Osmotic energy,existing between the seawater and river water,is a renewable energy source,which can be directly converted into electricity by ion-exchange membranes(IEM).In traditional IEMs,the ion transport channels ...Osmotic energy,existing between the seawater and river water,is a renewable energy source,which can be directly converted into electricity by ion-exchange membranes(IEM).In traditional IEMs,the ion transport channels are formed by nanophase separation of hydrophilic ion carriers and hydrophobic segments.It is difficult to realize high-density ion channels with controlled spatial arrangement and length scale of ion carriers.Herein,we construct high-density 1D ion wires as transmission channels.Through molecular design,hydrophilic imidazole groups and hydrophobic alkyl tails were introduced into the repeat units,which self-assembled into 1D ion transporting core and protecting shell along the main chains.The areal density of the ionic wire arrays is up to~10^(12)cm^(-2),which is the highest value.The ionic wires ensure both high ion flux transport and high selectivity,achieving an ultrahigh-power density of 40.5 W m^(-2)at a 500-fold salinity gradient.Besides,the ionic wire array membrane is well recyclable and antibacterial.The ionic wires provide novel concept for next generation of high-performance membranes.展开更多
Corn starch(CS)is a renewable,biodegradable polysaccharide valued for its film-forming ability,yet native CS films exhibit lowmechanical strength,highwater sensitivity,and limited thermal stability.This study improves...Corn starch(CS)is a renewable,biodegradable polysaccharide valued for its film-forming ability,yet native CS films exhibit lowmechanical strength,highwater sensitivity,and limited thermal stability.This study improves CS-based films by blending with poly(vinyl alcohol)(PVA)or glycerol(GLY)and using citric acid(CA)as a green,non-toxic cross-linker.Composite films were prepared by casting CS–PVA or CS-GLY with CA at 0%-0.20%(w/w of starch).The influence of CA on physicochemical,mechanical,optical,thermal,and water barrier properties was evaluated.CA crosslinking markedly enhanced the tensile strength,water resistance,and thermal stability of CS-PVA films while increasing transparency in CS–GLY films.At 0.20%CA,the composite achieved 34.99MPa tensile strength,reducedwater vapor permeability,andminimized water uptake.FTIR confirmed ester bond formation between CAand hydroxyl groups of CS,PVA,and GLY,whereas thermal analysis showed higher decomposition temperatures and lower weight loss in crosslinked films.Increasing CA levels also decreased opacity and improved light transmittance,indicating greater homogeneity and reduced crystallinity.This dual-polymer matrix combined with a natural crosslinking strategy provides a sustainable route to high-performance,biodegradable CS-based packaging materials.展开更多
The present study monitored bacterial succession,physicochemical properties,and volatile organic compounds(VOCs)changes in smoked chicken legs with modified atmosphere packaging(MAP,60% CO_(2) and 40%N_(2))during a 25...The present study monitored bacterial succession,physicochemical properties,and volatile organic compounds(VOCs)changes in smoked chicken legs with modified atmosphere packaging(MAP,60% CO_(2) and 40%N_(2))during a 25-day storage period at 4℃.After 15 days of storage,S erratia proteamaculans and Pseudomonas fragi became the predominant bacteria.Furthermore,physicochemical properties changed significantly,as evidenced by an increase in thiobarbituric acid reactive substances and b*(yellowness)value,and a decrease in hardness.A total of 65 VOCs were identified during storage.Correlation between bacterial succession and quality indicators(including VOCs and physicochemical properties)allowed the identification of 26 core dominant bacteria,including S.proteamaculans,Psychrobacter alimentarius,Pseudomonas putida,and Pseudomonas poae,which were positively related to spoilage VOCs(e.g.,1-octen-3-ol,1-pentanol,and 3-methyl-1-butanol)and could be defined as specific spoilage organisms(SSOs).The results of this study provide a systematic approach to predict SSOs in smoked chicken legs during storage,which can also provide a basis for product safety.展开更多
Packaging materials are indispensable in modern industries but also significantly contribute to environmental degradation,resource consumption,and waste generation.This systematic review critically assesses the integr...Packaging materials are indispensable in modern industries but also significantly contribute to environmental degradation,resource consumption,and waste generation.This systematic review critically assesses the integration of artificial intelligence(AI),life cycle sustainability assessment(LCSA)following ISO 14040 standards,and circularity mapping to overcome sustainability barriers in packaging.The study identifies environmental,economic,and social hotspots across the life cycle stages of packaging materials by examining real-worldcase studies such as Coca-Cola’s adoption of recycled PET bottles andUnilever’s commitment to 100% recyclable plastic.AI technologies highlight transformative tools for optimising resource allocation,enhancing waste management,and supporting predictive maintenance in packaging systems.To maximise their impact,circular economy(CE)strategies,including material substitution,reusable packaging,and recycling,are discussed with AI-driven approaches.Policy frameworks like mandatory life cycle reporting and AI-focused capacity-building initiatives drive systemic change.The packaging industry achieves significant sustainability improvements by combining LCSA,CE principles,and AI while fostering economic benefits and social equity.This paper provides a comprehensive foundation for future research and practical applications to transform the packaging sector into a more sustainable and circular system.This review is the first to integrate LCSA,circular economy mapping,and AI applications in sustainable packaging.It highlights practical strategies and identifies research gaps to guide academia,industry,and policymakers toward scalable and intelligent sustainability solutions.Moreover,the review bridges methodological rigour with practical implementation by aligning digital intelligence with material sustainability frameworks,thus forming a multidisciplinary blueprint for a circular future in packaging.展开更多
With the growing demands for food safety,quality,and environmental protection,active food packaging is playing an increasingly vital role in the food industry.Traditional food packaging primarily protects products and...With the growing demands for food safety,quality,and environmental protection,active food packaging is playing an increasingly vital role in the food industry.Traditional food packaging primarily protects products and facilitates transportation.Active food packaging,however,not only fulfills these fundamental functions but also actively interacts with the food or its environment to extend shelf life and enhance food safety.From current research advancements and market applications,active food packaging demonstrates the following prominent development trends.展开更多
The extensive use of polymeric materials in single-use packaging has driven the need to develop biodegradable alternatives.This study investigates the incorporation of graphene oxide(GO)and Moringa oleifera seed oil(M...The extensive use of polymeric materials in single-use packaging has driven the need to develop biodegradable alternatives.This study investigates the incorporation of graphene oxide(GO)and Moringa oleifera seed oil(MOSO)into a gelatin matrix to create polymer films and evaluate their potential as active packaging materials.The properties of these films were evaluated using structural,thermal,mechanical,optical,and physicochemical methods to determine their suitability for food packaging applications.The results showed that GO and MOSO were homogeneously dispersed in the gelatin matrix,forming colloidal particles(around 5μm in diameter).The addition of GO increased opacity by approximately 20 times the base value while MOSO affected light transmittance without impacting opacity.Mechanical properties were affected differently,GO acted as a crosslinking agent reducing elongation and increasing tensile strength at break,on the other hand MOSO acted as a plasticizer,making films more plastic increasing elongation a 30%.These effects counteracted each other,and similar behavior was recorded in differential scanning calorimetry.The films exhibited an improved water vapor resistance,which is crucial for food packaging.These findings indicate that the incorporation of GO and MOSO into a gelatin matrix may produce biodegradable polymer films with enhanced properties,suitable for active packaging in the food industry.展开更多
With over 141 million tons of packaging waste generated globally each year and limited recycling efficiency,packaging pollution has become a pressing environmental issue,driving increased scholarly interest in green p...With over 141 million tons of packaging waste generated globally each year and limited recycling efficiency,packaging pollution has become a pressing environmental issue,driving increased scholarly interest in green packaging.However,existing studies have primarily focused on individual domains,lacking a systematic and comprehensive review,which restricts interdisciplinary integration and obscures overarching trends and gaps.To address this,we conducted a bibliometric analysis of green packaging research using CiteSpace and VOSviewer,drawing on peer-reviewed English-language articles published between 2000 and 2023 in the Web of Science Core Collection.The analysis examined collaboration networks,co-citation patterns,and keyword co-occurrence trends.Results reveal significant growth in publications since 2018,with research spanning environmental science,food technology,and business,alongside increasing interdisciplinary integration.Collaboration networks are particularly strong within China and Malaysia,though international collaboration remains limited,while co-citation analysis highlights high-impact work on material performance,consumer behavior,and supply chain strategies,with life cycle assessment emerging as the most widely applied analytical tool.This study synthesizes the current knowledge framework,identifies key trends and challenges,and outlines future research directions-including consumer payment behavior,corporate sustainability strategies,and the development of innovative packaging materials-providing strategic guidance for advancing green packaging research.展开更多
As electronic devices continue to evolve toward higher power densities,faster speeds,and smaller form factors,the demand for high-performance electronic packaging materials has become increasingly critical.These mater...As electronic devices continue to evolve toward higher power densities,faster speeds,and smaller form factors,the demand for high-performance electronic packaging materials has become increasingly critical.These materials serve as the physical and functional interface between semiconductor components and their operating environment,impacting the overall reliability,thermal management,mechanical protection,and electrical performance of modern electronic systems.This study investigates the development,formulation,and performance evaluation of advanced packaging materials,focusing on polymer-based composites,metal and ceramic matrix systems,and nanomaterial-enhanced formulations.A comprehensive analysis of key performance metrics-including thermal conductivity,electrical insulation,mechanical robustness,and environmental resistance-is presented,alongside strategies for material optimization through interface engineering and processing innovations.Furthermore,the study explores cutting-edge integration technologies such as 3D packaging compatibility,low-temperature co-firing,and high-density interconnects.The findings provide critical insights into the structure-property-processing relationships that define the effectiveness of next-generation packaging materials and offer a roadmap for material selection and system integration in high-reliability electronic applications.展开更多
Metal-support interactions and hydrogen spillover effects in heterogeneous catalysts play a crucial role in aromatic hydrogenation reactions;however,these effects are limited by the metal dispersion on the catalyst an...Metal-support interactions and hydrogen spillover effects in heterogeneous catalysts play a crucial role in aromatic hydrogenation reactions;however,these effects are limited by the metal dispersion on the catalyst and the number of acceptable H*receptors.This study prepares highly dispersed Ni nanoparticles(NPs)catalysts on a Beta substrate via precursor structure topology transformation.In contrast to traditional support materials,the coordination and electronic structure changes between the Ni NPs and the support were achieved,further optimizing the active interface sites and enhancing hydrogen activation and hydrogenation performance.Additionally,the-OH groups at the strong acid sites in zeolite effectively intensified the hydrogen spillover effect as receptors for H^(*)migration and anchoring,accelerating the hydrogenation rate of aromatic rings.Under solvent-free conditions,this catalyst was used for the hydrogenation reaction of aromatic-rich oils,directly producing a C_(8)-C_(14)branched cycloalkanes mixture with an aromatic conversion rate of>99%.The cycloalkanes mixture produced by this method features high density(0.92 g/mL)and a low freezing point(<-60℃),making it suitable for use as high-density aviation fuel or as an additive to enhance the volumetric heat value of conventional aviation fuels in practical applications.展开更多
In rotationally extruded fittings,high-density polyethylene(HDPE)pipes prepared using conventional processing methods often suffer from poor pressure resistance and low toughness.This study introduces an innovative ro...In rotationally extruded fittings,high-density polyethylene(HDPE)pipes prepared using conventional processing methods often suffer from poor pressure resistance and low toughness.This study introduces an innovative rotary shear system(RSS)to address these deficiencies through controlled mandrel rotation and cooling rates.We successfully prepared self-reinforced HDPE pipes with a three-layer structure combining spherical and shish-kebab crystals.Rotational processing aligned the molecular chains in the ring direction and formed shish-kebab crystals.As a result,the annular tensile strength of the rotationally processed three-layer shish-kebab structure(TSK)pipe increased from 26.7 MPa to 76.3 MPa,an enhancement of 185.8%.Notably,while maintaining excellent tensile strength(73.4 MPa),the elongation at break of the spherulite shishkebab spherulite(SKS)tubes was improved to 50.1%,as compared to 33.8%in the case of shish-kebab spherulite shish-kebab(KSK)tubes.This improvement can be attributed to the changes in the micro-morphology and polymer structure within the SKS tubes,specifically due to the formation of small-sized shish-kebab crystals and the low degrees of interlocking.In addition,2D-SAXS analysis revealed that KSK tubes have higher tensile strength due to smaller crystal sizes and larger shish dimensions,forming dense interlocking structures.In contrast,the SKS and TSK tubes had thicker amorphous regions and smaller shish sizes,resulting in reduced interlocking and mechanical performance.展开更多
Petrochemical plastics are widely used for food protection and preservation;however,they exhibit poor biodegradability,resisting natural degradation through physical,chemical,or enzymatic processes.As a sustainable al...Petrochemical plastics are widely used for food protection and preservation;however,they exhibit poor biodegradability,resisting natural degradation through physical,chemical,or enzymatic processes.As a sustainable alternative to conventional plastic packaging,edible films offer effective barriers against moisture,gases,and microbial contamination while being biodegradable,biocompatible,and environmentally friendly.In this study,novel active food packaging materials(in film form)were developed by incorporating starch,carrageenan,nanocellulose(NC),Aloe vera,and hibiscus flower extract.The effects of varying the matrix composition(26.5–73.5 wt.%starch/carrageenan),NC concentration(2.77-17.07 wt.%),and particle type(fibers or crystals)on the film structure and characteristics were analyzed using various methods.Scanning electron microscopy demonstrated good homogeneity and effective dispersion of NC within the blendmatrix.An increased carrageenan content in the filmimproved wettability,moisture absorption,solubility,and water vapor permeability.The mechanical properties of the films were enhanced by NC incorporation and higher carrageenan content.The developed films also exhibited effective UV radiation barriers and biodegradability.Films with low carrageenan content(less than 33.3%)and high NC content(7%,10% crystals or 10%,15% fibers)exhibited optimal properties,including enhanced water resistance,hydrophobicity,and mechanical strength,along with reduced water vapor permeability.However,the high water solubility and moisture absorption(above 55% and 14%,respectively)indicated their unsuitability as packaging materials for food products with wet surfaces and high humidity.The results suggest that these films are well suited for use as edible food packaging for fruits and vegetables.展开更多
Evaluation of backfilling effectiveness plays a crucial role in the geological environment management and restoration of abandoned open-pit quarries,providing a scientific basis for subsequent greening efforts.Backfil...Evaluation of backfilling effectiveness plays a crucial role in the geological environment management and restoration of abandoned open-pit quarries,providing a scientific basis for subsequent greening efforts.Backfill soil,predominantly composed of silty clay,demonstrates high water retention capacity and elevated moisture content,leading to a pronounced resistivity contrast with the bedrock exposed by quarrying activities.To investigate the distribution of backfill soil subsurface and assess backfilling effectiveness in the study area,this study conducted a comprehensive geophysical investigation utilizing the high-density electrical resistivity tomography(ERT).A total of 19 ERT survey lines were deployed across three distinct areas in Liuyao Village,Huaibei City,Anhui Province,China.The inversion results,derived from both two-dimensional(2D)and three-dimensional(3D),reveal distinct electrical properties of the subsurface materials:the backfill soil layer shows low resistivity features,the fill stone layer exhibits medium to high resistivity,and the bedrock shows the highest resistivity.The 2D inversion results,from the data measured using the Wenner array effectively capture the spatial distribution and structural features of the backfill soil layer.The findings indicate a gradual east-west thinning of the clay layer within the quarry.Furthermore,the northern pit area exhibits a uniform distribution of backfill soil layer,indicative of effective backfilling operations.In contrast,the southern pit area lacks a well-defined clay layer,suggesting suboptimal backfilling effectiveness.展开更多
Nano-twinned copper(nt-Cu),with a preferred orientation,is highly promising as interconnect materials in high-density advanced packaging due to its considerable mechanical strength,excellent electrical conductivity,an...Nano-twinned copper(nt-Cu),with a preferred orientation,is highly promising as interconnect materials in high-density advanced packaging due to its considerable mechanical strength,excellent electrical conductivity,and resistance to thermal migration.However,its application is impeded by sulfur-containing byproducts from the electroplating process,exacerbating the formation of Kirkendall voids within solder joints during thermal aging.Herein,through the incorporation of Zinc(Zn)into the nt-Cu layer,we develop a nt-Cu/Zn composite structure.Our findings provide the first definitive confirmation of the mechanism by which sulfur atoms migrate to the Cu_(3)Sn/nt-Cu interface through interstitial diffusion,thereby reducing the activation energy for vacancy formation.We further demonstrate that Zn effectively an-choring sulfur atoms,forming ZnS within the nt-Cu layer during heat treatment,which increases the vacancy formation energy and inhibits the development of Kirkendall voids.Remarkably,no Kirkendall voids are observed in the modified interconnects even after prolonged aging at 150℃ for 1000 h.The nt-Cu/Zn composite metallization layers significantly decrease the growth rate of interfacial intermetallic compounds by 33.6% and enhance the shear strength of solder interconnections to 228.9%.This research underscores the potential of nt-Cu in advanced electronic packaging,offering new pathways for improving the power density and reliability of electronic devices.展开更多
The global demand for renewable and sustainable non-petroleum-based resources is rapidly increasing.Lignocellulosic biomass is a valuable resource with broad potential for nanocellulose(NC)production.However,limited s...The global demand for renewable and sustainable non-petroleum-based resources is rapidly increasing.Lignocellulosic biomass is a valuable resource with broad potential for nanocellulose(NC)production.However,limited studies are available regarding the potential toxicological impact of NC.We provide an overview of the nanosafety implications associated mainly with nanofibrillated cellulose(CNF)and identify knowledge gaps.For this purpose,we present an analysis of the studies published from 2014 to 2025 in which the authors mention aspects related to toxicity in the context of packaging.We also analyze the main methods used for toxicity evaluations and the main studies about toxicity evaluation using different biomarkers for a broad interpretation.This comprehensive biblio-graphic review highlights the critical need for further research to elucidate the mechanisms fully underlining NC toxicity,mainly due to its nanofibrillar structure.We focus on the cellular responses across different evaluated cell types through in vitro evaluation,always within the context of the dose used,the type of material or its source,and the type of biomarkers used in the assessments.The importance of addressing safety considerations and key knowledge gaps for the responsible use of CNF derived fromlignocellulosic biomass and its bionanocomposites in food packaging is highlighted.展开更多
High-density interconnect(HDI)soft electronics that can integrate multiple individual functions into one miniaturized monolithic system is promising for applications related to smart healthcare,soft robotics,and human...High-density interconnect(HDI)soft electronics that can integrate multiple individual functions into one miniaturized monolithic system is promising for applications related to smart healthcare,soft robotics,and human-machine interactions.However,despite the recent advances,the development of three-dimensional(3D)soft electronics with both high resolution and high integration is still challenging because of the lack of efficient manufacturing methods to guarantee interlayer alignment of the high-density vias and reliable interlayer electrical conductivity.Here,an advanced 3D laser printing pathway,based on femtosecond laser direct writing(FLDW),is demonstrated for preparing liquid metal(LM)-based any layer HDI soft electronics.FLDW technology,with the characteristics of high spatial resolution and high precision,allows the maskless fabrication of high-resolution embedded LM microchannels and high-density vertical interconnect accesses for 3D integrated circuits.High-aspect-ratio blind/through LM microstructures are formed inside the elastomer due to the supermetalphobicity induced during laser ablation.The LM-based HDI circuit featuring high resolution(~1.5μm)and high integration(10-layer electrical interconnection)is achieved for customized soft electronics,including various customized multilayer passive electric components,soft multilayer circuit,and cross-scale multimode sensors.The 3D laser printing method provides a versatile approach for developing chip-level soft electronics.展开更多
Cu nanoparticles exhibit excellent properties as high-temperature-resistant,conductive,heat-dissipating,and connecting materials.However,their susceptibility to oxidation poses a major challenge to the production of h...Cu nanoparticles exhibit excellent properties as high-temperature-resistant,conductive,heat-dissipating,and connecting materials.However,their susceptibility to oxidation poses a major challenge to the production of high-quality sintered bodies in the air,severely limiting their widespread adoption in power electronics packaging.This study presents a novel approach to the synthesis of Cu nanoparticles capped with oleylamine ligands.By employing a simple solvent-cleaning process,effective control of the density of oleylamine ligands on particle surfaces was achieved,resulting in high-performance Cu nanoparticles with both oxidation resistance and air-sintering susceptibility.Moreover,through our research,the solvent-cleaning mechanism was clarified,a model for the oleylamine ligand decomposition was developed,the air-sintering behavior of Cu nanoparticles was analyzed,and the impacts of both the sintered bodies and interfaces on the sintering performance were explained.Additionally,Cu nanoparticles subjected to 5 cleaning rounds followed by sintering at 280℃and 5 MPa in air were confirmed to be able to produce the highest shear strength(49.2±3.51 MPa)and lowest resistivity(6.15±0.32μΩ·cm).Based on these results,flexible capacitive pressure sensors with Cu sintered electrodes were fabricated and demonstrated a stable pressure-capacitance response over the temperature range of 25-250℃.These findings underscore the impressive robustness and durability of sintered structures and the potential for high-temperature applications of oleylamine-capped Cu nanoparticles.Our study provides reliable application demonstrations for the low-cost manufacture of high-performance power electronics packaging structures that can operate in high-current-density,high-heat-flow-density,high-temperature,and high-stress environments.展开更多
Based on the concept of sustainable design,we are committed to seeking innovative solutions and designinga complete express packaging recycling machine.The device consists of a vibration device,a compression device,a ...Based on the concept of sustainable design,we are committed to seeking innovative solutions and designinga complete express packaging recycling machine.The device consists of a vibration device,a compression device,a winding device and an electronic control system to promote the recycling of resources and environmental protection.This device can further improve the recycling efficiency and feasibility.It provides new ideas and solutions for the express industry and promotes the development of sustainable design in the field of express packaging recycling and reuse devices.展开更多
The food industry prioritizes food safety throughout the entire production process.This involves closely monitoring and evaluating all potential sources of biological or chemical contamination,starting from entering r...The food industry prioritizes food safety throughout the entire production process.This involves closely monitoring and evaluating all potential sources of biological or chemical contamination,starting from entering raw materials into the production chain and continuing to the final product.Biofilms on food surfaces or containers can harbor dangerous pathogens,such as Listeria monocytogenes.Therefore,it is essential to continuously manage microbial contamination on food contact surfaces to prevent foodborne infections.Recently,there has been increasing interest in using nanomaterials as surface coatings with antimicrobial properties in the food industry,especially since traditional disinfectants or antibiotics may contribute to developing resistance.However,the use of antibiofilm materials for long-term food storage remains underexplored,and there is a notable lack of focused reviews on nanomaterialbased antibiofilm coatings specifically for long-term food preservation.This review aims to consolidate recently reported nanoparticle-based antibiofilm food packaging materials.We discuss the effectiveness of various metal and metal oxide nanoparticles and biopolymer nanocomposites in combating biofilms.Additionally,we highlight the growing importance of biodegradable nanocomposite materials for antibiofilm food packaging.Furthermore,we explore the mechanisms of action,processing methods,and safety aspects of these nanomaterials being developed for food packaging applications.展开更多
Dislocation strengthening,as one of the methods to simultaneously enhance the room temperature strength and ductility of alloys,does not achieve the desired strengthening and plasticity effect during elevated-temperat...Dislocation strengthening,as one of the methods to simultaneously enhance the room temperature strength and ductility of alloys,does not achieve the desired strengthening and plasticity effect during elevated-temperature deformation.Here,we report a novel strategy to boost the dislocation multiplication and accumulation during deformation at elevated temperatures through dynamic strain aging(DSA).With the introduction of the rare-earth element Ho in Mg-Y-Zn alloy,Ho atoms diffuse toward dislocations during deformation at elevated temperatures,provoking the DSA effect,which increases the dislocation density significantly via the interactions of mobile dislocations and Ho atoms.The resulting alloy achieves a great enhancement of dislocation hardening and obtains the dual benefits of high strength and good ductility simultaneously at high homologous temperatures.The present work provides an effective strategy to enhancing the strength and ductility for elevated-temperature materials.展开更多
Growing environmental concerns and the need for sustainable alternatives to synthetic materials have led to increased interest in bio-based composites.This study investigates the development and characterization of su...Growing environmental concerns and the need for sustainable alternatives to synthetic materials have led to increased interest in bio-based composites.This study investigates the development and characterization of sustainable egg packaging waste(EPW)biocomposites derived from recycled wood fibers and fungal mycelium filaments as a natural binder.Three formulations were prepared using EPW as the primary substrate,with and without the addition of hemp shives and sawdust as co-substrates.The composites were evaluated for granulometry,density,mechanical strength,hygroscopic behavior,thermal conductivity,and fire performance using cone calorimetry.Biocomposites,composed exclusively of egg packaging waste,exhibited favorable fire resistance,lower total heat release(THR)and total smoke release(TSR),extended time to ignition(TTI),reduced hygroscopicity,and higher flexural strength.Biocomposites,containing hemp shives,demonstrated improved compressive strength and thermal insulation but showed weaker fire resistance.Biocomposites,incorporating sawdust,showed intermediate properties with the longest flameout time(TTF)and highest heat release values.Overall,the results demonstrate that EPW-based biocomposites can be tailored through substrate composition to achieve desirable combinations of mechanical,thermal,and fire-retardant properties,highlighting their potential as sustainable alternatives to conventional syntheticmaterials in building and packaging applications.展开更多
基金financially supported by the Key R&D Program of Shandong Province(2022SFGC0801)the National Natural Science Foundation of China(No.22005162 and 22175009)the Natural Science Foundation of Shandong Province(No.ZR2020QE093)。
文摘Osmotic energy,existing between the seawater and river water,is a renewable energy source,which can be directly converted into electricity by ion-exchange membranes(IEM).In traditional IEMs,the ion transport channels are formed by nanophase separation of hydrophilic ion carriers and hydrophobic segments.It is difficult to realize high-density ion channels with controlled spatial arrangement and length scale of ion carriers.Herein,we construct high-density 1D ion wires as transmission channels.Through molecular design,hydrophilic imidazole groups and hydrophobic alkyl tails were introduced into the repeat units,which self-assembled into 1D ion transporting core and protecting shell along the main chains.The areal density of the ionic wire arrays is up to~10^(12)cm^(-2),which is the highest value.The ionic wires ensure both high ion flux transport and high selectivity,achieving an ultrahigh-power density of 40.5 W m^(-2)at a 500-fold salinity gradient.Besides,the ionic wire array membrane is well recyclable and antibacterial.The ionic wires provide novel concept for next generation of high-performance membranes.
基金supported through RIIM Competition funding from the Indonesia Endowment Fund for Education Agency,Ministry of Finance of the Republic of Indonesia and National Research and Innovation Agency of Indonesia according to the contract number:61/IV/KS/5/2023 and 2131/UN6.3.1/PT.00/2023.
文摘Corn starch(CS)is a renewable,biodegradable polysaccharide valued for its film-forming ability,yet native CS films exhibit lowmechanical strength,highwater sensitivity,and limited thermal stability.This study improves CS-based films by blending with poly(vinyl alcohol)(PVA)or glycerol(GLY)and using citric acid(CA)as a green,non-toxic cross-linker.Composite films were prepared by casting CS–PVA or CS-GLY with CA at 0%-0.20%(w/w of starch).The influence of CA on physicochemical,mechanical,optical,thermal,and water barrier properties was evaluated.CA crosslinking markedly enhanced the tensile strength,water resistance,and thermal stability of CS-PVA films while increasing transparency in CS–GLY films.At 0.20%CA,the composite achieved 34.99MPa tensile strength,reducedwater vapor permeability,andminimized water uptake.FTIR confirmed ester bond formation between CAand hydroxyl groups of CS,PVA,and GLY,whereas thermal analysis showed higher decomposition temperatures and lower weight loss in crosslinked films.Increasing CA levels also decreased opacity and improved light transmittance,indicating greater homogeneity and reduced crystallinity.This dual-polymer matrix combined with a natural crosslinking strategy provides a sustainable route to high-performance,biodegradable CS-based packaging materials.
基金funded by the National Natural Science Foundation of China(U22A20547)the Major Science and Technology Projects of Heilongjiang Province(2021ZX12B05 and 2020ZX07B02)。
文摘The present study monitored bacterial succession,physicochemical properties,and volatile organic compounds(VOCs)changes in smoked chicken legs with modified atmosphere packaging(MAP,60% CO_(2) and 40%N_(2))during a 25-day storage period at 4℃.After 15 days of storage,S erratia proteamaculans and Pseudomonas fragi became the predominant bacteria.Furthermore,physicochemical properties changed significantly,as evidenced by an increase in thiobarbituric acid reactive substances and b*(yellowness)value,and a decrease in hardness.A total of 65 VOCs were identified during storage.Correlation between bacterial succession and quality indicators(including VOCs and physicochemical properties)allowed the identification of 26 core dominant bacteria,including S.proteamaculans,Psychrobacter alimentarius,Pseudomonas putida,and Pseudomonas poae,which were positively related to spoilage VOCs(e.g.,1-octen-3-ol,1-pentanol,and 3-methyl-1-butanol)and could be defined as specific spoilage organisms(SSOs).The results of this study provide a systematic approach to predict SSOs in smoked chicken legs during storage,which can also provide a basis for product safety.
文摘Packaging materials are indispensable in modern industries but also significantly contribute to environmental degradation,resource consumption,and waste generation.This systematic review critically assesses the integration of artificial intelligence(AI),life cycle sustainability assessment(LCSA)following ISO 14040 standards,and circularity mapping to overcome sustainability barriers in packaging.The study identifies environmental,economic,and social hotspots across the life cycle stages of packaging materials by examining real-worldcase studies such as Coca-Cola’s adoption of recycled PET bottles andUnilever’s commitment to 100% recyclable plastic.AI technologies highlight transformative tools for optimising resource allocation,enhancing waste management,and supporting predictive maintenance in packaging systems.To maximise their impact,circular economy(CE)strategies,including material substitution,reusable packaging,and recycling,are discussed with AI-driven approaches.Policy frameworks like mandatory life cycle reporting and AI-focused capacity-building initiatives drive systemic change.The packaging industry achieves significant sustainability improvements by combining LCSA,CE principles,and AI while fostering economic benefits and social equity.This paper provides a comprehensive foundation for future research and practical applications to transform the packaging sector into a more sustainable and circular system.This review is the first to integrate LCSA,circular economy mapping,and AI applications in sustainable packaging.It highlights practical strategies and identifies research gaps to guide academia,industry,and policymakers toward scalable and intelligent sustainability solutions.Moreover,the review bridges methodological rigour with practical implementation by aligning digital intelligence with material sustainability frameworks,thus forming a multidisciplinary blueprint for a circular future in packaging.
文摘With the growing demands for food safety,quality,and environmental protection,active food packaging is playing an increasingly vital role in the food industry.Traditional food packaging primarily protects products and facilitates transportation.Active food packaging,however,not only fulfills these fundamental functions but also actively interacts with the food or its environment to extend shelf life and enhance food safety.From current research advancements and market applications,active food packaging demonstrates the following prominent development trends.
基金the University of Cartagena for funding through the Strengthening Project Acta 048-2023.
文摘The extensive use of polymeric materials in single-use packaging has driven the need to develop biodegradable alternatives.This study investigates the incorporation of graphene oxide(GO)and Moringa oleifera seed oil(MOSO)into a gelatin matrix to create polymer films and evaluate their potential as active packaging materials.The properties of these films were evaluated using structural,thermal,mechanical,optical,and physicochemical methods to determine their suitability for food packaging applications.The results showed that GO and MOSO were homogeneously dispersed in the gelatin matrix,forming colloidal particles(around 5μm in diameter).The addition of GO increased opacity by approximately 20 times the base value while MOSO affected light transmittance without impacting opacity.Mechanical properties were affected differently,GO acted as a crosslinking agent reducing elongation and increasing tensile strength at break,on the other hand MOSO acted as a plasticizer,making films more plastic increasing elongation a 30%.These effects counteracted each other,and similar behavior was recorded in differential scanning calorimetry.The films exhibited an improved water vapor resistance,which is crucial for food packaging.These findings indicate that the incorporation of GO and MOSO into a gelatin matrix may produce biodegradable polymer films with enhanced properties,suitable for active packaging in the food industry.
文摘With over 141 million tons of packaging waste generated globally each year and limited recycling efficiency,packaging pollution has become a pressing environmental issue,driving increased scholarly interest in green packaging.However,existing studies have primarily focused on individual domains,lacking a systematic and comprehensive review,which restricts interdisciplinary integration and obscures overarching trends and gaps.To address this,we conducted a bibliometric analysis of green packaging research using CiteSpace and VOSviewer,drawing on peer-reviewed English-language articles published between 2000 and 2023 in the Web of Science Core Collection.The analysis examined collaboration networks,co-citation patterns,and keyword co-occurrence trends.Results reveal significant growth in publications since 2018,with research spanning environmental science,food technology,and business,alongside increasing interdisciplinary integration.Collaboration networks are particularly strong within China and Malaysia,though international collaboration remains limited,while co-citation analysis highlights high-impact work on material performance,consumer behavior,and supply chain strategies,with life cycle assessment emerging as the most widely applied analytical tool.This study synthesizes the current knowledge framework,identifies key trends and challenges,and outlines future research directions-including consumer payment behavior,corporate sustainability strategies,and the development of innovative packaging materials-providing strategic guidance for advancing green packaging research.
文摘As electronic devices continue to evolve toward higher power densities,faster speeds,and smaller form factors,the demand for high-performance electronic packaging materials has become increasingly critical.These materials serve as the physical and functional interface between semiconductor components and their operating environment,impacting the overall reliability,thermal management,mechanical protection,and electrical performance of modern electronic systems.This study investigates the development,formulation,and performance evaluation of advanced packaging materials,focusing on polymer-based composites,metal and ceramic matrix systems,and nanomaterial-enhanced formulations.A comprehensive analysis of key performance metrics-including thermal conductivity,electrical insulation,mechanical robustness,and environmental resistance-is presented,alongside strategies for material optimization through interface engineering and processing innovations.Furthermore,the study explores cutting-edge integration technologies such as 3D packaging compatibility,low-temperature co-firing,and high-density interconnects.The findings provide critical insights into the structure-property-processing relationships that define the effectiveness of next-generation packaging materials and offer a roadmap for material selection and system integration in high-reliability electronic applications.
基金financially supported by the National Natural Science Foundation of China(Grant 22278439,21776313)the Shandong Province Higher Education Youth Innovation Technology Support Program(Grant 2022KJ074)。
文摘Metal-support interactions and hydrogen spillover effects in heterogeneous catalysts play a crucial role in aromatic hydrogenation reactions;however,these effects are limited by the metal dispersion on the catalyst and the number of acceptable H*receptors.This study prepares highly dispersed Ni nanoparticles(NPs)catalysts on a Beta substrate via precursor structure topology transformation.In contrast to traditional support materials,the coordination and electronic structure changes between the Ni NPs and the support were achieved,further optimizing the active interface sites and enhancing hydrogen activation and hydrogenation performance.Additionally,the-OH groups at the strong acid sites in zeolite effectively intensified the hydrogen spillover effect as receptors for H^(*)migration and anchoring,accelerating the hydrogenation rate of aromatic rings.Under solvent-free conditions,this catalyst was used for the hydrogenation reaction of aromatic-rich oils,directly producing a C_(8)-C_(14)branched cycloalkanes mixture with an aromatic conversion rate of>99%.The cycloalkanes mixture produced by this method features high density(0.92 g/mL)and a low freezing point(<-60℃),making it suitable for use as high-density aviation fuel or as an additive to enhance the volumetric heat value of conventional aviation fuels in practical applications.
基金supported by the National Natural Science Foundation of China(Nos.52373045 and 52033005).
文摘In rotationally extruded fittings,high-density polyethylene(HDPE)pipes prepared using conventional processing methods often suffer from poor pressure resistance and low toughness.This study introduces an innovative rotary shear system(RSS)to address these deficiencies through controlled mandrel rotation and cooling rates.We successfully prepared self-reinforced HDPE pipes with a three-layer structure combining spherical and shish-kebab crystals.Rotational processing aligned the molecular chains in the ring direction and formed shish-kebab crystals.As a result,the annular tensile strength of the rotationally processed three-layer shish-kebab structure(TSK)pipe increased from 26.7 MPa to 76.3 MPa,an enhancement of 185.8%.Notably,while maintaining excellent tensile strength(73.4 MPa),the elongation at break of the spherulite shishkebab spherulite(SKS)tubes was improved to 50.1%,as compared to 33.8%in the case of shish-kebab spherulite shish-kebab(KSK)tubes.This improvement can be attributed to the changes in the micro-morphology and polymer structure within the SKS tubes,specifically due to the formation of small-sized shish-kebab crystals and the low degrees of interlocking.In addition,2D-SAXS analysis revealed that KSK tubes have higher tensile strength due to smaller crystal sizes and larger shish dimensions,forming dense interlocking structures.In contrast,the SKS and TSK tubes had thicker amorphous regions and smaller shish sizes,resulting in reduced interlocking and mechanical performance.
基金funded by the Russian Federation represented by the Ministry of Science and Higher Education,Russia,grant number 075-15-2022-1231 on 18.10.2022National Research Foundation(NRF),South Africa,grant number 150508Brazilian National Council for Scientific and Technological Development(CNPq),Brazil,grant number 440057/2022-1.
文摘Petrochemical plastics are widely used for food protection and preservation;however,they exhibit poor biodegradability,resisting natural degradation through physical,chemical,or enzymatic processes.As a sustainable alternative to conventional plastic packaging,edible films offer effective barriers against moisture,gases,and microbial contamination while being biodegradable,biocompatible,and environmentally friendly.In this study,novel active food packaging materials(in film form)were developed by incorporating starch,carrageenan,nanocellulose(NC),Aloe vera,and hibiscus flower extract.The effects of varying the matrix composition(26.5–73.5 wt.%starch/carrageenan),NC concentration(2.77-17.07 wt.%),and particle type(fibers or crystals)on the film structure and characteristics were analyzed using various methods.Scanning electron microscopy demonstrated good homogeneity and effective dispersion of NC within the blendmatrix.An increased carrageenan content in the filmimproved wettability,moisture absorption,solubility,and water vapor permeability.The mechanical properties of the films were enhanced by NC incorporation and higher carrageenan content.The developed films also exhibited effective UV radiation barriers and biodegradability.Films with low carrageenan content(less than 33.3%)and high NC content(7%,10% crystals or 10%,15% fibers)exhibited optimal properties,including enhanced water resistance,hydrophobicity,and mechanical strength,along with reduced water vapor permeability.However,the high water solubility and moisture absorption(above 55% and 14%,respectively)indicated their unsuitability as packaging materials for food products with wet surfaces and high humidity.The results suggest that these films are well suited for use as edible food packaging for fruits and vegetables.
基金Supported by National Key Research and Development Program of China(No.2023YFC3707901)。
文摘Evaluation of backfilling effectiveness plays a crucial role in the geological environment management and restoration of abandoned open-pit quarries,providing a scientific basis for subsequent greening efforts.Backfill soil,predominantly composed of silty clay,demonstrates high water retention capacity and elevated moisture content,leading to a pronounced resistivity contrast with the bedrock exposed by quarrying activities.To investigate the distribution of backfill soil subsurface and assess backfilling effectiveness in the study area,this study conducted a comprehensive geophysical investigation utilizing the high-density electrical resistivity tomography(ERT).A total of 19 ERT survey lines were deployed across three distinct areas in Liuyao Village,Huaibei City,Anhui Province,China.The inversion results,derived from both two-dimensional(2D)and three-dimensional(3D),reveal distinct electrical properties of the subsurface materials:the backfill soil layer shows low resistivity features,the fill stone layer exhibits medium to high resistivity,and the bedrock shows the highest resistivity.The 2D inversion results,from the data measured using the Wenner array effectively capture the spatial distribution and structural features of the backfill soil layer.The findings indicate a gradual east-west thinning of the clay layer within the quarry.Furthermore,the northern pit area exhibits a uniform distribution of backfill soil layer,indicative of effective backfilling operations.In contrast,the southern pit area lacks a well-defined clay layer,suggesting suboptimal backfilling effectiveness.
基金financially supported by National Natural Science Foundation of China(No.U2241223)Pre-Research Foundation of China(No.909010203-202).
文摘Nano-twinned copper(nt-Cu),with a preferred orientation,is highly promising as interconnect materials in high-density advanced packaging due to its considerable mechanical strength,excellent electrical conductivity,and resistance to thermal migration.However,its application is impeded by sulfur-containing byproducts from the electroplating process,exacerbating the formation of Kirkendall voids within solder joints during thermal aging.Herein,through the incorporation of Zinc(Zn)into the nt-Cu layer,we develop a nt-Cu/Zn composite structure.Our findings provide the first definitive confirmation of the mechanism by which sulfur atoms migrate to the Cu_(3)Sn/nt-Cu interface through interstitial diffusion,thereby reducing the activation energy for vacancy formation.We further demonstrate that Zn effectively an-choring sulfur atoms,forming ZnS within the nt-Cu layer during heat treatment,which increases the vacancy formation energy and inhibits the development of Kirkendall voids.Remarkably,no Kirkendall voids are observed in the modified interconnects even after prolonged aging at 150℃ for 1000 h.The nt-Cu/Zn composite metallization layers significantly decrease the growth rate of interfacial intermetallic compounds by 33.6% and enhance the shear strength of solder interconnections to 228.9%.This research underscores the potential of nt-Cu in advanced electronic packaging,offering new pathways for improving the power density and reliability of electronic devices.
基金funded by General Secretariat of Science and Technology,National University of Misiones(SGCyT-UNaM),grant number:16/Q2384-PI.
文摘The global demand for renewable and sustainable non-petroleum-based resources is rapidly increasing.Lignocellulosic biomass is a valuable resource with broad potential for nanocellulose(NC)production.However,limited studies are available regarding the potential toxicological impact of NC.We provide an overview of the nanosafety implications associated mainly with nanofibrillated cellulose(CNF)and identify knowledge gaps.For this purpose,we present an analysis of the studies published from 2014 to 2025 in which the authors mention aspects related to toxicity in the context of packaging.We also analyze the main methods used for toxicity evaluations and the main studies about toxicity evaluation using different biomarkers for a broad interpretation.This comprehensive biblio-graphic review highlights the critical need for further research to elucidate the mechanisms fully underlining NC toxicity,mainly due to its nanofibrillar structure.We focus on the cellular responses across different evaluated cell types through in vitro evaluation,always within the context of the dose used,the type of material or its source,and the type of biomarkers used in the assessments.The importance of addressing safety considerations and key knowledge gaps for the responsible use of CNF derived fromlignocellulosic biomass and its bionanocomposites in food packaging is highlighted.
基金supported by the National Science Foundation of China under the Grant Nos.12127806 and 62175195the International Joint Research Laboratory for Micro/Nano Manufacturing and Measurement Technologies。
文摘High-density interconnect(HDI)soft electronics that can integrate multiple individual functions into one miniaturized monolithic system is promising for applications related to smart healthcare,soft robotics,and human-machine interactions.However,despite the recent advances,the development of three-dimensional(3D)soft electronics with both high resolution and high integration is still challenging because of the lack of efficient manufacturing methods to guarantee interlayer alignment of the high-density vias and reliable interlayer electrical conductivity.Here,an advanced 3D laser printing pathway,based on femtosecond laser direct writing(FLDW),is demonstrated for preparing liquid metal(LM)-based any layer HDI soft electronics.FLDW technology,with the characteristics of high spatial resolution and high precision,allows the maskless fabrication of high-resolution embedded LM microchannels and high-density vertical interconnect accesses for 3D integrated circuits.High-aspect-ratio blind/through LM microstructures are formed inside the elastomer due to the supermetalphobicity induced during laser ablation.The LM-based HDI circuit featuring high resolution(~1.5μm)and high integration(10-layer electrical interconnection)is achieved for customized soft electronics,including various customized multilayer passive electric components,soft multilayer circuit,and cross-scale multimode sensors.The 3D laser printing method provides a versatile approach for developing chip-level soft electronics.
基金supported by the Natural Science Foundation of Fujian Province(No.2022J01044)the Digital Twin and Intelligent Transportation Maintenance Engineering Research Centre of Genting Applied Technology R&D Platform at Xiamen City University.
文摘Cu nanoparticles exhibit excellent properties as high-temperature-resistant,conductive,heat-dissipating,and connecting materials.However,their susceptibility to oxidation poses a major challenge to the production of high-quality sintered bodies in the air,severely limiting their widespread adoption in power electronics packaging.This study presents a novel approach to the synthesis of Cu nanoparticles capped with oleylamine ligands.By employing a simple solvent-cleaning process,effective control of the density of oleylamine ligands on particle surfaces was achieved,resulting in high-performance Cu nanoparticles with both oxidation resistance and air-sintering susceptibility.Moreover,through our research,the solvent-cleaning mechanism was clarified,a model for the oleylamine ligand decomposition was developed,the air-sintering behavior of Cu nanoparticles was analyzed,and the impacts of both the sintered bodies and interfaces on the sintering performance were explained.Additionally,Cu nanoparticles subjected to 5 cleaning rounds followed by sintering at 280℃and 5 MPa in air were confirmed to be able to produce the highest shear strength(49.2±3.51 MPa)and lowest resistivity(6.15±0.32μΩ·cm).Based on these results,flexible capacitive pressure sensors with Cu sintered electrodes were fabricated and demonstrated a stable pressure-capacitance response over the temperature range of 25-250℃.These findings underscore the impressive robustness and durability of sintered structures and the potential for high-temperature applications of oleylamine-capped Cu nanoparticles.Our study provides reliable application demonstrations for the low-cost manufacture of high-performance power electronics packaging structures that can operate in high-current-density,high-heat-flow-density,high-temperature,and high-stress environments.
基金Yingkou Institute of Technology school level scientificresearch project(Grant:ZDIL202302).
文摘Based on the concept of sustainable design,we are committed to seeking innovative solutions and designinga complete express packaging recycling machine.The device consists of a vibration device,a compression device,a winding device and an electronic control system to promote the recycling of resources and environmental protection.This device can further improve the recycling efficiency and feasibility.It provides new ideas and solutions for the express industry and promotes the development of sustainable design in the field of express packaging recycling and reuse devices.
文摘The food industry prioritizes food safety throughout the entire production process.This involves closely monitoring and evaluating all potential sources of biological or chemical contamination,starting from entering raw materials into the production chain and continuing to the final product.Biofilms on food surfaces or containers can harbor dangerous pathogens,such as Listeria monocytogenes.Therefore,it is essential to continuously manage microbial contamination on food contact surfaces to prevent foodborne infections.Recently,there has been increasing interest in using nanomaterials as surface coatings with antimicrobial properties in the food industry,especially since traditional disinfectants or antibiotics may contribute to developing resistance.However,the use of antibiofilm materials for long-term food storage remains underexplored,and there is a notable lack of focused reviews on nanomaterialbased antibiofilm coatings specifically for long-term food preservation.This review aims to consolidate recently reported nanoparticle-based antibiofilm food packaging materials.We discuss the effectiveness of various metal and metal oxide nanoparticles and biopolymer nanocomposites in combating biofilms.Additionally,we highlight the growing importance of biodegradable nanocomposite materials for antibiofilm food packaging.Furthermore,we explore the mechanisms of action,processing methods,and safety aspects of these nanomaterials being developed for food packaging applications.
基金supported by the National Key Research and Development Project(2023YFA1609100)the NSFC Funding(U2141207,52171111,52001083)+6 种基金Natural Science Foundation of Heilongjiang(YQ2023E026)China Postdoctoral Science foundation(2024M754149)Postdoctoral Fellowship Program of CPSF(GZC20242192)support from the National Science Foundation(DMR-1611180 and 1809640)with the program directors,DrsHKU Seed Fund for Collaborative Research(#2207101618)support by Croucher Senior Research Fellowship and City U Project(Project No.9229019)Shenzhen Science and Technology Program(Project No.JCYJ20220818101203007)。
文摘Dislocation strengthening,as one of the methods to simultaneously enhance the room temperature strength and ductility of alloys,does not achieve the desired strengthening and plasticity effect during elevated-temperature deformation.Here,we report a novel strategy to boost the dislocation multiplication and accumulation during deformation at elevated temperatures through dynamic strain aging(DSA).With the introduction of the rare-earth element Ho in Mg-Y-Zn alloy,Ho atoms diffuse toward dislocations during deformation at elevated temperatures,provoking the DSA effect,which increases the dislocation density significantly via the interactions of mobile dislocations and Ho atoms.The resulting alloy achieves a great enhancement of dislocation hardening and obtains the dual benefits of high strength and good ductility simultaneously at high homologous temperatures.The present work provides an effective strategy to enhancing the strength and ductility for elevated-temperature materials.
基金funded by the Latvian Research Council FLPP project No.lzp-2023/1-0633“Innovative mycelium biocomposites(MB)from plant residual biomass with enhanced properties for sustainable solutions”.
文摘Growing environmental concerns and the need for sustainable alternatives to synthetic materials have led to increased interest in bio-based composites.This study investigates the development and characterization of sustainable egg packaging waste(EPW)biocomposites derived from recycled wood fibers and fungal mycelium filaments as a natural binder.Three formulations were prepared using EPW as the primary substrate,with and without the addition of hemp shives and sawdust as co-substrates.The composites were evaluated for granulometry,density,mechanical strength,hygroscopic behavior,thermal conductivity,and fire performance using cone calorimetry.Biocomposites,composed exclusively of egg packaging waste,exhibited favorable fire resistance,lower total heat release(THR)and total smoke release(TSR),extended time to ignition(TTI),reduced hygroscopicity,and higher flexural strength.Biocomposites,containing hemp shives,demonstrated improved compressive strength and thermal insulation but showed weaker fire resistance.Biocomposites,incorporating sawdust,showed intermediate properties with the longest flameout time(TTF)and highest heat release values.Overall,the results demonstrate that EPW-based biocomposites can be tailored through substrate composition to achieve desirable combinations of mechanical,thermal,and fire-retardant properties,highlighting their potential as sustainable alternatives to conventional syntheticmaterials in building and packaging applications.
