National high-tech industrial development zones represent a major strategy of the Chinese government in developing high-tech industries and spurring regional economic growth. The effect of this policy is yet to be pro...National high-tech industrial development zones represent a major strategy of the Chinese government in developing high-tech industries and spurring regional economic growth. The effect of this policy is yet to be proven. Based on the panel data of 283 Chinese cities between 1984 and 2012, this paper investigates the effect of high-tech zones on regional economic development. Empirical results suggest that first, national hightech zones have remarkably enhanced regional GDP and per capita GDP growth, and this conclusion still holds true after multiple rounds of robustness test; second, the economic effect of national high-tech zones is subject to diminishing marginal return and compared with higher-tier cities, lower-tier cities benefited more from the creation of national hightech zones. This paper concludes that national high-tech zones where special policies are experimented and offered not only drive economic development but, if properly distributed across regions, may help reduce regional economic disparities as well. The results of this study provide important implications for the future distribution of national high-tech zones and the creation of other relevant policies.展开更多
The National High-tech Zone(NHTZs)is an important strategic platform for cultivating high-tech industries and realizing high-quality economic development in China.Based on the combined data from 2006 to 2014 of the in...The National High-tech Zone(NHTZs)is an important strategic platform for cultivating high-tech industries and realizing high-quality economic development in China.Based on the combined data from 2006 to 2014 of the industrial enterprise database,the customs database,and the China Development Zones Audit and Announcement Catalogue(abbreviated asthe Catalogue),this paper systematically investigates the influence of the construction of NHTZs on enterprise’s total factor productivity(TFP).Results show that NHTZs have a positive impact on the TFP of enterprises in the zone,and this conclusion is still valid after considering endogeneity problems.Furthermore,the above productivity effects of NHTZs are heterogeneous in terms of enterprise ownership,external environment and establishment time,and NHTZs have greater stimulation effects on enterprise productivity after comparing with other types of functional zones.An investigation of the specific mechanisms at play shows that NHTZs promote the TFP of enterprises in the zone through the release of preferential policies,strengthening the“technology spillover effects”of imported intermediate goods,enhancing enterprise’s innovation ability and attracting talent.In addition,based on the decomposition of industry productivity,this paper also investigates the impact of NHTZs on changes in industry productivity and finds that NHTZs promote the overall productivity of specific industries mainly by stimulating the productivity improvement of incumbent enterprises and expanding the market share of high-productivity enterprises.Moreover,the preferential policies of NHTZs do not significantly stimulate high-productivity enterprises to enter the zones,nor do they cause low-productivity enterprises to exit.This research is helpful in objectively evaluating the economic effects of the NHTZs in China and in providing a theoretical basis for its further adjustment.展开更多
Indigenous innovation focused on the development of technical standards has become the core of China's innovation policy,since China released the "Outline of the National Program for Longand Medium-Term Scien...Indigenous innovation focused on the development of technical standards has become the core of China's innovation policy,since China released the "Outline of the National Program for Longand Medium-Term Scientific and Technological Development (2006-2020)" in 2006.Meanwhile,standardization issues are greatly emphasized by high-tech zones which serve as the major carriers of national economic growth as well as innovation clusters in the context of fast-growing international standardization.By means of the effective guide of the government,the standardization of high-tech zones in China now presents a wide range of operating modes.Specifically,they can be divided predominantly into the government promotion mode,the alliance collaboration mode,the research-standard-industry linkage mode,and the talent training mode,in terms of the main body of work and influence factors.展开更多
Wetlands are vital ecosystems that perform essential functions such as climate regulation,environmental purification,material circulation and energy flow.They play an essential role in global biogeochemical cycles,dri...Wetlands are vital ecosystems that perform essential functions such as climate regulation,environmental purification,material circulation and energy flow.They play an essential role in global biogeochemical cycles,driven primarily by microorganisms.Understanding the distribution of wetland microorganisms across different temperature zones is key to comprehending their ecological roles.A meta-analysis of 704 wetland soil samples on microbial communities was conducted,using statistical methods like analysis of variance,principal component analysis,non-metric nultidimensional scaling,and structural equation modeling to examine biogeography and diversity across temperature zones.Our findings revealed a clear latitudinal diversity gradient pattern,with the highest microbial abundance in the tropics and the lowest in the southern temperate zone,which differed significantly from other temperature zones.Proteobacteria(37.76%-51.04%),Acidobacteria(5.11%-30.70%)and Bacteroidetes(3.43%-16.16%)dominanted the bacterial communities.Notably,the southern temperate zone showed significant variations,with a higher prevalence of Acidobacteria(30.07%).To investigate the causes of this variability,we screened 177 core microbiome and identified latitude as the core environmental factor influencing microbial community composition.Moreover,soil microorganisms exhibited strong nitrogen cycling potentials(particularly nirD and nirB)and carbon cycling potentials(especially accA),with gene abundances showing little variation across temperature zones.Wetland bacterial communities also demonstrated high stability,with average variation degree index values ranging from 0.1 to 0.3.Our results improve the understanding of the diversity and biogeographic mechanisms of wetland bacterial communities and hold significant implications for the management and conservation of wetlands.展开更多
Ensuring national food security amidst rapid population growth and increasing extreme weather events remains a critical global challenge.However,the extent to which agricultural modernization in China enhances grain y...Ensuring national food security amidst rapid population growth and increasing extreme weather events remains a critical global challenge.However,the extent to which agricultural modernization in China enhances grain yield and contributes to food security remains unclear.Therefore,using panel data from 327 Chinese cities(2013–2021),this study employs spatial econometric models to analyze the spatial spillover effects of agricultural modernization level(AML)on grain yield and to reveal regional heterogeneity across nine major agricultural zones.The results showed a cumulative grain yield increase of 23.7 million tons,with peak productivity concentrated along the Hu Line and declining eastward and westward.AML also exhibited a steady increase but a clear spatial gradient,decreasing from coastal to inland regions,with the highest level observed in Southern China(SC).A key finding was that a 1%increase in AML directly raised local grain yield by an average of 4.185%,accompanied by significant positive spillover effects on neighboring regions.Regional variations revealed distinct patterns:the direct effects of AML were more pronounced in southern and eastern zones,while spillover effects dominated in northern and western zones.The largest positive direct impact of AML on grain yield was observed in the SC(8.499%),while Middle-Lower Yangtze Plain ranked second but exhibited the strongest positive spatial spillover effect(4.534%).These findings highlight the critical role of agricultural modernization in promoting grain production and provide a solid basis for optimizing regional agricultural systems,ensuring food security,and advancing sustainable agriculture.展开更多
Anaerobic ammonium oxidation(anammox)plays a vital role in the global nitrogen cycle by mitigating reactive nitrogen.In recent years,its ecological importance has drawn increasing attention.Despite its widespread occu...Anaerobic ammonium oxidation(anammox)plays a vital role in the global nitrogen cycle by mitigating reactive nitrogen.In recent years,its ecological importance has drawn increasing attention.Despite its widespread occurrence,the distribution and quantitative contribution of anammox to global nitrogen loss remain unclear.We collected 390 reported anammox activity measurements which were obtained using 15N isotope tracing techniques and analyzed anammox rate and environmental factors including soil/sediment and water property using generalized additive models(GAMs).Moreover,based on the division of the anammox activity region,we estimated anammox-driven nitrogen loss across different ecosystems including wetlands and oxygen minimum zones(OMZs)ecosystems.Our findings revealed that soil moisture content was the most significant predictor of anammox activity in wetlands ecosystems.Paddy fields contributed 51%of anammox-driven nitrogen loss(32.0 Tg N/yr),followed by rivers/lakes(29%)and wetlands(20%).Asia emerged as the dominant region for anammoxdriven nitrogen loss(30.7 Tg N/yr),with paddy fields making a substantial contribution.North America was the second-largest contributor(25.4 Tg N/yr),with rivers/lakes being the main sources of nitrogen loss.In OMZs ecosystems,nitrate and dissolved oxygen were key factors influencing anammox rates.OMZs were hotspots for anammox,with peak activity at 300 m depth and nitrogen loss totaling 68.6 Tg N/yr,mostly between 100 and 500 m depths.This study underscores the critical role of anammox in global nitrogen cycling and offers a basis for environmental nitrogen management through predictive anammox modeling.展开更多
Against the backdrop of accelerated development of new forms of trade,the question of whether rapid expansion of cross-border e-commerce(CBEC)can help to reduce carbon emissions among Chinese enterprises is of great s...Against the backdrop of accelerated development of new forms of trade,the question of whether rapid expansion of cross-border e-commerce(CBEC)can help to reduce carbon emissions among Chinese enterprises is of great significance for seizing new opportunities in foreign trade,and advancing firms’green and low-carbon transformation.This study treats the creation of CBEC pilot zones as a quasi-natural experiment,employing panel data from Chinese A-share listed companies matched with city-level information from 2006 to 2021.We construct a multi-period difference-in-differences model to identify the impact of CBEC pilot zone policy on corporate carbon emissions.Our findings indicate the construction of these pilot zones significantly reduces firms’carbon emissions intensity,and the results are robust across multiple tests.We show the pilot zone initiative contributes to emission reductions by enhancing the adoption of digital infrastructure,promoting green technological innovation,and increasing environmental awareness among enterprises.Quantile regressions reveal pilot zones exert a more pronounced carbon-reduction effect on firms characterized by high carbon emissions intensity and advanced levels of digital transformation.Moreover,the policy effect is especially significant in heavily polluting industries,and regions with weaker governmental environmental regulations or lower public environmental concerns.This study makes an innovative contribution to the literature by empirically verifying the environmental governance effect of establishing CBEC pilot zones,and offers practical guidance for governments in formulating cross-border e-commerce policies and for enterprises pursuing low carbon development.展开更多
Economic and technological development zone and high-tech industrial zone are important types of development zone in China,and there are differences in their connotation and goal setting.In this paper,basic data of na...Economic and technological development zone and high-tech industrial zone are important types of development zone in China,and there are differences in their connotation and goal setting.In this paper,basic data of national and provincial economic and technological development zones and high-tech industrial zones in China were collected and arranged.Kernel density analysis and other GIS spatial analysis techniques were used to analyze the evolution laws of spatial patterns of economic and technological development zones and high-tech industrial zones in cities from 2006 to 2018.First,the agglomeration intensity was compared by measuring the degree of regional agglomeration and dispersion on the two time nodes.Next,kernel density method was used to explore the evolution of the two in the spatial layout and location,and analyze development commonness and difference of economic and technological development zones and high-tech industrial zones.Finally,the trend and reason of spatial evolution of development zones with different leading industries were explored.Research results show that:①the agglomeration degree of layout of high-tech industrial zones is stronger than that of economic and technological development zones,and there are similarities and differences in distribution trend of spatial patterns of the two types of development zones;②the distribution of labor-intensive,capital-intensive and technology-intensive development zones is concentrated at smaller scales and dispersed at larger ones;③although there are differences between the economic and technological development zones and the high-tech industrial zones in the goal,support,structure and function,management system and so on,their spatial development presents a trend of convergence.In the future,when enhancing urban-rural planning and public administration,governments should combine the trend of industrial transformation and upgrading,and optimize spatial layout of development zones by adjusting industrial structure,layout,transportation and land use.展开更多
There are three ports in this poper.Part I is involved in discussion of threeessential soft factors acting at development of high-tech industry-location,nctworkand comptehensive factors.It strobes the role of brains a...There are three ports in this poper.Part I is involved in discussion of threeessential soft factors acting at development of high-tech industry-location,nctworkand comptehensive factors.It strobes the role of brains and practical capeity inhigh-tech development,clarifying the same importance of qualified personnel networkas information network,elucidating both intemal and external impetus Part II dealswith locatkinal comparison among high-tech industrial zones in Ch;. for which anAnalysis of Hierarchy Process (AHP) method is used. Upe esults, Chinesehigh-tech industrial zones are divided into four grades. The las. p proposes four aspects as implementation measures for high-tech industrial zone in China.展开更多
The Anninghe–Zemuhe Fault and the Xiaojiang Fault are critical active faults along the middle-eastern boundary of the South Chuan–Dian Block. Many researchers have identified these faults as potential strong-earthqu...The Anninghe–Zemuhe Fault and the Xiaojiang Fault are critical active faults along the middle-eastern boundary of the South Chuan–Dian Block. Many researchers have identified these faults as potential strong-earthquake risk zones. In this study, we leveraged a dense seismic array to investigate the high-resolution shallow crust shear wave velocity(Vs) structure beneath the junction of the Zemuhe Fault Zone and the Xiaojiang Fault Zone, one of the most complex parts of the eastern boundary of the South Chuan–Dian Block. We analyzed the distribution of microseismic events detected between November 2022 and February 2023 based on the fine-scale Vs model obtained. The microseismicity in the study region was clustered into three groups, all spatially related to major faults in this region. These microseismic events indicate near-vertical fault planes, consistent with the fault geometry revealed by other researchers.Moreover, these microseismic events are influenced by the impoundment of the downstream Baihetan Reservoir and the complex tectonic stress near the junction of the Zemuhe Fault Zone and the Xiaojiang Fault Zone. The depths of these microseismic events are shallower in the junction zone, whereas moving south along the Xiaojiang Fault Zone, the microseismic events become deeper.Additionally, we compared our fine-scale local Vs model with velocity models obtained by other researchers and found that our model offers greater detail in characterizing subsurface heterogeneity while demonstrating improved reliability in delineating fault systems.展开更多
This work focuses on the influence of Al content on the precipitation of nanoprecipitates,growth of prior austenite grains(PAGs),and impact toughness in simulated coarse-grained heat-affected zones (CGHAZs) of two exp...This work focuses on the influence of Al content on the precipitation of nanoprecipitates,growth of prior austenite grains(PAGs),and impact toughness in simulated coarse-grained heat-affected zones (CGHAZs) of two experimental shipbuilding steels after being subjected to high-heat input welding at 400 kJ·cm^(-1).The base metals (BMs) of both steels contained three types of precipitates Type Ⅰ:cubic (Ti,Nb)(C,N),Type Ⅱ:precipitate with cubic (Ti,Nb)(C,N) core and Nb-rich cap,and Type Ⅲ:ellipsoidal Nb-rich precipitate.In the BM of 60Al and 160Al steels,the number densities of the precipitates were 11.37×10^(5) and 13.88×10^(5) mm^(-2),respectively The 60Al and 160Al steel contained 38.12% and 6.39% Type Ⅲ precipitates,respectively.The difference in the content of Type Ⅲ precipitates in the 60Al steel reduced the pinning effect at the elevated temperature of the CGHAZ,which facilitated the growth of PAGs The average PAG sizes in the CGHAZ of the 60Al and 160Al steels were 189.73 and 174.7μm,respectively.In the 60Al steel,the low lattice mismatch among Cu_(2)S,TiN,and γ-Al_(2)O_(3)facilitated the precipitation of Cu_(2)S and TiN onto γ-Al_(2)O_(3)during welding,which decreased the number density of independently precipitated (Ti,Nb)(C,N) particles but increased that of γ-Al_(2)O_(3)–Ti N–Cu_(2)S particles.Thus abnormally large PAGs formed in the CGHAZ of the 60Al steel,and they reached a maximum size of 1 mm.These PAGs greatly reduced the microstructural homogeneity and consequently decreased the impact toughness from 134 (0.016wt%Al) to 54 J (0.006wt%Al)at-40℃.展开更多
In recent years,high-tech development zones(hi-tech zones)have always occupied a very important position in the strategy of promoting China's innovative development.The combination of the"four-transform and t...In recent years,high-tech development zones(hi-tech zones)have always occupied a very important position in the strategy of promoting China's innovative development.The combination of the"four-transform and three-famous"coordinated economic development strategy pioneered by Zhejiang Province in 2015 and the coordinated economic development of high-tech zones is particularly important for modern China at a critical time for innovative economic development.In this article,based on the research on the coordination mechanism of economic activities and development of Nanchang High-tech Zone,the development course of high-tech zones in China is elaborated,the early economic models in high-tech zones of Nanchang and China are analyzed,the existing problems in the structure of economic development of high-tech zones are analyzed in depth,the main driving factors for promoting the economic development of high-tech zones are studied from the aspects of capital,space,industry,economic model,etc.,and corresponding development strategies for high-tech development zones in China are proposed.展开更多
Nanjing High-tech Industrial Devel-opment Zone It is a state-level high-tech in-dustrial development zone approved by theState Council, with an area of 16.5 sq km,comprising seven sq km of industrial area,five sq km o...Nanjing High-tech Industrial Devel-opment Zone It is a state-level high-tech in-dustrial development zone approved by theState Council, with an area of 16.5 sq km,comprising seven sq km of industrial area,five sq km of Taiwan invested area, three sqkm of university teaching and scientificresearch area and 1.5 sq km of compositeservice area. The development zone is 13.5 kmfrom the city center, with convenient trafficconditions, three state highways and a pro-展开更多
The faults and associated fracture zones in the tight sandstone reservoirs of the fifth member of the Triassic Xujiahe Formation(Xu-5 Member)in the Wubaochang area,northeastern Sichuan Basin,play a critical role in co...The faults and associated fracture zones in the tight sandstone reservoirs of the fifth member of the Triassic Xujiahe Formation(Xu-5 Member)in the Wubaochang area,northeastern Sichuan Basin,play a critical role in controlling gas well productivity.To delineate the distribution patterns of the faults and associated fracture zones in this area,a transfer-trained convolutional neural network(CNN)model and an XGBoost(eXtreme Gradient Boosting)-based intelligent seismic attribute fusion method were employed to identify faults and fracture zones,respectively,enabling precise characterization of their spatial distribution.The faults in the Wubaochang area are classified into first-to fourth-order structures,with the average fracture zone width on the hanging wall exceeding that of the footwall,demonstrating a strong positive correlation between fracture zone width and fault displacement.The study area is divided into three distinct deformation regions(southern,central and northern regions)featuring five fault structural styles(duplex,duplex-backthrust,imbricate thrust,synclinorium imbricate-backthrust,and anticlinorium imbricate-backthrust)and four corresponding fracture zone development patterns(duplex,duplex-backthrust,synclinorium imbricate-backthrust,and anticlinorium imbricate-backthrust).Based on the controlling effects of faults on gas enrichment,the dual-source hydrocarbon-supply zones are interpreted to be distributed in the northern and central regions,while the southern region is identified as gas-escape zones.By integrating the distribution of favorable reservoir development areas and fracture zones,two classes of gas enrichment zones(Class Ⅰ and Ⅱ)are delineated.Class Ⅰ zones are primarily distributed in the northern region and the transitional zone from the southern to central regions,whereas Class Ⅱ zones are concentrated in the central region.Class Ⅰ zones exhibit dual-source hydrocarbon-supply conditions,larger-scale fracture zone development,and higher favorability compared to Class Ⅱ zones.According to the defined gas accumulation effectiveness in different types of fracture zones,a high-productivity gas well model for the Wubaochang area is proposed,emphasizing“dual-source faults controlling enrichment,effective fracture zones controlling high production,and high matrix porosity ensuring sustained production”.Targeted drilling directions for different favorable zones are further optimized based on this model.展开更多
The study of natural hybridization facilitates our understanding of potential adaptive mechanisms in evolution and the process involved in speciation.In this study,we used multiple data types,including morphological t...The study of natural hybridization facilitates our understanding of potential adaptive mechanisms in evolution and the process involved in speciation.In this study,we used multiple data types,including morphological traits,ddRAD-seq and ecological niche data,to investigate the differences among Rhododendron×duclouxii hybrid zones and the mechanisms underlying natural hybridization and possible future evolutionary pathways.Our results show that the origins of each hybrid zone are independent,with variations in hybrid formation,structural characteristics,and patterns of genetic components and morphological trait differentiation.There were no significant differences in morphological traits or genetic variation between the F_(1)and F_(2)generations;however,the range of variation of the F_(2)generation was broader than that of the F_(1)generation.The distribution and ecological characteristics of R.×duclouxii did not significantly differ from those of the two parental species,indicating weak ecological niche preferences between the hybrid and parental taxa.These results imply that the hybrid zones of R.×duclouxii are characterized by considerable variability,with the magnitude of hybridization in each case likely influenced by unique combinations of biological and ecological factors specific to each hybrid zone.We predict that R.×duclouxii hybrid zones will persist and give rise to complex hybrid swarms,each potentially leading to different evolutionary outcomes.展开更多
Magnesium alloys,the lightest metallic materials for structural applications,have met the bottleneck in the applications at 300℃ due to limited creep resistance.The degradation of creep resistance closely depends on ...Magnesium alloys,the lightest metallic materials for structural applications,have met the bottleneck in the applications at 300℃ due to limited creep resistance.The degradation of creep resistance closely depends on the microstructural deterioration,especially the formation of precipitate-free zones(PFZs),but the detailed evolution process remains unclear in this regard.The present study adopted a quasi-in-situ methodology to track the evolution process of the PFZs in Mg-2.5Gd-0.1Zr(at.%)alloy during creep at 300℃ under 60 MPa.In the early creep stage,the widening of PFZs and phase transformation of intragranular precipitates are repressed by the applied stress.In the steady and accelerated creep stages,propagation of dislocations generates misorientation between PFZs and their parent grains,leading to the formation of Type-A PFZs.Meanwhile,vacancy diffusion leads to inverse migration of grain boundaries,and produces PFZs with serrated grain boundaries between split rows of grain boundary particles,causing the formation of Type-B PFZs.Secondary intergranular cracks tend to develop in Type-B PFZs in the accelerated creep stage,but the strain accumulation in Type-A PFZs is the key contributor to premature creep failure.展开更多
Subduction zones,linking the surface and deep carbon reservoirs,significantly affect the Earth’s long-term climate change and habitability.The subducting slabs undergo decarbonation with increasing pressure and tempe...Subduction zones,linking the surface and deep carbon reservoirs,significantly affect the Earth’s long-term climate change and habitability.The subducting slabs undergo decarbonation with increasing pressure and temperature,during which partial carbon mobilizes out of the slab and returns to the surface by arc volcanism or degassing,while the residual carbon continues to descend to greater depths in the mantle.The estimated carbon influx at subduction zones depends strongly on the calculation model,with contributions from sediments ranging from 15 to 60 Mt C/yr,altered ocean basalts from 18 to 61 Mt C/yr,and serpentinized perdotites from 1.3 to 36 Mt C/yr.The carbon influx varies in space and time.Carbon removal from subducting slab occurs through metamorphic reactions,carbonate dissolution,diapirism,hydrocarbon formation and melting.Among these decarbonation mechanisms,diapirism and slab meting play a decisive role in dictating the depth at which surface carbonates can subduct.Specifically,diapirism may restrict sedimentary carbonates at shallow depths(<200 km),while slab melting exhausts all carbonates from the altered ocean crust near transition zones(410–660 km).Consequently,a mechanism enabling surface carbonates to reach the lower mantle,i.e.,ultra-deep carbon cycle,is required to be in accordance with observations by natural samples.展开更多
Over 90%of Earth’s carbon is stored in the mantle and core.The deep carbon cycle plays a critical role in regulating surface carbon fluxes,global climate,and the habitability of Earth.Carbon mainly residing within th...Over 90%of Earth’s carbon is stored in the mantle and core.The deep carbon cycle plays a critical role in regulating surface carbon fluxes,global climate,and the habitability of Earth.Carbon mainly residing within the sediments,altered oceanic crust,and mantle peridotite as carbonate minerals and organic carbon is transported to the deep Earth via plate subduction.A series of reactions(e.g.,metamorphism,dissolution,and melting)occurring in the subducting slab drive the carbon removal.Some of the car-bon is recycled to the surface via arc volcanism,while the rest is carried into the deeper Earth.More than two-thirds of the global subduction carbon input comes from sedimen-tary carbon,whose fate during subduction directly affects the flux in the global carbon cycle.Over the past two dec-ades,the sedimentary carbon cycle in subduction zones has been extensively studied by experiments and computational approaches.Here,we provide a comprehensive review of the sources,species,decarbonation reactions,carbon cycle trac-ing,and fluxes of sedimentary carbon in subduction zones,and the role of sedimentary carbon subduction in climate evolution and mantle chemistry.Further research is required for our understanding of deep carbon cycle processes and their role in Earth’s climate.展开更多
Micro(nano)plastics,as an emerging environmental pollutant,are gradually discovered in hyporheic zones and groundwaterworldwide.Recent studies have focused on the origin and spatial/temporal distribution of micro(nano...Micro(nano)plastics,as an emerging environmental pollutant,are gradually discovered in hyporheic zones and groundwaterworldwide.Recent studies have focused on the origin and spatial/temporal distribution of micro(nano)plastics in regional groundwater,together with the influence of their properties and effects of environmental factors on their transport.However,the transport of micro(nano)plastics in the whole hyporheic zone-groundwater system and the behavior of co-existing substances still lack a complete theoretical interpretation.To provide systematic theoretical support for that,this review summarizes the current pollution status of micro(nano)plastics in the hyporheic zone-groundwater system,provides a comprehensive introduction of their sources and fate,and classifies the transport mechanisms into mechanical transport,physicochemical transport and biological processes assisted transport fromthe perspectives ofmechanical stress,physicochemical reactions,and bioturbation,respectively.Ultimately,this review proposes to advance the understanding of the multi-dimensional hydrosphere transport of micro(nano)plastics centered on groundwater,themicroorganisms-mediated synergistic transformation and co-transport involving the intertidal circulation.Overall,this review systematically dissects the presence and transport cycles of micro(nano)plastics within the hyporheic zone-groundwater system and proposes prospects for future studies based on the limitations of current studies.展开更多
Based on the waterflooding development in carbonate reservoirs in the Middle East,this study analyzes the geological characteristics and waterflooding behaviors/patterns of different types of high permeability zones(H...Based on the waterflooding development in carbonate reservoirs in the Middle East,this study analyzes the geological characteristics and waterflooding behaviors/patterns of different types of high permeability zones(HPZs),and proposes rational waterflooding strategies and modes.Four types of HPZs,i.e.sedimentation-dominated,sedimentation-diagenesis coupling,biogenic and composite,are identified in the carbonate reservoirs in the Middle East.Based on their distribution patterns,flow mechanisms,and waterflooding behaviors/patterns,five waterflooding modes are established:(1)the mode with stepwise-infilled areal vertical well pattern,for composite HFZs in patchy distribution;(2)the mode with regular row vertical well pattern for TypeⅠchannel“network”HFZs(with dominant water flow pathways at the base),and the mode with irregular differentiated vertical well pattern for TypeⅡchannel“network”HFZs(where multi-stage superimposition leads to“layered flooding”),for sedimentation-diagenesis coupling HFZs;(3)the mode with row horizontal wells through bottom injection and top production,for biogenic HFZs characterized by thin,contiguous distribution and rapid advancing of injected water along a工-shaped path;and(4)the mode with progressive waterflooding through edge water injection via vertical well and oil production via horizontal well,for sedimentation-dominated HFZs characterized by thick,contiguous distribution and flood first in upper anti-rhythmic reservoirs.Development practices demonstrate that the proposed waterflooding modes are efficient in the highly heterogeneous carbonate reservoirs in the Middle East,with balanced employment of reserves in the adjacent reservoirs and enhanced oil recovery.展开更多
基金sponsored by the National Natural Science Foundation Program(Approval No.71303185)the Social Sciences Planning Foundation Program of the Ministry of Education(Approval No.13XJA790003)+2 种基金the Social Sciences Foundation Program of Shaanxi Province(Approval No.12D124)the Program of Shaanxi Provincial Department of Education(Approval No.12JK0152)the Support Program for Outstanding Young Teachers of Northwest University(Approval No.PR12152)
文摘National high-tech industrial development zones represent a major strategy of the Chinese government in developing high-tech industries and spurring regional economic growth. The effect of this policy is yet to be proven. Based on the panel data of 283 Chinese cities between 1984 and 2012, this paper investigates the effect of high-tech zones on regional economic development. Empirical results suggest that first, national hightech zones have remarkably enhanced regional GDP and per capita GDP growth, and this conclusion still holds true after multiple rounds of robustness test; second, the economic effect of national high-tech zones is subject to diminishing marginal return and compared with higher-tier cities, lower-tier cities benefited more from the creation of national hightech zones. This paper concludes that national high-tech zones where special policies are experimented and offered not only drive economic development but, if properly distributed across regions, may help reduce regional economic disparities as well. The results of this study provide important implications for the future distribution of national high-tech zones and the creation of other relevant policies.
文摘The National High-tech Zone(NHTZs)is an important strategic platform for cultivating high-tech industries and realizing high-quality economic development in China.Based on the combined data from 2006 to 2014 of the industrial enterprise database,the customs database,and the China Development Zones Audit and Announcement Catalogue(abbreviated asthe Catalogue),this paper systematically investigates the influence of the construction of NHTZs on enterprise’s total factor productivity(TFP).Results show that NHTZs have a positive impact on the TFP of enterprises in the zone,and this conclusion is still valid after considering endogeneity problems.Furthermore,the above productivity effects of NHTZs are heterogeneous in terms of enterprise ownership,external environment and establishment time,and NHTZs have greater stimulation effects on enterprise productivity after comparing with other types of functional zones.An investigation of the specific mechanisms at play shows that NHTZs promote the TFP of enterprises in the zone through the release of preferential policies,strengthening the“technology spillover effects”of imported intermediate goods,enhancing enterprise’s innovation ability and attracting talent.In addition,based on the decomposition of industry productivity,this paper also investigates the impact of NHTZs on changes in industry productivity and finds that NHTZs promote the overall productivity of specific industries mainly by stimulating the productivity improvement of incumbent enterprises and expanding the market share of high-productivity enterprises.Moreover,the preferential policies of NHTZs do not significantly stimulate high-productivity enterprises to enter the zones,nor do they cause low-productivity enterprises to exit.This research is helpful in objectively evaluating the economic effects of the NHTZs in China and in providing a theoretical basis for its further adjustment.
文摘Indigenous innovation focused on the development of technical standards has become the core of China's innovation policy,since China released the "Outline of the National Program for Longand Medium-Term Scientific and Technological Development (2006-2020)" in 2006.Meanwhile,standardization issues are greatly emphasized by high-tech zones which serve as the major carriers of national economic growth as well as innovation clusters in the context of fast-growing international standardization.By means of the effective guide of the government,the standardization of high-tech zones in China now presents a wide range of operating modes.Specifically,they can be divided predominantly into the government promotion mode,the alliance collaboration mode,the research-standard-industry linkage mode,and the talent training mode,in terms of the main body of work and influence factors.
基金supported by the National Natural Science Foundation of China(No.52070019).
文摘Wetlands are vital ecosystems that perform essential functions such as climate regulation,environmental purification,material circulation and energy flow.They play an essential role in global biogeochemical cycles,driven primarily by microorganisms.Understanding the distribution of wetland microorganisms across different temperature zones is key to comprehending their ecological roles.A meta-analysis of 704 wetland soil samples on microbial communities was conducted,using statistical methods like analysis of variance,principal component analysis,non-metric nultidimensional scaling,and structural equation modeling to examine biogeography and diversity across temperature zones.Our findings revealed a clear latitudinal diversity gradient pattern,with the highest microbial abundance in the tropics and the lowest in the southern temperate zone,which differed significantly from other temperature zones.Proteobacteria(37.76%-51.04%),Acidobacteria(5.11%-30.70%)and Bacteroidetes(3.43%-16.16%)dominanted the bacterial communities.Notably,the southern temperate zone showed significant variations,with a higher prevalence of Acidobacteria(30.07%).To investigate the causes of this variability,we screened 177 core microbiome and identified latitude as the core environmental factor influencing microbial community composition.Moreover,soil microorganisms exhibited strong nitrogen cycling potentials(particularly nirD and nirB)and carbon cycling potentials(especially accA),with gene abundances showing little variation across temperature zones.Wetland bacterial communities also demonstrated high stability,with average variation degree index values ranging from 0.1 to 0.3.Our results improve the understanding of the diversity and biogeographic mechanisms of wetland bacterial communities and hold significant implications for the management and conservation of wetlands.
基金National Natural Science Foundation of China,No.42471455,No.42230113National Key Research and Development Program of China,No.2022YFC3800804-01。
文摘Ensuring national food security amidst rapid population growth and increasing extreme weather events remains a critical global challenge.However,the extent to which agricultural modernization in China enhances grain yield and contributes to food security remains unclear.Therefore,using panel data from 327 Chinese cities(2013–2021),this study employs spatial econometric models to analyze the spatial spillover effects of agricultural modernization level(AML)on grain yield and to reveal regional heterogeneity across nine major agricultural zones.The results showed a cumulative grain yield increase of 23.7 million tons,with peak productivity concentrated along the Hu Line and declining eastward and westward.AML also exhibited a steady increase but a clear spatial gradient,decreasing from coastal to inland regions,with the highest level observed in Southern China(SC).A key finding was that a 1%increase in AML directly raised local grain yield by an average of 4.185%,accompanied by significant positive spillover effects on neighboring regions.Regional variations revealed distinct patterns:the direct effects of AML were more pronounced in southern and eastern zones,while spillover effects dominated in northern and western zones.The largest positive direct impact of AML on grain yield was observed in the SC(8.499%),while Middle-Lower Yangtze Plain ranked second but exhibited the strongest positive spatial spillover effect(4.534%).These findings highlight the critical role of agricultural modernization in promoting grain production and provide a solid basis for optimizing regional agricultural systems,ensuring food security,and advancing sustainable agriculture.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0750400)the National Natural Science Foundation of China(Nos.91851204,42177063,and 52370185)+1 种基金the Special project of eco-environmental technology for peak carbon dioxide emissions and carbon neutrality(No.RCEES-TDZ-2021-20)the State Key Joint Laboratory of Environmental Simulation and Pollution Control(Research Center for Eco-environmental Sciences,Chinese Academy of Sciences)(No.24Z01ESPCR).
文摘Anaerobic ammonium oxidation(anammox)plays a vital role in the global nitrogen cycle by mitigating reactive nitrogen.In recent years,its ecological importance has drawn increasing attention.Despite its widespread occurrence,the distribution and quantitative contribution of anammox to global nitrogen loss remain unclear.We collected 390 reported anammox activity measurements which were obtained using 15N isotope tracing techniques and analyzed anammox rate and environmental factors including soil/sediment and water property using generalized additive models(GAMs).Moreover,based on the division of the anammox activity region,we estimated anammox-driven nitrogen loss across different ecosystems including wetlands and oxygen minimum zones(OMZs)ecosystems.Our findings revealed that soil moisture content was the most significant predictor of anammox activity in wetlands ecosystems.Paddy fields contributed 51%of anammox-driven nitrogen loss(32.0 Tg N/yr),followed by rivers/lakes(29%)and wetlands(20%).Asia emerged as the dominant region for anammoxdriven nitrogen loss(30.7 Tg N/yr),with paddy fields making a substantial contribution.North America was the second-largest contributor(25.4 Tg N/yr),with rivers/lakes being the main sources of nitrogen loss.In OMZs ecosystems,nitrate and dissolved oxygen were key factors influencing anammox rates.OMZs were hotspots for anammox,with peak activity at 300 m depth and nitrogen loss totaling 68.6 Tg N/yr,mostly between 100 and 500 m depths.This study underscores the critical role of anammox in global nitrogen cycling and offers a basis for environmental nitrogen management through predictive anammox modeling.
基金support provided by the National Natural Science Foundation of China[Grant No.72204202]2025 Annual Research Program of the China Society for Commercial Statistics[Grant No.2025STY10]General Project of Philosophy Society in Jiangsu Province Universities[Grant Nos.2023SJYB0923 and 2025SJYB0708].
文摘Against the backdrop of accelerated development of new forms of trade,the question of whether rapid expansion of cross-border e-commerce(CBEC)can help to reduce carbon emissions among Chinese enterprises is of great significance for seizing new opportunities in foreign trade,and advancing firms’green and low-carbon transformation.This study treats the creation of CBEC pilot zones as a quasi-natural experiment,employing panel data from Chinese A-share listed companies matched with city-level information from 2006 to 2021.We construct a multi-period difference-in-differences model to identify the impact of CBEC pilot zone policy on corporate carbon emissions.Our findings indicate the construction of these pilot zones significantly reduces firms’carbon emissions intensity,and the results are robust across multiple tests.We show the pilot zone initiative contributes to emission reductions by enhancing the adoption of digital infrastructure,promoting green technological innovation,and increasing environmental awareness among enterprises.Quantile regressions reveal pilot zones exert a more pronounced carbon-reduction effect on firms characterized by high carbon emissions intensity and advanced levels of digital transformation.Moreover,the policy effect is especially significant in heavily polluting industries,and regions with weaker governmental environmental regulations or lower public environmental concerns.This study makes an innovative contribution to the literature by empirically verifying the environmental governance effect of establishing CBEC pilot zones,and offers practical guidance for governments in formulating cross-border e-commerce policies and for enterprises pursuing low carbon development.
基金Sponsored by Peking University (Shenzhen) Future City Lab Tiehan Research Fund。
文摘Economic and technological development zone and high-tech industrial zone are important types of development zone in China,and there are differences in their connotation and goal setting.In this paper,basic data of national and provincial economic and technological development zones and high-tech industrial zones in China were collected and arranged.Kernel density analysis and other GIS spatial analysis techniques were used to analyze the evolution laws of spatial patterns of economic and technological development zones and high-tech industrial zones in cities from 2006 to 2018.First,the agglomeration intensity was compared by measuring the degree of regional agglomeration and dispersion on the two time nodes.Next,kernel density method was used to explore the evolution of the two in the spatial layout and location,and analyze development commonness and difference of economic and technological development zones and high-tech industrial zones.Finally,the trend and reason of spatial evolution of development zones with different leading industries were explored.Research results show that:①the agglomeration degree of layout of high-tech industrial zones is stronger than that of economic and technological development zones,and there are similarities and differences in distribution trend of spatial patterns of the two types of development zones;②the distribution of labor-intensive,capital-intensive and technology-intensive development zones is concentrated at smaller scales and dispersed at larger ones;③although there are differences between the economic and technological development zones and the high-tech industrial zones in the goal,support,structure and function,management system and so on,their spatial development presents a trend of convergence.In the future,when enhancing urban-rural planning and public administration,governments should combine the trend of industrial transformation and upgrading,and optimize spatial layout of development zones by adjusting industrial structure,layout,transportation and land use.
文摘There are three ports in this poper.Part I is involved in discussion of threeessential soft factors acting at development of high-tech industry-location,nctworkand comptehensive factors.It strobes the role of brains and practical capeity inhigh-tech development,clarifying the same importance of qualified personnel networkas information network,elucidating both intemal and external impetus Part II dealswith locatkinal comparison among high-tech industrial zones in Ch;. for which anAnalysis of Hierarchy Process (AHP) method is used. Upe esults, Chinesehigh-tech industrial zones are divided into four grades. The las. p proposes four aspects as implementation measures for high-tech industrial zone in China.
基金funded by the National Key R&D Program of China (Grant No. 2021YFC3000704)the National Natural Science Foundation of China (Grant No. 42125401)the Central Public-interest Scientific Institution Basal Research Fund (Grant No. CEAIEF20240401)。
文摘The Anninghe–Zemuhe Fault and the Xiaojiang Fault are critical active faults along the middle-eastern boundary of the South Chuan–Dian Block. Many researchers have identified these faults as potential strong-earthquake risk zones. In this study, we leveraged a dense seismic array to investigate the high-resolution shallow crust shear wave velocity(Vs) structure beneath the junction of the Zemuhe Fault Zone and the Xiaojiang Fault Zone, one of the most complex parts of the eastern boundary of the South Chuan–Dian Block. We analyzed the distribution of microseismic events detected between November 2022 and February 2023 based on the fine-scale Vs model obtained. The microseismicity in the study region was clustered into three groups, all spatially related to major faults in this region. These microseismic events indicate near-vertical fault planes, consistent with the fault geometry revealed by other researchers.Moreover, these microseismic events are influenced by the impoundment of the downstream Baihetan Reservoir and the complex tectonic stress near the junction of the Zemuhe Fault Zone and the Xiaojiang Fault Zone. The depths of these microseismic events are shallower in the junction zone, whereas moving south along the Xiaojiang Fault Zone, the microseismic events become deeper.Additionally, we compared our fine-scale local Vs model with velocity models obtained by other researchers and found that our model offers greater detail in characterizing subsurface heterogeneity while demonstrating improved reliability in delineating fault systems.
基金support from the National Natural Science Foundation of China (No. U1960202)the Opening Foundation from Shanghai Engineering Research Center of Hot Manufacturing, China (No. 18DZ2253400)。
文摘This work focuses on the influence of Al content on the precipitation of nanoprecipitates,growth of prior austenite grains(PAGs),and impact toughness in simulated coarse-grained heat-affected zones (CGHAZs) of two experimental shipbuilding steels after being subjected to high-heat input welding at 400 kJ·cm^(-1).The base metals (BMs) of both steels contained three types of precipitates Type Ⅰ:cubic (Ti,Nb)(C,N),Type Ⅱ:precipitate with cubic (Ti,Nb)(C,N) core and Nb-rich cap,and Type Ⅲ:ellipsoidal Nb-rich precipitate.In the BM of 60Al and 160Al steels,the number densities of the precipitates were 11.37×10^(5) and 13.88×10^(5) mm^(-2),respectively The 60Al and 160Al steel contained 38.12% and 6.39% Type Ⅲ precipitates,respectively.The difference in the content of Type Ⅲ precipitates in the 60Al steel reduced the pinning effect at the elevated temperature of the CGHAZ,which facilitated the growth of PAGs The average PAG sizes in the CGHAZ of the 60Al and 160Al steels were 189.73 and 174.7μm,respectively.In the 60Al steel,the low lattice mismatch among Cu_(2)S,TiN,and γ-Al_(2)O_(3)facilitated the precipitation of Cu_(2)S and TiN onto γ-Al_(2)O_(3)during welding,which decreased the number density of independently precipitated (Ti,Nb)(C,N) particles but increased that of γ-Al_(2)O_(3)–Ti N–Cu_(2)S particles.Thus abnormally large PAGs formed in the CGHAZ of the 60Al steel,and they reached a maximum size of 1 mm.These PAGs greatly reduced the microstructural homogeneity and consequently decreased the impact toughness from 134 (0.016wt%Al) to 54 J (0.006wt%Al)at-40℃.
文摘In recent years,high-tech development zones(hi-tech zones)have always occupied a very important position in the strategy of promoting China's innovative development.The combination of the"four-transform and three-famous"coordinated economic development strategy pioneered by Zhejiang Province in 2015 and the coordinated economic development of high-tech zones is particularly important for modern China at a critical time for innovative economic development.In this article,based on the research on the coordination mechanism of economic activities and development of Nanchang High-tech Zone,the development course of high-tech zones in China is elaborated,the early economic models in high-tech zones of Nanchang and China are analyzed,the existing problems in the structure of economic development of high-tech zones are analyzed in depth,the main driving factors for promoting the economic development of high-tech zones are studied from the aspects of capital,space,industry,economic model,etc.,and corresponding development strategies for high-tech development zones in China are proposed.
文摘Nanjing High-tech Industrial Devel-opment Zone It is a state-level high-tech in-dustrial development zone approved by theState Council, with an area of 16.5 sq km,comprising seven sq km of industrial area,five sq km of Taiwan invested area, three sqkm of university teaching and scientificresearch area and 1.5 sq km of compositeservice area. The development zone is 13.5 kmfrom the city center, with convenient trafficconditions, three state highways and a pro-
基金Supported by National Natural Science Foundation of China and Enterprise Innovation and Development Joint Fund(U21B2062).
文摘The faults and associated fracture zones in the tight sandstone reservoirs of the fifth member of the Triassic Xujiahe Formation(Xu-5 Member)in the Wubaochang area,northeastern Sichuan Basin,play a critical role in controlling gas well productivity.To delineate the distribution patterns of the faults and associated fracture zones in this area,a transfer-trained convolutional neural network(CNN)model and an XGBoost(eXtreme Gradient Boosting)-based intelligent seismic attribute fusion method were employed to identify faults and fracture zones,respectively,enabling precise characterization of their spatial distribution.The faults in the Wubaochang area are classified into first-to fourth-order structures,with the average fracture zone width on the hanging wall exceeding that of the footwall,demonstrating a strong positive correlation between fracture zone width and fault displacement.The study area is divided into three distinct deformation regions(southern,central and northern regions)featuring five fault structural styles(duplex,duplex-backthrust,imbricate thrust,synclinorium imbricate-backthrust,and anticlinorium imbricate-backthrust)and four corresponding fracture zone development patterns(duplex,duplex-backthrust,synclinorium imbricate-backthrust,and anticlinorium imbricate-backthrust).Based on the controlling effects of faults on gas enrichment,the dual-source hydrocarbon-supply zones are interpreted to be distributed in the northern and central regions,while the southern region is identified as gas-escape zones.By integrating the distribution of favorable reservoir development areas and fracture zones,two classes of gas enrichment zones(Class Ⅰ and Ⅱ)are delineated.Class Ⅰ zones are primarily distributed in the northern region and the transitional zone from the southern to central regions,whereas Class Ⅱ zones are concentrated in the central region.Class Ⅰ zones exhibit dual-source hydrocarbon-supply conditions,larger-scale fracture zone development,and higher favorability compared to Class Ⅱ zones.According to the defined gas accumulation effectiveness in different types of fracture zones,a high-productivity gas well model for the Wubaochang area is proposed,emphasizing“dual-source faults controlling enrichment,effective fracture zones controlling high production,and high matrix porosity ensuring sustained production”.Targeted drilling directions for different favorable zones are further optimized based on this model.
基金supported by the National Natural Science Foundation of China,China(32300200,31670213,32160240)Postdoctoral Directional Training Foundation of Yunnan Province,China(E33O31C261)+2 种基金the Key Basic Research Program of Yunnan Province,China(202101BC070003)the CAS President’s International Fellowship Initiative,China(2024PVA0087)supported by the Rural and Environment Science and Analytical Services Division of the Scottish Government,United Kingdom.
文摘The study of natural hybridization facilitates our understanding of potential adaptive mechanisms in evolution and the process involved in speciation.In this study,we used multiple data types,including morphological traits,ddRAD-seq and ecological niche data,to investigate the differences among Rhododendron×duclouxii hybrid zones and the mechanisms underlying natural hybridization and possible future evolutionary pathways.Our results show that the origins of each hybrid zone are independent,with variations in hybrid formation,structural characteristics,and patterns of genetic components and morphological trait differentiation.There were no significant differences in morphological traits or genetic variation between the F_(1)and F_(2)generations;however,the range of variation of the F_(2)generation was broader than that of the F_(1)generation.The distribution and ecological characteristics of R.×duclouxii did not significantly differ from those of the two parental species,indicating weak ecological niche preferences between the hybrid and parental taxa.These results imply that the hybrid zones of R.×duclouxii are characterized by considerable variability,with the magnitude of hybridization in each case likely influenced by unique combinations of biological and ecological factors specific to each hybrid zone.We predict that R.×duclouxii hybrid zones will persist and give rise to complex hybrid swarms,each potentially leading to different evolutionary outcomes.
基金funded by the Key-Area Research and Develop-ment Program of Guangdong Province No.2020B010186001)the National Natural Science Foundation of China(Nos.51671128 and U2037601)+1 种基金support from the Na-tional Natural Science Foundation of China(No.52101018)the Shanghai Pujiang Program(No.21PJ1405800).
文摘Magnesium alloys,the lightest metallic materials for structural applications,have met the bottleneck in the applications at 300℃ due to limited creep resistance.The degradation of creep resistance closely depends on the microstructural deterioration,especially the formation of precipitate-free zones(PFZs),but the detailed evolution process remains unclear in this regard.The present study adopted a quasi-in-situ methodology to track the evolution process of the PFZs in Mg-2.5Gd-0.1Zr(at.%)alloy during creep at 300℃ under 60 MPa.In the early creep stage,the widening of PFZs and phase transformation of intragranular precipitates are repressed by the applied stress.In the steady and accelerated creep stages,propagation of dislocations generates misorientation between PFZs and their parent grains,leading to the formation of Type-A PFZs.Meanwhile,vacancy diffusion leads to inverse migration of grain boundaries,and produces PFZs with serrated grain boundaries between split rows of grain boundary particles,causing the formation of Type-B PFZs.Secondary intergranular cracks tend to develop in Type-B PFZs in the accelerated creep stage,but the strain accumulation in Type-A PFZs is the key contributor to premature creep failure.
基金supported by the Marine S&T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology(Qingdao)(No.2022QNLM050201-3)the National Key R&D Program of China(No.2022YFF0801000)the National Natural Science Foundation of China(Nos.92158206,42003049).
文摘Subduction zones,linking the surface and deep carbon reservoirs,significantly affect the Earth’s long-term climate change and habitability.The subducting slabs undergo decarbonation with increasing pressure and temperature,during which partial carbon mobilizes out of the slab and returns to the surface by arc volcanism or degassing,while the residual carbon continues to descend to greater depths in the mantle.The estimated carbon influx at subduction zones depends strongly on the calculation model,with contributions from sediments ranging from 15 to 60 Mt C/yr,altered ocean basalts from 18 to 61 Mt C/yr,and serpentinized perdotites from 1.3 to 36 Mt C/yr.The carbon influx varies in space and time.Carbon removal from subducting slab occurs through metamorphic reactions,carbonate dissolution,diapirism,hydrocarbon formation and melting.Among these decarbonation mechanisms,diapirism and slab meting play a decisive role in dictating the depth at which surface carbonates can subduct.Specifically,diapirism may restrict sedimentary carbonates at shallow depths(<200 km),while slab melting exhausts all carbonates from the altered ocean crust near transition zones(410–660 km).Consequently,a mechanism enabling surface carbonates to reach the lower mantle,i.e.,ultra-deep carbon cycle,is required to be in accordance with observations by natural samples.
基金supported by the National Natural Science Foundation of China(No.42274137).
文摘Over 90%of Earth’s carbon is stored in the mantle and core.The deep carbon cycle plays a critical role in regulating surface carbon fluxes,global climate,and the habitability of Earth.Carbon mainly residing within the sediments,altered oceanic crust,and mantle peridotite as carbonate minerals and organic carbon is transported to the deep Earth via plate subduction.A series of reactions(e.g.,metamorphism,dissolution,and melting)occurring in the subducting slab drive the carbon removal.Some of the car-bon is recycled to the surface via arc volcanism,while the rest is carried into the deeper Earth.More than two-thirds of the global subduction carbon input comes from sedimen-tary carbon,whose fate during subduction directly affects the flux in the global carbon cycle.Over the past two dec-ades,the sedimentary carbon cycle in subduction zones has been extensively studied by experiments and computational approaches.Here,we provide a comprehensive review of the sources,species,decarbonation reactions,carbon cycle trac-ing,and fluxes of sedimentary carbon in subduction zones,and the role of sedimentary carbon subduction in climate evolution and mantle chemistry.Further research is required for our understanding of deep carbon cycle processes and their role in Earth’s climate.
基金supported by the National Natural Science Foundation of China(Nos.22036001,42342057,and 22236006).
文摘Micro(nano)plastics,as an emerging environmental pollutant,are gradually discovered in hyporheic zones and groundwaterworldwide.Recent studies have focused on the origin and spatial/temporal distribution of micro(nano)plastics in regional groundwater,together with the influence of their properties and effects of environmental factors on their transport.However,the transport of micro(nano)plastics in the whole hyporheic zone-groundwater system and the behavior of co-existing substances still lack a complete theoretical interpretation.To provide systematic theoretical support for that,this review summarizes the current pollution status of micro(nano)plastics in the hyporheic zone-groundwater system,provides a comprehensive introduction of their sources and fate,and classifies the transport mechanisms into mechanical transport,physicochemical transport and biological processes assisted transport fromthe perspectives ofmechanical stress,physicochemical reactions,and bioturbation,respectively.Ultimately,this review proposes to advance the understanding of the multi-dimensional hydrosphere transport of micro(nano)plastics centered on groundwater,themicroorganisms-mediated synergistic transformation and co-transport involving the intertidal circulation.Overall,this review systematically dissects the presence and transport cycles of micro(nano)plastics within the hyporheic zone-groundwater system and proposes prospects for future studies based on the limitations of current studies.
基金Supported by the China National Petroleum Corporation Major Science and Technology Project(2023ZZ19-01,2023ZZ19-07).
文摘Based on the waterflooding development in carbonate reservoirs in the Middle East,this study analyzes the geological characteristics and waterflooding behaviors/patterns of different types of high permeability zones(HPZs),and proposes rational waterflooding strategies and modes.Four types of HPZs,i.e.sedimentation-dominated,sedimentation-diagenesis coupling,biogenic and composite,are identified in the carbonate reservoirs in the Middle East.Based on their distribution patterns,flow mechanisms,and waterflooding behaviors/patterns,five waterflooding modes are established:(1)the mode with stepwise-infilled areal vertical well pattern,for composite HFZs in patchy distribution;(2)the mode with regular row vertical well pattern for TypeⅠchannel“network”HFZs(with dominant water flow pathways at the base),and the mode with irregular differentiated vertical well pattern for TypeⅡchannel“network”HFZs(where multi-stage superimposition leads to“layered flooding”),for sedimentation-diagenesis coupling HFZs;(3)the mode with row horizontal wells through bottom injection and top production,for biogenic HFZs characterized by thin,contiguous distribution and rapid advancing of injected water along a工-shaped path;and(4)the mode with progressive waterflooding through edge water injection via vertical well and oil production via horizontal well,for sedimentation-dominated HFZs characterized by thick,contiguous distribution and flood first in upper anti-rhythmic reservoirs.Development practices demonstrate that the proposed waterflooding modes are efficient in the highly heterogeneous carbonate reservoirs in the Middle East,with balanced employment of reserves in the adjacent reservoirs and enhanced oil recovery.
