Given the current global energy and environmental issues resulting from the fast pace of industrialization,the discovery of new functional materials has become increasingly imperative in order to advance science and t...Given the current global energy and environmental issues resulting from the fast pace of industrialization,the discovery of new functional materials has become increasingly imperative in order to advance science and technology and address the associated challenges.The boom in metal–organic frameworks(MOFs)and MOF-derived materials in recent years has stimulated profound interest in exploring their structures and applications.The preparation,characterization,and processing of MOF materials are the basis of their full engagement in industrial implementation.With intensive research in these topics,it is time to promote the practical utilization of MOFs on an industrial scale,such as for green chemical engineering,by taking advantage of their superior functions.Many famous MOFs have already demonstrated superiority over traditional materials in solving real-world problems.This review starts with the basic concept of MOF chemistry and ends with a discussion of the industrial production and exploitation of MOFs in several fields.Its goal is to provide a general scope of application to inspire MOF researchers to convert their focus on academic research to one on practical applications.After the obstacles of cost,scale-up preparation,processability,and stability have been overcome,MOFs and MOF-based devices will gradually enter the factory,become a part of our daily lives,and help to create a future based on green production and green living.展开更多
【目的】探讨我国英文科技期刊提升国际影响力的举措,为我国科技期刊特别是新创英文科技期刊提供一些思路和借鉴。【方法】以新创期刊Green Chemical Engineering(《绿色化学工程(英文)》,以下简称GreenChE)为例,总结GreenChE在国际化...【目的】探讨我国英文科技期刊提升国际影响力的举措,为我国科技期刊特别是新创英文科技期刊提供一些思路和借鉴。【方法】以新创期刊Green Chemical Engineering(《绿色化学工程(英文)》,以下简称GreenChE)为例,总结GreenChE在国际化发展过程中的实践和举措,重点从人才队伍、稿件质量、多维度传播等方面进行探索讨论。【结果】从筹备至今,经过近两年的探索发展,GreenChE已取得一定的建设成效,学术质量与国际影响力逐步提升,先后被DOAJ、Scopus、CSCD等数据库收录。【结论】新创英文科技期刊在筹办与发展过程中会面临很多困难与挑战,在借鉴成功办刊经验的基础上,结合GreenChE的实际,进一步探索出设置编委分类名单、打造期刊品牌效应、细化邮件推送策略等特色举措,从而实现新创期刊国际影响力的快速提升。展开更多
In order to move towards sustainable development, the discovery of energy-efficient and environmentally friendly materials has become increasingly imperative. Covalent organic frameworks(COFs) as emerging designable c...In order to move towards sustainable development, the discovery of energy-efficient and environmentally friendly materials has become increasingly imperative. Covalent organic frameworks(COFs) as emerging designable crystalline porous materials have captured increasing attention for a wide array of clean-energy and environmental applications, attributed to their attractive advantages of low density, high surface area, adjustable and periodic pores, and functional skeletons. This review attempts to highlight the key advancements made in the green synthesis of COFs, processing of COFs, energy and environment-related applications, including gas storage, water treatment, the separation of gas mixture and organic molecules, catalysis, supercapacitors, fuel cell, and rechargeable batteries. Finally, a perspective regarding the remaining challenges and future directions on the synthesis and promising application for green chemical engineering of COFs has also been presented based on current achievements.展开更多
The microbubble and microinterface play key roles in the development and progress of the technology in the field of chemical engineering,which has attracted broad attention from the scientific and industrial community...The microbubble and microinterface play key roles in the development and progress of the technology in the field of chemical engineering,which has attracted broad attention from the scientific and industrial community.Recently,Zhang et al.published a book about microinterfacial mass transfer intensification technology,where they systematically introduced scientific essence,reaction mechanism,equipment structure,and influence law of multiphase reaction process strengthened by microinterface.I believe this book can promote the technological innovation of microbubble-related processes,and also the development of the green chemical industry!展开更多
The preparation of Nd(OH)3 powder by the direct hydration method using Nd2O3 as a raw material was studied,and the effects of stirring mode,H2O and Nd2O3 molar ratio,stirring rate,and reaction time on temperature chan...The preparation of Nd(OH)3 powder by the direct hydration method using Nd2O3 as a raw material was studied,and the effects of stirring mode,H2O and Nd2O3 molar ratio,stirring rate,and reaction time on temperature change and conversion rate in a hydration system were analyzed.The reasonable process conditions for the direct hydration of Nd(OH)3 by Nd2O3 were then determined.Process,morphology,and structure were considered in the preparation of neodymium hydroxide powder,and its composition was investigated by X-ray powder diffraction,scanning electron microscopy,laser particle size analysis,thermogravimetric differential thermal analysis,and chemical analysis.It has been proved that the process is simple and feasible,in line with the concept of modern green chemistry,and the products also meet the market requirements.展开更多
With the continuous development of the chemical industry,the concept of advocating green development has become increasingly popular.Glycolic acid(GA),serving as the monomer for biodegradable plastic polyglycolic acid...With the continuous development of the chemical industry,the concept of advocating green development has become increasingly popular.Glycolic acid(GA),serving as the monomer for biodegradable plastic polyglycolic acid,plays a crucial role in combating plastic pollution and fostering an eco-friendly society.The selective oxidation of ethylene glycol(EG)to produce GA represents a novel green production technology.Controlling reaction parameters to achieve multi-objective optimization of product distribution and direct CO_(2)emissions is crucial for scaling up the process.With the advent of the big data era,the integration of the chemical industry with artificial intelligence to achieve engineering scale-up is an important trend.This study proposes a neural network model for production prediction and optimization.The model is trained using experimental data,reaction mechanism data,and physical information,enabling rapid prediction of GA production.After validating with 40%of experimental data and 16%of reaction mechanism data,the model's prediction error was within±5%,and the linear correlation coefficient R^(2)between the predicted values and actual values was 0.998.Furthermore,this study integrated a multi-objective optimization algorithm based on the model,enabling surrogate optimization of reaction parameters during production.After optimization,the direct CO_(2)emissions were reduced by over 99%and overall greenhouse gas emissions were reduced by 4.6%.The research paradigm proposed in this research can offer guidance and technical support for the optimized operation of EG selective oxidation to GA.展开更多
基金We acknowledge financial support from the National Natural Science Foundation of China(51621003,21771012,and 22038001)the Science&Technology Project of Beijing Municipal Education Committee(KZ201810005004).
文摘Given the current global energy and environmental issues resulting from the fast pace of industrialization,the discovery of new functional materials has become increasingly imperative in order to advance science and technology and address the associated challenges.The boom in metal–organic frameworks(MOFs)and MOF-derived materials in recent years has stimulated profound interest in exploring their structures and applications.The preparation,characterization,and processing of MOF materials are the basis of their full engagement in industrial implementation.With intensive research in these topics,it is time to promote the practical utilization of MOFs on an industrial scale,such as for green chemical engineering,by taking advantage of their superior functions.Many famous MOFs have already demonstrated superiority over traditional materials in solving real-world problems.This review starts with the basic concept of MOF chemistry and ends with a discussion of the industrial production and exploitation of MOFs in several fields.Its goal is to provide a general scope of application to inspire MOF researchers to convert their focus on academic research to one on practical applications.After the obstacles of cost,scale-up preparation,processability,and stability have been overcome,MOFs and MOF-based devices will gradually enter the factory,become a part of our daily lives,and help to create a future based on green production and green living.
文摘【目的】探讨我国英文科技期刊提升国际影响力的举措,为我国科技期刊特别是新创英文科技期刊提供一些思路和借鉴。【方法】以新创期刊Green Chemical Engineering(《绿色化学工程(英文)》,以下简称GreenChE)为例,总结GreenChE在国际化发展过程中的实践和举措,重点从人才队伍、稿件质量、多维度传播等方面进行探索讨论。【结果】从筹备至今,经过近两年的探索发展,GreenChE已取得一定的建设成效,学术质量与国际影响力逐步提升,先后被DOAJ、Scopus、CSCD等数据库收录。【结论】新创英文科技期刊在筹办与发展过程中会面临很多困难与挑战,在借鉴成功办刊经验的基础上,结合GreenChE的实际,进一步探索出设置编委分类名单、打造期刊品牌效应、细化邮件推送策略等特色举措,从而实现新创期刊国际影响力的快速提升。
基金supported by the National Natural Science Foundation of China(22001131)the Frontiers Science Center for New Organic Matter of Nankai University(63181206)+1 种基金111 Projects(B12015)the Postdoctoral Science Foundation of China(2019M660974)。
文摘In order to move towards sustainable development, the discovery of energy-efficient and environmentally friendly materials has become increasingly imperative. Covalent organic frameworks(COFs) as emerging designable crystalline porous materials have captured increasing attention for a wide array of clean-energy and environmental applications, attributed to their attractive advantages of low density, high surface area, adjustable and periodic pores, and functional skeletons. This review attempts to highlight the key advancements made in the green synthesis of COFs, processing of COFs, energy and environment-related applications, including gas storage, water treatment, the separation of gas mixture and organic molecules, catalysis, supercapacitors, fuel cell, and rechargeable batteries. Finally, a perspective regarding the remaining challenges and future directions on the synthesis and promising application for green chemical engineering of COFs has also been presented based on current achievements.
基金funded by the National Natural Science Foundation of China(21890762)。
文摘The microbubble and microinterface play key roles in the development and progress of the technology in the field of chemical engineering,which has attracted broad attention from the scientific and industrial community.Recently,Zhang et al.published a book about microinterfacial mass transfer intensification technology,where they systematically introduced scientific essence,reaction mechanism,equipment structure,and influence law of multiphase reaction process strengthened by microinterface.I believe this book can promote the technological innovation of microbubble-related processes,and also the development of the green chemical industry!
基金financial support for this study by the Natural Science Foundation of Inner Mongolia(CN)(2016ZD05)。
文摘The preparation of Nd(OH)3 powder by the direct hydration method using Nd2O3 as a raw material was studied,and the effects of stirring mode,H2O and Nd2O3 molar ratio,stirring rate,and reaction time on temperature change and conversion rate in a hydration system were analyzed.The reasonable process conditions for the direct hydration of Nd(OH)3 by Nd2O3 were then determined.Process,morphology,and structure were considered in the preparation of neodymium hydroxide powder,and its composition was investigated by X-ray powder diffraction,scanning electron microscopy,laser particle size analysis,thermogravimetric differential thermal analysis,and chemical analysis.It has been proved that the process is simple and feasible,in line with the concept of modern green chemistry,and the products also meet the market requirements.
基金the support from the National Natural Science Foundation of China (No. 22108307)the support from the open project of the State Key Laboratory of Heavy Oil Processing
文摘With the continuous development of the chemical industry,the concept of advocating green development has become increasingly popular.Glycolic acid(GA),serving as the monomer for biodegradable plastic polyglycolic acid,plays a crucial role in combating plastic pollution and fostering an eco-friendly society.The selective oxidation of ethylene glycol(EG)to produce GA represents a novel green production technology.Controlling reaction parameters to achieve multi-objective optimization of product distribution and direct CO_(2)emissions is crucial for scaling up the process.With the advent of the big data era,the integration of the chemical industry with artificial intelligence to achieve engineering scale-up is an important trend.This study proposes a neural network model for production prediction and optimization.The model is trained using experimental data,reaction mechanism data,and physical information,enabling rapid prediction of GA production.After validating with 40%of experimental data and 16%of reaction mechanism data,the model's prediction error was within±5%,and the linear correlation coefficient R^(2)between the predicted values and actual values was 0.998.Furthermore,this study integrated a multi-objective optimization algorithm based on the model,enabling surrogate optimization of reaction parameters during production.After optimization,the direct CO_(2)emissions were reduced by over 99%and overall greenhouse gas emissions were reduced by 4.6%.The research paradigm proposed in this research can offer guidance and technical support for the optimized operation of EG selective oxidation to GA.
