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Resin-free aramid honeycombs with extraordinary microwave absorption,thermal insulation,flame retardant and mechanical performance
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作者 Hao Sun Meiyun Zhang +5 位作者 Dexian Ji Cong Ma Baolong Yuan Ronghua Feng Jiaojun Tan Bin Yang 《Journal of Materials Science & Technology》 2025年第30期132-143,共12页
Although lightweight aramid paper honeycombs are highly desirable for microwave absorption owing to their dual functions of both load-bearing and microwave-absorbing,unsatisfactory microwave absorption,inferior mechan... Although lightweight aramid paper honeycombs are highly desirable for microwave absorption owing to their dual functions of both load-bearing and microwave-absorbing,unsatisfactory microwave absorption,inferior mechanical and inadequate thermal properties present significant challenges for practical applications in diverse complex scenarios.Herein,lightweight,high-strength and flame-retardant aramid nanofibers-based honeycombs(MANHs)for integrated microwave absorption and thermal insulation are successfully fabricated via the hydrogen bonding assembly,mold forming and aerogel filling strategy using aramid waste as raw material.The dense network structure formed by the interwoven aramid nanofibers(ANFs)in the honeycomb body acts as a framework endows the MANH with impressive mechanical performance,and the specific strength and toughness of MANH reach 153.6 MPa g^(−1) cm^(−3) and 13.9 MJ m^(−3),respectively,which are 3.5 and 19 times higher than those of commercial microwave absorption honeycombs(CMAH).The ultralight MXene/ANFs aerogels(a density of 25 mg cm^(−3))with multiscale pore structure filled in the honeycomb apertures give the honeycomb outstanding microwave absorption performance,with a minimum reflection loss of−62.5 dB,and can cover the entire X-band with a thickness of only 3.5 mm.Meanwhile,compared with CMAH,the thermal insulation and flame-retardant performance of MANH are also significantly improved.Notably,MANH also demonstrates favorable sound absorption performance at high-frequency bands.The MANH is considered to be a promising candidate for aerospace and military stealth applications as a result of its lightweight,high strength,exceptional microwave absorption,and remarkable thermal insulation performance. 展开更多
关键词 Aramid nanofibers Multifunctional honeycomb Microwave absorption Mechanical property Flame retardancy
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In-plane crushing behavior and energy absorption design of composite honeycombs 被引量:16
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作者 H.X.Wu Y.Liu X.C.Zhang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2018年第6期1108-1123,共16页
Theoretical analysis and numerical simulation methods were used to study the in-plane crushing behavior of single-cell structures and regular and composite honeycombs.Square,hexagonal,and circular honeycombs were sele... Theoretical analysis and numerical simulation methods were used to study the in-plane crushing behavior of single-cell structures and regular and composite honeycombs.Square,hexagonal,and circular honeycombs were selected as honeycomb layers to establish composite honeycomb models in the form of composite structures and realize the complementary advantages of honeycombs with type Ⅰ and type Ⅱ structures.The effects of honeycomb layer arrangement,plastic collapse strength,relative density,and crushing velocity on the deformation mode,plateau stress,load uniformity,and energy absorption performance of the composite honeycombs were mainly considered.A semi-empirical formula for plateau stress and energy absorption rate per unit mass for the composite honeycombs was developed.The results showed that the arrangement mode of honeycomb layers is an important factor that affects their mechanical properties.Appropriately selecting the arrangement of honeycomb layers and the proportion of honeycomb layers with different structures in a composite honeycomb can effectively improve its load uniformity and control the magnitude of plateau stress and energy absorption capacity. 展开更多
关键词 COMPOSITE honeycombs Dynamic CRUSHING Load UNIFORMITY Energy ABSORPTION FINITE element analysis
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Optimization design of chiral hexagonal honeycombs with prescribed elastic properties under large deformation 被引量:7
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作者 Kepeng QIU Ruoyao WANG +1 位作者 Jihong ZHU Weihong ZHANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2020年第3期902-909,共8页
Flexible chiral honeycomb cores generally exhibit nonlinear elastic properties due to large geometric deformation.The effective elastic moduli and Poisson's ratio typically vary with an increase in deformation.Her... Flexible chiral honeycomb cores generally exhibit nonlinear elastic properties due to large geometric deformation.The effective elastic moduli and Poisson's ratio typically vary with an increase in deformation.Here,the size and shape optimization of the chiral hexagonal honeycombs was performed to keep the Young's moduli and Poisson's ratio unchanged under large deformations.The size of the honeycomb unit cell and the position coordinates of the key points were defined simultaneously as design variables.The equivalent Young's modulus and Poisson's ratio of chiral honeycombs were calculated through geometric nonlinear analysis.The objective was to minimize the allowable tolerance between the prescribed and actual properties within the range of the target strain.A genetic algorithm was then adopted.The optimal results demonstrate that the chiral honeycombs can maintain effective elastic properties that do not vary under large deformation.These results are meaningful to morphing aircraft designs. 展开更多
关键词 Chiral hexagonal honeycombs Genetic algorithm Geometric nonlinearity Large deformation Shape optimization
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Dynamic crushing behaviors and enhanced energy absorption of bio-inspired hierarchical honeycombs with different topologies 被引量:4
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作者 Xin-chun Zhang Nan-nan Liu +3 位作者 Chao-chao An He-xiang Wu Na Li Ke-ming Hao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第4期99-111,共13页
In order to pursue good crushing load uniformity and enchance energy absorption efficiency of conventional honeycombs, a kind of bio-inspired hierarchical honeycomb model is proposed by mimicking the arched crab shell... In order to pursue good crushing load uniformity and enchance energy absorption efficiency of conventional honeycombs, a kind of bio-inspired hierarchical honeycomb model is proposed by mimicking the arched crab shell structures. Three bio-inspired hierarchical honeycombs(BHHs) with different topologies are designed by replacing each vertex of square honeycombs with smaller arc-shaped structures. The effects of hierarchical topologies and multi-material layout on in-plane dynamic crushings and absorbed-energy capacities of the BHHs are explored based on the explicit finite element(FE) analysis.Different deformation modes can be observed from the BHHs, which mainly depend upon hierarchical topologies and impact velocities. According to energy efficiency method and one-dimensional(1D) shock theory, calculation formulas of densification strains and plateau stresses for the BHHs are derived to characterize the dynamic bearing capacity, which is consistent well with FE results. Compared with conventional honeycombs, the crushing load efficiency and energy absorption capacity of the BHHs can be improved by changing the proper hierarchical topology and multi-material layout. These researches will provide theoretical guidance for innovative design and dynamic response performance controllability of honeycombs. 展开更多
关键词 Bio-inspired honeycombs Crushing load uniformity Energy absorption Hierarchical topologies Finite element analysis
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OUT-OF-PLANE COMPRESSIVE PROPERTIES OF HEXAGONAL PAPER HONEYCOMBS 被引量:28
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作者 WANG Dongmei WANG Zhiwei 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2007年第2期115-119,共5页
The compressive behaviour of paper honeycombs is studied by means of an experimental analysis. Experiment results show how geometry aspects of hexagonal paper honeycombs, e.g. the height of paper honeycomb, the thickn... The compressive behaviour of paper honeycombs is studied by means of an experimental analysis. Experiment results show how geometry aspects of hexagonal paper honeycombs, e.g. the height of paper honeycomb, the thickness and length of honeycomb cell-wall, the drawing ratio of hexagonal honeycomb, affect the compressive properties of the paper honeycombs. It is in good agreement with the theory model. The constraint factor K of the critical buckling stress is mainly determined by the length of honeycomb cell-wail. It can be described as K=1.54 for B type paper honeycombs and K=3.32 for D type paper honeycombs. The plateau stress is the power exponent function of the thickness to length ratio of honeycomb cell-wall, and the experiment results show that the constant is 13.2 and the power exponent is 1.77. The research results can be used to characterize and improve efficiently the compressive properties of paper honeycombs. 展开更多
关键词 Paper honeycombs Compressive behaviour Geometry structure Constraint factor
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Elastic properties of chiral,anti-chiral,and hierarchical honeycombs:A simple energy-based approach 被引量:18
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作者 Davood Mousanezhad Babak Haghpanah +3 位作者 Ranajay Ghosh Abdel Magid Hamouda Harold Nayeb-Hashemi Ashkan Vaziri 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2016年第2期81-96,共16页
The effects of two geometric refinement strategies widespread in natural structures, chirality and self-similar hierarchy, on the in-plane elastic response of two-dimensional honeycombs were studied systematically. Si... The effects of two geometric refinement strategies widespread in natural structures, chirality and self-similar hierarchy, on the in-plane elastic response of two-dimensional honeycombs were studied systematically. Simple closed-form expressions were derived for the elastic moduli of several chiral, anti- chiral, and hierarchical honeycombs with hexagon and square based networks. Finite element analysis was employed to validate the analytical estimates of the elastic moduli. The results were also compared with the numerical and experimental data available in the literature. We found that introducing a hier- archical refinement increases the Young's modulus of hexagon based honeycombs while decreases their shear modulus. For square based honeycombs, hierarchy increases the shear modulus while decreasing their Young's modulus. Introducing chirality was shown to always decrease the Young's modulus and Poisson's ratio of the structure. However, chirality remains the only route to auxeticity. In particular, we found that anti-tetra-chiral structures were capable of simultaneously exhibiting anisotropy, auxeticity, and remarkably low shear modulus as the magnitude of the chirality of the unit cell increases. 展开更多
关键词 Chiral Hierarchical Honeycomb Metamaterial Auxetic
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Energy Absorption Performance of Bio-inspired Honeycombs:Numerical and Theoretical Analysis 被引量:3
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作者 John Sherman Wen Zhang Jun Xu 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2021年第6期884-894,共11页
Energy absorption performance has been a long-pursued research topic in designing desired materials and structures subject to external dynamic loading.Inspired by natural bio-structures,herein,we develop both numerica... Energy absorption performance has been a long-pursued research topic in designing desired materials and structures subject to external dynamic loading.Inspired by natural bio-structures,herein,we develop both numerical and theoretical models to analyze the energy absorption behaviors of Weaire,Floret,and Kagome-shaped thin-walled structures.We demonstrate that these bio-inspired structures possess superior energy absorption capabilities compared to the traditional thin-walled structures,with the specific energy absorption about 44%higher than the traditional honeycomb.The developed mechanical model captures the fundamental characteristics of the bio-inspired honeycomb,and the mean crushing force in all three structures is accurately predicted.Results indicate that although the basic energy absorption and deformation mode remain the same,varied geometry design and the corresponding material distribution can further boost the energy absorption of the structure,providing a much broader design space for the next-generation impact energy absorption structures and systems. 展开更多
关键词 Bio-inspired honeycomb Energy absorption Impact resistance Finite element analysis MODELING
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Dynamic Crushing Strength Analysis of Auxetic Honeycombs 被引量:21
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作者 Xiuhui Hou Zichen Deng Kai Zhang 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2016年第5期490-501,共12页
The in-plane dynamic crushing behavior of re-entrant honeycomb is analyzed and compared with the conventional hexagon topology.Detailed deformation modes along two orthogonal directions are examined,where a parametric... The in-plane dynamic crushing behavior of re-entrant honeycomb is analyzed and compared with the conventional hexagon topology.Detailed deformation modes along two orthogonal directions are examined,where a parametric study of the effect of impact velocity and cell wall aspect ratio is performed.An analytical formula of the dynamic crushing strength is then deduced based on the periodic collapse mechanism of cell structures.Comparisons with the finite element results validate the effectiveness of the proposed analytical method.Numerical results also reveal higher plateau stress of re-entrant honeycomb over conventional hexagon topology,implying better energy absorption properties.The underlying physical understanding of the results is emphasized,where the auxetic effect(negative Poisson's ratio) induced in the re-entrant topology is believed to be responsible for this superior impact resistance. 展开更多
关键词 honeycomb topology collapse plateau emphasized perfectly directions deduced validate Poisson
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Experimental investigation of chimney-enhanced natural convection in hexagonal honeycombs 被引量:2
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作者 Xiaohu Yang Jiaxi Bai +1 位作者 Tianjian Lu Tongbeum Kim 《Theoretical & Applied Mechanics Letters》 CAS 2014年第3期49-54,共6页
The natural convective heat transfer performance of an aluminum hexagonal honeycomb acting as a novel heat sink for LED cooling is experi- mentally investigated. The concept of adding an adiabatic square chimney ex- t... The natural convective heat transfer performance of an aluminum hexagonal honeycomb acting as a novel heat sink for LED cooling is experi- mentally investigated. The concept of adding an adiabatic square chimney ex- tension for heat transfer enhancement is proposed, and the effects of chimney shape, height, and diameter are quantified. The average Nuav of a heated hon- eycomb with straight chimney is significantly higher than that without chimney, and the enhancement increases with increasing chimney height. At a given chim- ney height, honeycombs with divergent chimneys perform better than those with convergent ones. For a fixed divergent angle, the Nuav number increases mono- tonically with increasing chimney height. In contrast, with the convergent angle fixed, there exists an optimal chimney height to achieve maximum heat transfer. 展开更多
关键词 natural convection HONEYCOMB adiabatic chimney experiment
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Dual-level stress plateaus in honeycombs subjected to impact loading:perspectives from bucklewaves, buckling and cell-wall progressive folding 被引量:1
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作者 Lang Li Zhenyu Zhao +3 位作者 Rui Zhang Bin Han Qiantheng Zhang Tian Jian Lu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2019年第1期70-77,I0003,共9页
Dual-level stress plateaus (i.e., relatively short peak stress plateaus, followed by prolonged crushing stress plateaus) in metallic hexagonal honeycombs subjected to out-of-plane impact loading are characterized usin... Dual-level stress plateaus (i.e., relatively short peak stress plateaus, followed by prolonged crushing stress plateaus) in metallic hexagonal honeycombs subjected to out-of-plane impact loading are characterized using a combined numerical and analytical study, with the influence of the strain-rate sensitivity of the honeycomb pare nt material accounted for. The predicti ons are validated against existing experimental measurements, and good agreement is achieved. It is demonstrated that honeycombs exhibit dual-level stress plateaus when bucklewaves are initiated and propagate in cell walls, followed by buckling and progressive folding of the cell walls. The abrupt stress drop from peak to crushing plateau in the compressive stress versus strain curve can be explained in a way similar to the quasi-static buckling of a clamped plate. The duration of the peak stress plateau is more evident for strain-rate insensitive honeycombs. 展开更多
关键词 Honeycomb Impact loading Dual-level STRESS Strain-rate sensitivity
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Finite Element Analysis for In-Plane Crushing Behaviour of Aluminium Honeycombs 被引量:1
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作者 ZHU Feng ZHAO Longmao LU Guoxing 《Transactions of Tianjin University》 EI CAS 2006年第B09期142-146,共5页
A number of finite element simulations were performed to analyze the in-plane crushing behaviour of aluminium honeycombs and the results are presented and discussed. The simulations include both X1 and X2 cases. All t... A number of finite element simulations were performed to analyze the in-plane crushing behaviour of aluminium honeycombs and the results are presented and discussed. The simulations include both X1 and X2 cases. All the analyses are quasi-static, and can be divided into three groups, which are designed to investigate the effects of cell size, foil thickness and yield stress of the foil material, respectively, on the structural response of honeycombs. The result indicates that these factors can significantly affect the plateau stresses of honeycomb cellular structures in both directions, and the plateau stresses in X2 direction are slightly smaller than those in X1 direction. The simulation results were further compared with published theoretical predictions and show higher values. The difference was then analyzed and a new expression for the plateau stress of honeycombs was suggested. 展开更多
关键词 finite element analysis/simulation aluminium honeycomb crushing/compression behaviour LS- DYNA
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Studies on the Compressive Mechanical Properties of Antitetrachiral Honeycombs with Different Thickness Ratios of Ligament to Cylinder
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作者 Jinshun Hu Yongshui Lin Wei Chen 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2022年第3期470-480,共11页
This paper investigated the compressive mechanical properties of antitetrachiral honeycombs with different thickness ratios of ligament to cylinder.The deformation and energy absorption performance of the structures w... This paper investigated the compressive mechanical properties of antitetrachiral honeycombs with different thickness ratios of ligament to cylinder.The deformation and energy absorption performance of the structures were characterized by the cooperation of experimental and numerical methods.First,two types(small and large thickness ratios)of antitetrachiral honeycombs were manufactured by 3D printing.Then,the deformation mode,negative Poisson’s ratio(NPR)and crushing stress of the honeycombs were obtained experimentally.After that,a finite element(FE)model was established by using ABAQUS/Explicit,and the numerical model and method were validated.Based on experimental and numerical results,the X mode,double-parallel line mode and cylinder mode were obtained in the compressive deformation of the honeycomb with a small thickness ratio.The Bi-V mode,“e”mode and Z mode were obtained in the compressive deformation of the honeycomb with a large thickness ratio.The influence of the thickness ratio of ligament to cylinder was studied,and a thickness ratio of 1.625 was the critical value for the transformation of the antitetrachiral honeycomb deformation modes. 展开更多
关键词 Antitetrachiral honeycomb Negative Poisson's ratio Thickness ratio Deformation mode Compression
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HCL Net: Deep Learning for Accurate Classification of Honeycombing Lung and Ground Glass Opacity in CT Images
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作者 Hairul Aysa Abdul Halim Sithiq Liyana Shuib +1 位作者 Muneer Ahmad Chermaine Deepa Antony 《Computers, Materials & Continua》 2026年第1期999-1023,共25页
Honeycombing Lung(HCL)is a chronic lung condition marked by advanced fibrosis,resulting in enlarged air spaces with thick fibrotic walls,which are visible on Computed Tomography(CT)scans.Differentiating between normal... Honeycombing Lung(HCL)is a chronic lung condition marked by advanced fibrosis,resulting in enlarged air spaces with thick fibrotic walls,which are visible on Computed Tomography(CT)scans.Differentiating between normal lung tissue,honeycombing lungs,and Ground Glass Opacity(GGO)in CT images is often challenging for radiologists and may lead to misinterpretations.Although earlier studies have proposed models to detect and classify HCL,many faced limitations such as high computational demands,lower accuracy,and difficulty distinguishing between HCL and GGO.CT images are highly effective for lung classification due to their high resolution,3D visualization,and sensitivity to tissue density variations.This study introduces Honeycombing Lungs Network(HCL Net),a novel classification algorithm inspired by ResNet50V2 and enhanced to overcome the shortcomings of previous approaches.HCL Net incorporates additional residual blocks,refined preprocessing techniques,and selective parameter tuning to improve classification performance.The dataset,sourced from the University Malaya Medical Centre(UMMC)and verified by expert radiologists,consists of CT images of normal,honeycombing,and GGO lungs.Experimental evaluations across five assessments demonstrated that HCL Net achieved an outstanding classification accuracy of approximately 99.97%.It also recorded strong performance in other metrics,achieving 93%precision,100%sensitivity,89%specificity,and an AUC-ROC score of 97%.Comparative analysis with baseline feature engineering methods confirmed the superior efficacy of HCL Net.The model significantly reduces misclassification,particularly between honeycombing and GGO lungs,enhancing diagnostic precision and reliability in lung image analysis. 展开更多
关键词 Deep learning honeycombing lung ground glass opacity Resnet50v2 multiclass classification
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Crashworthiness Optimization Design of Thin-Walled Tube Filled with Re-entrant Triangles Honeycombs 被引量:3
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作者 Fangwu Ma Ying Zhao +2 位作者 Guowang Wang Liang Wu Yongfeng Pu 《Automotive Innovation》 EI CSCD 2019年第1期1-13,共13页
A novel re-entrant triangles-filled tube(RTT)is proposed through decoupling structural stiffness and energy absorption.Inner re-entrant triangles are employed to satisfy energy absorption,and outer thin wall is used t... A novel re-entrant triangles-filled tube(RTT)is proposed through decoupling structural stiffness and energy absorption.Inner re-entrant triangles are employed to satisfy energy absorption,and outer thin wall is used to acquire high stiffness.This paper starts from establishment of theoretical models between geometric parameters of re-entrant triangles and relative density,equivalent elastic modulus and energy absorption characteristics,which are validated by experiments.On this basis,the optimal geometric parameters of unit cell are sought to maximize unit volume energy absorption and minimize relative density by adopting NSGA-II method.Subsequently,the cross-section of tube with optimal stiffness is obtained with targets for maximizing axial stiffness and lateral stiffness by employing static topology optimization method.To verify the proposed optimization method,RTT is analyzed and compared with positive Poisson’s ratio foam-filled tube(PFT),non-filled traditionally optimized tube(NTT)and pre-optimized square tube(PST).The results show that the novel RTT can improve stiffness and energy absorption performance simultaneously.Compared with the positive Poisson’s ratio material,re-entrant triangles honeycomb shows superior advantages in energy absorption.In comparison with the PFT,energy absorption of the RTT increases by 17.23%,and the peak crush force reduces by 5.04%.Therefore,the proposed decoupling design method demonstrates superiority in satisfying various performance requirements simultaneously. 展开更多
关键词 Thin-walled tube Re-entrant triangles honeycomb Multi-objective optimization Energy absorption Structural stiffness
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The effects of ripple amplitude on heat transfer and fluid flow of X-lattice corrugated honeycombs 被引量:2
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作者 CHEN JunJun XIE GongNan YAN HongBin 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2023年第12期3412-3421,共10页
A previous study showed that the thermal performance of the X-lattice cored corrugated honeycomb(XCCH)is better than that of most other periodic cellular materials(PCMs).To further improve the thermal performance of t... A previous study showed that the thermal performance of the X-lattice cored corrugated honeycomb(XCCH)is better than that of most other periodic cellular materials(PCMs).To further improve the thermal performance of the XCCH,the effects of different ripple amplitudes(i.e.,a=0.5,0.7 and 1.0)on the characteristics of the flow and heat transfer are numerically investigated by thorough comparisons.In terms of the flow characteristics,with the increase of ripple amplitude,the vortex interaction in the channel becomes stronger,which results in evident increase of kinetic energy of turbulence at the boundary of vortex and reduction in the turbulent kinetic energy dissipation.As far as the heat transfer is concerned,within the Reynolds number range of 3696–7436,the heat transfer increases with the increase of ripple amplitude.The overall Nusselt number of the XCCH with a=1.0 is 15.7%higher than that with a=0.5.Within the corresponding range of pumping power,the thermal performance of the XCCH with a=1.0 is up to 7%higher than that with a=0.5 at relatively higher Reynolds numbers. 展开更多
关键词 X-lattice honeycomb ripple amplitude enhanced heat transfer turbulent flow
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Thermo-fluidic characteristics of natural convection in honeycombs:The role of chimney enhancement 被引量:1
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作者 YANG XiaoHu YAN HongBin +3 位作者 WANG WenBin JIN LiWen LU TianJian ICHIMIYA Koichi 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第8期1318-1327,共10页
The natural convective heat transfer performance and thermo-fluidic characteristics of honeycombs with/without chimney extensions are numerically investigated.The present numerical simulations are validated by the pur... The natural convective heat transfer performance and thermo-fluidic characteristics of honeycombs with/without chimney extensions are numerically investigated.The present numerical simulations are validated by the purposely-designed experimental measurements on honeycombs with/without chimney.Good agreement between numerical simulation and experimental measurement is obtained.The influences of inclination angle and geometric parameters such as cell shape,streamwise and spanwise length are also numerically quantified.With the increment in inclination angle,the overall heat transfer rate decreases for the honeycombs with/without chimney.For honeycombs with the same void volume fraction but different cell shapes,there is little difference on the overall heat transfer rate.To enhance the natural convective heat transfer of honeycombs,these techniques including increasing the length of honeycomb in the streamwise/spanwise direction,increasing the thermal conductivity of hon-eycomb structure or adding a chimney extension may be helpful. 展开更多
关键词 natural convection HONEYCOMB adiabatic chimney inclination angle
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Multi-interface structure design of bamboo-based carbon/Co/CoO composite electromagnetic wave absorber based on biomimetic honeycomb-shaped superstructure 被引量:2
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作者 Yanting Wang He Han +2 位作者 Huiyang Bian Yanjun Li Zhichao Lou 《International Journal of Minerals,Metallurgy and Materials》 2025年第3期631-644,共14页
The rapid development of 5G communication technology and smart electronic and electrical equipment will inevitably lead to electromagnetic radiation pollution.Enriching heterointerface polarization relaxation through ... The rapid development of 5G communication technology and smart electronic and electrical equipment will inevitably lead to electromagnetic radiation pollution.Enriching heterointerface polarization relaxation through nanostructure design and interface modifica-tion has proven to be an effective strategy to obtain efficient electromagnetic wave absorption.Here,this work implements an innovative method that combines biomimetic honeycomb superstructure to constrain hierarchical porous heterostructure composed of Co/CoO nano-particles to improve the interfacial polarization intensity.The method effectively controlled the absorption efficiency of Co^(2+)through de-lignification modification of bamboo,and combined with the bionic carbon-based natural hierarchical porous structure to achieve uniform dispersion of nanoparticles,which is conducive to the in-depth construction of heterogeneous interfaces.In addition,the multiphase struc-ture brought about by high-temperature pyrolysis provides the best dielectric loss and impedance matching for the material.Therefore,the obtained bamboo-based Co/CoO multiphase composite showed excellent electromagnetic wave absorption performance,achieving excel-lent reflection loss(RL)of-79 dB and effective absorption band width of 4.12 GHz(6.84-10.96 GHz)at low load of 15wt%.Among them,the material’s optimal radar cross-section(RCS)reduction value can reach 31.9 dB·m^(2).This work provides a new approach to the micro-control and comprehensive optimization of macro-design of microwave absorbers,and offers new ideas for the high-value utiliza-tion of biomass materials. 展开更多
关键词 biomass honeycomb porous heterojunction structure interfacial polarization electromagnetic wave absorption
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Exploring Kitaev Physics in Honeycomb Magnets A_(3)Ni_(2)XO_(6)(A=Li,Na;X=Bi,Sb):Insights from First-Principles Calculations
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作者 Shi-Bo Zhao Jia-WanLi Yusheng Hou 《Chinese Physics Letters》 2025年第10期263-289,共27页
Magnets exhibiting the Kitaev interaction,a bond-dependent magnetic interaction in honeycomb lattices,are generally regarded as promising candidates for hosting novel phenomena like quantum spin liquid states.However,... Magnets exhibiting the Kitaev interaction,a bond-dependent magnetic interaction in honeycomb lattices,are generally regarded as promising candidates for hosting novel phenomena like quantum spin liquid states.However,realizing such magnets remains a significant challenge.Recently,some studies have suggested honeycomb magnets A_(3)Ni_(2)XO_(6)(A=Li,Na;X=Bi,Sb)with a high spin S=1 could serve as potential candidates for realizing strong Kitaev interactions.In this work,we systematically investigate their magnetic properties,with a particular emphasis on their Kitaev interactions,using first-principles calculations and Monte Carlo simulations.Our results indicate that all A_(3)Ni_(2)XO_(6)compounds are zigzag antiferromagnets,and their magnetic moments almost tend to be out of plane.We find that their dominant magnetic interactions are the nearest-neighbor ferromagnetic and third-nearest-neighbor antiferromagnetic Heisenberg interactions,while their Kitaev interactions are extremely weak.By analyzing their electronic structures and the mechanism of generating their magnetic interactions,we reveal that either artificially tuning spin-orbit coupling or applying strain cannot produce sufficient spin-orbit entangled states to realize the intriguing Kitaev interactions.Our work advances the understanding of the magnetism in A_(3)Ni_(2)XO_(6)compounds and provides insights for further exploration of Kitaev physics in honeycomb magnets. 展开更多
关键词 honeycomb latticesare kitaev interactiona honeycomb magnets magnetic properties Kitaev physics Ni XO quantum spin liquid stateshoweverrealizing first principles calculations
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Effect of sodium content on the electrochemical performance of P2-Na_(2)Ni_(2)TeO_(6)layered oxide cathode for sodium-ion batteries
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作者 Iqra Moeez Ali Hussain Umar Bhatti +4 位作者 Min-Kyung Cho Dieky Susanto Muhammad Akbar Ghulam Ali Kyung Yoon Chung 《Carbon Energy》 2025年第2期109-120,共12页
Sodium-ion batteries(SIBs)employ P2-type layered transition metal oxides as promising cathode materials,primarily due to their abundant natural reserves and environmentally friendly characteristics.However,structural ... Sodium-ion batteries(SIBs)employ P2-type layered transition metal oxides as promising cathode materials,primarily due to their abundant natural reserves and environmentally friendly characteristics.However,structural instability and complex phase transitions during electrochemical cycling pose significant challenges to their practical applications.Employing cation substitution serves as a straightforward yet effective strategy for stabilizing the structure and improving the kinetics of the active material.In this study,we introduce a Ni-rich honeycomb-layered Na_(2+x)Ni_(2)TeO_(6)(NNTO)cathode material with variable sodium content(x=0,0.03,0.05,0.10).Physicochemical characterizations reveal that excess sodium content at the atomic scale modifies the surface and suppresses phase transitions,while preserving the crystal structure.This results in enhanced cyclic performance and improved electrochemical kinetics at room temperature.Furthermore,we investigate the performance of the NNTO cathode material containing 10%excess sodium at a relatively high temperature of 60℃,where it exhibits 71.6%capacity retention compared to 60%for the pristine.Overall,our results confirm that a preconstructed surface layer(induced by excess sodium)effectively safeguards the Ni-based cathode material from surface degradation and phase transitions during the electrochemical processes,thus exhibiting superior capacity retention relative to the pristine NNTO cathode.This study of the correlation between structure and performance can potentially be applied to the commercialization of SIBs. 展开更多
关键词 honeycomb structure layered oxides sodium content sodium-ion battery structure disorder
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Synthesis and Characterization of Fe3O4 Nanoparticles by Sol-Gel Method Using Water as a Solvent
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作者 Ahmad Mustafa Usman Ali +4 位作者 Mukarama   Ali Iqbal Maria Qayyum Inam Ul Haq Fakhar Islam 《Advances in Nanoparticles》 2025年第1期1-11,共11页
Ferromagnetic Fe3O4 nanoparticles were synthesized using water as the solvent through the sol-gel method, which was selected for its cost-effectiveness, simplicity, and eco-friendly nature. The synthesized nanoparticl... Ferromagnetic Fe3O4 nanoparticles were synthesized using water as the solvent through the sol-gel method, which was selected for its cost-effectiveness, simplicity, and eco-friendly nature. The synthesized nanoparticles were characterized using a variety of techniques, including Fourier Transform Infrared (FTIR) spectroscopy, X-ray powder diffraction (XRD), Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA), and Vibrating Sample Magnetometer (VSM). These characterizations confirmed the successful formation of Fe3O4 nanoparticles. The FTIR spectra identified characteristic peaks corresponding to the functional groups present, and XRD analysis, using Scherer’s equation, determined an average crystalline size of 1.2 nm for the Fe3O4 nanoparticles. TGA results demonstrated the thermal stability of the nanoparticles, SEM imaging revealed distinct honeycomb-like structures for the nanoparticles synthesized with water as the solvent, while the VSM analysis was used to determine the magnetic behavior of the nanoparticles. 展开更多
关键词 Fe3O4 Nanoparticles Sol-Gel Synthesis Honeycomb Structures FTIR XRD SEM TGA VSM
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