The non-isothermal decomposition reaction of Nd[(C_5H_ 10NS_2)_3(C_ 12H_8N_2)] were carried out by means of TG-DTG and the thermal decomposition mechanism, and the associated kinetics was investigated. The kinetic par...The non-isothermal decomposition reaction of Nd[(C_5H_ 10NS_2)_3(C_ 12H_8N_2)] were carried out by means of TG-DTG and the thermal decomposition mechanism, and the associated kinetics was investigated. The kinetic parameters are obtained from an analysis of the TG-DTG curves at different heating rate by integral and differential methods. The most probable kinetic model function of the decomposition reaction is Maple Power of n=3/2, f(α)=2/3α -1/2 and the apparent activation energy E is 116.67 kJ·mol -1 and the pre-exponential factor lg[A/s -1] is 7.6891.展开更多
The efficientseparation of C_(3)H_(6) and C_(3)H_(8) is a key challenge in the petrochemical industry.A zinc-based flexible metal—organic framework(Zn—anthracenedicarboxylic acid(ADC)—triazole(TRZ))was designed thr...The efficientseparation of C_(3)H_(6) and C_(3)H_(8) is a key challenge in the petrochemical industry.A zinc-based flexible metal—organic framework(Zn—anthracenedicarboxylic acid(ADC)—triazole(TRZ))was designed through dual ligand construction.The material forms a two-dimensional layered structure via TRZ ligands,with ADC ligands serving as interlayer pillars to construct a three-dimensional pillarlayered structure,combining the stability of rigid aromatic rings with the dynamic responsiveness of flexible structures.The flexible pores of Zn—ADC—TRZ can be reversibly opened and closed under the thermal effect,and the adsorption capacity and the opening pressure of the gas can be adjusted with the increase of temperature,thereby enabling achieve the best separation effect under different partial pressures of the gas.Specifically,temperature modulation leads to increase the opening pressure of Zn—ADC—TRZ,enabling significantadsorption difference between C_(3)H_(6) and C_(3)H_(8).At 313 K and 50 kPa,Zn—ADC—TRZ achieves the highest adsorption ratio(24)of C_(3)H_(6) and C_(3)H_(8) while maintaining substantial C_(3)H_(6) adsorption capacity,thereby facilitating efficientseparation of equimolar gases.This work demonstrates the potential of temperature-responsive flexible metal—organic frameworks for energyefficientolefinpurification,offering novel insights into low-energy consumption separation technology.展开更多
In this context,the present study proposes the use of microwave irradiation to improve the dehydration rate and efficiency of strontium hydroxide octahydrate(Sr(OH)_(2)·8H_(2)O)without introducing contaminants.Th...In this context,the present study proposes the use of microwave irradiation to improve the dehydration rate and efficiency of strontium hydroxide octahydrate(Sr(OH)_(2)·8H_(2)O)without introducing contaminants.This study revealed that the use of microwave irradiation to dehydrate Sr(OH)_(2)·8H_(2)O is feasible and surprisingly efficient.The effects of this approach on important parameters were investigated using response surface methodology(RSM).The results revealed that the microwave dehydration process follows a linear polynomial model.In addition,compared with the heating time and material thickness,the microwave-assisted dehydration of Sr(OH)_(2)·8H_(2)O is sensitive to the microwave power and not to the material mass.The relative dehydration percentage reached 99.99%when heated in a microwave oven at 950Wfor just 3 min.In contrast,a relative dehydration percentage of 94.6%was reached when heated in an electric furnace at 180℃for 120 min.The XRD spectra also revealed that most of the Sr(OH)_(2)·8H_(2)O transformed into Sr(OH)_(2)after dehydration via microwave irradiation,whereas a significant portion of the Sr(OH)_(2)·H_(2)O remained after conventional electric dehydration.The experimental data were fitted and analyzed via the thin-layer drying dynamics model,and the results indicated that the dehydrating behavior of Sr(OH)_(2)·8H_(2)O could be well described by the Page model.展开更多
Fresh Pd/CeO/AlOclose coupled catalyst was prepared by the stepwise impregnation method and calcined at 550 °C for 3 h, which was then pretreated at 700, 800, and 900 °C for 3 h, respectively. Finally, these...Fresh Pd/CeO/AlOclose coupled catalyst was prepared by the stepwise impregnation method and calcined at 550 °C for 3 h, which was then pretreated at 700, 800, and 900 °C for 3 h, respectively. Finally, these pretreated catalysts were aged at 1000 °C for 3 h to study their anti-aging properties. The catalytic activities of the catalysts were investigated detailedly, and the results showed that the catalyst pretreated at 800 °C before aging treatment possessed the best anti-aging performance for CHoxidation. XRD and XPS results indicated that well-crystallized CeOparticles were formed during calcinations at 800 °C, which made CeOan effective promoter. HRTEM revealed that Pd particles found on the edge of CeOover the aged catalyst pretreated at 800 °C were relatively smaller than those over the catalysts without pretreatment. H-TPR and XPS results also implied that the interaction between well-crystallized CeOand Pd suppressed the deactivation of PdO sites and further enhanced the catalytic performance.展开更多
文摘The non-isothermal decomposition reaction of Nd[(C_5H_ 10NS_2)_3(C_ 12H_8N_2)] were carried out by means of TG-DTG and the thermal decomposition mechanism, and the associated kinetics was investigated. The kinetic parameters are obtained from an analysis of the TG-DTG curves at different heating rate by integral and differential methods. The most probable kinetic model function of the decomposition reaction is Maple Power of n=3/2, f(α)=2/3α -1/2 and the apparent activation energy E is 116.67 kJ·mol -1 and the pre-exponential factor lg[A/s -1] is 7.6891.
基金financial support from the National Natural Science Foundation of China(22422810,22090062,22278288)Natural Science Foundation of Shanxi Province(202203021223004).
文摘The efficientseparation of C_(3)H_(6) and C_(3)H_(8) is a key challenge in the petrochemical industry.A zinc-based flexible metal—organic framework(Zn—anthracenedicarboxylic acid(ADC)—triazole(TRZ))was designed through dual ligand construction.The material forms a two-dimensional layered structure via TRZ ligands,with ADC ligands serving as interlayer pillars to construct a three-dimensional pillarlayered structure,combining the stability of rigid aromatic rings with the dynamic responsiveness of flexible structures.The flexible pores of Zn—ADC—TRZ can be reversibly opened and closed under the thermal effect,and the adsorption capacity and the opening pressure of the gas can be adjusted with the increase of temperature,thereby enabling achieve the best separation effect under different partial pressures of the gas.Specifically,temperature modulation leads to increase the opening pressure of Zn—ADC—TRZ,enabling significantadsorption difference between C_(3)H_(6) and C_(3)H_(8).At 313 K and 50 kPa,Zn—ADC—TRZ achieves the highest adsorption ratio(24)of C_(3)H_(6) and C_(3)H_(8) while maintaining substantial C_(3)H_(6) adsorption capacity,thereby facilitating efficientseparation of equimolar gases.This work demonstrates the potential of temperature-responsive flexible metal—organic frameworks for energyefficientolefinpurification,offering novel insights into low-energy consumption separation technology.
基金supported by the Research Program of the Science and Technology Department of Guizhou Province(Qiankehe Jichu[2019]1418)the Research Program of Talented Scholars of Guizhou Institute of Technology(XJGC20190965).
文摘In this context,the present study proposes the use of microwave irradiation to improve the dehydration rate and efficiency of strontium hydroxide octahydrate(Sr(OH)_(2)·8H_(2)O)without introducing contaminants.This study revealed that the use of microwave irradiation to dehydrate Sr(OH)_(2)·8H_(2)O is feasible and surprisingly efficient.The effects of this approach on important parameters were investigated using response surface methodology(RSM).The results revealed that the microwave dehydration process follows a linear polynomial model.In addition,compared with the heating time and material thickness,the microwave-assisted dehydration of Sr(OH)_(2)·8H_(2)O is sensitive to the microwave power and not to the material mass.The relative dehydration percentage reached 99.99%when heated in a microwave oven at 950Wfor just 3 min.In contrast,a relative dehydration percentage of 94.6%was reached when heated in an electric furnace at 180℃for 120 min.The XRD spectra also revealed that most of the Sr(OH)_(2)·8H_(2)O transformed into Sr(OH)_(2)after dehydration via microwave irradiation,whereas a significant portion of the Sr(OH)_(2)·H_(2)O remained after conventional electric dehydration.The experimental data were fitted and analyzed via the thin-layer drying dynamics model,and the results indicated that the dehydrating behavior of Sr(OH)_(2)·8H_(2)O could be well described by the Page model.
基金Project supported by the National Natural Science Foundation of China(21173153)the National Hi-tech Research Development Program of China(863 Program,2013AA065304)the Sichuan Science and Technology Agency Supported Project(2012FZ0008)
文摘Fresh Pd/CeO/AlOclose coupled catalyst was prepared by the stepwise impregnation method and calcined at 550 °C for 3 h, which was then pretreated at 700, 800, and 900 °C for 3 h, respectively. Finally, these pretreated catalysts were aged at 1000 °C for 3 h to study their anti-aging properties. The catalytic activities of the catalysts were investigated detailedly, and the results showed that the catalyst pretreated at 800 °C before aging treatment possessed the best anti-aging performance for CHoxidation. XRD and XPS results indicated that well-crystallized CeOparticles were formed during calcinations at 800 °C, which made CeOan effective promoter. HRTEM revealed that Pd particles found on the edge of CeOover the aged catalyst pretreated at 800 °C were relatively smaller than those over the catalysts without pretreatment. H-TPR and XPS results also implied that the interaction between well-crystallized CeOand Pd suppressed the deactivation of PdO sites and further enhanced the catalytic performance.
