the insulating performance.The development of air gap and par... The air gap at the interface inside the cable terminations for high-speed trains and the partial discharge caused by it are two important factors affecting the insulating performance.The development of air gap and partial discharge will eventually lead to breakdown faults.To investigate the evolutionary characteristics of the air gap and partial discharge,the simulation models and samples of cable terminations containing defects are constructed in this paper.By analysing the variation law of the electric field and the multidimensional information of partial discharge,the evolution process of the air gap is divided into four wellcharacterised stages.Especially in the third stage,the partial discharge extinction voltage is 51.41%lower than that of the defect-free samples and even lower than the working voltage.The asymmetry of discharge is the most significant factor.The volume of discharge in the third quadrant is significantly higher than that in the first quadrant.This important feature can be applied to the inspection and evaluation of the insulating state of the cable terminations.The partial discharge characteristics of the air gap revealed in this paper are proposed to provide an important theoretical supplement to the study of interface discharges between heterogeneous dielectrics. 展开更多
关键词 simulation models cable terminations partial dischargethe high voltage cable termination breakdown faultsto air gap partial discharge
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Nonlinear dynamical response of high-voltage transmission lines based on cable dropping 被引量:1
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作者 夏开全 刘云 钱振东 《Journal of Southeast University(English Edition)》 EI CAS 2009年第1期52-56,共5页
In order to study the dynamic response of high-voltage transmission lines under mechanical failure, a finite element model of a domestic 500-kV high-voltage transmission line system is established. The initial equilib... In order to study the dynamic response of high-voltage transmission lines under mechanical failure, a finite element model of a domestic 500-kV high-voltage transmission line system is established. The initial equilibrium condition of the coupling system model is verified by nonlinear static analysis. The transient dynamic analysis method is proposed to analyze the variation law of dynamic response under cable or insulator rupture, and the dynamic response of structural elements next to the broken span is calculated. The results show that upper crossarm cable rupture has no effect on cable tension at adjacent suspension points, but it has a significant influence on tension in the insulator and the tower component of the upper crossarm next to the broken span. The peak tension in the conductor of the upper crossarm at the suspension point exceeds the design value under insulator rupture. Insulator rupture has no effect on the tower component of the upper crossarm, but it has a significant influence on insulator tension of the upper crossarm. Insulator rupture should be taken into account in the design of overhead transmission lines. The research results can provide a theoretical basis for the design of transmission lines. 展开更多
关键词 high-voltage transmission line transient response cable dropping numerical simulation finite element method
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Online Monitoring Method Based on Locus-analysis for High-voltage Cable Faults 被引量:1
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作者 Wei Zhao Xiangyang Xia +4 位作者 Mingde Li Hai Huang Shanqiu Chen Ruiqi Wang Yan Liu 《Chinese Journal of Electrical Engineering》 CSCD 2019年第3期42-48,共7页
Online diagnosis methods for high-voltage(HV)cable faults have been extensively studied.Power cable fault monitoring is not accurate,and the degree of data fusion analysis of current methods is insufficient.To address... Online diagnosis methods for high-voltage(HV)cable faults have been extensively studied.Power cable fault monitoring is not accurate,and the degree of data fusion analysis of current methods is insufficient.To address these problems,an online monitoring method based on the locus-analysis for HV cable faults is developed.By simultaneously measuring two circulating currents in a coaxial cable,a two-dimensional locus diagram is drawn.The fault criteria and database are established to detect the fault by analyzing the changes of the locus characteristic parameters.A cross-connected grounding simulation model of a high-voltage cable is developed,and several faults at different locations are simulated.Fault identification is established based on the changes in the long axis,short axis,eccentricity,and tilt angle of the track.The simulation and field experiments show that this method can provide an increased amount of fault-monitoring reference information,which can improve the monitoring accuracy and provide a new approach to cable fault monitoring. 展开更多
关键词 Locus-analysis high-voltage cable online monitoring characteristic parameters
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Coupled numerical modelling of high-voltage electric pulse(HVEP)rock fracturing using COMSOL and 4D-LSM
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作者 Chenghui Liu Qin Li +3 位作者 Fuxin Rui Tubing Yin Yang Zou Gaofeng Zhao 《International Journal of Mining Science and Technology》 2026年第3期517-533,共17页
High-voltage electric pulse(HVEP)rock fragmentation has demonstrated substantial potential for sustainable fracturing of hard rocks owing to its energy efficiency.The transient nature and highly disruptive characteris... High-voltage electric pulse(HVEP)rock fragmentation has demonstrated substantial potential for sustainable fracturing of hard rocks owing to its energy efficiency.The transient nature and highly disruptive characteristics of its physical fracturing process render experimental investigation of the underlying rock-breaking mechanisms challenging.However,existing numerical studies lack comprehensive models that precisely link electrical breakdown phenomena with mechanical disintegration processes.This study combines COMSOL electrical breakdown simulations with four-dimension lattice spring model(4D-LSM)mechanical analysis to establish a coupled HVEP rock fragmentation model.The core concept of the model construction is to import the temperature field of the plasma channel obtained from the electrical breakdown into the mechanical solver to realize the precise connection between the two stages.The validated numerical model elucidates the full process of HVEP-induced fragmentation under varying electrical parameters.Furthermore,the effects of confining pressure and mineral grain size on fragmentation behavior have been investigated.Finally,parametric simulations across 25 electrical parameter combinations demonstrate the critical role of electrode spacing optimization in achieving energy-efficient rock fragmentation.These findings provide a predictive tool for designing efficient HVEP systems in deep resource extraction and mineral processing engineering. 展开更多
关键词 Rock fracturing high-voltage electric pulse Thermal-mechanical coupling Lattice spring model
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High-voltage Zn||monoclinic Prussian blue analog batteries enabled by a low-concentration,flame-retardant,and water-retaining electrolyte
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作者 Xianjia Cao Zijun Gao +7 位作者 Mengxuan Qin Lei Zhu Changyou Zhang Qiwang Shao Qing Li Dongming Liu Donghong Wang Chunyi Zhi 《Journal of Energy Chemistry》 2026年第3期676-685,共10页
Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,th... Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,the underlying causes of the instability of monoclinic K^(+) -containing MnFePBA(KMnFePBA)cathodes in aqueous electrolytes were investigated.To prevent irreversible phase transitions,a lowconcentration,flame-retardant organic electrolyte operable under open-air conditions was developed.Utilizing triethyl phosphate(TEP)as the electrolyte solvent,the KMnFePBA cathode exhibited two distinct redox peaks at approximately 1.83 and 1.70 V,coupled with a high reversible capacity of -130 m A h g^(-1).The TEP electrolyte offers not only flame-retardant and anti-drying properties but also benefits from the inclusion of trace amounts of water,which enhances the redox kinetics.The optimized electrolyte enables Zn||KMnFePBA batteries to operate reversibly without structural degradation,function effectively across a wide temperature range,and suppress Zn dendrite formation by modulating the zinc-ion solvation structure and interfacial environment.This study presents a practical electrolyte engineering strategy for stabilizing monoclinic MnFePBA cathodes while simultaneously extending the lifespan of Zn anodes in ZIBs. 展开更多
关键词 Zinc ion batteries Manganese-based Prussian blue analogues high-voltage Stability Zn dendrites
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Design and Control of a Bionic Inspection Robot for Suspension Bridge Main Cables
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作者 Shengkai Liu Chao Wang +1 位作者 Xiaoqiang Yuan Ning Ding 《Journal of Bionic Engineering》 2026年第1期159-174,共16页
The main cable is the primary load-bearing component of a suspension bridge,continuously exposed to harsh environmental conditions,such as wind and rain,throughout the year.These adverse conditions contribute to varyi... The main cable is the primary load-bearing component of a suspension bridge,continuously exposed to harsh environmental conditions,such as wind and rain,throughout the year.These adverse conditions contribute to varying degrees of degradation and damage to the main cable,necessitating regular inspections to prevent catastrophic failures.Traditional manual inspection methods not only suffer from low efficiency but also pose significant safety risks to personnel.To address these challenges and ensure the safe and effective inspection of suspension bridge main cables,this study introduces a novel cooperative climbing robot,designated as Main Cable Robot Version II(CCRobot-M-II),inspired by the locomotion of the inchworm.The robot employs an alternating opening and closing mechanism of four gripper sets,mimicking the inchworm's movement to achieve efficient crawling along the suspension bridge handrails.This paper provides a comprehensive analysis of the structural design,key components,and motion mechanisms of CCRobot-M-II.A detailed force analysis of the robot's crawling process is also presented,followed by the design of the control system and the development of an efficient motion control algorithm.Laboratory experiments demonstrate that the robot achieves a positional error of 00.64%during crawling,with a maximum average crawling speed of 7.6 m/min.Furthermore,the biomimetic design enables the robot to overcome obstacles up to 30 mm in height and possess the capability to handle suspension bridge cables with spans ranging from 740 to 1100 mm.Finally,CCRobot-M-II successfully conducted an inspection of the main cable on a suspension bridge,marking the world's first successful deployment of a climbing robot for main cable inspection on a suspension bridge. 展开更多
关键词 Bionic design Suspension bridge Main cable inspection Climbing robot Motion control
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Pull-out capacity and energy absorption of cable bolts under impact loading
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作者 Adel Mottahedi Naj Aziz +1 位作者 Alex Remennikov Ali Mirzaghorbanali 《International Journal of Mining Science and Technology》 2026年第1期23-42,共20页
This study investigates the performance of high-strength cable bolts under impact loading conditions representative of rock bursts in underground environments.Although widely used,the dynamic behaviour of these cable ... This study investigates the performance of high-strength cable bolts under impact loading conditions representative of rock bursts in underground environments.Although widely used,the dynamic behaviour of these cable bolts has received limited experimental attention,and their effectiveness in seismically active zones remains a subject of ongoing debate.To address this gap,a reverse pull-out test machine integrated with a drop hammer rig was employed.Tests were conducted on 70-t SUMO bulbed and non-bulbed cable bolts with encapsulation lengths of 300 and 450 mm,subjected to an impact energy of 14.52 k J.Results indicate that non-bulbed cables,despite showing lower initial peak loads(average 218 vs.328 k N for bulbed cables at 300 mm encapsulation),demonstrated superior energy absorption(average 11.26 vs.8.75 k J)and displacement capacity(average 48.40 vs.36.25 mm).Increasing the encapsulation length for bulbed cables led to a reduction in initial peak load but improved displacement and energy absorption.The dominant failure mechanism was debonding at the cable-grout interface,characterised by frictional sliding and cable rotation.These findings provide new insights into the energy dissipation mechanisms of cables and support the development of more resilient ground support systems for dynamically active conditions. 展开更多
关键词 Rock reinforcement cable bolt Impact loading Pull-out testing Mine seismicity Rock burst
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Experimental and Numerical Optimization of Prestressed Anchor Cable Support for In-Situ Large-Span Tunnel Expansion with an Energy Balance Framework
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作者 Ying Zhu Minghui Hu +5 位作者 Shengxu Wang Xiaoliang Dong Xuewen Xiao Richeng Liu Meng Wang Zheng Yuan 《Computer Modeling in Engineering & Sciences》 2026年第2期550-585,共36页
In-situ enlargement of super-large-span tunnels can intensify excavation-induced unloading in the surrounding rock,increasing deformation demand and failure risk during construction.This study combines laboratory mode... In-situ enlargement of super-large-span tunnels can intensify excavation-induced unloading in the surrounding rock,increasing deformation demand and failure risk during construction.This study combines laboratory model tests with FLAC3D simulations to evaluate the stabilizing role of prestressed anchor cables and to establish an energy-balance framework for support optimization.Comparative model tests of existing and enlarged tunnel sections,with and without anchors,show that reinforcement increases load-carrying capacity,reduces displacement,and confines damage to more localized zones.The numerical simulations reproduce displacement fields,shear-strain localization,and plastic-zone evolution with good agreement against the experimental observations.The energy framework is implemented in the in-situ simulations by quantifying unloading-related energy release in the rock mass and reinforcement work contributed by the anchors,and by introducing an energy release–reinforcement ratio as a stability indicator.Parametric analyses indicate that anchor length,spacing,and prestress influence stability in a nonlinear manner,with diminishing returns once reinforcement extends beyond the mechanically dominant deformation zone.An efficient parameter window is identified that improves deformation and yielding control while avoiding unnecessary reinforcement.The results provide an energy-consistent and design-oriented basis for prestressed anchorage selection in large-span tunnel expansion. 展开更多
关键词 Large-span tunnel anchor cable support tunnel expansion energy balance FLAC3D parameter optimization
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有线电视Cable接入网演进方案研究 被引量:1
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作者 谭诗荣 张宇 刘光 《广播电视网络》 2025年第2期81-85,共5页
本文对有线电视Cable接入网向全光接入网的演进进行了痛点分析,研究了当前可能采取的技术路线,遵循“业务引领、精准投资、光进铜退、资源沿用、落地可行”的原则,从不同维度对各种技术要素进行了对比分析,提出了切实可行的融合演进策略。
关键词 cable接入网技术 融合演进 技术路线
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Mini review:Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries 被引量:2
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作者 Lingjiang Kou Yong Wang +5 位作者 Jiajia Song Taotao Ai Wenhu Li Mohammad Yeganeh Ghotbi Panya Wattanapaphawong Koji Kajiyoshi 《Chinese Chemical Letters》 2025年第1期214-224,共11页
As battery technology evolves and demand for efficient energy storage solutions,aqueous zinc ion batteries(AZIBs)have garnered significant attention due to their safety and environmental benefits.However,the stability... As battery technology evolves and demand for efficient energy storage solutions,aqueous zinc ion batteries(AZIBs)have garnered significant attention due to their safety and environmental benefits.However,the stability of cathode materials under high-voltage conditions remains a critical challenge in improving its energy density.This review systematically explores the failure mechanisms of high-voltage cathode materials in AZIBs,including hydrogen evolution reaction,phase transformation and dissolution phenomena.To address these challenges,we propose a range of advanced strategies aimed at improving the stability of cathode materials.These strategies include surface coating and doping techniques designed to fortify the surface properties and structure integrity of the cathode materials under high-voltage conditions.Additionally,we emphasize the importance of designing antioxidant electrolytes,with a focus on understanding and optimizing electrolyte decomposition mechanisms.The review also highlights the significance of modifying conductive agents and employing innovative separators to further enhance the stability of AZIBs.By integrating these cutting-edge approaches,this review anticipates substantial advancements in the stability of high-voltage cathode materials,paving the way for the broader application and development of AZIBs in energy storage. 展开更多
关键词 Aqueous zinc ion battery high-voltage cathode materials Stability enhancement Failure mechanisms Electrolyte optimization
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Accelerating lithium ion conduction via activated interfacial dipole layer for long-life and high-voltage solid-state lithium-metal battery 被引量:1
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作者 Lv Xu Meng Yao +7 位作者 Liyu Du Yong Chen Yanqiang Wei Du Yuan Hao Wu Haitao Zhang Yun Zhang Guoxiu Wang 《Journal of Energy Chemistry》 2025年第9期92-100,I0004,共10页
The absence of efficient ion transport pathways in composite solid-state electrolytes(CSEs)usually results in low ionic conductivity,which remains a great challenge for developing solid-state lithiummetal batteries(SL... The absence of efficient ion transport pathways in composite solid-state electrolytes(CSEs)usually results in low ionic conductivity,which remains a great challenge for developing solid-state lithiummetal batteries(SLMBs).Herein,we report achieving accelerated Li^(+)conduction in CSEs by a novel activation of the interfacial dipole layer.Polycationic ionic liquids and polyacrylonitrile with highly polar functional groups(-C≡N)are utilized to modulate the interfacial dipole layer in MOF-based CSEs,facilitating long-range pathways for the connectivity of Li^(+)conduction and enhancing rapid transport kinetics.The as-synthesized CSEs exhibit a high ionic conductivity of 0.59 mS cm^(-1)and a lithium transfer number of 0.85.The assembled SLMBs(Li/CSE/LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2))delivered a high-capacity retention of 88.7%with a minimal discharge voltage attenuation of 17.1 mV after 500 cycles(0.03 mV per cycle)at0.5 C.This work offers an effective approach to creating interpenetrating lithium-ion transport pathways with rapid ion transport kinetics for solid-state electrolytes,thereby advancing the development of solidstate lithium metal batteries. 展开更多
关键词 Interfacial dipole layer high-voltage lithium-metal battery Composite solid electrolyte Lithium-ion conduction channels
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Effect of Core Structure on the Mechanical and Electromagnetic Properties of High-Temperature Superconducting Cables 被引量:1
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作者 Jiangtao Yan Yuanwen Gao 《Acta Mechanica Solida Sinica》 2025年第1期14-24,共11页
Research on the mechanical–electrical properties is crucial for designing and preparing high-temperature superconducting(HTS)cables.Various winding core structures can influence the mechanical–electrical behavior of... Research on the mechanical–electrical properties is crucial for designing and preparing high-temperature superconducting(HTS)cables.Various winding core structures can influence the mechanical–electrical behavior of cables,but the impact of alterations in the winding core structure on the mechanical–electrical behavior of superconducting cables remains unclear.This paper presents a 3D finite element model to predict the performance of three cables with different core structures when subjected to transverse compression and axial tension.The three cables analyzed are CORC(conductor-on-round-core),CORT(conductor-on-round-tube),and HFRC(conductor-on-spiral-tube).A parametric analysis is carried out by varying the core diameter and inner-to-outer diameter ratio.Results indicate that the CORT cable demonstrates better performance in transverse compression compared to the CORC cable,aligning with experimental data.Among the three cables,the HFRC cables exhibit the weakest resistance to transverse deformation.However,the HFRC cable demonstrates superior tensile deformation resistance compared to the CORT cable,provided that the transverse compression properties are maintained.Finite element results also show that the optimum inner-to-outer diameter ratios for achieving the best transverse compression performance are approximately 0.8 for CORT cables and 0.6 for HFRC cables.Meanwhile,the study explores the effect of structural changes in HTS cable winding cores on their electromagnetic properties.It recommends utilizing small tape gaps,lower frequencies,and spiral core construction to minimize eddy losses.The findings presented in this paper offer valuable insights for the commercialization and practical manufacturing of HTS cables. 展开更多
关键词 Superconducting cables Winding core structure Transverse compression Axial tension Eddy loss
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Analysis of wind-induced vibration response characteristics of multispan double-layer cable photovoltaic support structure 被引量:3
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作者 ZOU Lianghao WANG Jian +2 位作者 SONG Jie ZHOU Rui WANG Hao 《Journal of Southeast University(English Edition)》 2025年第1期37-43,共7页
To investigate the wind⁃induced vibration re⁃sponse characteristics of multispan double⁃layer cable photo⁃voltaic(PV)support structures,wind tunnel tests using an aeroelastic model were carried out to obtain the wind⁃... To investigate the wind⁃induced vibration re⁃sponse characteristics of multispan double⁃layer cable photo⁃voltaic(PV)support structures,wind tunnel tests using an aeroelastic model were carried out to obtain the wind⁃induced vibration response data of a three⁃span four⁃row double⁃layer cable PV support system.The wind⁃induced vibration characteristics with different PV module tilt angles,wind speeds,and wind direction angles were analyzed.The results showed that the double⁃layer cable large⁃span flexible PV support can effectively control the wind⁃induced vibration response and prevent the occur⁃rence of flutter under strong wind conditions.The maxi⁃mum value of the wind⁃induced vibration displacement of the flexible PV support system occurs in the windward first row.The upstream module has a significant shading effect on the downstream module,with a maximum effect of 23%.The most unfavorable wind direction angles of the structure are 0°and 180°.The change of the wind direction angle in the range of 0°to 30°has little effect on the wind vi⁃bration response.The change in the tilt angle of the PV modules has a greater impact on the wind vibration in the downwind direction and a smaller impact in the upwind di⁃rection.Special attention should be paid to the structural wind⁃resistant design of such systems in the upwind side span. 展开更多
关键词 double⁃layer cable photovoltaic support aero⁃elastic model wind tunnel test wind⁃induced vibration re⁃sponse
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Design of a high-voltage radiation-tolerant driver with a novel comparator and drain-surrounding-source structure 被引量:1
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作者 Wei Huang Hong-Xia Liu Xing-Guo Gao 《Nuclear Science and Techniques》 2025年第7期34-43,共10页
This article introduces a novel 20 V radiation-hardened high-voltage metal-oxide-semiconductor field-effect transistor(MOSFET)driver with an optimized input circuit and a drain-surrounding-source(DSS)structure.The inp... This article introduces a novel 20 V radiation-hardened high-voltage metal-oxide-semiconductor field-effect transistor(MOSFET)driver with an optimized input circuit and a drain-surrounding-source(DSS)structure.The input circuit of a conventional inverter consists of a thick-gate-oxide n-type MOSFET(NMOS).These conventional drivers can tolerate a total ionizing dose(TID)of up to 100 krad(Si).In contrast,the proposed comparator input circuit uses both a thick-gate-oxide p-type MOSFET(PMOS)and thin-gate-oxide NMOS to offer a high input voltage and higher TID tolerance.Because the thick-gate-oxide PMOS and thin-gate-oxide NMOS collectively provide better TID tolerance than the thick-gate-oxide NMOS,the circuit exhibits enhanced TID tolerance of>300 krad(Si).Simulations and experimental date indicate that the DSS structure reduces the probability of unwanted parasitic bipolar junction transistor activation,yielding a better single-event effect tolerance of over 81.8 MeVcm^(2)mg^(-1).The innovative strategy proposed in this study involves circuit and layout design optimization,and does not require any specialized process flow.Hence,the proposed circuit can be manufactured using common commercial 0.35μm BCD processes. 展开更多
关键词 Total ionizing dose(TID) Single-event burnout(SEB) high-voltage driver Comparator input unit Drain-surrounding-source ring structure
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Melting plus reactive wetting of solid acid enabling stable high-voltage cycling of layered oxide cathodes for sodium-ion batteries 被引量:1
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作者 Debin Ye Guohu Chen +4 位作者 Junzhou Xie Chunliu Li Dan Liang Wenwei Wu Xuehang Wu 《Journal of Energy Chemistry》 2025年第6期252-260,I0007,共10页
Expanding the cutoff voltage of layered oxide cathodes for sodium-ion batteries(SIBs)is crucial for overcoming their existing energy density limitations.However,cationic/anodic redox-triggered multiple phase transitio... Expanding the cutoff voltage of layered oxide cathodes for sodium-ion batteries(SIBs)is crucial for overcoming their existing energy density limitations.However,cationic/anodic redox-triggered multiple phase transitions and unfavorable interfacial side reactions accelerate capacity and voltage decay.Herein,we present a straightforward melting plus reactive wetting strategy using H_(3)BO_(3)for surface modification of O_(3)-type Na_(0.9)Cu_(0.12)Ni_(0.33)Mn_(0.4)Ti_(0.15)O_(2)(CNMT).The transformation of H_(3)BO_(3)from solid to liquid under mild heating facilitates the uniform dispersion and complete surface coverage of CNMT particles.By neutralizing the residual alkali and extracting Na^(+)from the CNMT lattice,H_(3)BO_(3)forms a multifunctional Na_(2)B_(2)O_(5)-dominated layer on the CNMT surface.This Na_(x)B_(y)O_(z)(NBO)layer plays a positive role in providing low-barrier Na^(+)transport channels,suppressing phase transitions,and minimizing the generation of O_(2)/CO_(2)gases and resistive byproducts.As a result,at a charge cutoff voltage of 4.5 V,the NBO-coated CNMT delivers a high discharge capacity of 149,1 mAh g^(-1)at 10 mA g^(-1)and exhibits excellent cycling stability at 100 mA g^(-1)over 200 cycles with a higher capacity retention than that of pristine CNMT(86,4%vs,62.1%).This study highlights the effectiveness of surface modification using lowmelting-point solid acids,with potential applications for other layered oxide cathode materials to achieve stable high-voltage cycling.This proposed strategy opens new avenues for the construction of highquality coatings for high-voltage layered oxide cathodes in SIBs. 展开更多
关键词 Sodium-ion batteries O_(3)-type layered oxide Solid H_(3)BO_(3) Surface modification high-voltage stability
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High-Voltage Solid-State Lithium Batteries: A Review of Electrolyte Design, Interface Engineering, and Future Perspectives
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作者 Cheng Yang Zi-Xin Liang +3 位作者 Ming-Yun Zhang Ming-Zhe Chen Kai Zhang Li-Min Zhou 《电化学(中英文)》 北大核心 2025年第10期56-83,共28页
Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched wi... Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance.The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte,which is expected to be commercialized in the future.However,in high voltage conditions(>4.3 V),the decomposition of electrolyte components,structural degradation,and interface side reactions significantly reduce battery performance and hinder its further development.This review summarizes the latest research progress of inorganic electrolytes,polymer electrolytes,and composite electrolytes in high-voltage solid-state lithium batteries.At the same time,the designs of high-voltage polymer gel electrolyte and high-voltage quasi solid-state electrolyte are introduced in detail.In addition,interface engineering is crucial for improving the overall performance of high-voltage solid-state batteries.Finally,we highlight the challenges faced by high-voltage solid-state lithium batteries and put forward our own views on future research directions.This review offers instructive insights into the advancement of high-voltage solid-state lithium batteries for large-scale energy storage applications. 展开更多
关键词 Solid-state lithium batteries high-voltage Solid-state electrolyte Interface engineering
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Tuning surface functional groups and crystallinity in activated carbon for high-voltage lithium-ion capacitors
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作者 AN Ya-bin SUN Yu +5 位作者 ZHANG Ke-liang LI Chen SUN Xian-zhong WANG Kai ZHANG Xiong MA Yan-wei 《新型炭材料(中英文)》 北大核心 2025年第5期1085-1097,I0019-I0021,共16页
Lithium-ion capacitors(LICs)combine the high power dens-ity of electrical double-layer capacitors with the high energy density of lithium-ion batteries.However,they face practical limitations due to the narrow operati... Lithium-ion capacitors(LICs)combine the high power dens-ity of electrical double-layer capacitors with the high energy density of lithium-ion batteries.However,they face practical limitations due to the narrow operating voltage window of their activated carbon(AC)cathodes.We report a scalable thermal treatment strategy to develop high-voltage-tolerant AC cathodes.Through controlled thermal treatment of commer-cial activated carbon(Raw-AC)under a H_(2)/Ar atmosphere at 400-800℃,the targeted reduction of degradation-prone functional groups can be achieved while preserving the critical pore structure and increasing graph-itic microcrystalline ordering.The AC treated at 400℃(HAC-400)had a significant increase in specific capacity(96.0 vs.75.1 mAh/g at 0.05 A/g)and better rate capability(61.1 vs.36.1 mAh/g at 5 A/g)in half-cell LICs,along with an 83.5%capacity retention over 7400 cycles within an extended voltage range of 2.0-4.2 V in full-cell LICs.Scalability was demonstrated by a 120 g batch production,enabling fabrication of pouch-type LICs with commercial hard carbon anodes that delivered a higher energy density of 28.3 Wh/kg at 1 C,and a peak power density of 12.1 kW/kg compared to devices using raw AC.This simple,industry-compatible approach may be used for producing ad-vanced cathode materials for practical high-performance LICs. 展开更多
关键词 Activated carbon Lithium-ion capacitors Surface functional groups Microcrystalline domains high-voltage cathod
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The in-situ growth of Cu_(2)O–CuO on Cu foam coated with carbon derived from polydopamine as the flexible high-voltage cathode for thermal batteries
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作者 Xin-ya Bu Yan-li Zhu +4 位作者 Ting Quan Bin-chao Shi Shu Zhang Xiao-yu Wei Qi Xia 《Green Energy & Environment》 2025年第9期1922-1933,共12页
Thermal batteries are a type of thermally activated reserve battery,where the cathode material significantly influences the operating voltage and specific capacity.In this work,Cu_(2)O–CuO nanowires are prepared by i... Thermal batteries are a type of thermally activated reserve battery,where the cathode material significantly influences the operating voltage and specific capacity.In this work,Cu_(2)O–CuO nanowires are prepared by in-situ thermal oxidation method onto Cu foam,which are further coated with a carbon layer derived from polydopamine(PDA).The morphology of the nanowires has been examined using scanning electron microscopy(SEM)and transmission electron microscopy(TEM).The material shows a kind of core–shell structure,with CuO as the shell and Cu_(2)O as the core.To further explore the interaction between the material and lithium-ion(Li^(+)),the Lit adsorption energies of CuO and Cu_(2)O were calculated,revealing a stronger affinity of Li^(+) for CuO.The unique core–shell nanowire structure of Cu_(2)O–CuO can provide a good Li^(+)adsorption with the outer layer CuO and excellent structural stability with the inner layer Cu_(2)O.When applied in thermal batteries,Cu_(2)O–CuO–C nanowires exhibit specific capacity and specific energy of 326 mAh g^(-1)and 697 Wh kg^(-1)at a cut-off voltage of 1.5 V both of which are higher than those of Cu_(2)O–CuO(238 mAh g^(-1)and 445 Wh kg^(-1)).The discharge process includes the insertion of lithium ions and subsequent reduction reactions,ultimately resulting in the formation of lithium oxide and copper. 展开更多
关键词 high-voltage CuO nanowires PDA CATHODE Thermal battery
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Standardized Research on High-Voltage Safety of Drive Motor Systems
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作者 Bowen Yin Hang Sun +1 位作者 Yue Fu Hui Rong 《Journal of Electronic Research and Application》 2025年第3期1-9,共9页
This paper focuses on the high-voltage safety of drive motor systems in new energy vehicles and conducts standardized research on functional safety design in the concept phase. In view of the lack of high-voltage haza... This paper focuses on the high-voltage safety of drive motor systems in new energy vehicles and conducts standardized research on functional safety design in the concept phase. In view of the lack of high-voltage hazard analysis for drive motor systems in existing standards, based on theories such as GB/T 34590 and ISO 26262, the safety levels are deeply analyzed. The HAZOP method is innovatively used, and 16 types of guidewords are combined to comprehensively analyze the system functions, identifying vehicle hazards such as high-voltage electric shock caused by functional abnormalities, including high-voltage interlock function failure and abnormal active discharge. Subsequently, safety goals such as preventing high-voltage electric shock are set, functional safety requirements such as accurately obtaining collision signals and timely discharging high-voltage electricity are formulated, and requirements for external signal sources and other technologies are clearly defined, constructing a complete high-voltage safety protection system. The research results provide important technical support and standardized references for the high-voltage safety functional design of drive motor systems in new energy vehicles, and are of great significance for improving the high-voltage safety level of the new energy vehicle industry, expecting to play a key role in subsequent product development and standard improvement. 展开更多
关键词 Drive motor system high-voltage safety Functional safety design HAZOP method
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