The effects of BaO doping on the three-way catalytic activity of Pt-Rh catalyst and on water-gas shift were investigated. The results show that the light-off temperatures of hydrocarbon and carbon monoxide and nitroge...The effects of BaO doping on the three-way catalytic activity of Pt-Rh catalyst and on water-gas shift were investigated. The results show that the light-off temperatures of hydrocarbon and carbon monoxide and nitrogen oxides of the fresh catalysts slightly differ from those of the aged catalysts, and the catalysts containing CeO2-ZrO2-BaO have lower lightoff temperature and better catalytic activity than these containing BaO and CeO2-ZrO2 after hydrothermal aging for 5 h at 1000 ℃. The catalysts were characterized by means of the temperature-programmed reduction （TPR） in hydrogen and the temperature-programmed desorption （TPD） in oxygen. It is confirmed that the suggested route of CeO2-ZrO2-BaO by coprecipitation can improve the catalytic activity of catalysts.展开更多
The effect of BaO doping to the Pt-Rh catalysts on its three-way catalytic activity and water-gas transfer was investigated. The results show that the light-off temperatures of hydrocarbon and carbon monoxide and nitr...The effect of BaO doping to the Pt-Rh catalysts on its three-way catalytic activity and water-gas transfer was investigated. The results show that the light-off temperatures of hydrocarbon and carbon monoxide and nitrogen oxides have little difference in the fresh catalysts. But after the hydrothermal-aged 5 h at 1000 ℃, the catalysts containing CeO2-ZrO2-BaO has lower light-off temperature and better catalytic activity than the catalysts containing BaO and CeO2-ZrO2,展开更多
As a new material to be used widely in catalytic field, γ-Mo<sub>2</sub>N with high specific surface area(usually, S<sub>BET</sub>】100 m<sup>2</sup>·g<sup>-1</sup>...As a new material to be used widely in catalytic field, γ-Mo<sub>2</sub>N with high specific surface area(usually, S<sub>BET</sub>】100 m<sup>2</sup>·g<sup>-1</sup> has recently aroused much attention. Its catalytic activities re-semble those of noble metals （Rh, Pd and Pt） in hydrogenation of hydrocarbon. Especially,it has some marvelous characteristics for deep hydrodesulfurization （HDS）, hydrodeni-展开更多
基金Project supported by the National Natural Science Foundation of China (20273043) the National Nature Science KeyFoundation of China (20333030)
文摘The effects of BaO doping on the three-way catalytic activity of Pt-Rh catalyst and on water-gas shift were investigated. The results show that the light-off temperatures of hydrocarbon and carbon monoxide and nitrogen oxides of the fresh catalysts slightly differ from those of the aged catalysts, and the catalysts containing CeO2-ZrO2-BaO have lower lightoff temperature and better catalytic activity than these containing BaO and CeO2-ZrO2 after hydrothermal aging for 5 h at 1000 ℃. The catalysts were characterized by means of the temperature-programmed reduction （TPR） in hydrogen and the temperature-programmed desorption （TPD） in oxygen. It is confirmed that the suggested route of CeO2-ZrO2-BaO by coprecipitation can improve the catalytic activity of catalysts.
文摘The effect of BaO doping to the Pt-Rh catalysts on its three-way catalytic activity and water-gas transfer was investigated. The results show that the light-off temperatures of hydrocarbon and carbon monoxide and nitrogen oxides have little difference in the fresh catalysts. But after the hydrothermal-aged 5 h at 1000 ℃, the catalysts containing CeO2-ZrO2-BaO has lower light-off temperature and better catalytic activity than the catalysts containing BaO and CeO2-ZrO2,
文摘As a new material to be used widely in catalytic field, γ-Mo<sub>2</sub>N with high specific surface area(usually, S<sub>BET</sub>】100 m<sup>2</sup>·g<sup>-1</sup> has recently aroused much attention. Its catalytic activities re-semble those of noble metals （Rh, Pd and Pt） in hydrogenation of hydrocarbon. Especially,it has some marvelous characteristics for deep hydrodesulfurization （HDS）, hydrodeni-
