When discharge faults occur in dry air switchgear,the air decomposes to produce diverse gases,with NO_(2) reaching the highest levels.Detecting the NO_(2) level can reflect the operation status of the equipment.This p...When discharge faults occur in dry air switchgear,the air decomposes to produce diverse gases,with NO_(2) reaching the highest levels.Detecting the NO_(2) level can reflect the operation status of the equipment.This paper proposes to combine ZnO cluster with MoS_(2) to improve the gassensitive properties of the monolayer.Based on the Density Functional Theory(DFT),the effect of(ZnO)n size on the behavior of MoS_(2 )is considered.Key parameters such as adsorption energy and band gap of(ZnO)n-MoS_(2)/NO_(2) system were calculated.The ZnO-MoS_(2) heterojunction was successfully synthesized by a hydrothermal method.The gas sensor exhibits a remarkable response and a fast response-recovery time to 100 ppm NO_(2).In addition,it demonstrates excellent selectivity,long-term stability and a low detection limit.This work confirms the potential of the ZnO-MoS_(2) composite structure as a highly effective gas sensor for NO_(2) detection,which provides valuable theoretical and experimental insights for fault detection in dry air switchgear.展开更多
建立了一种在温和条件下,用可见光催化合成一系列3,4-二氢异喹啉-1(2H)-酮及其衍生物的方法。该方法在室温条件下,以2-烯丙基-N-甲氧基苯甲酰胺为模板底物,以碘化钾作为光催化剂,25 W 460 nm的蓝色LED灯照射下,合成一系列3,4-二氢异喹啉...建立了一种在温和条件下,用可见光催化合成一系列3,4-二氢异喹啉-1(2H)-酮及其衍生物的方法。该方法在室温条件下,以2-烯丙基-N-甲氧基苯甲酰胺为模板底物,以碘化钾作为光催化剂,25 W 460 nm的蓝色LED灯照射下,合成一系列3,4-二氢异喹啉-1(2H)-酮衍生物,最高产率可达到83%。该合成路径具有底物适用范围广、经济实用等特点,为3,4-二氢异喹啉-1(2H)-酮衍生物合成提供了一种经济简便的方法。展开更多
基金the financial support of National Natural Science Foundation of China(Nos.52207175 and 52407178)。
文摘When discharge faults occur in dry air switchgear,the air decomposes to produce diverse gases,with NO_(2) reaching the highest levels.Detecting the NO_(2) level can reflect the operation status of the equipment.This paper proposes to combine ZnO cluster with MoS_(2) to improve the gassensitive properties of the monolayer.Based on the Density Functional Theory(DFT),the effect of(ZnO)n size on the behavior of MoS_(2 )is considered.Key parameters such as adsorption energy and band gap of(ZnO)n-MoS_(2)/NO_(2) system were calculated.The ZnO-MoS_(2) heterojunction was successfully synthesized by a hydrothermal method.The gas sensor exhibits a remarkable response and a fast response-recovery time to 100 ppm NO_(2).In addition,it demonstrates excellent selectivity,long-term stability and a low detection limit.This work confirms the potential of the ZnO-MoS_(2) composite structure as a highly effective gas sensor for NO_(2) detection,which provides valuable theoretical and experimental insights for fault detection in dry air switchgear.
文摘建立了一种在温和条件下,用可见光催化合成一系列3,4-二氢异喹啉-1(2H)-酮及其衍生物的方法。该方法在室温条件下,以2-烯丙基-N-甲氧基苯甲酰胺为模板底物,以碘化钾作为光催化剂,25 W 460 nm的蓝色LED灯照射下,合成一系列3,4-二氢异喹啉-1(2H)-酮衍生物,最高产率可达到83%。该合成路径具有底物适用范围广、经济实用等特点,为3,4-二氢异喹啉-1(2H)-酮衍生物合成提供了一种经济简便的方法。
