Because of their effect on climate,carbon dioxide(CO_(2)),methane(CH_(4)),nitrous oxide(N_(2)O),and dimethylsulfide(DMS)are collectively designated as climate-relevant gases(CRGs).CO_(2),CH_(4),and N_(2)O are greenhou...Because of their effect on climate,carbon dioxide(CO_(2)),methane(CH_(4)),nitrous oxide(N_(2)O),and dimethylsulfide(DMS)are collectively designated as climate-relevant gases(CRGs).CO_(2),CH_(4),and N_(2)O are greenhouse gases contributing to global warming(positive climate feedback).Conversely,DMS is involved in the generation of cloud condensation nuclei,thus in the formation of clouds that cool the boundary layer by reflecting incoming solar radiation(negative climate feedback).Despite their scarcity,field observations and model results have demonstrated the essential role of polar oceans in the budget of CRGs.For example,the Southern Ocean represents a substantial CO_(2)sink but a source of N_(2)O and DMS,thereby exerting variable feedback on climate change.Unfortunately,because of the severe environmental conditions at polar latitudes,substantial knowledge gaps remain,for example on the mechanisms underlying CRGs formation or on the strength and distribution of their sources and sinks in the Southern and Arctic Oceans.Here,we review the most recent research results on the distribution,production-loss processes,and abundance variations of CRGs in the polar oceans.We list the remaining knowledge gaps and propose future directions of research on CRGs in the polar oceans,as a useful reference for future studies.展开更多
Electro-Optic Sampling(EOS)detection technique has been widely used in terahertz science and tech⁃nology,and it also can measure the field time waveform of the few-cycle laser pulse.Its frequency response and band lim...Electro-Optic Sampling(EOS)detection technique has been widely used in terahertz science and tech⁃nology,and it also can measure the field time waveform of the few-cycle laser pulse.Its frequency response and band limitation are determined directly by the electro-optic crystal and duration of the probe laser pulse.Here,we investigate the performance of the EOS with thin GaSe crystal in the measurement of the mid-infrared few-cycle la⁃ser pulse.The shift of the central frequency and change of the bandwidth induced by the EOS detection are calcu⁃lated,and then the pulse distortions induced in this detection process are discussed.It is found that this technique produces a red-shift of the central frequency and narrowing of the bandwidth.These changings decrease when the laser wavelength increases from 2μm to 10μm.This work can help to estimate the performance of the EOS de⁃tection technique in the mid-infrared band and offer a reference for the related experiment as well.展开更多
Due to the weak interlayer interactions,the binary Ⅲ-Ⅵ chalcogenides Ga Se can exist in several distinct polymorphs.Among them,the so-called β-and ε-phases simultaneously exhibit favorable total energies and moder...Due to the weak interlayer interactions,the binary Ⅲ-Ⅵ chalcogenides Ga Se can exist in several distinct polymorphs.Among them,the so-called β-and ε-phases simultaneously exhibit favorable total energies and moderate band gaps,which offer a good platform to explore their thermoelectric properties.Here,we demonstrate by first-principles calculations that the two systems have very similar band structures and phonon dispersions,despite different stacking sequences between adjacent layers.Interestingly,the lattice thermal conductivity of ε-GaSe is obviously lower than that of β-GaSe,which is inherently tied to stronger lattice anharmonicity caused by bonding heterogeneity.Besides,both systems exhibit higher p-type power factors due to doubly degenerate bands with weaker dispersions around the valence band maximum.As a consequence,a significantly enhanced p-type figure-of-merit of 2.1 can be realized at 700 K along the out-of-plane direction of theε-phase.展开更多
By doping with Mg atoms,the bandgap of Mg-doped NiO thin films can be adjusted larger.By using NiO and MgO as sputtering targets,Mg-doped NiO thin films were deposited using radio-frequency magnetron co-sputtering met...By doping with Mg atoms,the bandgap of Mg-doped NiO thin films can be adjusted larger.By using NiO and MgO as sputtering targets,Mg-doped NiO thin films were deposited using radio-frequency magnetron co-sputtering method in pure argon and pure oxygen gas,respectively.The crystal structure,morphological characteristics,composition and optical properties of the obtained films were compared by X-ray diffraction(XRD),scanning electron microscope(SEM),energy dispersive spectrometer(EDS)and ultraviolet(UV)-visible spectrophotometer.The properties of the thin films deposited in different sputtering gases are quite different.For the films deposited in pure argon gas,it is a polycrystalline thin film with(200)preferred orientation,while the film deposited in pure oxygen has no preferred orientation.The grain size,molar ratio of Mg to Ni atoms and optical bandgap are larger for the films deposited in pure argon gas than those deposited in oxygen gas.展开更多
The catalytic combustion technology for treating waste gases exiting from wastewater treatment system and oil separators in petrochemical enterprises was introduced in this article. Commercial application of this tech...The catalytic combustion technology for treating waste gases exiting from wastewater treatment system and oil separators in petrochemical enterprises was introduced in this article. Commercial application of this technology showed that the process ＂desulfurization and total hydrocarbon concentration homogenizationcatalytic combustion＂ and the associated WSH-1 combustion catalyst were suitable for treating volatile organic gases emitted from the oil separators, floatation tanks, inlet water-collecting well, waste oil tanks, etc. The commercial unit was equipped with an advanced auto-control system, featuring a simple operation and low energy consumption with good treatment effect. The purified gases could meet the national emission standard.展开更多
The structure, electrical transport, and optical properties of GaSe films fabricated by means of radio-frequency (RF) magnetron sputtering in Ar were investigated. The as-sputtered GaSe films were amorphous, and their...The structure, electrical transport, and optical properties of GaSe films fabricated by means of radio-frequency (RF) magnetron sputtering in Ar were investigated. The as-sputtered GaSe films were amorphous, and their optical energy gap Eg are 1.9～2.6 eV. The effect of the synthesis conditions on the optical and electrical properties of the GaSe films has also been studied展开更多
Forest fire, an important agent for change in many forest ecosystems, plays an important role in atmo- spheric chemical cycles and the carbon cycle. The primary emissions from forest fire, CO2, CO, CH4, long-chained h...Forest fire, an important agent for change in many forest ecosystems, plays an important role in atmo- spheric chemical cycles and the carbon cycle. The primary emissions from forest fire, CO2, CO, CH4, long-chained hydrocarbons and volatile organic oxides, however, have not been well quantified. Quantifying the carbonaceous gas emissions of forest fires is a critical part to better under- stand the significance of forest fire in calculating carbon balance and forecasting climate change. This study uses images from Enhanced Thematic Mapper Plus （ETM＋） on the Earth-observing satellite LANDSAT-7 for the year 2005 to estimate the total gases emitted by the 2006 Kanduhe forest fire in the Daxing＇an Mountains. Our results suggest that the fire emitted approximately 149,187.66 t CO2, 21,187.70 t CO, 1925.41 t CxHy, 470.76 t NO and 658.77 t SO2. In addition, the gases emitted from larch forests were significantly higher than from both broadleaf-needle leaf mixed forests and broadleaf mixed forests.展开更多
The natural gas in several gas fields in Pakistan is associated with varying percentages of inert gases(e.g.,CO_(2),N_(2),and H_2S).The heating capacity of such natural gas is measured in British thermal units(BTU)in ...The natural gas in several gas fields in Pakistan is associated with varying percentages of inert gases(e.g.,CO_(2),N_(2),and H_2S).The heating capacity of such natural gas is measured in British thermal units(BTU)in Pakistan and is based on the combustion of the natural gases.The study area of this work belongs to the Middle Indus Basin,which also covers some parts of the Sulaiman Foldbelt and the Punjab Platform.Petroleum wells drilled in the study area contain inert gases(mostly CO_(2)and N_2)in varying percentages,which decreases the BTU value of sweet gases and the economic value of the gas reserves.Attempts were made to analyze the varying compositions of inert gases(mostly CO_(2)and N_(2))along the deep-seated basement faults in the Zindapir Anticlinorium,eastern Sulaiman Foldbelt,but no specific relation could be established.Similarly,geothermal gradient zones were identified and the distribution of inert gases in these zones was studied,but even so,no well-established relation could be tracked.However,variations in the amounts of inert gases in the Chiltan Limestone of the Rodho Structure and the Afiband Structure point to the generation of in situ inert gases because both wells were drilled on the same anticlinorium and share the same geology,and possibly,the same source rock.Post-accumulation changes probably play an important role in the generation of in situ inert gases in varying concentrations.H_2S is also present in some parts of the Indus Basin.Therefore,a brief discussion about the possible origin of the H_2S is also included in this paper.展开更多
基金supported the National Natural Science Foundation of China(Grant nos.4227624,42376239 and 42476253)。
文摘Because of their effect on climate,carbon dioxide(CO_(2)),methane(CH_(4)),nitrous oxide(N_(2)O),and dimethylsulfide(DMS)are collectively designated as climate-relevant gases(CRGs).CO_(2),CH_(4),and N_(2)O are greenhouse gases contributing to global warming(positive climate feedback).Conversely,DMS is involved in the generation of cloud condensation nuclei,thus in the formation of clouds that cool the boundary layer by reflecting incoming solar radiation(negative climate feedback).Despite their scarcity,field observations and model results have demonstrated the essential role of polar oceans in the budget of CRGs.For example,the Southern Ocean represents a substantial CO_(2)sink but a source of N_(2)O and DMS,thereby exerting variable feedback on climate change.Unfortunately,because of the severe environmental conditions at polar latitudes,substantial knowledge gaps remain,for example on the mechanisms underlying CRGs formation or on the strength and distribution of their sources and sinks in the Southern and Arctic Oceans.Here,we review the most recent research results on the distribution,production-loss processes,and abundance variations of CRGs in the polar oceans.We list the remaining knowledge gaps and propose future directions of research on CRGs in the polar oceans,as a useful reference for future studies.
基金Supported by the National Natural Science Foundation of China(12064028)Jiangxi Provincial Natural Science Foundation(20232BAB201045).
文摘Electro-Optic Sampling(EOS)detection technique has been widely used in terahertz science and tech⁃nology,and it also can measure the field time waveform of the few-cycle laser pulse.Its frequency response and band limitation are determined directly by the electro-optic crystal and duration of the probe laser pulse.Here,we investigate the performance of the EOS with thin GaSe crystal in the measurement of the mid-infrared few-cycle la⁃ser pulse.The shift of the central frequency and change of the bandwidth induced by the EOS detection are calcu⁃lated,and then the pulse distortions induced in this detection process are discussed.It is found that this technique produces a red-shift of the central frequency and narrowing of the bandwidth.These changings decrease when the laser wavelength increases from 2μm to 10μm.This work can help to estimate the performance of the EOS de⁃tection technique in the mid-infrared band and offer a reference for the related experiment as well.
基金supported by the National Natural Science Foundation of China(Grant Nos.62074114 and 12474019)。
文摘Due to the weak interlayer interactions,the binary Ⅲ-Ⅵ chalcogenides Ga Se can exist in several distinct polymorphs.Among them,the so-called β-and ε-phases simultaneously exhibit favorable total energies and moderate band gaps,which offer a good platform to explore their thermoelectric properties.Here,we demonstrate by first-principles calculations that the two systems have very similar band structures and phonon dispersions,despite different stacking sequences between adjacent layers.Interestingly,the lattice thermal conductivity of ε-GaSe is obviously lower than that of β-GaSe,which is inherently tied to stronger lattice anharmonicity caused by bonding heterogeneity.Besides,both systems exhibit higher p-type power factors due to doubly degenerate bands with weaker dispersions around the valence band maximum.As a consequence,a significantly enhanced p-type figure-of-merit of 2.1 can be realized at 700 K along the out-of-plane direction of theε-phase.
基金supported by the Jilin Provincial Scientific and Technological Development Program(No.20220101036JC)。
文摘By doping with Mg atoms,the bandgap of Mg-doped NiO thin films can be adjusted larger.By using NiO and MgO as sputtering targets,Mg-doped NiO thin films were deposited using radio-frequency magnetron co-sputtering method in pure argon and pure oxygen gas,respectively.The crystal structure,morphological characteristics,composition and optical properties of the obtained films were compared by X-ray diffraction(XRD),scanning electron microscope(SEM),energy dispersive spectrometer(EDS)and ultraviolet(UV)-visible spectrophotometer.The properties of the thin films deposited in different sputtering gases are quite different.For the films deposited in pure argon gas,it is a polycrystalline thin film with(200)preferred orientation,while the film deposited in pure oxygen has no preferred orientation.The grain size,molar ratio of Mg to Ni atoms and optical bandgap are larger for the films deposited in pure argon gas than those deposited in oxygen gas.
基金supported by the Federal Target Program“The scientific and Scientific-pedagogical Personnel of Innovative Russia”(No.02.740.11.04444)Russian President Grant(SS4297.2010.2)
基金Supported by RFBR Project(No.10-02-01452-a)Presidium SB RAS under the Project Ⅶ.63.3.1 of Ⅶ.63.3 Prog.Integrated Projec of 2012－2014 and Join Proj. between Presidium SB RAS and Presidium NAS,Belarus No.10 of 2010
文摘The catalytic combustion technology for treating waste gases exiting from wastewater treatment system and oil separators in petrochemical enterprises was introduced in this article. Commercial application of this technology showed that the process ＂desulfurization and total hydrocarbon concentration homogenizationcatalytic combustion＂ and the associated WSH-1 combustion catalyst were suitable for treating volatile organic gases emitted from the oil separators, floatation tanks, inlet water-collecting well, waste oil tanks, etc. The commercial unit was equipped with an advanced auto-control system, featuring a simple operation and low energy consumption with good treatment effect. The purified gases could meet the national emission standard.
文摘The structure, electrical transport, and optical properties of GaSe films fabricated by means of radio-frequency (RF) magnetron sputtering in Ar were investigated. The as-sputtered GaSe films were amorphous, and their optical energy gap Eg are 1.9～2.6 eV. The effect of the synthesis conditions on the optical and electrical properties of the GaSe films has also been studied
基金supported by Fundamental Research Funds for Central Universities(No.DL13BA02)National Natural Science Foundation of China(Grant No.31400552)+1 种基金the Twelfth5-Year National Science and Technology Project In Rural Areas(No.2011BAD37B0104)the Forestry Industry Research Special Funds For Public Welfare Project(No.201004003-6)
文摘Forest fire, an important agent for change in many forest ecosystems, plays an important role in atmo- spheric chemical cycles and the carbon cycle. The primary emissions from forest fire, CO2, CO, CH4, long-chained hydrocarbons and volatile organic oxides, however, have not been well quantified. Quantifying the carbonaceous gas emissions of forest fires is a critical part to better under- stand the significance of forest fire in calculating carbon balance and forecasting climate change. This study uses images from Enhanced Thematic Mapper Plus （ETM＋） on the Earth-observing satellite LANDSAT-7 for the year 2005 to estimate the total gases emitted by the 2006 Kanduhe forest fire in the Daxing＇an Mountains. Our results suggest that the fire emitted approximately 149,187.66 t CO2, 21,187.70 t CO, 1925.41 t CxHy, 470.76 t NO and 658.77 t SO2. In addition, the gases emitted from larch forests were significantly higher than from both broadleaf-needle leaf mixed forests and broadleaf mixed forests.
文摘The natural gas in several gas fields in Pakistan is associated with varying percentages of inert gases(e.g.,CO_(2),N_(2),and H_2S).The heating capacity of such natural gas is measured in British thermal units(BTU)in Pakistan and is based on the combustion of the natural gases.The study area of this work belongs to the Middle Indus Basin,which also covers some parts of the Sulaiman Foldbelt and the Punjab Platform.Petroleum wells drilled in the study area contain inert gases(mostly CO_(2)and N_2)in varying percentages,which decreases the BTU value of sweet gases and the economic value of the gas reserves.Attempts were made to analyze the varying compositions of inert gases(mostly CO_(2)and N_(2))along the deep-seated basement faults in the Zindapir Anticlinorium,eastern Sulaiman Foldbelt,but no specific relation could be established.Similarly,geothermal gradient zones were identified and the distribution of inert gases in these zones was studied,but even so,no well-established relation could be tracked.However,variations in the amounts of inert gases in the Chiltan Limestone of the Rodho Structure and the Afiband Structure point to the generation of in situ inert gases because both wells were drilled on the same anticlinorium and share the same geology,and possibly,the same source rock.Post-accumulation changes probably play an important role in the generation of in situ inert gases in varying concentrations.H_2S is also present in some parts of the Indus Basin.Therefore,a brief discussion about the possible origin of the H_2S is also included in this paper.
