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Quantum Geometric Tensor for Mixed States Based on the Covariant Derivative
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作者 Qianyi Wang Ben Wang +1 位作者 Jun Wang Lijian Zhang 《Chinese Physics Letters》 2025年第7期171-181,共11页
The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned... The quantum geometric tensor(QGT)is a fundamental quantity for characterizing the geometric properties of quantum states and plays an essential role in elucidating various physical phenomena.The traditional QGT,defned only for pure states,has limited applicability in realistic scenarios where mixed states are common.To address this limitation,we generalize the defnition of the QGT to mixed states using the purifcation bundle and the covariant derivative.Notably,our proposed defnition reduces to the traditional QGT when mixed states approach pure states.In our framework,the real and imaginary parts of this generalized QGT correspond to the Bures metric and the mean gauge curvature,respectively,endowing it with a broad range of potential applications.Additionally,using our proposed mixed-state QGT,we derive the geodesic equation applicable to mixed states.This work establishes a unifed framework for the geometric analysis of both pure and mixed states,thereby deepening our understanding of the geometric properties of quantum states. 展开更多
关键词 characterizing geometric properties quantum states purifcation bundle elucidating various physical phenomenathe covariant derivative Bures metric quantum geometric tensor qgt quantum geometric tensor mixed states
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Geometric Accuracy Design of High Performance CNC Machine Tools:Modeling,Analysis,and Optimization
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作者 Liping Wang Jihui Han +3 位作者 Zihan Tang Yun Zhang Dong Wang Xuekun Li 《Chinese Journal of Mechanical Engineering》 2025年第3期29-60,共32页
The CNC machine tool is the fundamental equipment of the manufacturing industry,particularly in sectors where achieving high levels of accuracy is crucial.Geometric accuracy design is an important step in machine tool... The CNC machine tool is the fundamental equipment of the manufacturing industry,particularly in sectors where achieving high levels of accuracy is crucial.Geometric accuracy design is an important step in machine tool design and plays an essential role in determining the machining accuracy of the workpiece.Researchers have extensively studied methods to model,extract,optimize,and measure the geometric errors that affect the geometric accuracy of machine tools.This paper provides a comprehensive review of the state-of-the-art approaches and an overview of the latest research progress associated with geometric accuracy design in CNC machine tools.This paper explores the interrelated aspects of CNC machine tool accuracy design:modeling,analysis and optimization.Accuracy analysis,which includes geometric error modeling and sensitivity analysis,determines a machine tool’s output accuracy through its volumetric error model,given the known accuracy of its individual components.Conversely,accuracy allocation designs the accuracy of the machine tool components according to given output accuracy requirements to achieve optimization between the objectives of manufacturing cost,quality,reliability,and environmental impact.In addition to discussing design factors and evaluation methods,this paper outlines methods for verifying the accuracy of design results,aiming to provide a practical basis for ensuring that the designed accuracy is achieved.Finally,the challenges and future research directions in geometric accuracy design are highlighted. 展开更多
关键词 Accuracy design geometric error geometric accuracy Machine tool
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F-GEOMETRIC ERGODIC OF CONTINUOUS TIME MARKOV PROCESSES BY COUPLING METHOD
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作者 ZHU Zhi-feng ZHOU Jun-chao 《数学杂志》 2025年第6期493-501,共9页
In this paper,we study the geometric ergodicity of continuous time Markov pro-cesses in general state space.For the geometric ergodic continuous time Markov processes,the condition π(f^(p))<∞,p>1 is added.Usin... In this paper,we study the geometric ergodicity of continuous time Markov pro-cesses in general state space.For the geometric ergodic continuous time Markov processes,the condition π(f^(p))<∞,p>1 is added.Using the coupling method,we obtain the existence of a full absorbing set on which continuous time Markov processes are f-geometric ergodic. 展开更多
关键词 Markov process COUPLING f-norm geometric ergodicity f-geometric ergodicity
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Geometric size and forming force prediction in incremental flanging:A new analytical model 被引量:1
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作者 Chong TIAN Dawei ZHANG +1 位作者 Guangcan YANG Shengdun ZHAO 《Chinese Journal of Aeronautics》 2025年第2期519-540,共22页
A new analytical model for geometric size and forming force prediction in incremental flanging(IF)is presented in this work.The complex deformation characteristics of IF are considered in the modeling process,which ca... A new analytical model for geometric size and forming force prediction in incremental flanging(IF)is presented in this work.The complex deformation characteristics of IF are considered in the modeling process,which can accurately describe the strain and stress states in IF.Based on strain analysis,the model can predict the material thickness distribution and neck height after IF.By considering contact area,strain characteristics,material thickness changes,and friction,the model can predict specific moments and corresponding values of maximum axial forming force and maximum horizontal forming force during IF.In addition,an IF experiment involving different tool diameters,flanging diameters,and opening hole diameters is conducted.On the basis of the experimental strain paths,the strain characteristics of different deformation zones are studied,and the stable strain ratio is quantitatively described through two dimensionless parameters:relative tool diameter and relative hole diameter.Then,the changing of material thickness and forming force in IF,and the variation of minimum material thickness,neck height,maximum axial forming force,and maximum horizontal forming force with flanging parameters are studied,and the reliability of the analytical model is verified in this process.Finally,the influence of the horizontal forming force on the tool design and the fluctuation of the forming force are explained. 展开更多
关键词 Incremental flanging Analytical model Strain characteristic geometric size Forming force
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A Hybrid PSO-ACO Algorithm for Precise Localization and Geometric Error Reduction in Industrial Robots 被引量:1
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作者 Ghulam E Mustafa Abro Eman Mahmoud 《Instrumentation》 2025年第1期70-76,共7页
The proposed hybrid optimization algorithm integrates particle swarm optimizatio(PSO)with Ant Colony Optimization(ACO)to improve a number of pitfalls within PSO methods traditionally considered and/or applied to indus... The proposed hybrid optimization algorithm integrates particle swarm optimizatio(PSO)with Ant Colony Optimization(ACO)to improve a number of pitfalls within PSO methods traditionally considered and/or applied to industrial robots.Particle Swarm Optimization may frequently suffer from local optima and inaccuracies in identifying the geometric parameters,which are necessary for applications requiring high-accuracy performances.The proposed approach integrates pheromone-based learning of ACO with the D-H method of developing an error model;hence,the global search effectiveness together with the convergence accuracy is further improved.Comparison studies of the hybrid PSO-ACO algorithm show higher precision and effectiveness in the optimization of geometric error parameters compared to the traditional methods.This is a remarkable reduction of localization errors,thus yielding accuracy and reliability in industrial robotic systems,as the results show.This approach improves performance in those applications that demand high geometric calibration by reducing the geometric error.The paper provides an overview of input for developing robotics and automation,giving importance to precision in industrial engineering.The proposed hybrid methodology is a good way to enhance the working accuracy and effectiveness of industrial robots and shall enable their wide application to complex tasks that require a high degree of accuracy. 展开更多
关键词 particle swarm optimization local optima denavit-hartenberg ant colony optimization and geometric error
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Geometric Error Identification and Compensation of Swiveling Axes Based on Additional Rotational Rigid Body Motion Constraints
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作者 Jun Zha Xiaofei Peng 《Chinese Journal of Mechanical Engineering》 2025年第3期96-118,共23页
This study aimed to identify and compensate for the geometric errors of the double swiveling axes in a five-axis computer numerical control(CNC)machining center.Hence,a three-dimensional coordinate calculation algorit... This study aimed to identify and compensate for the geometric errors of the double swiveling axes in a five-axis computer numerical control(CNC)machining center.Hence,a three-dimensional coordinate calculation algorithm for a measured point with additional rotational rigid body motion constraints is proposed.The motion constraints of the rotational rigid body were analyzed,and a mathematical model of the measured point algorithm in the swiveling axes was established.The Levenberg-Marquard method was used to solve the nonlinear superstatically determined equations.The spatial coordinate error was used to separate the spatial deviation of the measured point.An identification model of the position-independent and position-dependent geometric errors was established.The three-dimensional coordinate-solving algorithm of the measured point in the swiveling axis and geometric error identification method based on the Monte Carlo method were analyzed numerically.Geometric error measurement and cutting experiments were performed on a VMC25100U five-axis machining center,which integrated two swiveling axes.Geometric errors of the A-and B-axes were identified and measured experimentally.The angular positioning errors before and after compensation were measured using a laser interferometer,which verified the effectiveness of the proposed algorithm.A cutting experiment of a round table part was performed.The shape and position accuracy of the processed part before and after compensation were detected using a coordinate measuring machine.It verified that the geometric error of the swiveling axis was effectively compensated by the algorithm proposed herein. 展开更多
关键词 geometric error IDENTIFICATION COMPENSATION Swiveling axis Machine tool Motion constraints
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In-Plane Bearing Capacity of CFST Truss Arch Bridges with Geometric Defects
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作者 Chao Luo Zhengsong Xiang +3 位作者 Yin Zhou Dingsong Qin Tianlei Cheng Qizhi Tang 《Structural Durability & Health Monitoring》 2025年第3期683-703,共21页
Failure tests were conducted on two concrete-filled steel tubular(CFST)truss arch bridges with a span of approximately 12 m to investigate the influence of initial geometric defects on the in-plane bearing capacity of... Failure tests were conducted on two concrete-filled steel tubular(CFST)truss arch bridges with a span of approximately 12 m to investigate the influence of initial geometric defects on the in-plane bearing capacity of CFST truss arch bridges.The effects of antisymmetric defect on the ultimate bearing capacity,failure mode,structural response,and steel–concrete confinement effect of CFST truss arch bridges under quarter-point loading were analyzed.On this basis,numerical simulations were conducted to investigate the in-plane bearing capacity of CFST truss arch bridges further under different scenarios.The initial defect formof the archwas obtained by using theoretical deduction,and the theoretical basis for the weakening of the ultimate bearing capacity of the arch bridge caused by geometric defects was clarified.Results indicate that the antisymmetric defect does not change the four-hinge failure mode of the model arch under quarter-point loading but increases the local cracking area and crack density of the concrete inside the pipe.The sine geometric defect with an amplitude of L/250 resulted in a 44.4%decrease in the yield load of the single hinge of the model arch,a 10.5%decrease in the failure load of the four hinges,and a 40.9%increase in themaximum vertical deformation during failure.At the initial stage of loading,the steel pipe and the concrete inside the pipe were subjected to relatively independent forces.After reaching 67%of the ultimate load,the catenary arch ribs began to produce a steel pipe concrete constraint effect.The initial geometric defects resulted in a decrease in the load when the constraint effect occurred.The antisymmetric defects with the same amplitude have a greater impact on the in-plane bearing capacity of the CFST arch bridge than the initial geometric defects with symmetry.The linear deviation at L/4 caused by constructionmust be controlled to be less than L/600 to ensure that the internal bearing capacity of the CFST arch bridge reaches 95%of the design bearing capacity.The structural deformation caused by geometric initial defects increases linearly with the increase in defect amplitude.The bearing capacity is weakened because the structural deflection and bending moment are amplified by initial defects. 展开更多
关键词 geometric defects CFST arch bridge ultimate bearing capacity model test numerical simulation theoretical derivation
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YGC-SLAM:A visual SLAM based on improved YOLOv5 and geometric constraints for dynamic indoor environments
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作者 Juncheng ZHANG Fuyang KE +2 位作者 Qinqin TANG Wenming YU Ming ZHANG 《虚拟现实与智能硬件(中英文)》 2025年第1期62-82,共21页
Background As visual simultaneous localization and mapping(SLAM)is primarily based on the assumption of a static scene,the presence of dynamic objects in the frame causes problems such as a deterioration of system rob... Background As visual simultaneous localization and mapping(SLAM)is primarily based on the assumption of a static scene,the presence of dynamic objects in the frame causes problems such as a deterioration of system robustness and inaccurate position estimation.In this study,we propose a YGC-SLAM for indoor dynamic environments based on the ORB-SLAM2 framework combined with semantic and geometric constraints to improve the positioning accuracy and robustness of the system.Methods First,the recognition accuracy of YOLOv5 was improved by introducing the convolution block attention model and the improved EIOU loss function,whereby the prediction frame converges quickly for better detection.The improved YOLOv5 was then added to the tracking thread for dynamic target detection to eliminate dynamic points.Subsequently,multi-view geometric constraints were used for re-judging to further eliminate dynamic points while enabling more useful feature points to be retained and preventing the semantic approach from over-eliminating feature points,causing a failure of map building.The K-means clustering algorithm was used to accelerate this process and quickly calculate and determine the motion state of each cluster of pixel points.Finally,a strategy for drawing keyframes with de-redundancy was implemented to construct a clear 3D dense static point-cloud map.Results Through testing on TUM dataset and a real environment,the experimental results show that our algorithm reduces the absolute trajectory error by 98.22%and the relative trajectory error by 97.98%compared with the original ORBSLAM2,which is more accurate and has better real-time performance than similar algorithms,such as DynaSLAM and DS-SLAM.Conclusions The YGC-SLAM proposed in this study can effectively eliminate the adverse effects of dynamic objects,and the system can better complete positioning and map building tasks in complex environments. 展开更多
关键词 Visual SLAM Dynamic SLAM Target detection geometric constraints
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Switchable Band Topology and Geometric Current in Sliding Bilayer Elemental Ferroelectric
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作者 Zhuang Qian Zhihao Gong +2 位作者 Jian Li Hua Wang Shi Liu 《Chinese Physics Letters》 2025年第7期410-418,共9页
We demonstrate that the sliding motion between two layers of the newly discovered ferroelectric and topologically trivial bismuth(Bi)monolayer[Nature 61767(2023)]can induce a sequence of topological phase transitions,... We demonstrate that the sliding motion between two layers of the newly discovered ferroelectric and topologically trivial bismuth(Bi)monolayer[Nature 61767(2023)]can induce a sequence of topological phase transitions,alternating between Z_(2)trivial and nontrivial states.The lateral shift,while preserving spatial symmetry,can switch the quantum spin Hall state on and of.The sliding-induced changes in out-of-plane atomic buckling,which are directly coupled to in-plane ferroelectricity,are shown to signifcantly modulate the band gap and drive the topological phase transitions.We map out the topological phase diagram and in-plane ferroelectricity with respect to sliding displacements.With appropriate sliding,the bismuth bilayer can transition into a nontrivial polar metal,exhibiting a pronounced shift current response arising from interband geometric quantities of electronic bands.Moreover,bilayer Bi supports a sliding-tunable nonlinear anomalous Hall response resulting from the geometric Berry curvature dipole.Confgurations that are Z_(2)nontrivial can generate drastically different transverse currents orthogonal to the external electric feld,as both the direction and magnitude of the Berry curvature dipole at the Fermi level are highly sensitive to the sliding displacement.Our results suggest that bilayer bismuth,with its ability to generate multiple types of geometric currents,ofers a versatile platform for power-efcient“Berry slidetronics”for multistate memory applications integrating both band topology and ferroelectricity. 展开更多
关键词 sliding bilayer switchable band topology geometric current elemental ferroelectric topological phase transitions topological phase transitionsalternating sliding motion lateral shiftwhile
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Level-Set-Based Topology Optimization of a Geometrically Nonlinear Structure Considering Thermo-mechanical Coupling Effect
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作者 Sujun Wang An Xu Ruohong Zhao 《Acta Mechanica Solida Sinica》 2025年第1期100-114,共15页
This paper presents an improved level set method for topology optimization of geometrically nonlinear structures accounting for the effect of thermo-mechanical couplings.It derives a new expression for element couplin... This paper presents an improved level set method for topology optimization of geometrically nonlinear structures accounting for the effect of thermo-mechanical couplings.It derives a new expression for element coupling stress resulting from the combination of mechanical and thermal loading,using geometric nonlinear finite element analysis.A topological model is then developed to minimize compliance while meeting displacement and frequency constraints to fulfill design requirements of structural members.Since the conventional Lagrange multiplier search method is unable to handle convergence instability arising from large deformation,a novel Lagrange multiplier search method is proposed.Additionally,the proposed method can be extended to multi-constrained geometrically nonlinear topology optimization,accommodating multiple physical field couplings. 展开更多
关键词 Topology optimization geometric nonlinearity Thermo-mechanical coupling effect Level set method Multiple constraints
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A New Geometric Constant Based on Isosceles Orthogonality
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作者 Yuxin WANG Qi LIU +2 位作者 Yuan WANG Qian LI Yongjin LI 《Journal of Mathematical Research with Applications》 2025年第5期677-688,共12页
In this paper,we introduce a new geometric constant R_(X)(κ)based on isosceles orthogonality.First,we explore some basic properties of this new constant and then provide several examples to estimate its exact values ... In this paper,we introduce a new geometric constant R_(X)(κ)based on isosceles orthogonality.First,we explore some basic properties of this new constant and then provide several examples to estimate its exact values in certain specific Banach spaces.Next,we investigate the relationships between this new constant and other classical constants.Specifically,we establish an inequality relationship between it and the J(X)constant,as well as an identity relationship between it and theρX(t)constant.Furthermore,we characterize some geometric properties of Banach spaces by means of this new constant.Finally,by restricting the above-mentioned constant to the unit sphere,we introduce another new constant,calculate its upper and lower bounds,and present a relevant example. 展开更多
关键词 Banach spaces isosceles orthogonality geometric constants uniformly non-square
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Efficacy of a New Geometric Stiffness Matrix for Buckling Load Analyses
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作者 Barry T.Rosson 《Journal of Civil Engineering and Architecture》 2025年第1期22-26,共5页
This paper investigates the development and performance of a new higher-order geometric stiffness matrix that more closely approximates the theoretically derived stiffness coefficients.Factors that influence the accur... This paper investigates the development and performance of a new higher-order geometric stiffness matrix that more closely approximates the theoretically derived stiffness coefficients.Factors that influence the accuracy of the solution are studied using two columns,two braced frames,and one unbraced frame.Discussion is provided when the new geometric stiffness matrix can be used to improve the buckling load analysis results and when it may provide only nominal additional benefit. 展开更多
关键词 geometric stiffness matrix buckling load stability functions structural frame
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Influence of geometric configurations on friction characteristics during incremental forming process of AA5052 sheet metal
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作者 Guang-can YANG Da-wei ZHANG +1 位作者 Chong TIAN Sheng-dun ZHAO 《Transactions of Nonferrous Metals Society of China》 2025年第3期715-733,共19页
The influence of geometric configuration on the friction characteristics during incremental sheet forming of AA5052 was analyzed by integrating surface morphology and its characteristic parameters,along with plastic s... The influence of geometric configuration on the friction characteristics during incremental sheet forming of AA5052 was analyzed by integrating surface morphology and its characteristic parameters,along with plastic strain,contact pressure,and area.The interface promotes lubrication and support when wall angles were≤40°,a 0.5 mm-thin sheet was used,and a 10 mm-large tool radius was employed.This mainly results in micro-plowing and plastic extrusion flow,leading to lower friction coefficient.However,when wall angles exceed 40°,significant plastic strain roughening occurs,leading to inadequate lubrication on the newly formed surface.Increased sheet thickness and decreased tool radius elevate contact pressure.These actions trigger micro-cutting and adhesion,potentially leading to localized scuffing and dimple tears,and higher friction coefficient.The friction mechanisms remain unaffected by the part’s plane curve features.As the forming process progresses,abrasive wear intensifies,and surface morphology evolves unfavorably for lubrication and friction reduction. 展开更多
关键词 AA5052 sheet metal incremental forming process geometric configurations surface morphology characteristics friction mechanism
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Magnetic Resonance Imaging Reconstruction Based on Butterfly Dilated Geometric Distillation
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作者 DUO Lin XU Boyu +1 位作者 REN Yong YANG Xin 《Journal of Shanghai Jiaotong university(Science)》 2025年第3期590-599,共10页
In order to improve the reconstruction accuracy of magnetic resonance imaging(MRI),an accurate natural image compressed sensing(CS)reconstruction network is proposed,which combines the advantages of model-based and de... In order to improve the reconstruction accuracy of magnetic resonance imaging(MRI),an accurate natural image compressed sensing(CS)reconstruction network is proposed,which combines the advantages of model-based and deep learning-based CS-MRI methods.In theory,enhancing geometric texture details in linear reconstruction is possible.First,the optimization problem is decomposed into two problems:linear approximation and geometric compensation.Aimed at the problem of image linear approximation,the data consistency module is used to deal with it.Since the processing process will lose texture details,a neural network layer that explicitly combines image and frequency feature representation is proposed,which is named butterfly dilated geometric distillation network.The network introduces the idea of butterfly operation,skillfully integrates the features of image domain and frequency domain,and avoids the loss of texture details when extracting features in a single domain.Finally,a channel feature fusion module is designed by combining channel attention mechanism and dilated convolution.The attention of the channel makes the final output feature map focus on the more important part,thus improving the feature representation ability.The dilated convolution enlarges the receptive field,thereby obtaining more dense image feature data.The experimental results show that the peak signal-to-noise ratio of the network is 5.43 dB,5.24 dB and 3.89 dB higher than that of ISTA-Net+,FISTA and DGDN networks on the brain data set with a Cartesian sampling mask CS ratio of 10%. 展开更多
关键词 butterfly geometric distillation dilation convolution channel attention image reconstruction
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Dynamics of quantum discord and geometric quantum discord in multiqubit interacting system
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作者 Xiao-Di Cheng Ya-Jun Zheng +1 位作者 Meng-Jie Ran Xiao-Yun Wang 《Chinese Physics B》 2025年第5期55-62,共8页
Using quantum discord(QD)and geometric quantum discord(GQD),quantum correlation dynamics is investigated for two coupled qubits within a multiqubit interacting system in the zero-temperature bosonic reservoir,under bo... Using quantum discord(QD)and geometric quantum discord(GQD),quantum correlation dynamics is investigated for two coupled qubits within a multiqubit interacting system in the zero-temperature bosonic reservoir,under both weak and strong qubit-reservoir coupling regimes.The multiqubit system is connected with either a common bosonic reservoir(CBR)or multiple independent bosonic reservoirs(IBRs).In the CBR case,our findings indicate that both QD and GQD can be strengthened by increasing the number of qubits in the multiqubit system.Furthermore,we study the steady state QD and GQD in the strong coupling regime,and find that the stable value in the long-time limit is determined exclusively by the number of qubits.The evolution period of QD and GQD gets longer as the dipole–dipole interaction(DDI)strength increases,which helps prolong the correlation time and thus preserves the quantum correlation under the weak coupling regime.Further analysis reveals notable differences between the CBR and IBRs scenarios.In the IBRs case,the decay of QD and GQD becomes slower compared to the CBR case,with both measures tending to zero at a reduced rate.Moreover,GQD consistently exhibits lower values than QD in both scenarios.These findings provide valuable insights into the selection of appropriate correlation measurement techniques for quantifying quantum correlations. 展开更多
关键词 quantum discord geometric quantum discord quantum correlation dynamics multiqubit system
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Accuracy allocation method for five-axis machine tools based on geometric error cost sensitivity prioritizing tool direction deviation
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作者 Xiaojian LIU Ao JIAO +7 位作者 Yang WANG Guodong YI Xiangyu GAO Xiaochen ZHANG Yiming ZHANG Yangjian JI Shuyou ZHANG Jianrong TAN 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 2025年第7期635-651,共17页
Accuracy allocation is crucial in the accuracy design of machining tools.Current accuracy allocation methods primarily focus on positional deviation,with little consideration for tool direction deviation.To address th... Accuracy allocation is crucial in the accuracy design of machining tools.Current accuracy allocation methods primarily focus on positional deviation,with little consideration for tool direction deviation.To address this issue,we propose a geometric error cost sensitivity-based accuracy allocation method for five-axis machine tools.A geometric error model consisting of 4l error components is constructed based on homogeneous transformation matrices.Volumetric points with positional and tool direction deviations are randomly sampled to evaluate the accuracy of the machine tool.The sensitivity of each error component at these sampling points is analyzed using the Sobol method.To balance the needs of geometric precision and manufacturing cost,a geometric error cost sensitivity function is developed to estimate the required cost.By allocating error components affecting tool direction deviation first and the remaining components second,this allocation scheme ensures that both deviations meet the requirements.We also perform numerical simulation of a BC-type(B-axis and C-axis type)five-axis machine tool to validate the method.The results show that the new allocation scheme reduces the total geometric error cost by 27.8%compared to a uniform allocation scheme,and yields the same positional and tool direction machining accuracies. 展开更多
关键词 Five-axis machine tool Accuracy allocation geometric error modeling Error cost sensitivity Tool direction deviation priority
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Neodymium-doped hollow Ir/IrO_(2)nanospheres with low geometric iridium density enable excellent acidic water oxidation performance
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作者 Xiaoqian Wei Hanyu Gao +7 位作者 Tiantian Wang Zijian Li Yanru Geng Guiping Zheng Min Gyu Kim Haeseong Jang Xien Liu Qing Qin 《Chinese Journal of Structural Chemistry》 2025年第7期3-10,共8页
Reducing the Ir loading while preserving catalytic performance and mechanical robustness in anodic catalyst layers remains a critical challenge for the large-scale implementation of proton exchange membrane water elec... Reducing the Ir loading while preserving catalytic performance and mechanical robustness in anodic catalyst layers remains a critical challenge for the large-scale implementation of proton exchange membrane water electrolysis(PEMWE).Herein,we present a structural engineering strategy involving neodymium-doped Ir/IrO_(2)(Nd-Ir/IrO_(2))hollow nanospheres with precisely adjustable shell thickness and cavity dimensions.The optimized catalyst demonstrates excellent oxygen evolution reaction(OER)performance in acidic media,achieving a remarkably low overpotential of 259 mV at a benchmark current density of 10 mA cm^(-2) while exhibiting substantially enhanced durability compared to commercial IrO_(2) and Ir/IrO_(2) counterparts.Notably,the Nd-Ir/IrO_(2) catalyst delivers a mass activity of 541.6 A gIr^(-1) at 1.50 V vs RHE,representing a 74.5-fold enhancement over conventional IrO_(2).Through comprehensive electrochemical analysis and advanced characterization techniques reveal that,the hierarchical hollow architecture simultaneously addresses multiple critical requirements:(i)abundant exposed active sites enabled by an enhanced electrochemical surface area,(ii)optimized mass transport pathways through engineered porosity,and(iii)preserved structural integrity via a continuous conductive framework,collectively enabling significant Ir loading reduction without compromising catalytic layer performance.Fundamental mechanistic investigations further disclose that Nd doping induces critical interfacial Nd-O-Ir configurations that stabilize lattice oxygen,together with intensified electron effect among mixed valent Ir that inhibits the overoxidation of Ir active sites during the OER process,synergistically ensuring enhanced catalytic durability.Our work establishes a dual-modulation paradigm integrating nanoscale architectural engineering with atomic-level heteroatom doping,providing a viable pathway toward high-performance PEMWE systems with drastically reduced noble metal requirements. 展开更多
关键词 Oxygen evolution catalyst Low iridium geometric density Electronic effect Nanoscale architectural engineering Anodic catalyst layer
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Automatic interpretation of geometric information of discontinuities and its influence on the stability of highly-jointed rock slopes
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作者 Yaping Wang Jiawen Zhou +3 位作者 Qin Chen Junlin Chen Chun Zhu Haibo Li 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第9期5479-5492,共14页
The discrete fracture system of a rock mass plays a crucial role in controlling the stability of rock slopes.To fully account for the geometric shape and distribution characteristics of jointed rock masses,terrestrial... The discrete fracture system of a rock mass plays a crucial role in controlling the stability of rock slopes.To fully account for the geometric shape and distribution characteristics of jointed rock masses,terrestrial laser scanning(TLS)was employed to acquire high-resolution point-cloud data,and a developed automatic discontinuity-identification technology was coupled to automatically interpret and characterize geometric information such as orientation,trace length,spacing,and set number of the discontinuities.The discrete element method(DEM)was applied to study the influence of the geometric morphology and distribution characteristics of discontinuities on slope stability by generating a discrete fracture network(DFN)with the same statistical characteristics as the actual discontinuities.Based on slope data from the Yebatan Hydropower Station,a simulation was conducted to verify the applicability of the automatic discontinuity identification technology and the discrete fracture network-discrete element method(DFN-DEM).Various geological parameters,including trace length,persistence,and density,were examined to investigate the morphological evolution and response characteristics of rock slope excavation under different joint combination conditions through simulation.The simulation results indicate that joint parameters affect slope stability,with density having the most significant impact.The impact of joint parameters on stability is relatively small within a reasonable range but becomes significant beyond a certain threshold,further validating that the accuracy of field geological surveys is critical for simulation.This study provides a scientific basis for the construction of complex rock slope models,engineering assessments,and disaster prevention and mitigation,which is of great value in both theory and engineering applications. 展开更多
关键词 Jointed rock mass Terrestrial laser scanning(TLS) geometric information interpretation Discrete fracture network(DFN) Rock slope stability
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Geometric error measuring,modeling,and compensation for CNC machine tools:A review 被引量:14
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作者 Zhao ZHANG Feng JIANG +3 位作者 Ming LUO Baohai WU Dinghua ZHANG Kai TANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2024年第2期163-198,共36页
Geometric error,mainly due to imperfect geometry and dimensions of machine components,is one of the major error sources of machine tools.Considering that geometric error has significant effects on the machining qualit... Geometric error,mainly due to imperfect geometry and dimensions of machine components,is one of the major error sources of machine tools.Considering that geometric error has significant effects on the machining quality of manufactured parts,it has been a popular topic for academic and industrial research for many years.A great deal of research work has been carried out since the 1970s for solving the problem and improving the machining accuracy.Researchers have studied how to measure,detect,model,identify,reduce,and compensate the geometric errors.This paper presents a thorough review of the latest research activities and gives an overview of the state of the art in understanding changes in machine tool performance due to geometric errors.Recent advances in measuring the geometrical errors of machine tools are summarized,and different kinds of error identification methods of translational axes and rotation axes are illustrated respectively.Besides,volumetric geometric error modeling,tracing,and compensation techniques for five-axis machine tools are emphatically introduced.Finally,research challenges in order to improve the volumetric accuracy of machine tools are also highlighted. 展开更多
关键词 Error compensation Error identification Error measurement Error modeling geometric error Machine tools
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Geometric Error Identification of Gantry-Type CNC Machine Tool Based on Multi-Station Synchronization Laser Tracers 被引量:3
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作者 Jun Zha Huijie Zhang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第2期150-162,共13页
Laser tracers are a three-dimensional coordinate measurement system that are widely used in industrial measurement.We propose a geometric error identification method based on multi-station synchronization laser tracer... Laser tracers are a three-dimensional coordinate measurement system that are widely used in industrial measurement.We propose a geometric error identification method based on multi-station synchronization laser tracers to enable the rapid and high-precision measurement of geometric errors for gantry-type computer numerical control(CNC)machine tools.This method also improves on the existing measurement efficiency issues in the single-base station measurement method and multi-base station time-sharing measurement method.We consider a three-axis gantry-type CNC machine tool,and the geometric error mathematical model is derived and established based on the combination of screw theory and a topological analysis of the machine kinematic chain.The four-station laser tracers position and measurement points are realized based on the multi-point positioning principle.A self-calibration algorithm is proposed for the coordinate calibration process of a laser tracer using the Levenberg-Marquardt nonlinear least squares method,and the geometric error is solved using Taylor’s first-order linearization iteration.The experimental results show that the geometric error calculated based on this modeling method is comparable to the results from the Etalon laser tracer.For a volume of 800 mm×1000 mm×350 mm,the maximum differences of the linear,angular,and spatial position errors were 2.0μm,2.7μrad,and 12.0μm,respectively,which verifies the accuracy of the proposed algorithm.This research proposes a modeling method for the precise measurement of errors in machine tools,and the applied nature of this study also makes it relevant both to researchers and those in the industrial sector. 展开更多
关键词 Multi-point positioning Multi-station synchronization CNC machine tool geometric error Error separation
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