Debate has persisted over whether the metamorphic basement of the Zhoushan Islands,easternmost Cathaysia Block,is Precambrian.Here,representative metamorphic rocks from the Qushan Islands were investigated using petro...Debate has persisted over whether the metamorphic basement of the Zhoushan Islands,easternmost Cathaysia Block,is Precambrian.Here,representative metamorphic rocks from the Qushan Islands were investigated using petrography,mineral chemistry,phase equilibria modeling and SHRIMP zircon U-Pb dating to constrain their metamorphic evolution and tectonic significance.Both the pelitic granulites(garnet-kyanite-perthite-biotite-quartz)and the mafic granulites(garnet-clinopyroxene-amphibole-plagioclase-quartz)reached high-pressure granulite-facies conditions of 1.2-1.4 GPa/820-900℃,and recorded three metamorphic stages along a clockwise P-T path with post-peak isothermal decompression.This trajectory indicated rapid exhumation of thickened continental crust during collisional orogeny.Metamorphic ages of 254±3 Ma,262±4 Ma and 259±3 Ma were obtained for mafic granulite,pelitic granulite and marble,respectively,and were consistent with the emplacement age of 259±4 Ma for a pegmatite vein.Detrital zircons in metasediments spanned 2706-330 Ma,which constrained the latest deposition to~330 Ma;thus represented mid-Paleozoic sediment metamorphosed during the late Paleozoic rather than Precambrian basement.We conclude that the Indosinian tectonothermal event in the Cathaysia Block had originated from late Paleozoic-early Mesozoic collisional orogeny between the South China Plate to the north and the Indochina Block to the south.展开更多
Although zircon U-Pb geochronometer has been widely used for dating metamorphism in moderate- to high-grade metamorphic rocks, it is still difficult to link the zircon U-Pb age to pressure and temperature （P-T） cond...Although zircon U-Pb geochronometer has been widely used for dating metamorphism in moderate- to high-grade metamorphic rocks, it is still difficult to link the zircon U-Pb age to pressure and temperature （P-T） conditions. In this study, zircon trace elements and Hf isotopes and REE partitioning between zircon and garnet are adopted to track the formation condition of zircon in the granu- lites from North Tongbai Orogen, Central China. Combined with previous metamorphic P-T path results, a quantitative integrated anticlockwise P-T-t path was established for Tongbai granulites. These grauulites recorded an early low-P heating followed by a dramatic pressure increase. Evidence for the prograde history （M1） is provided by cordierite, orthopyroxene and biotite inclusions in garnet. The prograde metamorphism occurred at around 443±3 Ma, with P-T conditions of ca. 730-820 ℃ and 〈6 kbar. The peak metamorphic （M2） condition is 〉920 ℃ and 8.5-10 kbar and the peak metamorphism age is ca. 432±4 Ma. At around 419 Ma, the granulites suffered an amphibolite-facies retrograde metamorphism （M3）, represented by the replacement of garnet by biotite and plagioclase, and clinopyroxene by amphibole, with metamorphic condition of ca. 700℃ and ca. 7 kbar. The last retrograde metamorphism （M4） is a greenschist-facies overprint with an age of ca. 404 Ma. It is concluded that the meta- morphism of Tongbai granulite lasted for more than 40 Ma, including a stage of more than 20 Ma granulitc-facies metamorphism. The prolonged granulite-facies metamorphism resulted from the continuous northward subduction of the Shangdan oceanic crust beneath the North Qinling terrane.展开更多
As a window of insight into the lower crust, high pressure granulite has received much attention since last decade. Yushugou high pressure granulite-peridotite Complex was located in the northeast margin of Southern T...As a window of insight into the lower crust, high pressure granulite has received much attention since last decade. Yushugou high pressure granulite-peridotite Complex was located in the northeast margin of Southern Tianshan, NW China. Previous ideas agreed that the peridotite unit in Yushugou, combined with the ultramafic rocks in Tonghuashan and Liuhuangshan, represent an ophiolite belt. However, the metamorphic evolution and tectonic mechanism of the Yushugou high pressure （HP） granulite remain controversial. Petrological investigations and phase equilibrium modelling for two representative fclsic granulitc samples suggest two stages metamorphism of the rocks in Yushugou Complex. Granulite facies metamorphism （Stage I） with P-T conditions of 9.8-10.4 kbar at 895-920℃ was recorded by the porphyroblastic garnet core; HP granulite facies metamorphism （Stage II） shows P-T conditions of 13.2-13.5 kbar at 845-860℃, based on the increasing grossular and decreasing pyrope contents of garnet rims. The Yushugou HP felsic granulites have recorded an anti- clockwise P-T path, characterized by the temperature decreasing and pressure increasing simultaneously. The LA-ICP-MS isotopic investigations on zircons from the felsic granulite show that the protolith ages of the granlulites are -430 Ma, with two age groups of-390 Ma and 340-350 Ma from the metamorphic rims of zircon, indicating the Stage I and II metamorphic events, respectively. A tectonic model was proposed to interpret the processes. The investigated felsic granulite was derived from deep rooted hanging wall, with Stage I granulite facies metamorphism of -390 Ma, which may he related to the Devonian arc magmatic intrusion; Stage II HP granulite facies metamorphism （340-350 Ma） may due to the involvement of being captured into the subducting slab and experienced the high pressure metamorphism.展开更多
The Rauer Group is located on the eastern margin of the early Paleozoic Prydz Belt in East Antarctica,and the typical ultrahigh-temperature(UHT,>900℃)granulites outcrop on Mather Peninsula.However,the timing of UH...The Rauer Group is located on the eastern margin of the early Paleozoic Prydz Belt in East Antarctica,and the typical ultrahigh-temperature(UHT,>900℃)granulites outcrop on Mather Peninsula.However,the timing of UHT metamorphism and P–T path of the UHT granulites have long been debated,which is critical to understanding the tectonic nature and evolution history of the Prydz Belt.Thus,both a sapphirine-bearing UHT metapelitic granulite and a garnet-bearing UHT mafic granulite are selected for zircon SHRIMP U-Pb age dating.The results show that metamorphic zircon mantles yield weighted mean^(206)Pb/^(238)U ages of 918±29 Ma and 901±29 Ma for the metapelitic and mafic granulites,respectively,while zircon rims and newly grown zircons yield weighted mean^(206)Pb/^(238)U ages of 523±9 Ma and 532±11 Ma,respectively.These new zircon age data suggest that the UHT granulites may have experienced polymetamorphism,in which pre-peak prograde stage occurred in the early Neoproterozoic Grenvillian orogenesis(1000–900 Ma),whereas the UHT metamorphism occurred in the late Neoproterozoic to early Paleozoic Pan-African orogenesis(580–460 Ma).This implies that P–T path of the UHT granulites should consist of two separate high-grade metamorphic events including the Grenvillian and Pan-African events,which are supposed to be related to assembly of Rodinia and Gondwana supercontinents respectively,and hence the overprinting UHT metamorphic event may actually reflect an important intracontinental reworking.展开更多
In this study, we investigate the possible record of a Late Mesoproterozoic paired metamorphic belt in the Aravalli-Delhi Mobile Belt(ADMB), NW India using a suite of supracrustal and metaigneous granulites from the P...In this study, we investigate the possible record of a Late Mesoproterozoic paired metamorphic belt in the Aravalli-Delhi Mobile Belt(ADMB), NW India using a suite of supracrustal and metaigneous granulites from the Pilwa-Chinwali granulite terrain at the north-western margin of the ADMB. Using metamorphic reaction textures, mineral chemistry, metamorphic reaction history, geothermobarometric computations and electron microprobe dating of monazite in 5 samples of pelitic granulite, leptynite gneiss, enderbite and charnockite, we have deduced a medium-pressure granulite facies metamorphism(P between 4.9 and 6.8 kbar, T> 760-815℃) along a heating-cooling, counterclockwise P-T path between 1.09 and 1.01 Ga. When collated with published metamorphic and chronological constraints and geological settings of the adjoining crustal domains of the ADMB, these findings provide new insights into the developments of two tectonic domains of contrasting thermal gradients at ca. 1.0 Ga, consistent with metamorphic transformations in tectonically thickened middle-lower crustal sections during continental collision to continental subduction and in the root zones of spatially adjacent island arc, as part of the Rodinia supercontinent assembly event.展开更多
The Yushugou HP granulite-peridotite complex is located at east of northern margin of southern Tianshan mountains,China,which consists of granulite unit and peridotite unit mainly.Because of the rare association of
Petrological analysis and LA-ICP-MS zircon U-Pb dating were conducted on high- pressure marie granulites, which occured as xenolith within TTG gneisses, from the Nanshankou Village of the Jiaobei terrane, Shandong Pen...Petrological analysis and LA-ICP-MS zircon U-Pb dating were conducted on high- pressure marie granulites, which occured as xenolith within TTG gneisses, from the Nanshankou Village of the Jiaobei terrane, Shandong Peninsula in the north-eastern part of the North China Craton （NCC）. The mafic HP grannlite is composed of garnet, clinopyroxene, orthopyroxene, amphibole and symplectitic clinopyroxene, orthopyroxene, plagioclase, ilmente and magnetite which were formed after the decomposition of porphyroblastic garnet and clinopyroxene. Four stages of metamorphic mineral assemblages for the mafic HP granulites were constrained by detail petrological and mineralogical in- vestigations. The early prograde assemblage is represented by the mineral inclusions within garnet and clinopyroxene porphyroblasts （Opx1＋Pl1＋Qtz1）, recording the metamorphic conditions at -754-757 ℃, 0.63-0.71 GPa; peak metamorphic conditions were determined at -874-891 ℃, 1.32-1.35 GPa with the mineral assemblage of Grt2＋Cpx2＋Amp2＋Pl2＋Qtz2. Retrograde minerals derived from symplectitic assemblage Opx3＋Cpx3＋Amp3＋Pl3＋Qtz3＋Ilm3±Mag3 were formed at 693-796℃, 0.60-0.84 GPa. A final greensehist to sub-greenschist facies event was recorded by the exsolution of actinolite and albite within a retrograded clinopyroxene, as well as the occurrence of prehnite, chlorite and calcite minerals. Accordingly, a clockwise P-T path was concluded on the basis of the different stages of mineral asseblage. Cathodoluminescence imaging, trace element and U-Pb dating of zircons from the mafic HP granulites recorded similar charactistics for three episodes of Paleo-Meso Proterozoic metamorphic events. These are the metamorphic events preserved in mafic and pelitic granulites in the Jiao-Liao-Ji belt （JLJB） with 207 pb/206pb ages of 2.0-1.9 Ga for peak metamorphism and of 1.86-1.84 Ga for decomposing process, followed by a retrograde amphibolite facies metamorphic event related to the post-orogenic extension at the age of 1.76-1.74 Ga, resulting the exhumation of the granulite to the upper crust level.展开更多
Pelitic granulite from the Huangtuyao area,occurrs in the Huai'an Complex,is located in the Trans-North China Orogen of the North China Craton.On the basis of petrolography,mineral component,and phase equilibrium ...Pelitic granulite from the Huangtuyao area,occurrs in the Huai'an Complex,is located in the Trans-North China Orogen of the North China Craton.On the basis of petrolography,mineral component,and phase equilibrium modeling studies,the P-T conditions and mineral assemblages of pelitic granulites can be divided into four metamorphic stages:the prograde metamorphic stage M1 defined by the stable mineral assemblage of Grt1(garnet core)+Pl+Bt+Kfs+Qz+Rt,the peak pressure Pmax stage M2 indicated by Grt2(garnet mantle)+Kfs±(Ky)+Rt+Qz+Liq(melt),peak temperature Tmax stage M3 characterized by Grt3(garnet rim)+Sill+Pl+Kfs+Qz+Ilm+Liq,and retrograde stage M4 represented by Grt(in matrix)+Kfs+Sill+Bt+Pl+Qz+Ilm.By using the THERMOCALC V340,the P-T conditions are estimated at^13.8–14.1 kbar and^840–850℃at stage M2,and 7–7.2 kbar and 909–915℃for the Tmax stage M3,indicating an ultra-high temperature(UHT)metamorphic overprinting during decompression and heating process after high pressure granulite facies metamorphism.The mineral assemblages and their P-T conditions presented a clockwise P-T trajectory for the Huangtuyao pelitic granulites.The major metamorphic events at^1.95 and^1.88 Ga obtained by the zircon U-Pb dating suggest that pelitic granulites from the Huangtuyao area has undergone HP granulite metamorphism which probably occurred in the prograde metamorphism and related to the collision between the Ordos and the Yinshan blocks,and afterwards UHT metamorphism is related to crustal extension after continental-continental collision.展开更多
The studied mafic granulites are located at Xiwangshan,Xuanhua region in the north of the Trans-North China Orogen(TNCO),occurring as lens within tonalite-trondhjemite-granodiorite(TTG)gneisses in the eastern part of ...The studied mafic granulites are located at Xiwangshan,Xuanhua region in the north of the Trans-North China Orogen(TNCO),occurring as lens within tonalite-trondhjemite-granodiorite(TTG)gneisses in the eastern part of the Xiwangshan area.The rocks contain the representative granulite-facies minerals such as garnet,clinopyroxene,orthopyroxene,plagioclase,amphibolite,rutile and quartz,and also well-developed melt pseudomorph and antiperthite.Although the prograde metamorphic stage(M1)cannot be retrieved due to rare preservation of pre-peak-stage mineral associations,three distinct mineral assemblages that formed in different metamorphic stages can be identified,based on petrography and mineralogy characteristics.The peak stage(M2)is characterized by Grt2+Cpx2+Amp2+Pl2+Rt+melt pseudomorphs,and a post-peak decompression stage(M3)contains a mineral assemblage of Grt3+Opx3+Cpx3+Amp3+Pl3,while a later-retrogression stage(M4)is featured by coronas of Amp4+Pl4 surrounding garnet.By calculating metamorphic P-T conditions using THERMOCALC,stage M2 was constrained to be 13.2–14.8 kbar and 1050–1080℃,and M3 recorded P-T conditions of 5.7–7.3 kbar and 825–875℃,while M4 yielded P of^5 kbar and T of^660℃,consistent with amphibolite facies metamorphism.Taking into account of all these petrological data,we propose that the mafic granulite experienced a high-pressure(HP)and ultra-high temperature(UHT)granulite-facies metamorphism during the peak metamorphism,which was accompanied with a clockwise P-T path.U-Pb dating of metamorphic zircons in the granulites yields two groups of ages at 1853±14 and 1744±44 Ma,respectively.We suggest that the older age corresponded to the HP-UHT metamorphism,while the younger age represented an retrograde metamorphic event during cooling.展开更多
The Grove Mountains are an inland continuation of the Prydz Belt in East Antarctica. Detailed metamorphic petrological and zircon U-Pb geochronological studies are performed on the high-pressure （HP） pelitic granu...The Grove Mountains are an inland continuation of the Prydz Belt in East Antarctica. Detailed metamorphic petrological and zircon U-Pb geochronological studies are performed on the high-pressure （HP） pelitic granulites from glacial moraines in the Grove Mountains. The metamorphic peak mineral assemblage of the HP pelitic granulites is characterized by garnet ＋ kyanite ＋ K-feldspar ＋ biotite ＋ plagioclase ＋ quartz, and the subsequent medium-pressure （MP） granulite facies retrogression is characterized by sillimanite replacing kyanite, the formation of the biolite ＋ sillimanite symplectite in the matrix. These mineral assemblages and their P-T estimates based on the P-T pseudosection constructed in MnNCKFMASHT system define a clockwise P-T path involving metamorphic peak of 11.6–13.6 kbar at 817–834°C followed by a near-isothermal decompression of 6.7–7.5 kbar at 806–828°C, comparable with those of associated HP mafic granulites from glacial moraines in the Grove Mountains. Zircon U-Pb dating, coupled with available metamorphic age data obtained for HP mafic granulites, reveals HP metamorphism occurred at 540–545 Ma. Combining the previous research results, the HP pelitic granulites and contemporary HP mafic granulites were widely distributed in glacial moraines from the Grove Mountains, suggesting at least part of the Grove Subglacial Highlands underwent Pan-Afrian HP granulite facies metamorphism, which provides new evidence for a collisional tectonic setting of the Pan-Afrian Prydz Belt.展开更多
Zircon is a key accessary mineral for metamorphic geochronology and geochemical tracing,but it has been a challenge to interpret its complex chemical zoning and age record acquired during multiple episodes of anatecti...Zircon is a key accessary mineral for metamorphic geochronology and geochemical tracing,but it has been a challenge to interpret its complex chemical zoning and age record acquired during multiple episodes of anatectic metamorphism in collisional orogens.This is illustrated by a combined study of petrography,phase equilibrium modeling and metamorphic P-T-t determination for granulites from the Bohemian Massif in the Variscan Orogen.These rocks record multiple episodes of zircon growth during anatectic metamorphism.They started from the compressional heating for prograde metamorphism to high-pressure(HP)to ultrahigh-pressure(UHP)eclogite facies with low degrees of partial melting.Afterwards,they underwent a decompressional stage from UHP eclogite facies to HP granulite facies for dehydration melting.These were followed by a further decompressional stage either to kyanite granulite facies or to sillimanite granulite facies at ultrahigh-temperature(UHT)conditions.Episodes of zircon growth are linked to specific metamorphic conditions for peritectic reactions on the basis of zoning patterns,trace element signatures,index mineral inclusions in dated domains and textural relationships to coexisting minerals.The results indicate that relict zircon domains are preserved even at UHT granulite facies conditions.A few zircon domains in the kyanite granulite grew during the prograde to peak UHP metamorphism,possibly corresponding to consumption of biotite and plagioclase but growth of garnet.During the decompressional exhumation to the HP granulite-facies,relict or prograde zircon domains were mostly dissolved into anatectic melts produced by muscovite breakdown.Most zircon grains grew during this transition to the HP granulite-facies in the kyanite granulite and are chemically related to continuous growth of garnet,whereas abundant zircon grains grew subsequently at the UHT granulite facies in the sillimanite granulite and are chemically related to garnet breakdown reactions.Another peak of zircon growth occurred at the final crystallization of anatectic melts in the sillimanite granulite rather than in the kyanite granulite,and these zircon grains mostly show oscillatory zoning,low HREE+Y contents and significantly negative Eu anomalies.In terms of the inference for protolith nature,it appears that zircon in metasedimentary rocks can grow at a short timescale in different stages of anatectic metamorphism,and its dissolution and growth are mainly dictated by anatectic conditions and extent,the property of peritectic reactions,and the stability of Ti-rich minerals.展开更多
The rock forming temperatures and pressures represent the p T points of the local regions in the lithosphere at a certain age, providing some important information on rock formation. Based on the preliminary sta...The rock forming temperatures and pressures represent the p T points of the local regions in the lithosphere at a certain age, providing some important information on rock formation. Based on the preliminary statistics on the temperatures and pressures for the formation of eclogites, granulites and peridotites in China, the variant ranges are given, in this paper, of temperatures, pressures and linear geothermal gradients of eclogites, granulites and peridotites. In addition, since the eclogite is different from granulite and peridotite in the p T diagram, these three rocks can be classified into two groups: the first group includes eclogites and the second group granulites and peridotites. Then, the p T correlation functions of these two groups of rocks are provided. Finally, the two groups of rocks have different geothermal gradients at the same pressure gradient or have different pressure gradients at the same geothermal gradient. The temperatures and pressures for the formation of the rocks can be calculated from the mineral chemical compositions, but the depths ( H ) for the rock formation can be calculated only under the hypotheses of given p H (or T H ) correlation functions. The explanations for the ultrahigh pressure metamorphism vary obviously with different hypotheses.展开更多
We report new petrological data and geochronological measurements of granulites from Vesleknausen in the highest-grade section of the L＆#252;tzow-Holm Complex, part of the Gondwana-assembling collisional orogen in Ea...We report new petrological data and geochronological measurements of granulites from Vesleknausen in the highest-grade section of the L＆#252;tzow-Holm Complex, part of the Gondwana-assembling collisional orogen in East Antarctica. The locality is dominated by felsic to intermediate orthogneiss （charnockite and minor biotite gneiss）, mafic orthogneiss, and hornblende-pyroxene granulite, with deformed and undeformed dykes of metagranite and felsic pegmatite. Pseudosection analysis of charnockite in the system NCKFMASHTO, supported by geothermometry of mafic orthogneiss, was used to infer peak metamorphic temperatures of 750e850 ？C, approximately 150 ？C lower than those estimated for met-asedimentary gneisses from Rundv？gshetta, 6 km to the northeast. SHRIMP U-Pb analysis of zircons from feldspar-pyroxene gneiss, which corresponds to a partially molten patch around mafic orthogneiss, yielded a Concordia upper intercept ages of 2507.9 ？ 7.4 Ma, corresponding to the time of formation of the magmatic protolith to the orthogneiss. Partial melting during peak metamorphism probably took place between 591 and 548 Ma, as recorded in rims overgrew around magmatic zircon. Our results suggest that Rundv？gshetta-Vesleknausen-Strandnibba region in southwestern L＆#252;tzow-Holm Bay, where orthogneisses are dominant, consists of a single crustal block, possibly formed by ca. 2.5 Ga arc mag-matism. The Neoarchean magmatic terrane was tectonically mingled with other fragments （such as metasedimentary units in northern L＆#252;tzow-Holm Bay） by subduction/collision events during the as-sembly of Gondwana supercontinent, and subsequently underwent w850 ？C granulite-facies meta-morphosed during Neoproterozoic to Cambrian final collisional event.展开更多
Madagascar,a major fragment of Gondwana,is mainly composed of Precambrian basenent rocks formed by Mesoarchean to Neoproterozoic tectono-thernial events and recording a Pan-African metamorphic overprint.The Ranotsara ...Madagascar,a major fragment of Gondwana,is mainly composed of Precambrian basenent rocks formed by Mesoarchean to Neoproterozoic tectono-thernial events and recording a Pan-African metamorphic overprint.The Ranotsara Shear Zone in southern Madagascar has been correlated with shear zones in southern India and eastern Africa in the reconstruction of the Gondwana supercontinent.Here we present detailed petrology,mineral chemistry,metamorphic P-T constraints using phase equilibrium modelling and zircon U-Pb geochronological data on high-grade metamorphic rocks from Ihosy within the Ranotsara Shear Zone.Garnet-cordierite gneiss from Ihosy experienced two stages of metamorphism.The peak mineral assemblage is interpreted as garnet+sillimanite+cordierite+quartz+plagioclase+Kfeldspar+magnetite+spinel+ilmenite,which is overprinted by a retrograde mineral assemblage of biotite+garnet+cordierite+quartz+plagioclase+K-feldspar+magnetite+spinel+ilmenite.Phase equilibria nodelling in the system Na2 O-CaO-K2 O-FeO-MgO-Al2 O3-SiO2-H2 O-TiO2-Fe2 O3(NCKFMASHTO)indicates peak metamorphic conditions of 850-960℃ and 6.9-77 kbar,and retrograde P-Tconditions of<740℃ and<4.8 kbar,that define a clockwise P-T path.Near-concordant ages of detrital zircon grains in the garnet-cordierite gneiss dominantly exhibit ages between 2030 Ma and 1784 Ma,indicating dominantly Paleoproterozoic sources.The lower intercept age of 514±33 Ma probably indicates the timing of high-grade metamorphism,which coincides with the assembly of the Gondwana supercontinent.The comparable rock types,zircon ages and metamorphic P-T paths between the Ranotsara Shear Zone and the Achankovil Suture Zone in southern India support an interpretation that the Ranotsara Shear Zone is a continuation of the Achankovil Suture Zone.展开更多
The Badu Complex is the oldest metamorphic rock in Cathaysia Block which experienced several episodes of metamorphism Especially indosinian metamorphic reworking in the southwestern Zhejiang Province, South China. The...The Badu Complex is the oldest metamorphic rock in Cathaysia Block which experienced several episodes of metamorphism Especially indosinian metamorphic reworking in the southwestern Zhejiang Province, South China. The degree of indosinian metamorphism reaches granulite facies. However, there is still insufficient understanding of the characteristics of the Indosinian granulite metamorphism in the Cathaysia and many interpretations of its tectonic significance. Therefore, we present detailed petrology, mineral chemistry and LA-ICP-MS zircon U-Pb age in this paper from pelitic granulites of the Badu Complex, which is composed of "sillimanite + garnet + cordierite + spinel + biotite + k-feldspar" assemblage and garnet pyroxenite with garnet amphibolite which is consists of "garnet + clinopyroxene + orthopyroxene + amphibole + plagioclase". By comprehensive study we get following new findings: Pelitic granulites record four stages of metamorphic mineral assemblages, including prograde(M1), pressure peak(M2), Peak(M3) and post-peak decompressional and then cooling(M4) stages. The prograde M1 assemblage consists of garnet1(core) + staurolite + kyanite + biotite + quartz ± rutile ± chlorite;The pressure peak M2 assemblage consists of garnet1(mantle) + sudoite + rutile + kyanite + corundum + biotite + quartz;The peak M3 have garnet2(rim-mantle) + biotite + sillimanite + quartz ± K-feldspar ± plagioclase ± ilmenite assemblag;the M4 stage is consist of garnet + cordierite + biotite + sillimanite + quartz + ilmenite ± spine ± K-feldspar. The garnet pyroxenite and garnet amphibolites have experienced three stages of metamorphic evolution. Peak high-pressure granulite facies stage M2 consists of garnet + sahlite ± ilmenite ± quartz;Post-peak near isothermal decompression medium granulite facies stage M3 is characterized by typical decompression reaction textures and assemblage of orthopyroxene + plagioclase(An=90–92);amphibolites facies retrograde metamorphic stage M4 is characterized by amphibole + plagioclase(An=33–35) + ilmenite ± sahlite ± quartz mineral assemblage. By means of phase equilibrium simulation and traditional thermobarometer, P-T conditions of 785–820 ℃ and 8.9–9.9 kbar for M3 stage, 780–860 ℃ and 5.7–6.2 kbar for decompressional M4 stage, 705–720 ℃ and 4.5–4.7 kbar for cooling M4 stage in pelitic granulites were obtained. And also 11.6–12.5 kbar and 780–840 ℃ for M2 stage, 7.4–8.2 kbar and 800–880 ℃ for M3 stage, 6.6–7.5 kbar and 500–560 ℃ for M4 stage were obtained in garnet pyroxenite and garnet amphibolite. A clockwise P-T path is confirmed in the two type rocks of the Badu Complex which reflected a near-isothermal decompressional metamorphic process. The peak metamorphism can reach highpressure granulite facies. In addition, the mineral assemblage of garnet + rutile + kyanite + corundum in the peak metamorphic stage of pelitic granulite indicates that it may underwent ultra-high-pressure metamorphism, and the acidic plagioclase exsolution of clinopyroxene in garnet pyroxenite also suggests that it may be retrograded eclogites, which indicates that the deeper Cathaysian block may have eclogite metamorphism. Analyses of LA-ICP-MS zircon U-Pb dating indicate that the metamorphic age of pelitic granulite is 233.5 Ma–subduction/collision followed by rapid exhumation and cooling events. The events may relate with the amalgamation of the Indochina BlockSouth China Block North China Block in the paleo-Tethyan domain.展开更多
The investigated area around Sarvapuram represents a part of the Karimnagar granulite terrane of the Eastern Dharwar Craton, India. Garnet–bearing gneiss is hosted as enclaves, pods within granite gneiss and charnock...The investigated area around Sarvapuram represents a part of the Karimnagar granulite terrane of the Eastern Dharwar Craton, India. Garnet–bearing gneiss is hosted as enclaves, pods within granite gneiss and charnockite. It is largely made up of garnet, orthopyroxene, cordierite, biotite, plagioclase, K–feldspar, sillimanite and quartz. The peak metamorphic stage is represented by the equilibrium mineral assemblage i.e. garnet, orthopyroxene, cordierite, biotite, plagioclase, sillimanite and quartz. Breakdown of the garnet as well as preservation of the orthopyroxene–cordierite symplectite, formation of cordierite with the consumption of the garnet + sillimanite + quartz represents the decompressional event. The thermobarometric calculations suggest a retrograde P–T path with a substantial decompression of c. 3.0 kbar. The water activity(XH2 O) conditions obtained with the win TWQ program for core and symplectite compositions from garnet–bearing gneiss are 0.07–0.14 and 0.11–0.16 respectively. The quantitative estimation of oxygen fugacity in garnet–bearing gneiss reveal log f O2 values ranging from-11.38 to-14.05. This high oxidation state could be one of the reasons that account for the absence of graphite in these rocks.展开更多
The Southern Granulite Terrane(Dharwar Craton),South India,is a key unit for understanding the origin of charnockite.New U-Pb and Lu-Hf analyses in zircon crys-tals from 16 samples representing a wide variety of litho...The Southern Granulite Terrane(Dharwar Craton),South India,is a key unit for understanding the origin of charnockite.New U-Pb and Lu-Hf analyses in zircon crys-tals from 16 samples representing a wide variety of litho-types from the quarries in Kabbaldurga reveal a complex geological history in the Archean and early Paleoprotero-zoic.Magmatic protoliths predominantly record Paleoar-chean ages between 3.4 and 3.2 Ga.Combined U-Pb and Lu-Hf signatures indicate a history of recurrent crustal anatexis,juvenile magmatic input,and felsic injections.Mesoarchaean magmatic charnockites were generated mainly from hornblende-dehydration melting of Paleoar-chaean mafic rocks.In addition,Peninsular Gneissic Com-plex of the Dharwar Craton,commonly described as TTG suites,are likely generated by melting of hydrated basalt.The new data are consistent with the idea of a convecting magmatic cycle and also support the proposal that the southern Dharwar Craton comprises a tilted cross-sec-tion through the Archaean crust.Paleoproterozoic high-temperature event is documented here as a complex unit involving juvenile mafic magmatism,granulite facies imprints and crustal anatexis as well as felsic injections,occurring within a short time period around 2.5 Ga.展开更多
The mafic granulites in Dinggye,as various scale lense-shaped enclaves within the high Himalayan crystalline rock series,occur along mylonitic foliations at the junction between the Southern Tibetan Detachment System(...The mafic granulites in Dinggye,as various scale lense-shaped enclaves within the high Himalayan crystalline rock series,occur along mylonitic foliations at the junction between the Southern Tibetan Detachment System(STDS)and the Xainza-Dinggye normal fault system.The main lithological assemblage comprises garnet plagioclase pyroxenite,garnet two-pyroxene granulite,pyroxene garnet amphibolite and so on.The detailed petrological analyses show that these mafic granulites underwent at least four-stage metamorphic evolution.The first metamor-phic stage,the garnet+clinopyroxene+quart mineral assemblage(M1)was probably formed un-der eclogite facies,the second stage,the plagioclase+clinopyroxene symplectite mineral as-semblage(M2)was produced under high-pressure granulite facies by the early decompressive breakdown of M1 mineral assemblage,the third stage,the plagioclase+clinopyroxene+hypersthene symplectite mineral assemblage(M3)was formed at granulite facies by the late period decompressive breakdown of M1 and M2 mineral assemblages and the final stage,pla-gioclase+hornblende mineral assemblage(M4)was formed by hydrolysis of earlier mineral as-semblages during late uplifting.The detailed mineral composition analyses suggest that garnets and clinopyroxenes within M1 and M2 mineral assemblages display similar compositions to the equivalents in the B and C types of eclogites,whereas the M3 clinopyroxenes are akin to these of the same kind of minerals in the granulite.These mineral chemistry features and P-T estimates calculated by mineral thermometers and barometers indicate that the early stage relic porphyro-blasts(M1)could be formed at the eclogite facies,the early decompressive breakdown(M2)occurred at the high-pressures granulite facies of 1.35―1.48 GPa and 625―675℃,the M3 mineral assemblage recorded the granulite facies of 0.7―0.95 GPa and 775―900℃and M4 plagioglase+hornblende retrograde mineral assemblage was produced under the amphibolite facies metamorphism with pressure of 0.4 to 0.75 GPa and temperature at between 660 and 700℃.These construct P-T paths from crustal subduction overthickening to tectonic uplift tectono-thermal evolution.The mineral chemical characteristics and P-T condition at every metamorphic stage of these granulites indicate that these rocks experienced the eclogite facies metamorphism during the early stage.Subsequently,these mafic granulites underwent the three-stage exhuma-tion of the eclogite facies tectonic uplift,isostatic uplift related to the transformation from ec-logite/high-pressure granulite to granulite facies and extensional uplift.展开更多
Ultrahigh-temperature(UHT)metamorphism is critical for understanding the most extreme thermal evolution of continental crust.However,UHT metamorphism predominantly occurred in the Precambrian and is rarely observed in...Ultrahigh-temperature(UHT)metamorphism is critical for understanding the most extreme thermal evolution of continental crust.However,UHT metamorphism predominantly occurred in the Precambrian and is rarely observed in the modern Earth.Here,we report the discovery of~25 Ma UHT granulites from the Mogok metamorphic belt(MMB)in Myanmar via a combined study of petrology and geochronology.The studied pelitic granulites well preserve a peak mineral assemblage of garnet+sillimanite+plagioclase(antiperthite)+K-feldspar+quartz+Ti-rich biotite+rutile+ilmenite.Pressure(P)-temperature(T)pseudosections and conventional geothermobarometry data only constrain the P-T conditions of the peak stage to<12 kbar and 780–890°C.However,high Zr contents in the matrix rutile(3005–4308 ppm)and high Ti contents(up to 9.2 wt% TiO_(2))in the biotite demonstrate that the Mogok granulites may have experienced UHT metamorphism.The Zr-in-rutile thermometer and X_(Grs) isopleth in the pseudosections yield peak P-T conditions of~12 kbar and>900°C.In situ SIMS and LAICP-MS U-Pb dating and trace element analyses show that both metamorphic zircon cores and rims have flat heavy rare earth element(HREE)patterns with negative Eu anomalies.The metamorphic zircon rims show the lowest HREE contents and yield ^(206)Pb/^(238)U ages of 24.9±0.5 and 25.4±0.6 Ma,respectively,representing the timing of UHT metamorphism.Our results indicate that the central MMB underwent~25 Ma UHT metamorphism,which is possibly induced by continental rifting along the thinned orogenic lithosphere.Our data,as well as reported Cenozoic UHT events,further suggest that UHT metamorphism can be produced in the modern plate tectonic regime by lithospheric extension.展开更多
High-temperature diffusion of major elements may obscure the records of early and peak metamorphic stages in granulites,while trace elements are more likely to preserve these records due to their lower diffusion rates...High-temperature diffusion of major elements may obscure the records of early and peak metamorphic stages in granulites,while trace elements are more likely to preserve these records due to their lower diffusion rates.Thus,using calibrated REE-based thermobarometers has proved essential for reconstructing these key stages,drawing considerable attention and application from scholars.However,the precision of these thermobarometers depends on including both major and trace elements from coexisting minerals to define the correlation coefficients(A,B,and D) among mineral pairs,indicating that the elemental composition of these pairs can affect the results.Our study examines the mafic-ultramafic granulites in the southern granulite terrain,India,employing integrated methods such as petrography,mineral chemistry,phase equilibrium modeling,and REE-based thermobarometers.We aim to determine their metamorphic conditions and evolutionary history and to identify potential challenges in using REE-based thermobarometers.The garnet,clinopyroxene,and orthopyroxene in the mafic-ultramafic granulite samples display homogeneous compositional profiles,with pronounced Fe-Mg diffusion zones at the interfaces between garnet and clinopyroxene.Conversely,the profiles of trace elements within garnet and clinopyroxene are better preserved.Investigations into Fe-Mg exchange and randomly selected mineral pairs significantly influence the accuracy of REE-based thermobarometers.Fe-Mg exchange can increase in coefficient A,while decreasing coefficient B for light rare earth elements(LREEs) and increasing it for heavy rare earth elements(HREEs),ultimately resulting in overestimations when calculating REE-based thermobarometers.For example,selecting major compositions with an Ex(=(X_(Mg)^(C)-X_(Mg)^(0))/X_(Mg)^(0)×100%;where X_(Mg)^(C) is the value after Fe-Mg exchange,X_(Mg)^(0) is the value before Fe-Mg exchange;X_(Mg)=Mg/(Fe^(2+)+Mg)) value of ~10 for calculation using the REE-in-Grt-Cpx thermobarometer will result in pressures and temperatures being ~10 kbar and 30-40℃ higher than the true values.Random pairing,such as selections based solely on the core or rim of minerals with changes in trace elements,can severely impact the distribution coefficient D,resulting in substantial discrepancies in thermobarometric calculations and potentially producing anomalous results.Thus,to minimize the impact of these factors,it is necessary to first analyze the profiles of major and trace elements in coexisting minerals before applying the REE-based thermobarometers to evaluate the P-T conditions of granulites.Based on this analysis,maj or element compositions less affected by Fe-Mg exchange(such as avoiding the selection of major compositions at the boundaries of minerals) and in relative equilibrium in trace element compositions among coexisting minerals(same growth periods) should be selected for pairing.Furthermore,integrating additional methods should also be considered when applying the REE-based thermobarometers,to prevent the misinterpretation of the P-T conditions obtained.展开更多
基金supported by the National Natural Science Foundation of China(42072223)Geological Survey project(DD20221649,DD20231429).
文摘Debate has persisted over whether the metamorphic basement of the Zhoushan Islands,easternmost Cathaysia Block,is Precambrian.Here,representative metamorphic rocks from the Qushan Islands were investigated using petrography,mineral chemistry,phase equilibria modeling and SHRIMP zircon U-Pb dating to constrain their metamorphic evolution and tectonic significance.Both the pelitic granulites(garnet-kyanite-perthite-biotite-quartz)and the mafic granulites(garnet-clinopyroxene-amphibole-plagioclase-quartz)reached high-pressure granulite-facies conditions of 1.2-1.4 GPa/820-900℃,and recorded three metamorphic stages along a clockwise P-T path with post-peak isothermal decompression.This trajectory indicated rapid exhumation of thickened continental crust during collisional orogeny.Metamorphic ages of 254±3 Ma,262±4 Ma and 259±3 Ma were obtained for mafic granulite,pelitic granulite and marble,respectively,and were consistent with the emplacement age of 259±4 Ma for a pegmatite vein.Detrital zircons in metasediments spanned 2706-330 Ma,which constrained the latest deposition to~330 Ma;thus represented mid-Paleozoic sediment metamorphosed during the late Paleozoic rather than Precambrian basement.We conclude that the Indosinian tectonothermal event in the Cathaysia Block had originated from late Paleozoic-early Mesozoic collisional orogeny between the South China Plate to the north and the Indochina Block to the south.
基金supported by the National Natural Science Foundation of China (No. 41302040)the China Geological Survey (No. DD20160201)
文摘Although zircon U-Pb geochronometer has been widely used for dating metamorphism in moderate- to high-grade metamorphic rocks, it is still difficult to link the zircon U-Pb age to pressure and temperature （P-T） conditions. In this study, zircon trace elements and Hf isotopes and REE partitioning between zircon and garnet are adopted to track the formation condition of zircon in the granu- lites from North Tongbai Orogen, Central China. Combined with previous metamorphic P-T path results, a quantitative integrated anticlockwise P-T-t path was established for Tongbai granulites. These grauulites recorded an early low-P heating followed by a dramatic pressure increase. Evidence for the prograde history （M1） is provided by cordierite, orthopyroxene and biotite inclusions in garnet. The prograde metamorphism occurred at around 443±3 Ma, with P-T conditions of ca. 730-820 ℃ and 〈6 kbar. The peak metamorphic （M2） condition is 〉920 ℃ and 8.5-10 kbar and the peak metamorphism age is ca. 432±4 Ma. At around 419 Ma, the granulites suffered an amphibolite-facies retrograde metamorphism （M3）, represented by the replacement of garnet by biotite and plagioclase, and clinopyroxene by amphibole, with metamorphic condition of ca. 700℃ and ca. 7 kbar. The last retrograde metamorphism （M4） is a greenschist-facies overprint with an age of ca. 404 Ma. It is concluded that the meta- morphism of Tongbai granulite lasted for more than 40 Ma, including a stage of more than 20 Ma granulitc-facies metamorphism. The prolonged granulite-facies metamorphism resulted from the continuous northward subduction of the Shangdan oceanic crust beneath the North Qinling terrane.
基金financially supported by the National Natural Science Foundation of China(Grants 41330210,41520104004)
文摘As a window of insight into the lower crust, high pressure granulite has received much attention since last decade. Yushugou high pressure granulite-peridotite Complex was located in the northeast margin of Southern Tianshan, NW China. Previous ideas agreed that the peridotite unit in Yushugou, combined with the ultramafic rocks in Tonghuashan and Liuhuangshan, represent an ophiolite belt. However, the metamorphic evolution and tectonic mechanism of the Yushugou high pressure （HP） granulite remain controversial. Petrological investigations and phase equilibrium modelling for two representative fclsic granulitc samples suggest two stages metamorphism of the rocks in Yushugou Complex. Granulite facies metamorphism （Stage I） with P-T conditions of 9.8-10.4 kbar at 895-920℃ was recorded by the porphyroblastic garnet core; HP granulite facies metamorphism （Stage II） shows P-T conditions of 13.2-13.5 kbar at 845-860℃, based on the increasing grossular and decreasing pyrope contents of garnet rims. The Yushugou HP felsic granulites have recorded an anti- clockwise P-T path, characterized by the temperature decreasing and pressure increasing simultaneously. The LA-ICP-MS isotopic investigations on zircons from the felsic granulite show that the protolith ages of the granlulites are -430 Ma, with two age groups of-390 Ma and 340-350 Ma from the metamorphic rims of zircon, indicating the Stage I and II metamorphic events, respectively. A tectonic model was proposed to interpret the processes. The investigated felsic granulite was derived from deep rooted hanging wall, with Stage I granulite facies metamorphism of -390 Ma, which may he related to the Devonian arc magmatic intrusion; Stage II HP granulite facies metamorphism （340-350 Ma） may due to the involvement of being captured into the subducting slab and experienced the high pressure metamorphism.
基金supported by the National Nature Science Foundation of China(Grant no.41972050).
文摘The Rauer Group is located on the eastern margin of the early Paleozoic Prydz Belt in East Antarctica,and the typical ultrahigh-temperature(UHT,>900℃)granulites outcrop on Mather Peninsula.However,the timing of UHT metamorphism and P–T path of the UHT granulites have long been debated,which is critical to understanding the tectonic nature and evolution history of the Prydz Belt.Thus,both a sapphirine-bearing UHT metapelitic granulite and a garnet-bearing UHT mafic granulite are selected for zircon SHRIMP U-Pb age dating.The results show that metamorphic zircon mantles yield weighted mean^(206)Pb/^(238)U ages of 918±29 Ma and 901±29 Ma for the metapelitic and mafic granulites,respectively,while zircon rims and newly grown zircons yield weighted mean^(206)Pb/^(238)U ages of 523±9 Ma and 532±11 Ma,respectively.These new zircon age data suggest that the UHT granulites may have experienced polymetamorphism,in which pre-peak prograde stage occurred in the early Neoproterozoic Grenvillian orogenesis(1000–900 Ma),whereas the UHT metamorphism occurred in the late Neoproterozoic to early Paleozoic Pan-African orogenesis(580–460 Ma).This implies that P–T path of the UHT granulites should consist of two separate high-grade metamorphic events including the Grenvillian and Pan-African events,which are supposed to be related to assembly of Rodinia and Gondwana supercontinents respectively,and hence the overprinting UHT metamorphic event may actually reflect an important intracontinental reworking.
基金financial support from the Indian Institute of Technology(IIT)Kharagpur in the form of a Cumulative Professional Development Allowance
文摘In this study, we investigate the possible record of a Late Mesoproterozoic paired metamorphic belt in the Aravalli-Delhi Mobile Belt(ADMB), NW India using a suite of supracrustal and metaigneous granulites from the Pilwa-Chinwali granulite terrain at the north-western margin of the ADMB. Using metamorphic reaction textures, mineral chemistry, metamorphic reaction history, geothermobarometric computations and electron microprobe dating of monazite in 5 samples of pelitic granulite, leptynite gneiss, enderbite and charnockite, we have deduced a medium-pressure granulite facies metamorphism(P between 4.9 and 6.8 kbar, T> 760-815℃) along a heating-cooling, counterclockwise P-T path between 1.09 and 1.01 Ga. When collated with published metamorphic and chronological constraints and geological settings of the adjoining crustal domains of the ADMB, these findings provide new insights into the developments of two tectonic domains of contrasting thermal gradients at ca. 1.0 Ga, consistent with metamorphic transformations in tectonically thickened middle-lower crustal sections during continental collision to continental subduction and in the root zones of spatially adjacent island arc, as part of the Rodinia supercontinent assembly event.
文摘The Yushugou HP granulite-peridotite complex is located at east of northern margin of southern Tianshan mountains,China,which consists of granulite unit and peridotite unit mainly.Because of the rare association of
基金supported by the National Natural Science Foundation of China (No. 41272072)the NSFC/NRF Research Cooperation Programm (No. 41761144061)the SDUST Research Fund (No. 2015TDJH101)
文摘Petrological analysis and LA-ICP-MS zircon U-Pb dating were conducted on high- pressure marie granulites, which occured as xenolith within TTG gneisses, from the Nanshankou Village of the Jiaobei terrane, Shandong Peninsula in the north-eastern part of the North China Craton （NCC）. The mafic HP grannlite is composed of garnet, clinopyroxene, orthopyroxene, amphibole and symplectitic clinopyroxene, orthopyroxene, plagioclase, ilmente and magnetite which were formed after the decomposition of porphyroblastic garnet and clinopyroxene. Four stages of metamorphic mineral assemblages for the mafic HP granulites were constrained by detail petrological and mineralogical in- vestigations. The early prograde assemblage is represented by the mineral inclusions within garnet and clinopyroxene porphyroblasts （Opx1＋Pl1＋Qtz1）, recording the metamorphic conditions at -754-757 ℃, 0.63-0.71 GPa; peak metamorphic conditions were determined at -874-891 ℃, 1.32-1.35 GPa with the mineral assemblage of Grt2＋Cpx2＋Amp2＋Pl2＋Qtz2. Retrograde minerals derived from symplectitic assemblage Opx3＋Cpx3＋Amp3＋Pl3＋Qtz3＋Ilm3±Mag3 were formed at 693-796℃, 0.60-0.84 GPa. A final greensehist to sub-greenschist facies event was recorded by the exsolution of actinolite and albite within a retrograded clinopyroxene, as well as the occurrence of prehnite, chlorite and calcite minerals. Accordingly, a clockwise P-T path was concluded on the basis of the different stages of mineral asseblage. Cathodoluminescence imaging, trace element and U-Pb dating of zircons from the mafic HP granulites recorded similar charactistics for three episodes of Paleo-Meso Proterozoic metamorphic events. These are the metamorphic events preserved in mafic and pelitic granulites in the Jiao-Liao-Ji belt （JLJB） with 207 pb/206pb ages of 2.0-1.9 Ga for peak metamorphism and of 1.86-1.84 Ga for decomposing process, followed by a retrograde amphibolite facies metamorphic event related to the post-orogenic extension at the age of 1.76-1.74 Ga, resulting the exhumation of the granulite to the upper crust level.
基金supported by funds from the NSFC/NRF Research Cooperation Programme (No. 41761144061)the NSFSD (No. ZR2016DM04)the SDUST Research Fund (No. 2015TDJH101)
文摘Pelitic granulite from the Huangtuyao area,occurrs in the Huai'an Complex,is located in the Trans-North China Orogen of the North China Craton.On the basis of petrolography,mineral component,and phase equilibrium modeling studies,the P-T conditions and mineral assemblages of pelitic granulites can be divided into four metamorphic stages:the prograde metamorphic stage M1 defined by the stable mineral assemblage of Grt1(garnet core)+Pl+Bt+Kfs+Qz+Rt,the peak pressure Pmax stage M2 indicated by Grt2(garnet mantle)+Kfs±(Ky)+Rt+Qz+Liq(melt),peak temperature Tmax stage M3 characterized by Grt3(garnet rim)+Sill+Pl+Kfs+Qz+Ilm+Liq,and retrograde stage M4 represented by Grt(in matrix)+Kfs+Sill+Bt+Pl+Qz+Ilm.By using the THERMOCALC V340,the P-T conditions are estimated at^13.8–14.1 kbar and^840–850℃at stage M2,and 7–7.2 kbar and 909–915℃for the Tmax stage M3,indicating an ultra-high temperature(UHT)metamorphic overprinting during decompression and heating process after high pressure granulite facies metamorphism.The mineral assemblages and their P-T conditions presented a clockwise P-T trajectory for the Huangtuyao pelitic granulites.The major metamorphic events at^1.95 and^1.88 Ga obtained by the zircon U-Pb dating suggest that pelitic granulites from the Huangtuyao area has undergone HP granulite metamorphism which probably occurred in the prograde metamorphism and related to the collision between the Ordos and the Yinshan blocks,and afterwards UHT metamorphism is related to crustal extension after continental-continental collision.
基金supported by the National Natural Science Foundation of China (No. 41761144061)the Shandong Provincial Natural Science Foundation (No. ZR2016DM04)the University Students Innovation Program of SDUST (No. 2015TDJH101)
文摘The studied mafic granulites are located at Xiwangshan,Xuanhua region in the north of the Trans-North China Orogen(TNCO),occurring as lens within tonalite-trondhjemite-granodiorite(TTG)gneisses in the eastern part of the Xiwangshan area.The rocks contain the representative granulite-facies minerals such as garnet,clinopyroxene,orthopyroxene,plagioclase,amphibolite,rutile and quartz,and also well-developed melt pseudomorph and antiperthite.Although the prograde metamorphic stage(M1)cannot be retrieved due to rare preservation of pre-peak-stage mineral associations,three distinct mineral assemblages that formed in different metamorphic stages can be identified,based on petrography and mineralogy characteristics.The peak stage(M2)is characterized by Grt2+Cpx2+Amp2+Pl2+Rt+melt pseudomorphs,and a post-peak decompression stage(M3)contains a mineral assemblage of Grt3+Opx3+Cpx3+Amp3+Pl3,while a later-retrogression stage(M4)is featured by coronas of Amp4+Pl4 surrounding garnet.By calculating metamorphic P-T conditions using THERMOCALC,stage M2 was constrained to be 13.2–14.8 kbar and 1050–1080℃,and M3 recorded P-T conditions of 5.7–7.3 kbar and 825–875℃,while M4 yielded P of^5 kbar and T of^660℃,consistent with amphibolite facies metamorphism.Taking into account of all these petrological data,we propose that the mafic granulite experienced a high-pressure(HP)and ultra-high temperature(UHT)granulite-facies metamorphism during the peak metamorphism,which was accompanied with a clockwise P-T path.U-Pb dating of metamorphic zircons in the granulites yields two groups of ages at 1853±14 and 1744±44 Ma,respectively.We suggest that the older age corresponded to the HP-UHT metamorphism,while the younger age represented an retrograde metamorphic event during cooling.
基金financial support from the National Natural Science Foundation of China (Grant no.41530209)the Central Public-Interest Scientific Institution Basal Research Fund (Grant no.JYYWF201819)+1 种基金the Chinese Polar Environment Comprehensive Investi-gation&Assessment Programs (Grant no.CHINARE2015-02-05)the Geological Investigation Project of the China Geological Survey (Grant no.12120113019000)
文摘The Grove Mountains are an inland continuation of the Prydz Belt in East Antarctica. Detailed metamorphic petrological and zircon U-Pb geochronological studies are performed on the high-pressure （HP） pelitic granulites from glacial moraines in the Grove Mountains. The metamorphic peak mineral assemblage of the HP pelitic granulites is characterized by garnet ＋ kyanite ＋ K-feldspar ＋ biotite ＋ plagioclase ＋ quartz, and the subsequent medium-pressure （MP） granulite facies retrogression is characterized by sillimanite replacing kyanite, the formation of the biolite ＋ sillimanite symplectite in the matrix. These mineral assemblages and their P-T estimates based on the P-T pseudosection constructed in MnNCKFMASHT system define a clockwise P-T path involving metamorphic peak of 11.6–13.6 kbar at 817–834°C followed by a near-isothermal decompression of 6.7–7.5 kbar at 806–828°C, comparable with those of associated HP mafic granulites from glacial moraines in the Grove Mountains. Zircon U-Pb dating, coupled with available metamorphic age data obtained for HP mafic granulites, reveals HP metamorphism occurred at 540–545 Ma. Combining the previous research results, the HP pelitic granulites and contemporary HP mafic granulites were widely distributed in glacial moraines from the Grove Mountains, suggesting at least part of the Grove Subglacial Highlands underwent Pan-Afrian HP granulite facies metamorphism, which provides new evidence for a collisional tectonic setting of the Pan-Afrian Prydz Belt.
基金supported by the Natural Science Foundation of China(Nos.41673030,41590624)the Strategy Guide Project B of the Chinese Academy of Sciences(No.XDB18020303)+1 种基金the Youth Innovation Promotion Association of CAS(No.2013283)the Fundamental Research Programs for the Central Universities。
文摘Zircon is a key accessary mineral for metamorphic geochronology and geochemical tracing,but it has been a challenge to interpret its complex chemical zoning and age record acquired during multiple episodes of anatectic metamorphism in collisional orogens.This is illustrated by a combined study of petrography,phase equilibrium modeling and metamorphic P-T-t determination for granulites from the Bohemian Massif in the Variscan Orogen.These rocks record multiple episodes of zircon growth during anatectic metamorphism.They started from the compressional heating for prograde metamorphism to high-pressure(HP)to ultrahigh-pressure(UHP)eclogite facies with low degrees of partial melting.Afterwards,they underwent a decompressional stage from UHP eclogite facies to HP granulite facies for dehydration melting.These were followed by a further decompressional stage either to kyanite granulite facies or to sillimanite granulite facies at ultrahigh-temperature(UHT)conditions.Episodes of zircon growth are linked to specific metamorphic conditions for peritectic reactions on the basis of zoning patterns,trace element signatures,index mineral inclusions in dated domains and textural relationships to coexisting minerals.The results indicate that relict zircon domains are preserved even at UHT granulite facies conditions.A few zircon domains in the kyanite granulite grew during the prograde to peak UHP metamorphism,possibly corresponding to consumption of biotite and plagioclase but growth of garnet.During the decompressional exhumation to the HP granulite-facies,relict or prograde zircon domains were mostly dissolved into anatectic melts produced by muscovite breakdown.Most zircon grains grew during this transition to the HP granulite-facies in the kyanite granulite and are chemically related to continuous growth of garnet,whereas abundant zircon grains grew subsequently at the UHT granulite facies in the sillimanite granulite and are chemically related to garnet breakdown reactions.Another peak of zircon growth occurred at the final crystallization of anatectic melts in the sillimanite granulite rather than in the kyanite granulite,and these zircon grains mostly show oscillatory zoning,low HREE+Y contents and significantly negative Eu anomalies.In terms of the inference for protolith nature,it appears that zircon in metasedimentary rocks can grow at a short timescale in different stages of anatectic metamorphism,and its dissolution and growth are mainly dictated by anatectic conditions and extent,the property of peritectic reactions,and the stability of Ti-rich minerals.
文摘The rock forming temperatures and pressures represent the p T points of the local regions in the lithosphere at a certain age, providing some important information on rock formation. Based on the preliminary statistics on the temperatures and pressures for the formation of eclogites, granulites and peridotites in China, the variant ranges are given, in this paper, of temperatures, pressures and linear geothermal gradients of eclogites, granulites and peridotites. In addition, since the eclogite is different from granulite and peridotite in the p T diagram, these three rocks can be classified into two groups: the first group includes eclogites and the second group granulites and peridotites. Then, the p T correlation functions of these two groups of rocks are provided. Finally, the two groups of rocks have different geothermal gradients at the same pressure gradient or have different pressure gradients at the same geothermal gradient. The temperatures and pressures for the formation of the rocks can be calculated from the mineral chemical compositions, but the depths ( H ) for the rock formation can be calculated only under the hypotheses of given p H (or T H ) correlation functions. The explanations for the ultrahigh pressure metamorphism vary obviously with different hypotheses.
基金partly supported by a Grant-in-Aid for Scientific Research (B) from Japan Society for the Promotion of Science (JSPS) to Tsunogae (Nos. 20340148, 22403017)
文摘We report new petrological data and geochronological measurements of granulites from Vesleknausen in the highest-grade section of the L＆#252;tzow-Holm Complex, part of the Gondwana-assembling collisional orogen in East Antarctica. The locality is dominated by felsic to intermediate orthogneiss （charnockite and minor biotite gneiss）, mafic orthogneiss, and hornblende-pyroxene granulite, with deformed and undeformed dykes of metagranite and felsic pegmatite. Pseudosection analysis of charnockite in the system NCKFMASHTO, supported by geothermometry of mafic orthogneiss, was used to infer peak metamorphic temperatures of 750e850 ？C, approximately 150 ？C lower than those estimated for met-asedimentary gneisses from Rundv？gshetta, 6 km to the northeast. SHRIMP U-Pb analysis of zircons from feldspar-pyroxene gneiss, which corresponds to a partially molten patch around mafic orthogneiss, yielded a Concordia upper intercept ages of 2507.9 ？ 7.4 Ma, corresponding to the time of formation of the magmatic protolith to the orthogneiss. Partial melting during peak metamorphism probably took place between 591 and 548 Ma, as recorded in rims overgrew around magmatic zircon. Our results suggest that Rundv？gshetta-Vesleknausen-Strandnibba region in southwestern L＆#252;tzow-Holm Bay, where orthogneisses are dominant, consists of a single crustal block, possibly formed by ca. 2.5 Ga arc mag-matism. The Neoarchean magmatic terrane was tectonically mingled with other fragments （such as metasedimentary units in northern L＆#252;tzow-Holm Bay） by subduction/collision events during the as-sembly of Gondwana supercontinent, and subsequently underwent w850 ？C granulite-facies meta-morphosed during Neoproterozoic to Cambrian final collisional event.
基金Partial funding for this project was produced by a Grant-in-Aid for Scientific Research(B) from Japan Society for the Promotion of Science(JSPS) to Tsunogae(Nos.22403017,26302009 and 18H01300)
文摘Madagascar,a major fragment of Gondwana,is mainly composed of Precambrian basenent rocks formed by Mesoarchean to Neoproterozoic tectono-thernial events and recording a Pan-African metamorphic overprint.The Ranotsara Shear Zone in southern Madagascar has been correlated with shear zones in southern India and eastern Africa in the reconstruction of the Gondwana supercontinent.Here we present detailed petrology,mineral chemistry,metamorphic P-T constraints using phase equilibrium modelling and zircon U-Pb geochronological data on high-grade metamorphic rocks from Ihosy within the Ranotsara Shear Zone.Garnet-cordierite gneiss from Ihosy experienced two stages of metamorphism.The peak mineral assemblage is interpreted as garnet+sillimanite+cordierite+quartz+plagioclase+Kfeldspar+magnetite+spinel+ilmenite,which is overprinted by a retrograde mineral assemblage of biotite+garnet+cordierite+quartz+plagioclase+K-feldspar+magnetite+spinel+ilmenite.Phase equilibria nodelling in the system Na2 O-CaO-K2 O-FeO-MgO-Al2 O3-SiO2-H2 O-TiO2-Fe2 O3(NCKFMASHTO)indicates peak metamorphic conditions of 850-960℃ and 6.9-77 kbar,and retrograde P-Tconditions of<740℃ and<4.8 kbar,that define a clockwise P-T path.Near-concordant ages of detrital zircon grains in the garnet-cordierite gneiss dominantly exhibit ages between 2030 Ma and 1784 Ma,indicating dominantly Paleoproterozoic sources.The lower intercept age of 514±33 Ma probably indicates the timing of high-grade metamorphism,which coincides with the assembly of the Gondwana supercontinent.The comparable rock types,zircon ages and metamorphic P-T paths between the Ranotsara Shear Zone and the Achankovil Suture Zone in southern India support an interpretation that the Ranotsara Shear Zone is a continuation of the Achankovil Suture Zone.
基金financially supported by Geological Survey Project(No.D1434-3)of China Geological Surveythe National Natural Science Foundation of China(No.41472164,41872192)
文摘The Badu Complex is the oldest metamorphic rock in Cathaysia Block which experienced several episodes of metamorphism Especially indosinian metamorphic reworking in the southwestern Zhejiang Province, South China. The degree of indosinian metamorphism reaches granulite facies. However, there is still insufficient understanding of the characteristics of the Indosinian granulite metamorphism in the Cathaysia and many interpretations of its tectonic significance. Therefore, we present detailed petrology, mineral chemistry and LA-ICP-MS zircon U-Pb age in this paper from pelitic granulites of the Badu Complex, which is composed of "sillimanite + garnet + cordierite + spinel + biotite + k-feldspar" assemblage and garnet pyroxenite with garnet amphibolite which is consists of "garnet + clinopyroxene + orthopyroxene + amphibole + plagioclase". By comprehensive study we get following new findings: Pelitic granulites record four stages of metamorphic mineral assemblages, including prograde(M1), pressure peak(M2), Peak(M3) and post-peak decompressional and then cooling(M4) stages. The prograde M1 assemblage consists of garnet1(core) + staurolite + kyanite + biotite + quartz ± rutile ± chlorite;The pressure peak M2 assemblage consists of garnet1(mantle) + sudoite + rutile + kyanite + corundum + biotite + quartz;The peak M3 have garnet2(rim-mantle) + biotite + sillimanite + quartz ± K-feldspar ± plagioclase ± ilmenite assemblag;the M4 stage is consist of garnet + cordierite + biotite + sillimanite + quartz + ilmenite ± spine ± K-feldspar. The garnet pyroxenite and garnet amphibolites have experienced three stages of metamorphic evolution. Peak high-pressure granulite facies stage M2 consists of garnet + sahlite ± ilmenite ± quartz;Post-peak near isothermal decompression medium granulite facies stage M3 is characterized by typical decompression reaction textures and assemblage of orthopyroxene + plagioclase(An=90–92);amphibolites facies retrograde metamorphic stage M4 is characterized by amphibole + plagioclase(An=33–35) + ilmenite ± sahlite ± quartz mineral assemblage. By means of phase equilibrium simulation and traditional thermobarometer, P-T conditions of 785–820 ℃ and 8.9–9.9 kbar for M3 stage, 780–860 ℃ and 5.7–6.2 kbar for decompressional M4 stage, 705–720 ℃ and 4.5–4.7 kbar for cooling M4 stage in pelitic granulites were obtained. And also 11.6–12.5 kbar and 780–840 ℃ for M2 stage, 7.4–8.2 kbar and 800–880 ℃ for M3 stage, 6.6–7.5 kbar and 500–560 ℃ for M4 stage were obtained in garnet pyroxenite and garnet amphibolite. A clockwise P-T path is confirmed in the two type rocks of the Badu Complex which reflected a near-isothermal decompressional metamorphic process. The peak metamorphism can reach highpressure granulite facies. In addition, the mineral assemblage of garnet + rutile + kyanite + corundum in the peak metamorphic stage of pelitic granulite indicates that it may underwent ultra-high-pressure metamorphism, and the acidic plagioclase exsolution of clinopyroxene in garnet pyroxenite also suggests that it may be retrograded eclogites, which indicates that the deeper Cathaysian block may have eclogite metamorphism. Analyses of LA-ICP-MS zircon U-Pb dating indicate that the metamorphic age of pelitic granulite is 233.5 Ma–subduction/collision followed by rapid exhumation and cooling events. The events may relate with the amalgamation of the Indochina BlockSouth China Block North China Block in the paleo-Tethyan domain.
文摘The investigated area around Sarvapuram represents a part of the Karimnagar granulite terrane of the Eastern Dharwar Craton, India. Garnet–bearing gneiss is hosted as enclaves, pods within granite gneiss and charnockite. It is largely made up of garnet, orthopyroxene, cordierite, biotite, plagioclase, K–feldspar, sillimanite and quartz. The peak metamorphic stage is represented by the equilibrium mineral assemblage i.e. garnet, orthopyroxene, cordierite, biotite, plagioclase, sillimanite and quartz. Breakdown of the garnet as well as preservation of the orthopyroxene–cordierite symplectite, formation of cordierite with the consumption of the garnet + sillimanite + quartz represents the decompressional event. The thermobarometric calculations suggest a retrograde P–T path with a substantial decompression of c. 3.0 kbar. The water activity(XH2 O) conditions obtained with the win TWQ program for core and symplectite compositions from garnet–bearing gneiss are 0.07–0.14 and 0.11–0.16 respectively. The quantitative estimation of oxygen fugacity in garnet–bearing gneiss reveal log f O2 values ranging from-11.38 to-14.05. This high oxidation state could be one of the reasons that account for the absence of graphite in these rocks.
基金funded by the India-Brazil bilateral co-operation Project:INT/BRAZIL/P-02/2013by Indian Statistical Institute,Geoscience Institute of São Paulo University,Brazil and Department of Geology,University of Calcutta.M.Hueck thanks FAPESP for a post-doctoral fellowship(grant 2019/06838-2).
文摘The Southern Granulite Terrane(Dharwar Craton),South India,is a key unit for understanding the origin of charnockite.New U-Pb and Lu-Hf analyses in zircon crys-tals from 16 samples representing a wide variety of litho-types from the quarries in Kabbaldurga reveal a complex geological history in the Archean and early Paleoprotero-zoic.Magmatic protoliths predominantly record Paleoar-chean ages between 3.4 and 3.2 Ga.Combined U-Pb and Lu-Hf signatures indicate a history of recurrent crustal anatexis,juvenile magmatic input,and felsic injections.Mesoarchaean magmatic charnockites were generated mainly from hornblende-dehydration melting of Paleoar-chaean mafic rocks.In addition,Peninsular Gneissic Com-plex of the Dharwar Craton,commonly described as TTG suites,are likely generated by melting of hydrated basalt.The new data are consistent with the idea of a convecting magmatic cycle and also support the proposal that the southern Dharwar Craton comprises a tilted cross-sec-tion through the Archaean crust.Paleoproterozoic high-temperature event is documented here as a complex unit involving juvenile mafic magmatism,granulite facies imprints and crustal anatexis as well as felsic injections,occurring within a short time period around 2.5 Ga.
基金This work was suppotted by the Ministry of Saance and Techmology of the People's Republic of China(Gant No 2002CB412608)the Specific Project for the Aunthos of Best Dissertations of Chimese Univarsities and Colleges(Grant No.200022).
文摘The mafic granulites in Dinggye,as various scale lense-shaped enclaves within the high Himalayan crystalline rock series,occur along mylonitic foliations at the junction between the Southern Tibetan Detachment System(STDS)and the Xainza-Dinggye normal fault system.The main lithological assemblage comprises garnet plagioclase pyroxenite,garnet two-pyroxene granulite,pyroxene garnet amphibolite and so on.The detailed petrological analyses show that these mafic granulites underwent at least four-stage metamorphic evolution.The first metamor-phic stage,the garnet+clinopyroxene+quart mineral assemblage(M1)was probably formed un-der eclogite facies,the second stage,the plagioclase+clinopyroxene symplectite mineral as-semblage(M2)was produced under high-pressure granulite facies by the early decompressive breakdown of M1 mineral assemblage,the third stage,the plagioclase+clinopyroxene+hypersthene symplectite mineral assemblage(M3)was formed at granulite facies by the late period decompressive breakdown of M1 and M2 mineral assemblages and the final stage,pla-gioclase+hornblende mineral assemblage(M4)was formed by hydrolysis of earlier mineral as-semblages during late uplifting.The detailed mineral composition analyses suggest that garnets and clinopyroxenes within M1 and M2 mineral assemblages display similar compositions to the equivalents in the B and C types of eclogites,whereas the M3 clinopyroxenes are akin to these of the same kind of minerals in the granulite.These mineral chemistry features and P-T estimates calculated by mineral thermometers and barometers indicate that the early stage relic porphyro-blasts(M1)could be formed at the eclogite facies,the early decompressive breakdown(M2)occurred at the high-pressures granulite facies of 1.35―1.48 GPa and 625―675℃,the M3 mineral assemblage recorded the granulite facies of 0.7―0.95 GPa and 775―900℃and M4 plagioglase+hornblende retrograde mineral assemblage was produced under the amphibolite facies metamorphism with pressure of 0.4 to 0.75 GPa and temperature at between 660 and 700℃.These construct P-T paths from crustal subduction overthickening to tectonic uplift tectono-thermal evolution.The mineral chemical characteristics and P-T condition at every metamorphic stage of these granulites indicate that these rocks experienced the eclogite facies metamorphism during the early stage.Subsequently,these mafic granulites underwent the three-stage exhuma-tion of the eclogite facies tectonic uplift,isostatic uplift related to the transformation from ec-logite/high-pressure granulite to granulite facies and extensional uplift.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.41822202,41490614).
文摘Ultrahigh-temperature(UHT)metamorphism is critical for understanding the most extreme thermal evolution of continental crust.However,UHT metamorphism predominantly occurred in the Precambrian and is rarely observed in the modern Earth.Here,we report the discovery of~25 Ma UHT granulites from the Mogok metamorphic belt(MMB)in Myanmar via a combined study of petrology and geochronology.The studied pelitic granulites well preserve a peak mineral assemblage of garnet+sillimanite+plagioclase(antiperthite)+K-feldspar+quartz+Ti-rich biotite+rutile+ilmenite.Pressure(P)-temperature(T)pseudosections and conventional geothermobarometry data only constrain the P-T conditions of the peak stage to<12 kbar and 780–890°C.However,high Zr contents in the matrix rutile(3005–4308 ppm)and high Ti contents(up to 9.2 wt% TiO_(2))in the biotite demonstrate that the Mogok granulites may have experienced UHT metamorphism.The Zr-in-rutile thermometer and X_(Grs) isopleth in the pseudosections yield peak P-T conditions of~12 kbar and>900°C.In situ SIMS and LAICP-MS U-Pb dating and trace element analyses show that both metamorphic zircon cores and rims have flat heavy rare earth element(HREE)patterns with negative Eu anomalies.The metamorphic zircon rims show the lowest HREE contents and yield ^(206)Pb/^(238)U ages of 24.9±0.5 and 25.4±0.6 Ma,respectively,representing the timing of UHT metamorphism.Our results indicate that the central MMB underwent~25 Ma UHT metamorphism,which is possibly induced by continental rifting along the thinned orogenic lithosphere.Our data,as well as reported Cenozoic UHT events,further suggest that UHT metamorphism can be produced in the modern plate tectonic regime by lithospheric extension.
基金supported by the National Natural Science Foundation of China (Grants Nos. 41890831 and 42302223)the State Key Laboratory of Continental Dynamics (Grant No. SKLCD-04)。
文摘High-temperature diffusion of major elements may obscure the records of early and peak metamorphic stages in granulites,while trace elements are more likely to preserve these records due to their lower diffusion rates.Thus,using calibrated REE-based thermobarometers has proved essential for reconstructing these key stages,drawing considerable attention and application from scholars.However,the precision of these thermobarometers depends on including both major and trace elements from coexisting minerals to define the correlation coefficients(A,B,and D) among mineral pairs,indicating that the elemental composition of these pairs can affect the results.Our study examines the mafic-ultramafic granulites in the southern granulite terrain,India,employing integrated methods such as petrography,mineral chemistry,phase equilibrium modeling,and REE-based thermobarometers.We aim to determine their metamorphic conditions and evolutionary history and to identify potential challenges in using REE-based thermobarometers.The garnet,clinopyroxene,and orthopyroxene in the mafic-ultramafic granulite samples display homogeneous compositional profiles,with pronounced Fe-Mg diffusion zones at the interfaces between garnet and clinopyroxene.Conversely,the profiles of trace elements within garnet and clinopyroxene are better preserved.Investigations into Fe-Mg exchange and randomly selected mineral pairs significantly influence the accuracy of REE-based thermobarometers.Fe-Mg exchange can increase in coefficient A,while decreasing coefficient B for light rare earth elements(LREEs) and increasing it for heavy rare earth elements(HREEs),ultimately resulting in overestimations when calculating REE-based thermobarometers.For example,selecting major compositions with an Ex(=(X_(Mg)^(C)-X_(Mg)^(0))/X_(Mg)^(0)×100%;where X_(Mg)^(C) is the value after Fe-Mg exchange,X_(Mg)^(0) is the value before Fe-Mg exchange;X_(Mg)=Mg/(Fe^(2+)+Mg)) value of ~10 for calculation using the REE-in-Grt-Cpx thermobarometer will result in pressures and temperatures being ~10 kbar and 30-40℃ higher than the true values.Random pairing,such as selections based solely on the core or rim of minerals with changes in trace elements,can severely impact the distribution coefficient D,resulting in substantial discrepancies in thermobarometric calculations and potentially producing anomalous results.Thus,to minimize the impact of these factors,it is necessary to first analyze the profiles of major and trace elements in coexisting minerals before applying the REE-based thermobarometers to evaluate the P-T conditions of granulites.Based on this analysis,maj or element compositions less affected by Fe-Mg exchange(such as avoiding the selection of major compositions at the boundaries of minerals) and in relative equilibrium in trace element compositions among coexisting minerals(same growth periods) should be selected for pairing.Furthermore,integrating additional methods should also be considered when applying the REE-based thermobarometers,to prevent the misinterpretation of the P-T conditions obtained.
