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Crystal structure,thermal analysis,and luminescence properties of six heterocyclic lanthanide complexes
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作者 SONG Zihe ZHAO Jinjin +1 位作者 REN Ning ZHANG Jianjun 《无机化学学报》 北大核心 2026年第1期181-192,共12页
Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'... Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6. 展开更多
关键词 lanthanide complexes fluorescence property crystal structure thermal analysis
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Macroscopic Structural Analysis on a 10 kW Class Lab-Scale Process Heat Exchanger Prototype under a High-Temperature Gas Loop Condition
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作者 Kee-Nam Song Sung-Deok Hong Hong-Yoon Park 《Engineering(科研)》 2013年第1期117-124,共8页
A PHE (Process Heat Exchanger) is a key component in transferring high-temperature heat generated from a VHTR (Very High Temperature Reactor) to a chemical reaction for the massive production of hydrogen. Last year, a... A PHE (Process Heat Exchanger) is a key component in transferring high-temperature heat generated from a VHTR (Very High Temperature Reactor) to a chemical reaction for the massive production of hydrogen. Last year, a 10 kW class lab-scale PHE prototype made of Hastelloy-X was manufactured at the Korea Atomic Energy Research Institute (KAERI), and a performance test of the PHE prototype is currently underway in a small-scale nitrogen gas loop at KAERI. The PHE prototype is composed of two kinds of flow plates: grooves 1.0 mm in diameter machined into the flow plate for the primary coolant, and waved channels bent into the flow plate for the secondary coolant. Inside the 10 kW class lab-scale PHE prototype, twenty flow plates for the primary and secondary coolants are stacked in turn. In this study, to understand the macroscopic structural behavior of the PHE prototype under the steady-state operating condition of the gas loop, high-temperature structural analyses on the 10 kW class lab-scale PHE prototype were performed for two extreme cases: in the event of contacting the flow plates together, and when not contacting them. The analysis results for the extreme cases were also compared. 展开更多
关键词 Process Heat EXCHANGER Very High Temperature Reactor high-temperature structural analysis Nuclear Hydrogen
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Research on structural design and mechanical properties of precision electroplating machinery for automobiles based on finite element analysis
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作者 Wang Jie Jiang Xiaobei 《电镀与精饰》 北大核心 2025年第11期10-21,共12页
Design a precision electroplating mechanical structure for automobiles based on finite element analysis method and analyze its mechanical properties.Taking the automobile steering knuckle as the research object,ABAQUS... Design a precision electroplating mechanical structure for automobiles based on finite element analysis method and analyze its mechanical properties.Taking the automobile steering knuckle as the research object,ABAQUS parametric modeling technology is used to construct its three-dimensional geometric model,and geometric simplification is carried out.Two surface treatment processes,HK-35 zinc nickel alloy electroplating and pure zinc electroplating,were designed,and the influence of different coatings on the mechanical properties of steering knuckles was compared and analyzed through numerical simulation.At the same time,standard specimens were prepared for salt spray corrosion testing and scratch method combined strength testing to verify the numerical simulation results.The results showed that under emergency braking and composite working conditions,the peak Von Mises stress of the zinc nickel alloy coating was 119.85 MPa,which was lower than that of the pure zinc coating and the alkaline electroplated zinc layer.Its equivalent strain value was 652×10^(-6),which was lower than that of the pure zinc coating and the alkaline electroplated zinc layer.Experimental data confirms that zinc nickel alloy coatings exhibit significant advantages in stress distribution uniformity,strain performance,and load-bearing capacity in high stress zones.The salt spray corrosion test further indicates that the coating has superior corrosion resistance and coating substrate interface bonding strength,which can significantly improve the mechanical stability and long-term reliability of automotive precision electroplating mechanical structures. 展开更多
关键词 finite element analysis electroplating machinery structure mechanical properties electroplating process salt spray corrosion bonding strength
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Machine learning based damage state identification:A novel perspective on fragility analysis for nuclear power plants considering structural uncertainties
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作者 Zheng Zhi Wang Yong +1 位作者 Pan Xiaolan Ji Duofa 《Earthquake Engineering and Engineering Vibration》 2025年第1期201-222,共22页
Seismic fragility analysis(SFA)is known as an effective probabilistic-based approach used to evaluate seismic fragility.There are various sources of uncertainties associated with this approach.A nuclear power plant(NP... Seismic fragility analysis(SFA)is known as an effective probabilistic-based approach used to evaluate seismic fragility.There are various sources of uncertainties associated with this approach.A nuclear power plant(NPP)system is an extremely important infrastructure and contains many structural uncertainties due to construction issues or structural deterioration during service.Simulation of structural uncertainties effects is a costly and time-consuming endeavor.A novel approach to SFA for the NPP considering structural uncertainties based on the damage state is proposed and examined.The results suggest that considering the structural uncertainties is essential in assessing the fragility of the NPP structure,and the impact of structural uncertainties tends to increase with the state of damage.Subsequently,machine learning(ML)is found to be superior in high-precision damage state identification of the NPP for reducing the time of nonlinear time-history analysis(NLTHA)and could be applied in the damage state-based SFA.Also,the impact of various sources of uncertainties is investigated through sensitivity analysis.The Sobol and Shapley additive explanations(SHAP)method can be complementary to each other and able to solve the problem of quantifying seismic and structural uncertainties simultaneously and the interaction effect of each parameter. 展开更多
关键词 seismic fragility analysis damage state structural uncertainties machine learning sensitivity analysis
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Dynamic Characteristic Analysis and Structural Optimization of Entire Double-Shaft-Driven Needle Punching Machine for C/C Crucible Preforms
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作者 SUN Zhihong DENG Qicai +4 位作者 QU Zhiyang WANG Zhenxi WANG Bing ZHANG Xi ZHANG Jingzhang 《Journal of Donghua University(English Edition)》 2025年第4期399-408,共10页
Double-shaft-driven needle punching machine is a specialized equipment designed for processing C/C crucible preforms.Its main needle punching module is operated by two sets of reciprocating crank-slider mechanisms.The... Double-shaft-driven needle punching machine is a specialized equipment designed for processing C/C crucible preforms.Its main needle punching module is operated by two sets of reciprocating crank-slider mechanisms.The intense vibration during needle punching not only generates huge noise,but also substantially reduces the quality of the preform.It is imperative to perform a dynamic analysis and optimization of the entire needle punching machine.In this paper,the three-dimensional(3D)model of the entire double-shaft-driven needle punching machine for C/C crucible preforms is established.Based on the modal analysis theory,the modal characteristics of the needle punching machine under various operating conditions are analyzed and its natural frequencies and vibration modes are determined.The harmonic response analysis is then employed to obtain the amplitude of the needle plate at different frequencies,and the structural weak points of the needle punching machine are identified and improved.The feasibility of the optimized scheme is subsequently reevaluated and verified.The results indicate that the first six natural frequencies of the machine increase,and the maximum amplitude of the needle plate decreases by 70.3%.The enhanced dynamic characteristics of the machine significantly improve its performance,enabling more efficient needle punching of C/C crucible preforms. 展开更多
关键词 needle punching machine dynamic characteristic modal analysis harmonic response analysis structural optimization
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Preliminary hydrogeological implications using structural analysis and cave mapping:a case study of the Pachnes Thrust,Central Lefka Ori,Crete
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作者 Daniel Moraetis Aris Leontaritis +12 位作者 Andreas Scharf Charalampos Fassoulas Stylianos Zacharias Arnauld Malard Frank Mattern Asma Alnaqbi Hamdan Hamdan Markos Digenis Christos Pennos Kostas Adamopoulos Xuan Yu Nikolaos Nikolaidis Kosmas Pavlopoulos 《Episodes》 2025年第4期385-401,共17页
This multidisciplinary study integrates structural and cave mapping,3D geological modeling,and Geographical Information System(GIS)analysis to provide constraints of the hydrogeological model for the central Lefka Ori... This multidisciplinary study integrates structural and cave mapping,3D geological modeling,and Geographical Information System(GIS)analysis to provide constraints of the hydrogeological model for the central Lefka Ori Massif.Through 44 km of linear mapping,we discovered the new mid-Miocene Pachnes Thrust(PT)which plays a key role in the central Lefka Ori Massif structural framework. 展开更多
关键词 hydrogeological model structural analysis hydrogeological implications linear mappingwe structural cave mapping d geological modelingand D geological modeling cave mapping geographical information system gis analysis
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Structural Design and Analysis of Lower Limb Exoskeleton Robotics
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作者 Mingshuo ZHANG Yutong LI +2 位作者 Sheng ZHANG Yuanhai DING Chuanqi LI 《Mechanical Engineering Science》 2025年第1期20-25,共6页
With the acceleration of the global aging process and the increase of cardiovascular ancerebrovascular diseases,more and more patients are paralyzed due to accidents,so theexoskeleton robot began to appear in people&#... With the acceleration of the global aging process and the increase of cardiovascular ancerebrovascular diseases,more and more patients are paralyzed due to accidents,so theexoskeleton robot began to appear in people's sight,and the lower limb exoskeleton robot withrehabilitation training is also favored by more and more people.In this paper,the structural designand analysis of the lower limb exoskeleton robot are carried out in view of the patients'expectation ofnormal walking.First,gait analysis and structural design of lower limb exoskeleton robot.Based onthe analysis of the walking gait of normal people,the freedom of the three key joints of the lower limbexoskeleton robot hip joint,knee joint and ankle joint is determined.at the same time,according tothe structuralcharacteristics of each joint,the three key joints are modeled respectively,and theoverall model assembly of the lower limb exoskeleton robot is completed.Secondly,the kinematicsanalysis of the lower limb exoskeleton robot was carried out to obtain the relationship between thelinear displacement,linear speed and acceleration of each joint,so as to ensure the coordination ofthe model with the human lower limb movement.Thirdly,the static analysis of typical gait of hipjoint,knee joint and ankle joint is carried out to verify the safety of the design model under thepremise of ensuring the structural strength requirements.Finally,the parts of the model were 3Dprinted,and the rationality of the design was further verified in the process of assembling the model. 展开更多
关键词 Exoskeleton Robots Mechanical structure Design Finite Element analysis Motion Simulation
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Structural Reliability Analysis Method Based on Kriging and Spherical Cap Area Integral
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作者 ZHANG Jixiang CHEN Zhenzhong +3 位作者 CHEN Ge LI Xiaoke ZHAO Pengcheng PAN Qianghua 《Journal of Donghua University(English Edition)》 2025年第4期409-416,共8页
In the structural reliability analysis,the first-order reliability method(FORM)often yields significant errors when addressing nonlinear problems.Although the second-order reliability method(SORM)can provide higher ac... In the structural reliability analysis,the first-order reliability method(FORM)often yields significant errors when addressing nonlinear problems.Although the second-order reliability method(SORM)can provide higher accuracy,the additional computation of the Hessian matrix leads to lower computational efficiency.Additionally,when the dimensionality of the random variables is high,the approximation formula of SORM can result in larger errors.To address these issues,a structural reliability analysis method based on Kriging and spherical cap area integral is proposed.Firstly,this method integrates FORM with the quasi-Newton algorithm Broyden-Fletcher-Goldfarb-Shanno(BFGS),trains the Kriging model by using sample points from the algorithm’s iteration process,and combines the Kriging model with gradient information to approximate the Hessian matrix.Then,the failure surface is approximated as a rotating paraboloid,utilizing the spherical cap to replace the complex surface.For the n-dimensional case,the hyperspherical cap area expression is combined with the integral method to calculate the failure probability.Finally,the method is validated through three examples,demonstrating improved computational accuracy and efficiency compared to traditional methods. 展开更多
关键词 structural reliability analysis quasi-Newton algorithm Kriging model spherical cap area integral
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Sensitivity Analysis of Structural Dynamic Behavior Based on the Sparse Polynomial Chaos Expansion and Material Point Method
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作者 Wenpeng Li Zhenghe Liu +4 位作者 Yujing Ma Zhuxuan Meng Ji Ma Weisong Liu Vinh Phu Nguyen 《Computer Modeling in Engineering & Sciences》 2025年第2期1515-1543,共29页
This paper presents a framework for constructing surrogate models for sensitivity analysis of structural dynamics behavior.Physical models involving deformation,such as collisions,vibrations,and penetration,are devel-... This paper presents a framework for constructing surrogate models for sensitivity analysis of structural dynamics behavior.Physical models involving deformation,such as collisions,vibrations,and penetration,are devel-oped using the material point method.To reduce the computational cost of Monte Carlo simulations,response surface models are created as surrogate models for the material point system to approximate its dynamic behavior.An adaptive randomized greedy algorithm is employed to construct a sparse polynomial chaos expansion model with a fixed order,effectively balancing the accuracy and computational efficiency of the surrogate model.Based on the sparse polynomial chaos expansion,sensitivity analysis is conducted using the global finite difference and Sobol methods.Several examples of structural dynamics are provided to demonstrate the effectiveness of the proposed method in addressing structural dynamics problems. 展开更多
关键词 structural dynamics DEFORMATION material point method sparse polynomial chaos expansion adaptive randomized greedy algorithm sensitivity analysis
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Finite Element Analysis of the Influence of End Grouting Defects in Grouted Sleeve on the Structural Performance of Precast Reinforced Concrete Columns
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作者 Shuoting Xiao Nikita Igorevich Fomin +1 位作者 Kirill Anatolyevich Khvostunkov Chong Liu 《Computer Modeling in Engineering & Sciences》 2025年第12期2821-2847,共27页
Precast concrete structures have gained popularity due to their advantages.However,the seismic performance of their connection joints remains an area of ongoing research and improvement.Grouted Sleeve Connection(GSC)o... Precast concrete structures have gained popularity due to their advantages.However,the seismic performance of their connection joints remains an area of ongoing research and improvement.Grouted Sleeve Connection(GSC)offers a solution for connecting reinforcements in precast components,but their vulnerability to internal defects,such as construction errors and material variability,can significantly impact performance.This article presents a finite element analysis(FEA)to evaluate the impact of internal grouting defects in GSC on the structural performance of precast reinforced concrete columns.Four finite elementmodels representing GSC with varying degrees of defects were used to investigate the effects on mechanical properties,including bearing capacity,stress-deformation behavior,and stiffness degradation.The study highlights the significant impact of internal grouting defects on the mechanical performance of GSC,with findings indicating a decrease in stiffness,increased plastic deformation,and reduced energy dissipation as the proportion of internal defects rises.The analysis reveals that the internal defects in GSC act as stress concentration points,leading to early crack formation and accelerated damage under cyclic loading.By improving construction quality and reducing the prevalence of grouting defects,the adverse effects on the performance of GSC can be mitigated.Compared to defect-free specimens,those with defects of 30%exhibited a 31.23%reduction in horizontal bearing capacity,highlighting the importance of minimizing defects in practical engineering applications. 展开更多
关键词 Precast concrete structures column grouted sleeve connections(GSC) seismic performance internal defects finite element analysis(FEA) mechanical properties
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Layer Structure Analysis of Low-Carbon Steel Containing Rare Earth by High-Temperature Carburizing of Liquid Cast-Iron
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作者 谌岩 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第S1期130-133,共4页
The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic micr... The layer structure of low-carbon steel containing RE by high-temperature (T>1200 ℃) carburizing of liquid cast-iron was studied and the diffusion activation energy of carbon was calculated by metallographic microscpe, chemical analysis etc. The result shows that the technology of carburizing in liquid cast-iron can expedite caburization distinctly and changes the carburizing layer structure. The carburizing rate is 60~80 times of that of the traditional technology, and there is about 43% decrease in the activation energy compared with gas-carburization. In outer structure layer, cementite is formed simultaneously both on the crystal boundary reticularly and inside the crystal grains stripedly. In inner carburizing layer, there is undissolved blocky ferrite in reticular cementite. Besides, rare earth element can expedite carburization process. 展开更多
关键词 low-carbon steel high-temperature carburizing of liquid cast-iron layer structure rare earths
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Theoretical research on structural damage alarming of long-span bridges using wavelet packet analysis 被引量:5
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作者 丁幼亮 李爱群 缪长青 《Journal of Southeast University(English Edition)》 EI CAS 2005年第4期459-462,共4页
The state equation and observation equation of the structural dynamic systems under various analysis scales are derived based on wavelet packet analysis. The time-frequency properties of structural dynamic response un... The state equation and observation equation of the structural dynamic systems under various analysis scales are derived based on wavelet packet analysis. The time-frequency properties of structural dynamic response under various scales are further formulated. The theoretical analysis results reveal that the wavelet packet energy spectrum (WPES) obtained from wavelet packet decomposition of structural dynamic response will detect the presence of structural damage. The sensitivity analysis of the WPES to structural damage and measurement noise is also performed. The transfer properties of the structural system matrix and the observation noise under various analysis scales are formulated, which verify the damage alarming reliability using the proposed WPES with preferable damage sensitivity and noise robusticity. 展开更多
关键词 structural damage alarming wavelet packet analysis wavelet packet energy spectrum long-span bridge
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Autodesk Revit与Robot Structural Analysis应用在高桩码头的信息互通技术研究 被引量:4
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作者 朱艳 顾倩燕 高加云 《中国水运(下半月)》 2018年第11期68-70,73,共4页
本文提出Autodesk Revit与Robot structural analysis应用在高桩码头的信息互通技术,介绍了信息互通工具,比较了常见的信息传递流程,提出了利用软件优势互补,分布建模,多次传递的BIM三维建模与计算分析模型的传递流程,实现三维建模与计... 本文提出Autodesk Revit与Robot structural analysis应用在高桩码头的信息互通技术,介绍了信息互通工具,比较了常见的信息传递流程,提出了利用软件优势互补,分布建模,多次传递的BIM三维建模与计算分析模型的传递流程,实现三维建模与计算分析的双向链接,并提出了现阶段高桩码头三维建模与计算分析中无法实现无缝链接的原因和解决方案。 展开更多
关键词 AUTODESK REVIT ROBOT structural analysis 高桩码头 信息互通
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Analysis and Flexible Structural Modeling for Oscillating Wing Utilizing Aeroelasticity
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作者 邵珂 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2008年第5期402-410,共9页
Making use of modal characteristics of the natural vibration of flexible structure to design the oscillating wing aircraft is proposed. A series of equations concerning the oscillating wing of flexible structures are ... Making use of modal characteristics of the natural vibration of flexible structure to design the oscillating wing aircraft is proposed. A series of equations concerning the oscillating wing of flexible structures are derived. The kinetic equation for aerodynamic force coupled with elastic movement is set up, and relevant formulae are derived. The unsteady aerodynamic one in that formulae is revised. The design principle, design process and range of application of such oscillating wing analytical method are elaborated. A flexible structural oscillating wing model is set up, and relevant time response analysis and frequency response analysis are conducted. The analytical results indicate that adopting the new-type driving way for the oscillating wing will not have flutter problems and will be able to produce propulsive force. Furthermore, it will consume much less power than the fixed wing for generating the same lift. 展开更多
关键词 aeroelasticity flexible structure modal characteristics oscillation wing EXCITE analysis
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Flutter and gust response analysis of a wing model including geometric nonlinearities based on a modified structural ROM 被引量:11
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作者 Chao AN Chao YANG +1 位作者 Changchuan XIE Lan YANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2020年第1期48-63,共16页
In this paper,a framework is established for nonlinear flutter and gust response analyses based on an efficient Reduced Order Model(ROM).The proposed method can be used to solve the aeroelastic response problems of wi... In this paper,a framework is established for nonlinear flutter and gust response analyses based on an efficient Reduced Order Model(ROM).The proposed method can be used to solve the aeroelastic response problems of wings containing geometric nonlinearities.A structural modeling approach presented herein describes the stiffness nonlinearities with a modal formulation.Two orthogonal spanwise modes describe the foreshortening effects of the wing.Dynamic linearization of the ROM under nonlinear equilibrium states is applied to a nonlinear flutter analysis,and the fully nonlinear ROM coupled with the non-planar Unsteady Vortex Lattice Method(UVLM)is applied to gust response analysis.Furthermore,extended Precise Integration Method(PIM)ensures accuracy of the dynamic equation solutions.To demonstrate applicability and accuracy of the method presented,a wind tunnel test is conducted and good agreements between theoretical and test results of nonlinear flutter speed and gust response deflection are reached.The method described in this paper is suitable for predicting the nonlinear flutter speed and calculating the gust responses of a large-aspect-ratio wing in time domain.Meanwhile,the results derived highlight the effects of geometric nonlinearities obviously. 展开更多
关键词 Aeroelasticity FLUTTER Geometric NONLINEARITY Reduced order models Response analysis structural model
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Synthesis and Structural Analysis of LDH-SO4-CO3 Whisker 被引量:9
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作者 WU Jiansong YANG Yifeng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2019年第5期1085-1088,共4页
High-quality LDH-SO4-CO3 whiskers were synthesized via liquid precipitation method using MgSO4·7 H2 O and Al2(SO4)3·18 H2O as precursors and Na2CO3-NaHCO3 buffer solution as precipitant. The influence of buf... High-quality LDH-SO4-CO3 whiskers were synthesized via liquid precipitation method using MgSO4·7 H2 O and Al2(SO4)3·18 H2O as precursors and Na2CO3-NaHCO3 buffer solution as precipitant. The influence of buffer solution concentration on the characteristics of the samples was investigated. The asgrown whiskers were characterized by X-ray diffraction, transmission electron microscopy, and BrunauerEmmett-Teller N2 specific surface area measurements. The results show that the buffer solution concentration has significant impact on whiskers with intercalated structure. The LDH-SO4-CO3 whiskers with well-defined geometry, distinct intercalated structure, decent quality, and excellent dispersing capability can be obtained under the following conditions: buffer solution volume ratio of 45%, reaction temperature of 83°C, and reaction time of 182 h. The obtained whiskers are well-crystallized and exhibit homogeneous morphology consisting of fiber bars. 展开更多
关键词 WHISKERS LDH-SO4-CO3 SYNTHESIS structural analysis
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Structural Analysis of Water-soluble Polysaccharide PIP_1 Extracted from the Cultured Mycelium of Phellinus igniarius 被引量:9
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作者 WU Ming-jiang JIANG De-zhi +1 位作者 LIU Tie-mei ZHANG Li-ping 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2006年第6期708-711,共4页
Water-soluble crude polyseccharide(PIP) was extracted from cultured mycelium of the fungus Phellinus igniarius. After ethanol precipitation and sepharose CL-6B gel filtration, the fraction of PIP1 was obtained, whic... Water-soluble crude polyseccharide(PIP) was extracted from cultured mycelium of the fungus Phellinus igniarius. After ethanol precipitation and sepharose CL-6B gel filtration, the fraction of PIP1 was obtained, which was shown to be a homogeneous polysaccharide by means of high-performance liquid chromatography. The structure of PIPt was determined by using several methods. C.,C analysis indicates that PIP1 is composed of the monosaccharides of glucose, galactose, and mannose. Their malar ratio is 3. 70: 4. 06: 1.00. The molar weight was estimated to be 17 kd via HPLC. IR, GC, partial hydrolysis with acid, pefiedate oxidation, Smith degradation, methylation, and GC-MS analysis were used for the structural analyses of PIP1. The results show that PIP1 has a small quantity of branch structure, The main glycosidic linkage of PIP1 has a β-configurafion. The main chain is made up of a large mass of glucose ( 1→3 ) and few mannose ( 1→4 ) ; the side chain is composed of glucose ( 1 →3 ) and galactose ( 1→6 ) ; the nonreduced end is composed of galactose and glucose. The side chains are branched at 6-0 of glucose( 1→3,6) and mannose(1→4,6). On an average, there are three branches among 20 residues. It is presumable that the existence of 1,3-linked Glc in the main and side chains is the main reason for its higher antitumor activity. 展开更多
关键词 Phellinus igniarus Cultured mycelium POLYSACCHARIDE structural analysis
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Evaluation on Spot Weld Models in Structural Dynamic Analysis of Automotive Body in White 被引量:9
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作者 LIANG Jianyong LIANG Jun +2 位作者 FANG Guodong PAN Zimin LI Wei 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2011年第1期84-90,共7页
Spot weld models are widely used in finite element analysis(FEA)of automotive body in white(BIW)to predict static,dynamic,durability and other characteristics of automotive BIW.However,few researches are done on evalu... Spot weld models are widely used in finite element analysis(FEA)of automotive body in white(BIW)to predict static,dynamic,durability and other characteristics of automotive BIW.However,few researches are done on evaluation of the validity of these spot weld models in structural dynamic analysis of BIW.To evaluate the validity and accuracy of spot weld models in structural dynamic analysis of BIW,two object functions,error function and deviation function,are introduced innovatively.Modal analysis of Two-panel and Double-hat structures,which are the dominated structures in BIW,is conducted,and the values of these two object functions are obtained.Based on the values of object functions,the validity of these spot weld models are evaluated.It is found that the area contact method(ACM2)and weld element connection(CWELD)can give more precise prediction in modal analysis of these two classical structures,thus are more applicable to structural dynamic analysis of automotive BIW.Modal analysis of a classical BIW is performed,which further confirms this evaluation.The error function and deviation function proposed in this research can give guidance on the adaptability of spot weld models in structural dynamic analysis of BIW.And this evaluation method can also be adopted in evaluation of other finite element models in static,dynamic and other kinds of analysis for automotive structures. 展开更多
关键词 spot weld model structural dynamic analysis modal analysis two-panel structure double-hat structure body in white
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Structural Modeling and Aeroelastic Analysis of High-Aspect-Ratio Composite Wings 被引量:9
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作者 赵永辉 胡海岩 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2005年第1期25-30,共6页
A unified structural model for high-aspect-ratio composite wing with arbitrary cross-section is developed. Two types of lay-ups of the composite wing, namely, circumferentially uniform stiffness (CUS) configuration ... A unified structural model for high-aspect-ratio composite wing with arbitrary cross-section is developed. Two types of lay-ups of the composite wing, namely, circumferentially uniform stiffness (CUS) configuration and circumferentially asymmetric stiffness (CAS) configuration, are investigated. The present structural modeling method is validated through ANSYS FEM software for the case of a composite box beam. Then, the case of a single-cell composite wing with NACA0012 airfoil shape is considered. To investigate the aeroelastic problem of high-aspect-ratio composite wings, the linear ONERA aerodynamic model is used to model the unsteady aerodynamic loads under the case of small angle of attack. Finally, flutter speeds of the high-aspect-ratio wing with various composite ply angles are determined by using U-g method. 展开更多
关键词 structural modeling aeroelastic analysis high-aspect-ratio composite wing
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Seismic analysis of diagrid structural frames with shear-link fuse devices 被引量:5
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作者 Nasim S. Moghaddasi B. Yunfeng Zhang 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2013年第3期463-472,共10页
This paper presents a new concept for enhancing the seismic ductility and damping capacity of diagrid structural frames by using shear-link fuse devices and its seismic performance is assessed through nonlinear static... This paper presents a new concept for enhancing the seismic ductility and damping capacity of diagrid structural frames by using shear-link fuse devices and its seismic performance is assessed through nonlinear static and dynamic analysis. The architectural elegancy of the diagrid structure attributed to its triangular leaning member configuration and high structural redundancy make this system a desirable choice for tall building design. However, forming a stable energy dissipation mechanism in diagrid framing remains to be investigated to expand its use in regions with high seismicity. To address this issue, a diagrid framing design is proposed here which provides a competitive design option in highly seismic regions through its increased ductility and improved energy dissipation capacity provided by replaceable shear links interconnecting the diagonal members at their ends.The structural characteristics and seismic behavior (capacity, stiffness, energy dissipation, ductility) of the diagrid structural frame are demonstrated with a 21-story building diagrid frame subjected to nonlinear static and dynamic analysis. The findings from the nonfinear time history analysis verify that satisfactory seismic performance can be achieved by the proposed diagrid frame subjected to design basis earthquakes in California. In particular, one appealing feature of the proposed diagrid building is its reduced residual displacement after strong earthquakes. 展开更多
关键词 diagrid structure nonlinear analysis seismic behavior shear link steel structure
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