A method for locating double bond in hexadecenyl acetates has been developed by analyzing the mass spectral patterns on a fuzzy classification. The procedure was tested with the spectra of Δ~2- to Δ^(15)-isomers and...A method for locating double bond in hexadecenyl acetates has been developed by analyzing the mass spectral patterns on a fuzzy classification. The procedure was tested with the spectra of Δ~2- to Δ^(15)-isomers and the original double-bond position in these acetates was located unambiguously.展开更多
A method for the identification of the double bond positional isomers of hexadecenyl acetate has been established by analysing similarity of the mass spectra patterns on a fuzzy classification, in which the intensity ...A method for the identification of the double bond positional isomers of hexadecenyl acetate has been established by analysing similarity of the mass spectra patterns on a fuzzy classification, in which the intensity ratios of six diagnostic pairs of the predominant ions were selected as standard parameters for the characterization of the double bond position. The procedure was tested with △2 to △15-isomers of chemically unmodified hexadecenyl acetate, and the original double bond position in the acetates was located unambiguously.展开更多
文摘A method for locating double bond in hexadecenyl acetates has been developed by analyzing the mass spectral patterns on a fuzzy classification. The procedure was tested with the spectra of Δ~2- to Δ^(15)-isomers and the original double-bond position in these acetates was located unambiguously.
文摘A method for the identification of the double bond positional isomers of hexadecenyl acetate has been established by analysing similarity of the mass spectra patterns on a fuzzy classification, in which the intensity ratios of six diagnostic pairs of the predominant ions were selected as standard parameters for the characterization of the double bond position. The procedure was tested with △2 to △15-isomers of chemically unmodified hexadecenyl acetate, and the original double bond position in the acetates was located unambiguously.