Zinc-ion batteries(ZIBs)are inexpensive and safe,but side reactions on the Zn anode and Zn dendrite growth hinder their practical applications.In this study,1,3,5-triformylphloroglycerol(Tp)and various diamine monomer...Zinc-ion batteries(ZIBs)are inexpensive and safe,but side reactions on the Zn anode and Zn dendrite growth hinder their practical applications.In this study,1,3,5-triformylphloroglycerol(Tp)and various diamine monomers(p-phenylenediamine(Pa),benzidine(BD),and 4,4"-diamino-p-terphenyl(DATP))were used to synthesize a series of two-dimensional covalent-organic frameworks(COFs).The resulting COFs were named TpPa,TpBD,and TpDATP,respectively,and they showed uniform zincophilic sites,different pore sizes,and high Young's moduli on the Zn anode.Among them,TpPa and TpBD showed lower surface work functions and higher ion transfer numbers,which were conducive to uniform galvanizing/stripping zinc and inhibited dendrite growth.Theoretical calculations showed that TpPa and TpBD had wider negative potential region and greater adsorption capacity for Zn2+than TpDATP,providing more electron donor sites to coordinate with Zn^(2+).Symmetric cells protected by TpPa and TpBD stably cycled for more than 2300 h,whereas TpDATP@Zn and the bare zinc symmetric cells failed after around 150 and200 h.The full cells containing TpPa and TpBD modification layers also showed excellent cycling capacity at 1 A/g.This study provides comprehensive insights into the construction of highly reversible Zn anodes via COF modification layers for advanced rechargeable ZIBs.展开更多
This study aimed to investigate the relationship between atmospheric conditions and cosmic ray (CR) muons using daily and monthly CR data collected by the KAAU muon detector in Jeddah, Saudi Arabia between 2007 and 20...This study aimed to investigate the relationship between atmospheric conditions and cosmic ray (CR) muons using daily and monthly CR data collected by the KAAU muon detector in Jeddah, Saudi Arabia between 2007 and 2012. Specifically, the study examined the effects of atmospheric pressure, air temperature, and relative humidity on CR muons at different time scales (annual, seasonal, and monthly). The results of the analysis revealed that atmospheric pressure and air temperature had a negative impact on CR muons, while relative humidity had a positive impact. Although air temperature and relative humidity had small mean values across all time scales, their coefficients varied significantly from month to month and season to season. In addition, the study conducted multivariable correlation analyses for each day, which showed that pressure coefficients had consistently negative mean values, while the temperature and humidity coefficients had varying effects, ranging from positive to negative values. The reasons for the variations in the coefficients are not yet fully understood, but the study proposed several possible terrestrial and extraterrestrial explanations. These findings provide important insights into the complex interactions between the Earth’s atmosphere and cosmic rays, which can contribute to a better understanding of the potential impacts of cosmic rays on the Earth’s climate and environment.展开更多
基金financially supported by the National Natural Science Foundation of China(62464010)Spring City Plan-Special Program for Young Talents(K202005007)+3 种基金Yunnan Talents Support Plan for Yong Talents(XDYC-QNRC-2022-0482)Yunnan Local Colleges Applied Basic Research Projects(202101BA070001-138)Key Laboratory of Artificial Microstructures in Yunnan Higher EducationFrontier Research Team of Kunming University 2023。
文摘Zinc-ion batteries(ZIBs)are inexpensive and safe,but side reactions on the Zn anode and Zn dendrite growth hinder their practical applications.In this study,1,3,5-triformylphloroglycerol(Tp)and various diamine monomers(p-phenylenediamine(Pa),benzidine(BD),and 4,4"-diamino-p-terphenyl(DATP))were used to synthesize a series of two-dimensional covalent-organic frameworks(COFs).The resulting COFs were named TpPa,TpBD,and TpDATP,respectively,and they showed uniform zincophilic sites,different pore sizes,and high Young's moduli on the Zn anode.Among them,TpPa and TpBD showed lower surface work functions and higher ion transfer numbers,which were conducive to uniform galvanizing/stripping zinc and inhibited dendrite growth.Theoretical calculations showed that TpPa and TpBD had wider negative potential region and greater adsorption capacity for Zn2+than TpDATP,providing more electron donor sites to coordinate with Zn^(2+).Symmetric cells protected by TpPa and TpBD stably cycled for more than 2300 h,whereas TpDATP@Zn and the bare zinc symmetric cells failed after around 150 and200 h.The full cells containing TpPa and TpBD modification layers also showed excellent cycling capacity at 1 A/g.This study provides comprehensive insights into the construction of highly reversible Zn anodes via COF modification layers for advanced rechargeable ZIBs.
文摘This study aimed to investigate the relationship between atmospheric conditions and cosmic ray (CR) muons using daily and monthly CR data collected by the KAAU muon detector in Jeddah, Saudi Arabia between 2007 and 2012. Specifically, the study examined the effects of atmospheric pressure, air temperature, and relative humidity on CR muons at different time scales (annual, seasonal, and monthly). The results of the analysis revealed that atmospheric pressure and air temperature had a negative impact on CR muons, while relative humidity had a positive impact. Although air temperature and relative humidity had small mean values across all time scales, their coefficients varied significantly from month to month and season to season. In addition, the study conducted multivariable correlation analyses for each day, which showed that pressure coefficients had consistently negative mean values, while the temperature and humidity coefficients had varying effects, ranging from positive to negative values. The reasons for the variations in the coefficients are not yet fully understood, but the study proposed several possible terrestrial and extraterrestrial explanations. These findings provide important insights into the complex interactions between the Earth’s atmosphere and cosmic rays, which can contribute to a better understanding of the potential impacts of cosmic rays on the Earth’s climate and environment.
