The heterogeneous UV/Fenton process with the appropriate amount of Fe-Mn-Cu-Y as catalyst was developed and various operation conditions for the degradation of phenol were evaluated. The results indicated that by usin...The heterogeneous UV/Fenton process with the appropriate amount of Fe-Mn-Cu-Y as catalyst was developed and various operation conditions for the degradation of phenol were evaluated. The results indicated that by using the het-erogeneous UV/Fenton process, the CODcr removal rate reached almost 100% for wastewater containing phenol. Compared with the homogeneous process, the developed catalyst could be used at wider pH range in the UV/Fenton process. Com-parison of various heterogeneous process showed that heterogeneous UV/Fenton process was best. The heterogeneous UV/Fenton process with Fe-Mn-Cu-Y catalyst is highly efficient in degrading various organic pollutants.展开更多
ZnFe2O4 nanoparticles （ZFNPs） were developed as catalyst for the degradation of benzotriazole （BTA） by heterogeneous photoelectro- Fenton （PE-Fenton） like process. ZFNPs were prepared by a co-precipitation proce...ZnFe2O4 nanoparticles （ZFNPs） were developed as catalyst for the degradation of benzotriazole （BTA） by heterogeneous photoelectro- Fenton （PE-Fenton） like process. ZFNPs were prepared by a co-precipitation process and then characterized with transmission electron microscopy （TEM）, X-ray fluorescence （XRF）, X-ray diffraction （XRD） and BET surface area. Using such ZFNPs as catalyst, the degradation of BTA was investigated. Due to the high catalytic activity of ZFNPs, PE-Fenton like process showed efficient degradation of BTA. The influencing factors such as pH, dosage of ZFNPs, applied potential and initial concentration of BTA were systematically investigated. Under the optimum conditions, 91.2% of BTA was removed after 180 rain treatment.展开更多
The degradation of phenol was carried out using heterogeneous Fenton-type catalysts in the presence of H_2O_2 and UV. Catalysts were prepared by exchanging and immobilizing Fe 2+ in zeolite 13X, silica gel or Al_2O...The degradation of phenol was carried out using heterogeneous Fenton-type catalysts in the presence of H_2O_2 and UV. Catalysts were prepared by exchanging and immobilizing Fe 2+ in zeolite 13X, silica gel or Al_2O_3. The concentration of phenol solution was 100 mg/L. The amount of H_2O_2 added was the stoichiometric amount of H_2O_2 required for the total oxidation of phenol. Under the irradiation of medium pressure light (300 W) phenol was mineralized within 1 h in the presence of Fe 2+/zeolite 13X. The COD removal rate was enhanced in the presence of Fe 2+/zeolite 13X compared to that of Fe 2+/silica gel or Fe 2+/Al_2O_3. Analogous homogenous photo-Fenton reaction with equivalent Fe 2+ was also carried out to evaluate the catalysis efficiency of Fe 2+/zeolite 13X. Results showed that the COD removal rate was near to that of homogeneous Fenton, while heterogeneous Fe 2+/zeolite 13X catalyst could be recycled.展开更多
Black clay (BC) was used as a catalyst for the decolorization of Azure B dye by Fenton process. BC was modi ed by acid, alkali, distilled water, and calcination to check their changes in characterization and e ciency ...Black clay (BC) was used as a catalyst for the decolorization of Azure B dye by Fenton process. BC was modi ed by acid, alkali, distilled water, and calcination to check their changes in characterization and e ciency on decolorization of Azure B. Among three modi ed catalysts, maximum decolorization was obtained by acid-modi ed BC (AMBC) catalyst due to the highest removal of impurities, comparatively. The characterization of AMBC was done by Fourier-transform infrared spectroscopy and X-ray di raction spectroscopy which show the presence of metal ion. The BET surface area, pore volume, pore size, and density of AMBC were calculated to be 79.402 m 2 /g, 0.0608 m 3 /g, 0.00306 nm, and 16 g/cm 3 , respectively. The highest decolorization of 97.59% was achieved only in 10 min using AMBC at optimized calcination of 100 °C and 3 h of aging. AMBC was considered as the main catalyst for optimizing the di erent process parameters. Optimized conditions were obtained: pH 2, 0.2 mL of H 2 O 2 , catalyst dose 0.3 g, room temperature (30 °C), and stirring speed 400 r/min. The catalyst has showed excellent stability and reusability. It could remove more than 85% of color even after four cycles of run and less than negligible leaching of iron. AMBC has good recycling ability among other modi ed catalysts. To check the selectivity of catalyst, di erent dyes such as Congo red and mixed dye (mixture of Azure B and Congo red) decolorization were studied. In the present work, kinetic study was also carried out and a three-stage decolorization process was found.展开更多
基金Project (No. 20176053) supported by the National Natural Science Foundation of China
文摘The heterogeneous UV/Fenton process with the appropriate amount of Fe-Mn-Cu-Y as catalyst was developed and various operation conditions for the degradation of phenol were evaluated. The results indicated that by using the het-erogeneous UV/Fenton process, the CODcr removal rate reached almost 100% for wastewater containing phenol. Compared with the homogeneous process, the developed catalyst could be used at wider pH range in the UV/Fenton process. Com-parison of various heterogeneous process showed that heterogeneous UV/Fenton process was best. The heterogeneous UV/Fenton process with Fe-Mn-Cu-Y catalyst is highly efficient in degrading various organic pollutants.
基金supported by the National Natural Science Foundation of China (No. 20977037)the Fundamental Research Funds for the Central Universities (No.2011TS062)
文摘ZnFe2O4 nanoparticles （ZFNPs） were developed as catalyst for the degradation of benzotriazole （BTA） by heterogeneous photoelectro- Fenton （PE-Fenton） like process. ZFNPs were prepared by a co-precipitation process and then characterized with transmission electron microscopy （TEM）, X-ray fluorescence （XRF）, X-ray diffraction （XRD） and BET surface area. Using such ZFNPs as catalyst, the degradation of BTA was investigated. Due to the high catalytic activity of ZFNPs, PE-Fenton like process showed efficient degradation of BTA. The influencing factors such as pH, dosage of ZFNPs, applied potential and initial concentration of BTA were systematically investigated. Under the optimum conditions, 91.2% of BTA was removed after 180 rain treatment.
基金TheNationalNaturalScienceFoundationofChina (No .2 0 1760 5 3 )
文摘The degradation of phenol was carried out using heterogeneous Fenton-type catalysts in the presence of H_2O_2 and UV. Catalysts were prepared by exchanging and immobilizing Fe 2+ in zeolite 13X, silica gel or Al_2O_3. The concentration of phenol solution was 100 mg/L. The amount of H_2O_2 added was the stoichiometric amount of H_2O_2 required for the total oxidation of phenol. Under the irradiation of medium pressure light (300 W) phenol was mineralized within 1 h in the presence of Fe 2+/zeolite 13X. The COD removal rate was enhanced in the presence of Fe 2+/zeolite 13X compared to that of Fe 2+/silica gel or Fe 2+/Al_2O_3. Analogous homogenous photo-Fenton reaction with equivalent Fe 2+ was also carried out to evaluate the catalysis efficiency of Fe 2+/zeolite 13X. Results showed that the COD removal rate was near to that of homogeneous Fenton, while heterogeneous Fe 2+/zeolite 13X catalyst could be recycled.
基金supported by Department of Science & Technology—Science & Engineering Research Board (No. YSS/2014/000996, India)
文摘Black clay (BC) was used as a catalyst for the decolorization of Azure B dye by Fenton process. BC was modi ed by acid, alkali, distilled water, and calcination to check their changes in characterization and e ciency on decolorization of Azure B. Among three modi ed catalysts, maximum decolorization was obtained by acid-modi ed BC (AMBC) catalyst due to the highest removal of impurities, comparatively. The characterization of AMBC was done by Fourier-transform infrared spectroscopy and X-ray di raction spectroscopy which show the presence of metal ion. The BET surface area, pore volume, pore size, and density of AMBC were calculated to be 79.402 m 2 /g, 0.0608 m 3 /g, 0.00306 nm, and 16 g/cm 3 , respectively. The highest decolorization of 97.59% was achieved only in 10 min using AMBC at optimized calcination of 100 °C and 3 h of aging. AMBC was considered as the main catalyst for optimizing the di erent process parameters. Optimized conditions were obtained: pH 2, 0.2 mL of H 2 O 2 , catalyst dose 0.3 g, room temperature (30 °C), and stirring speed 400 r/min. The catalyst has showed excellent stability and reusability. It could remove more than 85% of color even after four cycles of run and less than negligible leaching of iron. AMBC has good recycling ability among other modi ed catalysts. To check the selectivity of catalyst, di erent dyes such as Congo red and mixed dye (mixture of Azure B and Congo red) decolorization were studied. In the present work, kinetic study was also carried out and a three-stage decolorization process was found.
