Ternary blending as one of the most successful strategies has achieved continuous performance breakthroughs in organic solar cells(OSCs)over the past few years.Here,a small molecule featuring a dithieno[3,2-f:2′,3′-...Ternary blending as one of the most successful strategies has achieved continuous performance breakthroughs in organic solar cells(OSCs)over the past few years.Here,a small molecule featuring a dithieno[3,2-f:2′,3′-h]phthalimide derivative as the intermediate unit,named DTP-C8-R,is designed and utilized as the third component to construct ternary OSCs(TOSCs).The increased molecular packing of L8-BO as well as the charge transfer excitons between PM6 and DTP-C8-R lead to a very low nonradiative energy loss of 0.179 eV and a high open-circuit voltage(V_(OC))of 0.910 V in the TOSCs based on the PM6:L8-BO host blend.Moreover,the DTP-C8-R:PM6:L8-BO film(0.05:0.95:1.2,w/w)possesses better fibrous nanophase separation and the enhancedπ-πstacking ordering of the acceptors with a larger crystal coherence length compared with the PM6:L8-BO blend film,so the TOSCs present more efficient exciton dissociation,longer carrier lifetime,faster carrier transport and less charge recombination.It boosts the power conversion efficiency to 19.22%with a short-circuit current density of 27.10 mA cm^(-2).This work demonstrates that the small molecule based on a dithieno[3,2-f:2′,3′-h]phthalimide derivative as the minor component is an executable strategy to achieve high-performance TOSCs with high V_(OC).展开更多
Solubilities and properties (density, conductivity and pH value) of solutions in the quaternary system Li +,K +//CO 2- 3,B 4O 2- 7-H 2O at 288 K were experimentally studied with the isothermal equilibrium method. The ...Solubilities and properties (density, conductivity and pH value) of solutions in the quaternary system Li +,K +//CO 2- 3,B 4O 2- 7-H 2O at 288 K were experimentally studied with the isothermal equilibrium method. The phase diagram of the system consisted of two invariant points E and F, five univariant curves, and four crystallization fields that belonged to K 2CO 3·3/2H 2O,Li 2 B 4O 7·3H 2O, K 2 B 4O 7 ·4H 2O and Li 2CO 3. The composition of the solution corresponding to E was w(CO 2- 3)=2.27 %, w(B 4O 2- 7) =6.05 %, w(K + ) =4.30%,w(Li + )=0.30 % and the equilibrium solids were Li 2 B 4O 7· 3H 2O+K 2 B 4O 7·4H 2O+Li 2CO 3;The composition of the solution for F was w(CO 2- 3) =22.45%,w(B 4O 2- 7)=1.88%,w(K + )=29.96%,w(Li + )=0.03% and the equilibrium solids were K 2CO 3·3/2H 2O+ K 2 B 4O 7·4H 2O+Li 2CO 3. K 2CO 3 possesses strong salting-out effect on K 2 B 4O 7,Li 2CO 3 and Li 2 B 4O 7.展开更多
基金financially supported by the National Natural Science Foundation of China(51873177,52303252)the Natural Science Foundation of Hunan Province(2024JJ4039)+1 种基金the Advanced Photoelectricity and Supramolecular Functional Materials of the Ministry of Education(IRT-17R90)the Hunan 2011 Collaborative Innovation Centre of Chemical Engineering&Technology with Environmental Benignity and Effective Resource Utilization。
文摘Ternary blending as one of the most successful strategies has achieved continuous performance breakthroughs in organic solar cells(OSCs)over the past few years.Here,a small molecule featuring a dithieno[3,2-f:2′,3′-h]phthalimide derivative as the intermediate unit,named DTP-C8-R,is designed and utilized as the third component to construct ternary OSCs(TOSCs).The increased molecular packing of L8-BO as well as the charge transfer excitons between PM6 and DTP-C8-R lead to a very low nonradiative energy loss of 0.179 eV and a high open-circuit voltage(V_(OC))of 0.910 V in the TOSCs based on the PM6:L8-BO host blend.Moreover,the DTP-C8-R:PM6:L8-BO film(0.05:0.95:1.2,w/w)possesses better fibrous nanophase separation and the enhancedπ-πstacking ordering of the acceptors with a larger crystal coherence length compared with the PM6:L8-BO blend film,so the TOSCs present more efficient exciton dissociation,longer carrier lifetime,faster carrier transport and less charge recombination.It boosts the power conversion efficiency to 19.22%with a short-circuit current density of 27.10 mA cm^(-2).This work demonstrates that the small molecule based on a dithieno[3,2-f:2′,3′-h]phthalimide derivative as the minor component is an executable strategy to achieve high-performance TOSCs with high V_(OC).
文摘Solubilities and properties (density, conductivity and pH value) of solutions in the quaternary system Li +,K +//CO 2- 3,B 4O 2- 7-H 2O at 288 K were experimentally studied with the isothermal equilibrium method. The phase diagram of the system consisted of two invariant points E and F, five univariant curves, and four crystallization fields that belonged to K 2CO 3·3/2H 2O,Li 2 B 4O 7·3H 2O, K 2 B 4O 7 ·4H 2O and Li 2CO 3. The composition of the solution corresponding to E was w(CO 2- 3)=2.27 %, w(B 4O 2- 7) =6.05 %, w(K + ) =4.30%,w(Li + )=0.30 % and the equilibrium solids were Li 2 B 4O 7· 3H 2O+K 2 B 4O 7·4H 2O+Li 2CO 3;The composition of the solution for F was w(CO 2- 3) =22.45%,w(B 4O 2- 7)=1.88%,w(K + )=29.96%,w(Li + )=0.03% and the equilibrium solids were K 2CO 3·3/2H 2O+ K 2 B 4O 7·4H 2O+Li 2CO 3. K 2CO 3 possesses strong salting-out effect on K 2 B 4O 7,Li 2CO 3 and Li 2 B 4O 7.
