Polybutene-1(PB-1) is a semi-crystalline polymer with excellent mechanical properties. However, its practical application is significantly hindered by the slow Form Ⅱ-Ⅰ transition, which can take up to several days ...Polybutene-1(PB-1) is a semi-crystalline polymer with excellent mechanical properties. However, its practical application is significantly hindered by the slow Form Ⅱ-Ⅰ transition, which can take up to several days to complete. While prior research established that long-chain branching(LCB) structures synthesized via ω-alkenylmethyldichlorosilane copolymerization-hydrolysis(ACH) chemistry markedly accelerate this transition, this work demonstrates that H-shaped LCB structures constructed through copolymerization with 1,9-decadiene exhibit the capability to facilitate Form Ⅱ-Ⅰ transition in most systems evaluated herein. However, low branching efficiency concurrently generates extended alkyl pendant chains, which impose pronounced steric-hindrance-driven suppression on the transition kinetics, thereby substantially diminishing the net acceleration effect of the LCB structures, even resulting in a net retardation effect in certain systems. Notably, a significant synergistic acceleration effect emerged between the H-shaped LCB structures and propylene comonomer units. These findings confirm that the H-shaped LCB structures play a role in promoting the Form II-I transformation process, which is independent of the synthetic pathways, thereby providing more strategies for addressing the long-standing processing problems of PB-1.展开更多
Based on the introductions of a type of diaphragm-through connection between concrete-filled square steel tubular columns (CFSSTCs) and H-shaped steel beams,a finite element model of the connection is developed and us...Based on the introductions of a type of diaphragm-through connection between concrete-filled square steel tubular columns (CFSSTCs) and H-shaped steel beams,a finite element model of the connection is developed and used to investigate the seismic behavior of the connection.The results of the finite element model are validated by a set of cyclic loading tests.The cyclic loading tests and the finite element analyses indicate that the failure mode of the suggested connections is plastic hinge at the beam with inelastic rotation angle exceeding 0.04 rad.The suggested connections have sufficient strength,plastic deformation and energy dissipation capacity to be used in composite moment frames as beam-to-column rigid connections.展开更多
Despite the fact that some progress has been made in the self-assembly of H-shaped polymers, the corresponding self-assemblies that respond to external stimulus and are further utilized to adjust the release of drugs ...Despite the fact that some progress has been made in the self-assembly of H-shaped polymers, the corresponding self-assemblies that respond to external stimulus and are further utilized to adjust the release of drugs are still deficient. The stimuli-responsive segments with amphiphilic H-shaped structure are generally expected to enhance the controllability of self-assembly process. The synthesis and self-assembly behavior of thermo-responsive amphiphilic H-shaped polymers with poly（ethylene glycol） （PEG）, polytetrahydrofuran （PTHF） and poly（N-isopropyl acrylamide） （PNIPAM） as building blocks are reported in this paper. The inner architecture structure and size of complex micelles formed by H-shaped self-assemblies were effectively adjusted when the solution temperature was increased above the lower critical solution temperature of PNIPAM segments. Furthermore, it was found that the architecture of self-assemblies underwent a transition from the complex micelles based on primary micelles with hybrid PEG/PNIPAM shells to large complex micelles based on primary micelles with hybrid PTHF/PNIPAM cores and PEG shells during the thermal-induced self-assembly process. The adjustable release rate ofdoxorubicin （DOX） from the DOX-loaded complex micelles and basic cell experiments further proved the feasibility of these self-assemblies as the thermal-responsive drug delivery system.展开更多
A series of H-shaped （PS）2PEG（PS）2 block copolymers with different PS chain lengths were prepared. The influence of different confinements active on the crystallization and self-nucleation （SN） behavior of the P...A series of H-shaped （PS）2PEG（PS）2 block copolymers with different PS chain lengths were prepared. The influence of different confinements active on the crystallization and self-nucleation （SN） behavior of the PEG blocks was investigated by differential scanning calorimetry （DSC）. When the content of the crystalline block was high, a classical SN behavior was obtained. The block copolymer with PEG content of 49% （by weight） showed a classical SN behavior with a narrow self-nucleation domain and had bimodal crystallization exotherms. When the PEG dispersed as separated microdomains in the block copolymer, the self-nucleation domain disappeared and only annealing was observed.展开更多
As one of the main load-carrying components of cable-stayed bridges,bridge towers are typically required to remain elastic even when subjected to severe ground motions with a 2%-3%probability of exceedance in 50 years...As one of the main load-carrying components of cable-stayed bridges,bridge towers are typically required to remain elastic even when subjected to severe ground motions with a 2%-3%probability of exceedance in 50 years.To fulfill this special requirement imposed by current seismic design codes,reinforcement ratios in the bridge towers have to be kept significantly higher than if limited ductility behavior of the tower is allowed.In addition,since the foundation capacity is closely related to the moment and shear capacities of the bridge tower,a large increase in bridge construction cost for elastically designed cable-stayed bridge is inevitable.To further investigate the possibility of limited ductility bridge tower design strategies,a new 1/20-scale cable-stayed bridge model with H-shaped bridge towers designed according to strong strut-weak tower column design was tested.The shake table experimental results are compared with a previous strong tower column-weak strut designed full bridge model.A comparison of the results show that ductility design with plastic hinges located on tower columns,i.e.,strong strut-weak tower column design,is another effective seismic design strategy that results in only small residual displacement at the top of the tower column,even under very severe earthquake excitations.展开更多
304L H-shaped stainless steel is used as the support frame of the passive residual heat removal heat exchanger(PRHR HX) in a nuclear fission reactor. The extrusion process is adopted to manufacture the 304L H-shaped s...304L H-shaped stainless steel is used as the support frame of the passive residual heat removal heat exchanger(PRHR HX) in a nuclear fission reactor. The extrusion process is adopted to manufacture the 304L H-shaped stainless steel. Finite element method simulation is herein used to analyze metal flow characteristics, optimize the extrusion die, and predict the extrusion force at different temperatures and speeds. A Φ400-mm container and Φ388-mm forging billet are selected, and the 304L H-shaped stainless steel is successfully manufactured using a Germany SMS 60 MN horizontal extruder. The mechanical properties and microstructure of the manufactured 304L H-shaped stainless steel meet the requirements of the PRHR HX, and the surfaces of the product pass the dye penetration test. The H-shaped stainless steels are used in Haiyang nuclear power plant in Shandong Province.展开更多
Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, ...Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH,suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers.展开更多
Novel and effective H-shaped chromophores were doped into polymethyl methacrylate （PMMA） to form vip-host polymer thin films. The measurement results of Maker fringe method show that the polymer thin films contain...Novel and effective H-shaped chromophores were doped into polymethyl methacrylate （PMMA） to form vip-host polymer thin films. The measurement results of Maker fringe method show that the polymer thin films containing the H-shaped chromophores as a vip exhibit high second harmonic coefficients （d33） compared with other two-dimensional chromophores.展开更多
This study simulates natural convection flow resulting from heat partitions in an H-shaped enclosure filled with a nanofluid using an incompressible smoothed particle hydrodynamics(ISPH)method.The right area of the H-...This study simulates natural convection flow resulting from heat partitions in an H-shaped enclosure filled with a nanofluid using an incompressible smoothed particle hydrodynamics(ISPH)method.The right area of the H-shaped enclosure is saturated with non-Darcy porous media.The center variable partitions of the H-shaped enclosure walls are kept at a high-temperature Th.The left and right walls of the H-shaped enclosure are positioned at a low temperature Tc and the other walls are adiabatic.In ISPH method,the source term in pressure Poisson equation(PPE)is modified.The influences of the controlling parameters on the temperature distributions,the velocity field and average Nusselt number are discussed.The performed simulations proofed that the length of the heated partitions augments the velocity field and temperature distributions in an H-shaped enclosure.Rayleigh number rises the fluid velocity and heat transfer in an H-shaped enclosure.The porous layer on the right side of the H-shaped enclosure at a lower Darcy parameter causes a high resistance force for the fluid flow and heat transfer characteristic inside an H-shaped enclosure.Added nanoparticles reduces the velocity field and enhances the heat transfer inside an H-shaped enclosure.展开更多
A type of hollow cylinder joints connected with H-shaped beams is proposed for spatial structures. Based on von Mises yield criterion and perfect elasto-plasticity model, a series of finite element models of the joint...A type of hollow cylinder joints connected with H-shaped beams is proposed for spatial structures. Based on von Mises yield criterion and perfect elasto-plasticity model, a series of finite element models of the joints is established, in which the effect of geometric nonlinearity is taken into account. Then mechanical behavior and load-carrying capacity of the joints were investigated, which were subjected to axial load, in- and out-plane bending moments, and their combinations. The results show that the ultimate loads of the joints are determined by the maximum displacement. Furthermore, the case of one joint connected with multiple beams was discussed. Experiments on a set of typical full-scale joints were conducted to understand the structural behavior and the failure mechanism of joint, and also to validate the finite element models. Finally, the practical calculation method was established through finite elements analysis (FEA) results and numerical fitting. The results show that the joints are more ductile and materially economical than welded hollow spherical joints, and the practical calculation method can provide a reference for direct design and the revision of relevant design codes.展开更多
Conventional slot microstrip antenna is analyzed,an h-shaped multi-frequency and miniaturization slot microstrip antenna is proposed.Numerical simulation is performed for the characteristics of the antenna with the so...Conventional slot microstrip antenna is analyzed,an h-shaped multi-frequency and miniaturization slot microstrip antenna is proposed.Numerical simulation is performed for the characteristics of the antenna with the software HFSS11.0,which is a kind of simulation software based on Finite Element Method,the simulation results shown that the antenna operated at 2.26~2.42GHz,2.67~2.82GHz,4.28~4.39GHz and 5.76~5.89GHz when the return loss S11<-10dB,the size reduced compare to general microstrip antenna,demonstrated the effectiveness of the design scheme.The antenna structure is simple and easily to be implemented,met the wireless LAN 802.11a/b/g/n mobile terminal antenna miniaturization and multi-band requirements.展开更多
Analogizing with the definition of thermal efficiency of a heat exchanger,the entransy dissipation efficiency of a heat exchanger is defined as the ratio of dimensionless entransy dissipation rate to dimensionless pum...Analogizing with the definition of thermal efficiency of a heat exchanger,the entransy dissipation efficiency of a heat exchanger is defined as the ratio of dimensionless entransy dissipation rate to dimensionless pumping power of the heat exchanger.For the constraints of the total tube volume and total tube surface area of the heat exchanger,the constructal optimization of an H-shaped multi-scale heat exchanger is carried out by taking entransy dissipation efficiency maximization as optimization objective,and the optimal construct of the H-shaped multi-scale heat exchanger with maximum entransy dissipation efficiency is obtained.The results show that for the specified total tube volume of the heat exchanger,the optimal constructs of the first order T-shaped heat exchanger based on the maximizations of the thermal efficiency and entransy dissipation efficiency are obviously different with the lower mass flow rates of the cold and hot fluids.For the H-shaped multi-scale heat exchanger,the entransy dissipation efficiency decreases with the increase in mass flow rate when the heat exchanger order is fixed;for the specified dimensionless mass flow rate M(M<32.9),the entransy dissipation efficiency decreases with the increase in the heat exchanger order.The performance of the multi-scale heat exchanger is obviously improved compared with that of the single-scale heat exchanger.Moreover,the heat exchanger subjected to the total tube surface area constraint is also discussed in the paper.The optimization results obtained in this paper can provide a great compromise between the heat transfer and flow performances of the heat exchanger,provide some guidelines for the optimal designs of heat exchangers,and also enrich the connotation of entransy theory.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 52173013 and 52373015)。
文摘Polybutene-1(PB-1) is a semi-crystalline polymer with excellent mechanical properties. However, its practical application is significantly hindered by the slow Form Ⅱ-Ⅰ transition, which can take up to several days to complete. While prior research established that long-chain branching(LCB) structures synthesized via ω-alkenylmethyldichlorosilane copolymerization-hydrolysis(ACH) chemistry markedly accelerate this transition, this work demonstrates that H-shaped LCB structures constructed through copolymerization with 1,9-decadiene exhibit the capability to facilitate Form Ⅱ-Ⅰ transition in most systems evaluated herein. However, low branching efficiency concurrently generates extended alkyl pendant chains, which impose pronounced steric-hindrance-driven suppression on the transition kinetics, thereby substantially diminishing the net acceleration effect of the LCB structures, even resulting in a net retardation effect in certain systems. Notably, a significant synergistic acceleration effect emerged between the H-shaped LCB structures and propylene comonomer units. These findings confirm that the H-shaped LCB structures play a role in promoting the Form II-I transformation process, which is independent of the synthetic pathways, thereby providing more strategies for addressing the long-standing processing problems of PB-1.
基金Supported by National Natural Science Foundation of China(No.51268054)Natural Science Foundation of Tianjin(No.13JCQNJC07300)the foundation of Key Laboratory of Coast Civil Structure Safety(Tianjin University),Ministry of Education of China(No.2011-1)
文摘Based on the introductions of a type of diaphragm-through connection between concrete-filled square steel tubular columns (CFSSTCs) and H-shaped steel beams,a finite element model of the connection is developed and used to investigate the seismic behavior of the connection.The results of the finite element model are validated by a set of cyclic loading tests.The cyclic loading tests and the finite element analyses indicate that the failure mode of the suggested connections is plastic hinge at the beam with inelastic rotation angle exceeding 0.04 rad.The suggested connections have sufficient strength,plastic deformation and energy dissipation capacity to be used in composite moment frames as beam-to-column rigid connections.
基金financially supported by the National Natural Science Foundation of China(No.21674086)Scientific Research Program Funded by Shaanxi Provincial Education Department(No.17JK0103)
文摘Despite the fact that some progress has been made in the self-assembly of H-shaped polymers, the corresponding self-assemblies that respond to external stimulus and are further utilized to adjust the release of drugs are still deficient. The stimuli-responsive segments with amphiphilic H-shaped structure are generally expected to enhance the controllability of self-assembly process. The synthesis and self-assembly behavior of thermo-responsive amphiphilic H-shaped polymers with poly（ethylene glycol） （PEG）, polytetrahydrofuran （PTHF） and poly（N-isopropyl acrylamide） （PNIPAM） as building blocks are reported in this paper. The inner architecture structure and size of complex micelles formed by H-shaped self-assemblies were effectively adjusted when the solution temperature was increased above the lower critical solution temperature of PNIPAM segments. Furthermore, it was found that the architecture of self-assemblies underwent a transition from the complex micelles based on primary micelles with hybrid PEG/PNIPAM shells to large complex micelles based on primary micelles with hybrid PTHF/PNIPAM cores and PEG shells during the thermal-induced self-assembly process. The adjustable release rate ofdoxorubicin （DOX） from the DOX-loaded complex micelles and basic cell experiments further proved the feasibility of these self-assemblies as the thermal-responsive drug delivery system.
基金supported by the National Natural Science Foundation of China(No.50503022)Programs and the Fund for Creative Research Groups(No.50621302)
文摘A series of H-shaped （PS）2PEG（PS）2 block copolymers with different PS chain lengths were prepared. The influence of different confinements active on the crystallization and self-nucleation （SN） behavior of the PEG blocks was investigated by differential scanning calorimetry （DSC）. When the content of the crystalline block was high, a classical SN behavior was obtained. The block copolymer with PEG content of 49% （by weight） showed a classical SN behavior with a narrow self-nucleation domain and had bimodal crystallization exotherms. When the PEG dispersed as separated microdomains in the block copolymer, the self-nucleation domain disappeared and only annealing was observed.
基金National Key Research and Development Plan,China under Grant No.2017YFC1500702the National Natural Science Foundation of China under Grant No.51478338。
文摘As one of the main load-carrying components of cable-stayed bridges,bridge towers are typically required to remain elastic even when subjected to severe ground motions with a 2%-3%probability of exceedance in 50 years.To fulfill this special requirement imposed by current seismic design codes,reinforcement ratios in the bridge towers have to be kept significantly higher than if limited ductility behavior of the tower is allowed.In addition,since the foundation capacity is closely related to the moment and shear capacities of the bridge tower,a large increase in bridge construction cost for elastically designed cable-stayed bridge is inevitable.To further investigate the possibility of limited ductility bridge tower design strategies,a new 1/20-scale cable-stayed bridge model with H-shaped bridge towers designed according to strong strut-weak tower column design was tested.The shake table experimental results are compared with a previous strong tower column-weak strut designed full bridge model.A comparison of the results show that ductility design with plastic hinges located on tower columns,i.e.,strong strut-weak tower column design,is another effective seismic design strategy that results in only small residual displacement at the top of the tower column,even under very severe earthquake excitations.
基金supported by the State Key Laboratory for Mechanical Behavior of Materials(No.20171909)
文摘304L H-shaped stainless steel is used as the support frame of the passive residual heat removal heat exchanger(PRHR HX) in a nuclear fission reactor. The extrusion process is adopted to manufacture the 304L H-shaped stainless steel. Finite element method simulation is herein used to analyze metal flow characteristics, optimize the extrusion die, and predict the extrusion force at different temperatures and speeds. A Φ400-mm container and Φ388-mm forging billet are selected, and the 304L H-shaped stainless steel is successfully manufactured using a Germany SMS 60 MN horizontal extruder. The mechanical properties and microstructure of the manufactured 304L H-shaped stainless steel meet the requirements of the PRHR HX, and the surfaces of the product pass the dye penetration test. The H-shaped stainless steels are used in Haiyang nuclear power plant in Shandong Province.
基金financially supported by the National Natural Science Foundation of China (Nos. 21504047, 21774061)the Six Peak Talents Foundation of Jiangsu Province (No. XCL-CXTD009)+1 种基金Natural Science Foundation of Jiangsu Province (No. BK20150834)Synergetic Innovation Center for Organic Electronics and Information Displays
文摘Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH,suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers.
基金supported by a Start-up Grant from Southeast University to Dr Chao-Zhi Zhang and the Science Foundation of Jiangsu Province of China(No.BK2004085).
文摘Novel and effective H-shaped chromophores were doped into polymethyl methacrylate （PMMA） to form vip-host polymer thin films. The measurement results of Maker fringe method show that the polymer thin films containing the H-shaped chromophores as a vip exhibit high second harmonic coefficients （d33） compared with other two-dimensional chromophores.
基金The authors would like to extend their appreciations to the Deanship of Scientific Research at King Khalid University,Abha,Saudi Arabia,for funding this work through the Research Group Project under Grant Number(R.G.P 2/70/41).
文摘This study simulates natural convection flow resulting from heat partitions in an H-shaped enclosure filled with a nanofluid using an incompressible smoothed particle hydrodynamics(ISPH)method.The right area of the H-shaped enclosure is saturated with non-Darcy porous media.The center variable partitions of the H-shaped enclosure walls are kept at a high-temperature Th.The left and right walls of the H-shaped enclosure are positioned at a low temperature Tc and the other walls are adiabatic.In ISPH method,the source term in pressure Poisson equation(PPE)is modified.The influences of the controlling parameters on the temperature distributions,the velocity field and average Nusselt number are discussed.The performed simulations proofed that the length of the heated partitions augments the velocity field and temperature distributions in an H-shaped enclosure.Rayleigh number rises the fluid velocity and heat transfer in an H-shaped enclosure.The porous layer on the right side of the H-shaped enclosure at a lower Darcy parameter causes a high resistance force for the fluid flow and heat transfer characteristic inside an H-shaped enclosure.Added nanoparticles reduces the velocity field and enhances the heat transfer inside an H-shaped enclosure.
基金Project supported by the National Natural Science Foundation of China (No. 51178414)the Science Foundation of Zhejiang Province (No. Y1110438), China
文摘A type of hollow cylinder joints connected with H-shaped beams is proposed for spatial structures. Based on von Mises yield criterion and perfect elasto-plasticity model, a series of finite element models of the joints is established, in which the effect of geometric nonlinearity is taken into account. Then mechanical behavior and load-carrying capacity of the joints were investigated, which were subjected to axial load, in- and out-plane bending moments, and their combinations. The results show that the ultimate loads of the joints are determined by the maximum displacement. Furthermore, the case of one joint connected with multiple beams was discussed. Experiments on a set of typical full-scale joints were conducted to understand the structural behavior and the failure mechanism of joint, and also to validate the finite element models. Finally, the practical calculation method was established through finite elements analysis (FEA) results and numerical fitting. The results show that the joints are more ductile and materially economical than welded hollow spherical joints, and the practical calculation method can provide a reference for direct design and the revision of relevant design codes.
基金supported by the Science Technology of The Chongqing Education Commission(KJ100512)the Natural Science Foundation of Chongqing province of China(CSTC 2010BB2412)
文摘Conventional slot microstrip antenna is analyzed,an h-shaped multi-frequency and miniaturization slot microstrip antenna is proposed.Numerical simulation is performed for the characteristics of the antenna with the software HFSS11.0,which is a kind of simulation software based on Finite Element Method,the simulation results shown that the antenna operated at 2.26~2.42GHz,2.67~2.82GHz,4.28~4.39GHz and 5.76~5.89GHz when the return loss S11<-10dB,the size reduced compare to general microstrip antenna,demonstrated the effectiveness of the design scheme.The antenna structure is simple and easily to be implemented,met the wireless LAN 802.11a/b/g/n mobile terminal antenna miniaturization and multi-band requirements.
基金supported by the National Natural Science Foundation of China (Grant No. 51176203)the Natural Science Foundation for Youngsters of Naval University of Engineering (Grant No. HGDQNJJ11008)
文摘Analogizing with the definition of thermal efficiency of a heat exchanger,the entransy dissipation efficiency of a heat exchanger is defined as the ratio of dimensionless entransy dissipation rate to dimensionless pumping power of the heat exchanger.For the constraints of the total tube volume and total tube surface area of the heat exchanger,the constructal optimization of an H-shaped multi-scale heat exchanger is carried out by taking entransy dissipation efficiency maximization as optimization objective,and the optimal construct of the H-shaped multi-scale heat exchanger with maximum entransy dissipation efficiency is obtained.The results show that for the specified total tube volume of the heat exchanger,the optimal constructs of the first order T-shaped heat exchanger based on the maximizations of the thermal efficiency and entransy dissipation efficiency are obviously different with the lower mass flow rates of the cold and hot fluids.For the H-shaped multi-scale heat exchanger,the entransy dissipation efficiency decreases with the increase in mass flow rate when the heat exchanger order is fixed;for the specified dimensionless mass flow rate M(M<32.9),the entransy dissipation efficiency decreases with the increase in the heat exchanger order.The performance of the multi-scale heat exchanger is obviously improved compared with that of the single-scale heat exchanger.Moreover,the heat exchanger subjected to the total tube surface area constraint is also discussed in the paper.The optimization results obtained in this paper can provide a great compromise between the heat transfer and flow performances of the heat exchanger,provide some guidelines for the optimal designs of heat exchangers,and also enrich the connotation of entransy theory.
