To explore the geochemical characteristics and genesis of the elements in ferromanganese nodules from the Northwest Pacific,this study analyses the mineral composition,elemental content,occurrence phase and genetic me...To explore the geochemical characteristics and genesis of the elements in ferromanganese nodules from the Northwest Pacific,this study analyses the mineral composition,elemental content,occurrence phase and genetic mechanisms of samples by X-ray diffraction(XRD),inductively coupled plasma-optical emission spectrometry(ICP-OES),inductively coupled plasma-mass spectrometry(ICP-MS)and phase analysis methods.The results show that ferromanganese nodules are mainly hydrogenetic,and Mn/Fe content ratio ranges from 0.95 to 2.05.The major minerals are vernadite(δ-MnO_(2))and amorphous ferric oxyhydroxide(FeOOH),and the secondary minerals include todorokite,birnessite,quartz and plagioclase.Ferromanganese nodules contain high contents of Co(0.24%-0.42%),Cu(0.23%-0.73%),Ni(0.33%-0.86%)and rare earth elements(REEs,1192-1990μg/g),which have positive Ce and negative Y anomalies but no Eu anomaly.A cluster analysis suggests that the elements in ferromanganese nodules can be divided into three groups:hydrogenetic components,including Fe,Ti,Zr,P,Pb,Co,Ba,Sr,V and REEs;diagenetic components,including Mn,Ni,Mg,Zn and Cu;and detrital components,including Al,Na,K and Ca.According to chemical leaching,ferromanganese nodules can be divided into four phases:Na,Ca,Mg and Sr are mainly enriched in the carbonate phase;Mn,Co,Ni and Ba are mainly enriched in the Mn-oxide phase;Fe,P,Ti,Cu,Pb,V,Zn,Zr and REEs are mainly enriched in the Fe-oxide phase;and Al and K are mainly enriched in the residual phase.A combination of the two different methods reveal selective enrichment of metal elements from seawater by ferromanganese nodules,featuring multisource mineralization.Moreover,through ion exchange and adsorption,approximately 71.2%of REEs are enriched in the Fe-oxide phase,15.4%in the Mn-oxide phase and 12.4%in the residual phase,while REE contents in the carbonate phase are relatively low.In addition,under the oxic conditions of seawater,the oxidation of soluble Ce^(3+)to insoluble CeO_(2)together with Fe-Mn minerals results in Ce enrichment in ferromanganese nodules.This study provides a reference for the metallogenesis of ferromanganese nodules from the Northwest Pacific.展开更多
The Baibokoum syenitic pluton(BSP),located in southern Chad,to the NE of the Adamawa-Yadédomain,is one of the few strongly potassic magmatic bodies in the southern part of the Central African Fold Belt(CAFB)in Ch...The Baibokoum syenitic pluton(BSP),located in southern Chad,to the NE of the Adamawa-Yadédomain,is one of the few strongly potassic magmatic bodies in the southern part of the Central African Fold Belt(CAFB)in Chad.It has been previously studied petrologically,but its petrogenesis has remained poorly known.Petrographic and whole-rock geochemical data presented in this article highlight their magma genesis and geodynamic evolution.The BSP consists of medium-to coarse-grained syenites associated with minor microdiorites,which occur as syn-plutonic dikes and mafic microgranular enclaves(MME)coarse-and medium-grained syenites outcrop respectively to the core and the border of the BSP.The syenite displays high-K and alkaline to trans-alkaline affinity.Petrographic and geochemical data suggest that medium-to coarse-grained syenites are from single magma source that evolved and differentiated by fractional crystallization in a magma reservoir.REE profiles show enriched LREEs(La_(N)/Yb_(N)=6.19-45.55)while HREEs show an almost flat profile(Dy_(N)/Yb_(N)=1.0-2.23),and the La/Sm and Sm/Yb ratios have led to propose that the aforementioned rocks derived from the partial melting of a garnet-spinel-lherzolite mantle source.Negative Nb and Ta anomalies indicate that this mantle source was modified by the addition of subduction-related material.Th/Yb ratios associated with high Ba/La ratios indicate that enrichment of the source could be related to slab-derived fluids.The parental magma of the BSP was generated by partial melting of the metasomatized lithospheric mantle that was modified into arc-magmatism material in a subduction setting.Its emplacement took place in two successive stages:a static stage of fractional crystallization and crystal settling in a deep magma source and a dynamic stage in a shear deformation setting during which stratified magma rises towards the upper crust,with evolved syenite magma being emplaced first and diorite later.The emplacement of the BSP was probably controlled by the evolution of the Tcholliré-Banyo Fault and M'BéréShear Zone during the Pan-African orogeny.展开更多
The 10000-m ultradeep dolomite reservoir holds significant potential as a successor field for future oil and gas exploration in China's marine craton basin.However,major challenges such as the genesis of dolomite,...The 10000-m ultradeep dolomite reservoir holds significant potential as a successor field for future oil and gas exploration in China's marine craton basin.However,major challenges such as the genesis of dolomite,the formation time of high-quality reservoirs,and the preservation mechanism of reservoirs have always limited exploration decision-making.This research systematically elaborates on the genesis and reservoir-forming mechanisms of Sinian-Cambrian dolomite,discussing the ancient marine environment where microorganisms and dolomite develop,which controls the formation of large-scale Precambrian-Cambrian dolomite.The periodic changes inMg isotopes and sedimentary cycles show that the thick-layered dolomite is the result of different dolomitization processes superimposed on a spatiotemporal scale.Lattice defects and dolomite embryos can promote dolomitization.By simulating the dissolution of typical calcite and dolomite crystal faces in different solution systems and calculating their molecular weights,the essence of heterogeneous dissolution and pore formation on typical calcite and dolomite crystal faces was revealed,and the mechanism of dolomitization was also demonstrated.The properties of calcite and dolomite(104)/(110)grain boundaries and their dissolution mechanism in carbonate solution were revealed,showing the limiting factors of the dolomitization process and the preservation mechanism of deep buried dolomite reservoirs.The in situ laser U-Pb isotope dating technique has demonstrated the timing of dolomitization and pore formation in ancient carbonate rocks.This research also proposed that dolomitization occurred during the quasi-contemporaneous or shallow-burial periods within 50Ma after deposition and pores formed during the quasi-contemporaneous to the early diagenetic periods.And it was clear that the quasi-contemporaneous dolomitization was the key period for reservoir formation.The systematic characterization of the spatial distribution of the deepest dolomite reservoirs in multiple sets of the Sinian and the Cambrian in the Chinese craton basins provides an important basis for the distribution prediction of large-scale dolomite reservoirs.It clarifies the targets for oil and gas exploration at depths over 10000 m.The research on dolomite in this study will greatly promote China's ultradeep oil and gas exploration and lead the Chinese petroleum industry into a new era of 10000-m deep oil exploration.展开更多
The Jizhong-Yanbian Cu-Mo-Au-Pb-Zn polymetallic metallogenic belt is a major nonferrous and precious metal resource base in Northeastern China.The genesis of ore deposits in this district has remained controversial.To...The Jizhong-Yanbian Cu-Mo-Au-Pb-Zn polymetallic metallogenic belt is a major nonferrous and precious metal resource base in Northeastern China.The genesis of ore deposits in this district has remained controversial.To constrain ore genetic models and provide information for exploration,we conducted precise Zn-Cd isotopic measurements on sphalerite and galena.Theδ^(66)Zn_(AA-ETH)values of galena and sphalerite range from−0.07‰to 0.03‰and−0.68‰to−0.12‰,respectively;and theirδ^(114/110)Cd_(NIST SRM 3108)values vary from−0.96‰to 3.83‰and−0.63‰to 0.77‰,respectively.Our study suggests that the Xiaohongshilazi Pb-Zn-(Ag)deposit should be classified as a Mississippi Valley Type(MVT)-like deposit,because both its geological,sulfide trace elemental,and S-Pb-Fe-Zn-Cd isotopic characteristics are similar to those of the typical MVT deposit,except for the differences of the wall rocks.Rayleigh fractionation during sphalerite precipitation is identified as the primary mechanism for Zn-Cd isotopic variations,which is validated by the Zn-Cd fractionation models from 100℃to 250℃.Finally,we propose an ore prospecting model based on migration pathways of ore-forming fluid and the Zn isotopic fractionation model of sphalerite under 100℃.This model indicates potential resources undiscovered at shallow/peripheral and deep zones of current mining level in both the Eastern and Western Ore Block,with parts of the potential resources having been corroborated by recent drilling.Despite the complexity of mineralization,processes,this study provides new insights into the application of Zn-Cd isotopes in understanding ore genesis and guiding mineral exploration in similar contexts.展开更多
The Xialonggang Pb-Zn-Sb deposit is a newly discovered large-scale polymetallic deposit within the Tethyan Himalayan metallogenic belt.Although significant prospecting breakthroughs have been made at Xialonggang in re...The Xialonggang Pb-Zn-Sb deposit is a newly discovered large-scale polymetallic deposit within the Tethyan Himalayan metallogenic belt.Although significant prospecting breakthroughs have been made at Xialonggang in recent years,the geology and mineralization process are poorly understood.This study conducted monazite U-Pb geochronology,fluid inclusion,and O-H-S isotope of the Xialonggang Pb-Zn-Sb deposit.Analytical results indicate that the ore-forming fluids constituted a H_(2)O-NaCl-CO_(2)-CH_(4)-N_(2)system characterized by moderate temperatures(261-314℃)and moderate to low salinities(2.9-8.9 wt%NaCl eqv.).The early-stage fluids exhibited signatures close to magmatic fluids,while the late-stage fluids showed characteristics indicative of mixing between magmatic fluids and meteoric water.Sulfur isotope analysis(mainly range primarily from 1.2‰to 6.44‰,with one sphalerite up to 8.19‰)revealed that a predominantly deep-sourced sulfur composition with minor contribution from sedimentary strata.This study demonstrates that the Xialonggang Pb-Zn-Sb deposit is controlled by the NE-trending fault system.A hydrothermal circulation system driven by substantial deep-seated magmatic heat,leached materials from the surrounding strata.The hydrothermal fluids migrated upwards along the fault system,filling the NE-trending tensional fractures to form a hydrothermal vein-type Pb-Zn-Sb deposit.展开更多
Cloud resolving Weather Research and Forecasting(WRF)model simulations are used to investigate tropical cyclone(TC)genesis efficiency in an environment with a near bottom vortex(EBV)and an environment with a mid-level...Cloud resolving Weather Research and Forecasting(WRF)model simulations are used to investigate tropical cyclone(TC)genesis efficiency in an environment with a near bottom vortex(EBV)and an environment with a mid-level vortex(EMV).Sensitivity experiments show that the genesis timing depends greatly on initial vorticity vertical profiles.The larger the initial column integrated absolute vorticity,the greater the genesis efficiency is.Given the same column integrated absolute vorticity,a bottom vortex has higher genesis efficiency than a mid-level vortex.A common feature among these experiments is the formation of a mid-level vorticity maximum prior to TC genesis irrespective where the initial vorticity maximum locates.Both the EMV and EBV scenarios share the following development characteristics:1)a transition from non-organized cumulus-scale(~5 km)convective cells into an organized meso-vortex-scale(~50 to 100 km)system through upscale cascade processes,2)the establishment of a nearly saturated air column prior to a rapid drop of the central minimum pressure,and 3)a multiple convective-stratiform phase transition.A genesis efficiency index(GEI)is formulated that includes the following factors:initial column integrated absolute vorticity,vorticity at top of the boundary layer and vertically integrated relative humidity.The calculated GEI reflects well the simulated genesis efficiency and thus may be used to estimate how fast a tropical disturbance develops into a TC.展开更多
The diversity of sandstone diagenesis mechanisms caused by the complex geological conditions of oil/gas basins in China could hardly be reasonably explained by the traditional concept of burial diagenesis. Three genes...The diversity of sandstone diagenesis mechanisms caused by the complex geological conditions of oil/gas basins in China could hardly be reasonably explained by the traditional concept of burial diagenesis. Three genesis types of thermal diagenesis, tectonic diagenesis and fluid diagenesis are presented on the basis of the dynamic environment of the oil/gas basins and.the controlling factors and mechanisms of sandstone diagenesis. Thermal diagenesis of sandstone reservoirs is related not only to the effect of formation temperature on diagenesis, but also to the significant changes in diagenesis caused by geothermal gradients. The concept of thermal compaction is presented. Thermal compaction becomes weaker with increasing depth and becomes stronger at a higher geothermal gradient. At the same formation temperature, the sandstone porosity in the region with a lower geothermal gradient is e^0.077+0.0042T times higher than that in the region with a higher geothermal gradient. Both sudden and gradual changes are observed in diagenetic evolution caused by structural deformation. Average sandstone compaction increased by 0.1051% for every 1.0MPa increase of lateral tectonic compressional stress, while late tectonic napping helped to preserve a higher porosity of underlying sandstone reservoir. Fluid diagenesis is a general phenomenon. The compaction caused by fluid properties is significant. The coarser the grain size, the stronger the fluid effect on compaction. The greater the burial depth, the weaker the fluid effect on compaction for the specific reservoir lithology and the greater the difference in the fluid effects on compaction between different grain sizes.展开更多
The quasi-biweekly oscillation (QBWO) is the second most dominant intraseasonal mode over the westem North Pacific (WNP) during boreal summer. In this study, the modulation of WNP tropical cyclogenesis (TCG) by ...The quasi-biweekly oscillation (QBWO) is the second most dominant intraseasonal mode over the westem North Pacific (WNP) during boreal summer. In this study, the modulation of WNP tropical cyclogenesis (TCG) by the QBWO and its association with large-scale patterns are investigated. A strong modulation of WNP TCG events by the QBWO is found. More TCG events occur during the QBWO's convectively active phase. Based on the genesis potential index (GPI), we further evaluate the role of environmental factors in affecting WNP TCG. The positive GPI anomalies associated with the QBWO correspond well with TCG counts and locations. A large positive GPI anomaly is spatially correlated with WNP TCG events during a life cycle of the QBWO. The low-level relative vorticity and mid-level relative humidity appear to be two dominant contributors to the QBWO-composited GPI anomalies during the QBWO's active phase, followed by the nonlinear and potential intensity terms. These positive contributions to the GPI anomalies are partly offset by the negative contribution from the vertical wind shear. During the QBWO's inactive phase, the mid-level relative humidity appears to be the largest contributor, while weak contributions are also made by the nonlinear and low-level relative vorticity terms. Meanwhile, these positive contributions are partly cancelled out by the negative contribution from the potential intensity. The contributions of these environmental factors to the GPI anomalies associated with the QBWO are similar in all five flow patterns--the monsoon shear line, monsoon confluence region, monsoon gyre, easterly wave, and Rossby wave energy dispersion associated with a preexisting TC. Further analyses show that the QBWO strongly modulates the synoptic-scale wave trains (SSWs) over the WNP, with larger amplitude SSWs during the QBWO's active phase. This implies a possible enhanced (weakened) relationship between TCG and SSWs during the active (inactive) phase. This study improves our understanding of the modulation of WNP TCG by the QBWO and thus helps with efforts to improve the intraseasonal prediction of WNP TCG.展开更多
基金The Fund of Laoshan Laboratory under contract No.LSKJ202203602the National key R&D Program of China under contract No.2022YFC2803600the Taishan Scholarship from Shandong Province.
文摘To explore the geochemical characteristics and genesis of the elements in ferromanganese nodules from the Northwest Pacific,this study analyses the mineral composition,elemental content,occurrence phase and genetic mechanisms of samples by X-ray diffraction(XRD),inductively coupled plasma-optical emission spectrometry(ICP-OES),inductively coupled plasma-mass spectrometry(ICP-MS)and phase analysis methods.The results show that ferromanganese nodules are mainly hydrogenetic,and Mn/Fe content ratio ranges from 0.95 to 2.05.The major minerals are vernadite(δ-MnO_(2))and amorphous ferric oxyhydroxide(FeOOH),and the secondary minerals include todorokite,birnessite,quartz and plagioclase.Ferromanganese nodules contain high contents of Co(0.24%-0.42%),Cu(0.23%-0.73%),Ni(0.33%-0.86%)and rare earth elements(REEs,1192-1990μg/g),which have positive Ce and negative Y anomalies but no Eu anomaly.A cluster analysis suggests that the elements in ferromanganese nodules can be divided into three groups:hydrogenetic components,including Fe,Ti,Zr,P,Pb,Co,Ba,Sr,V and REEs;diagenetic components,including Mn,Ni,Mg,Zn and Cu;and detrital components,including Al,Na,K and Ca.According to chemical leaching,ferromanganese nodules can be divided into four phases:Na,Ca,Mg and Sr are mainly enriched in the carbonate phase;Mn,Co,Ni and Ba are mainly enriched in the Mn-oxide phase;Fe,P,Ti,Cu,Pb,V,Zn,Zr and REEs are mainly enriched in the Fe-oxide phase;and Al and K are mainly enriched in the residual phase.A combination of the two different methods reveal selective enrichment of metal elements from seawater by ferromanganese nodules,featuring multisource mineralization.Moreover,through ion exchange and adsorption,approximately 71.2%of REEs are enriched in the Fe-oxide phase,15.4%in the Mn-oxide phase and 12.4%in the residual phase,while REE contents in the carbonate phase are relatively low.In addition,under the oxic conditions of seawater,the oxidation of soluble Ce^(3+)to insoluble CeO_(2)together with Fe-Mn minerals results in Ce enrichment in ferromanganese nodules.This study provides a reference for the metallogenesis of ferromanganese nodules from the Northwest Pacific.
文摘The Baibokoum syenitic pluton(BSP),located in southern Chad,to the NE of the Adamawa-Yadédomain,is one of the few strongly potassic magmatic bodies in the southern part of the Central African Fold Belt(CAFB)in Chad.It has been previously studied petrologically,but its petrogenesis has remained poorly known.Petrographic and whole-rock geochemical data presented in this article highlight their magma genesis and geodynamic evolution.The BSP consists of medium-to coarse-grained syenites associated with minor microdiorites,which occur as syn-plutonic dikes and mafic microgranular enclaves(MME)coarse-and medium-grained syenites outcrop respectively to the core and the border of the BSP.The syenite displays high-K and alkaline to trans-alkaline affinity.Petrographic and geochemical data suggest that medium-to coarse-grained syenites are from single magma source that evolved and differentiated by fractional crystallization in a magma reservoir.REE profiles show enriched LREEs(La_(N)/Yb_(N)=6.19-45.55)while HREEs show an almost flat profile(Dy_(N)/Yb_(N)=1.0-2.23),and the La/Sm and Sm/Yb ratios have led to propose that the aforementioned rocks derived from the partial melting of a garnet-spinel-lherzolite mantle source.Negative Nb and Ta anomalies indicate that this mantle source was modified by the addition of subduction-related material.Th/Yb ratios associated with high Ba/La ratios indicate that enrichment of the source could be related to slab-derived fluids.The parental magma of the BSP was generated by partial melting of the metasomatized lithospheric mantle that was modified into arc-magmatism material in a subduction setting.Its emplacement took place in two successive stages:a static stage of fractional crystallization and crystal settling in a deep magma source and a dynamic stage in a shear deformation setting during which stratified magma rises towards the upper crust,with evolved syenite magma being emplaced first and diorite later.The emplacement of the BSP was probably controlled by the evolution of the Tcholliré-Banyo Fault and M'BéréShear Zone during the Pan-African orogeny.
基金National Natural Science Foundation of China,Grant/Award Number:42230812。
文摘The 10000-m ultradeep dolomite reservoir holds significant potential as a successor field for future oil and gas exploration in China's marine craton basin.However,major challenges such as the genesis of dolomite,the formation time of high-quality reservoirs,and the preservation mechanism of reservoirs have always limited exploration decision-making.This research systematically elaborates on the genesis and reservoir-forming mechanisms of Sinian-Cambrian dolomite,discussing the ancient marine environment where microorganisms and dolomite develop,which controls the formation of large-scale Precambrian-Cambrian dolomite.The periodic changes inMg isotopes and sedimentary cycles show that the thick-layered dolomite is the result of different dolomitization processes superimposed on a spatiotemporal scale.Lattice defects and dolomite embryos can promote dolomitization.By simulating the dissolution of typical calcite and dolomite crystal faces in different solution systems and calculating their molecular weights,the essence of heterogeneous dissolution and pore formation on typical calcite and dolomite crystal faces was revealed,and the mechanism of dolomitization was also demonstrated.The properties of calcite and dolomite(104)/(110)grain boundaries and their dissolution mechanism in carbonate solution were revealed,showing the limiting factors of the dolomitization process and the preservation mechanism of deep buried dolomite reservoirs.The in situ laser U-Pb isotope dating technique has demonstrated the timing of dolomitization and pore formation in ancient carbonate rocks.This research also proposed that dolomitization occurred during the quasi-contemporaneous or shallow-burial periods within 50Ma after deposition and pores formed during the quasi-contemporaneous to the early diagenetic periods.And it was clear that the quasi-contemporaneous dolomitization was the key period for reservoir formation.The systematic characterization of the spatial distribution of the deepest dolomite reservoirs in multiple sets of the Sinian and the Cambrian in the Chinese craton basins provides an important basis for the distribution prediction of large-scale dolomite reservoirs.It clarifies the targets for oil and gas exploration at depths over 10000 m.The research on dolomite in this study will greatly promote China's ultradeep oil and gas exploration and lead the Chinese petroleum industry into a new era of 10000-m deep oil exploration.
基金supported by the Open Research Project from the Young Elite Scientists Sponsorship Program by BAST(No.BYESS2023411)the State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences(GPMR202407)the Enterprise Authorized Item from Jilin Sanhe Mining Development Co.LTD(3-4-2021-120).
文摘The Jizhong-Yanbian Cu-Mo-Au-Pb-Zn polymetallic metallogenic belt is a major nonferrous and precious metal resource base in Northeastern China.The genesis of ore deposits in this district has remained controversial.To constrain ore genetic models and provide information for exploration,we conducted precise Zn-Cd isotopic measurements on sphalerite and galena.Theδ^(66)Zn_(AA-ETH)values of galena and sphalerite range from−0.07‰to 0.03‰and−0.68‰to−0.12‰,respectively;and theirδ^(114/110)Cd_(NIST SRM 3108)values vary from−0.96‰to 3.83‰and−0.63‰to 0.77‰,respectively.Our study suggests that the Xiaohongshilazi Pb-Zn-(Ag)deposit should be classified as a Mississippi Valley Type(MVT)-like deposit,because both its geological,sulfide trace elemental,and S-Pb-Fe-Zn-Cd isotopic characteristics are similar to those of the typical MVT deposit,except for the differences of the wall rocks.Rayleigh fractionation during sphalerite precipitation is identified as the primary mechanism for Zn-Cd isotopic variations,which is validated by the Zn-Cd fractionation models from 100℃to 250℃.Finally,we propose an ore prospecting model based on migration pathways of ore-forming fluid and the Zn isotopic fractionation model of sphalerite under 100℃.This model indicates potential resources undiscovered at shallow/peripheral and deep zones of current mining level in both the Eastern and Western Ore Block,with parts of the potential resources having been corroborated by recent drilling.Despite the complexity of mineralization,processes,this study provides new insights into the application of Zn-Cd isotopes in understanding ore genesis and guiding mineral exploration in similar contexts.
基金financially supported by the China Geological Survey(Grant Nos.DD20240014 and DD20243090)Central governmentguided local scientific and technological development fund project(Grant No.XZ202401YD0006-07)Ministry of Natural Resources of China(Grant No.ZKKJ202427)。
文摘The Xialonggang Pb-Zn-Sb deposit is a newly discovered large-scale polymetallic deposit within the Tethyan Himalayan metallogenic belt.Although significant prospecting breakthroughs have been made at Xialonggang in recent years,the geology and mineralization process are poorly understood.This study conducted monazite U-Pb geochronology,fluid inclusion,and O-H-S isotope of the Xialonggang Pb-Zn-Sb deposit.Analytical results indicate that the ore-forming fluids constituted a H_(2)O-NaCl-CO_(2)-CH_(4)-N_(2)system characterized by moderate temperatures(261-314℃)and moderate to low salinities(2.9-8.9 wt%NaCl eqv.).The early-stage fluids exhibited signatures close to magmatic fluids,while the late-stage fluids showed characteristics indicative of mixing between magmatic fluids and meteoric water.Sulfur isotope analysis(mainly range primarily from 1.2‰to 6.44‰,with one sphalerite up to 8.19‰)revealed that a predominantly deep-sourced sulfur composition with minor contribution from sedimentary strata.This study demonstrates that the Xialonggang Pb-Zn-Sb deposit is controlled by the NE-trending fault system.A hydrothermal circulation system driven by substantial deep-seated magmatic heat,leached materials from the surrounding strata.The hydrothermal fluids migrated upwards along the fault system,filling the NE-trending tensional fractures to form a hydrothermal vein-type Pb-Zn-Sb deposit.
基金Office of Naval Research(N000140810256,N000141010774)National Science Foundation of China(41075037)+2 种基金Japan Agency for Marine-Earth Science and Technology(JAMSTEC)NASA(NNX07AG53G)NOAA(NA17RJ1230)
文摘Cloud resolving Weather Research and Forecasting(WRF)model simulations are used to investigate tropical cyclone(TC)genesis efficiency in an environment with a near bottom vortex(EBV)and an environment with a mid-level vortex(EMV).Sensitivity experiments show that the genesis timing depends greatly on initial vorticity vertical profiles.The larger the initial column integrated absolute vorticity,the greater the genesis efficiency is.Given the same column integrated absolute vorticity,a bottom vortex has higher genesis efficiency than a mid-level vortex.A common feature among these experiments is the formation of a mid-level vorticity maximum prior to TC genesis irrespective where the initial vorticity maximum locates.Both the EMV and EBV scenarios share the following development characteristics:1)a transition from non-organized cumulus-scale(~5 km)convective cells into an organized meso-vortex-scale(~50 to 100 km)system through upscale cascade processes,2)the establishment of a nearly saturated air column prior to a rapid drop of the central minimum pressure,and 3)a multiple convective-stratiform phase transition.A genesis efficiency index(GEI)is formulated that includes the following factors:initial column integrated absolute vorticity,vorticity at top of the boundary layer and vertically integrated relative humidity.The calculated GEI reflects well the simulated genesis efficiency and thus may be used to estimate how fast a tropical disturbance develops into a TC.
文摘The diversity of sandstone diagenesis mechanisms caused by the complex geological conditions of oil/gas basins in China could hardly be reasonably explained by the traditional concept of burial diagenesis. Three genesis types of thermal diagenesis, tectonic diagenesis and fluid diagenesis are presented on the basis of the dynamic environment of the oil/gas basins and.the controlling factors and mechanisms of sandstone diagenesis. Thermal diagenesis of sandstone reservoirs is related not only to the effect of formation temperature on diagenesis, but also to the significant changes in diagenesis caused by geothermal gradients. The concept of thermal compaction is presented. Thermal compaction becomes weaker with increasing depth and becomes stronger at a higher geothermal gradient. At the same formation temperature, the sandstone porosity in the region with a lower geothermal gradient is e^0.077+0.0042T times higher than that in the region with a higher geothermal gradient. Both sudden and gradual changes are observed in diagenetic evolution caused by structural deformation. Average sandstone compaction increased by 0.1051% for every 1.0MPa increase of lateral tectonic compressional stress, while late tectonic napping helped to preserve a higher porosity of underlying sandstone reservoir. Fluid diagenesis is a general phenomenon. The compaction caused by fluid properties is significant. The coarser the grain size, the stronger the fluid effect on compaction. The greater the burial depth, the weaker the fluid effect on compaction for the specific reservoir lithology and the greater the difference in the fluid effects on compaction between different grain sizes.
基金jointly supported by the National Natural Science Foundation of China(Grant Nos.41675072,41305050,41275093,41475091 and 41305039)the National Basic Research Program of China(Grant Nos.2013CB430301,2013CB430103 and 2015CB452803)+5 种基金the Jiangsu Provincial Natural Science Fund Project(Grant No.BK20150910)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(Grant No.14KJA170005)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the Project of Global Change and Air–Sea Interaction(Grant No.GASI-03-IPOVAI-04)the base funding of the Atlantic Oceanographic and Meteorological Laboratory(AOML)Earth System Modelling Center Contribution Number 117
文摘The quasi-biweekly oscillation (QBWO) is the second most dominant intraseasonal mode over the westem North Pacific (WNP) during boreal summer. In this study, the modulation of WNP tropical cyclogenesis (TCG) by the QBWO and its association with large-scale patterns are investigated. A strong modulation of WNP TCG events by the QBWO is found. More TCG events occur during the QBWO's convectively active phase. Based on the genesis potential index (GPI), we further evaluate the role of environmental factors in affecting WNP TCG. The positive GPI anomalies associated with the QBWO correspond well with TCG counts and locations. A large positive GPI anomaly is spatially correlated with WNP TCG events during a life cycle of the QBWO. The low-level relative vorticity and mid-level relative humidity appear to be two dominant contributors to the QBWO-composited GPI anomalies during the QBWO's active phase, followed by the nonlinear and potential intensity terms. These positive contributions to the GPI anomalies are partly offset by the negative contribution from the vertical wind shear. During the QBWO's inactive phase, the mid-level relative humidity appears to be the largest contributor, while weak contributions are also made by the nonlinear and low-level relative vorticity terms. Meanwhile, these positive contributions are partly cancelled out by the negative contribution from the potential intensity. The contributions of these environmental factors to the GPI anomalies associated with the QBWO are similar in all five flow patterns--the monsoon shear line, monsoon confluence region, monsoon gyre, easterly wave, and Rossby wave energy dispersion associated with a preexisting TC. Further analyses show that the QBWO strongly modulates the synoptic-scale wave trains (SSWs) over the WNP, with larger amplitude SSWs during the QBWO's active phase. This implies a possible enhanced (weakened) relationship between TCG and SSWs during the active (inactive) phase. This study improves our understanding of the modulation of WNP TCG by the QBWO and thus helps with efforts to improve the intraseasonal prediction of WNP TCG.