Based on the LOM(Laminated Object Manufacturing)process,an inert gas-assisted laser method for wood cutting was proposed.The carbonization degree of wood surface was improved by the introduction of helium(He)gas,and t...Based on the LOM(Laminated Object Manufacturing)process,an inert gas-assisted laser method for wood cutting was proposed.The carbonization degree of wood surface was improved by the introduction of helium(He)gas,and the influence of process parameters on the carbonization layer of wood surface was solved,it was significance to reduce the post-processing of LOM and improve the quality of forming workpiece.The cherry wood veneer was used as the experimental material,under the condition of the same process parameters,the wood was cut with or without inert gas-assisted,and the influence factors of kerf quality were studied by variance analysis.The results showed that under the same condition,compared with traditional laser processing,the kerf width was obviously reduced in the inert gas-assisted cutting.Because the He gas had oxygen-isolation and flame retardant effect,which prevented heat accumulation and conduction.The micro morphology of the kerf surface showed that the flatness was better in the inert gas-assisted cutting.As the excess heat was blown out by the cooling and purging of the gas,the phenomenon of oxidation and burning was reduced,the range of HAZ(heat affected zone)was reduced,and the carbonization phenomenon was obviously improved.The surface quality of kerf was improved effectively.According to the analysis of variance,in addition to the effect of laser power,cutting speed and inert gas flow on the cutting width,the interaction between inert gas flow and laser power,laser power and cutting speed were also the main factors which affected the cutting width.The feasibility of the combined inert gas and laser processing to improve wood cutting quality has been verified through experimental research,which provided a certain reference for the followup research on improving the wood processing quality.展开更多
Focused ion beam (FIB) machining can be used to fabricate gallium arsenide-based devices, which have a surface fnish of several nanometers, and the FIB machining speed and surface fnish can be greatly improved using x...Focused ion beam (FIB) machining can be used to fabricate gallium arsenide-based devices, which have a surface fnish of several nanometers, and the FIB machining speed and surface fnish can be greatly improved using xenon difuoride (XeF2) gas-assisted etching. Although the refresh time is one of the most important parameters in the gas-assisted etching process, its efect on the machining quality of the surface fnish has rarely been studied. Therefore, in this work, we investigated the efect of the refresh time on the etching process, including the dissociation process of XeF2, the refresh time dependency of the sputter in yield under diferent incident angles, and the surface fnish under diferent refresh times. The results revealed that a selective etching mechanism occurred at diferent refresh times. At an incidence angle of 0°, the sputtering yield increased with the refresh time and reached its maximum value at 500 ms;at an incidence angle of 30°, the sputtering yield reached its minimum value at a refresh time of 500 ms. For surface roughness, the incident angle played a more important role than the refresh time. The surface fnish was slightly better at an incidence angle of 30° than at 0°. In addition, both F and Xe elements were detected in the processed area: Xe elements were evenly distributed throughout the processing area, while F elements tended to accumulate in the whole processing area. The results suggest that the optimum surface can be obtained when a larger refresh time is employed.展开更多
Tight glutenite reservoirs are known for strong heterogeneity,complex wettability,and challenging development.Gas-Assisted Gravity Drainage(GAGD)technology has the potential to significantly improve recovery efficienc...Tight glutenite reservoirs are known for strong heterogeneity,complex wettability,and challenging development.Gas-Assisted Gravity Drainage(GAGD)technology has the potential to significantly improve recovery efficiency in glutenite reservoir.However,there is currently limited research on GAGD processes specifically designed for glutenite reservoirs,and there is a lack of relevant dimensionless numbers for predicting recovery efficiency.In this study,we developed a theoretical model based on the characteristics of glutenite reservoirs and used phase-field method to track the oil-gas interface for numerical simulations of dynamic GAGD processes.To explore the factors influencing gas-driven recovery,we simulated the effects of strong heterogeneity and dynamic wettability on the construction process under gravity assistance.Additionally,we introduced multiple dimensionless numbers(including capillary number,viscosity ratio,and Bond number)and conducted a series of numerical simulations.The results demonstrate that gravity enhances the stability of the oil-gas interface but causes unstable pressure fluctuations when passing through different-sized throat regions,particularly leading to front advancement in smaller throats.Although strong heterogeneity has negative impacts on GAGD,they can be mitigated by reducing injection velocity.Increasing oil-wettability promotes oil displacement by overcoming capillary forces,particularly in narrower pores,allowing residual oils to be expelled.Among the dimensionless numbers,the recovery efficiency is directly proportional to the Bond number and inversely proportional to the capillary number and viscosity ratio.Through sensitivity analysis of the dimensionless numbers’impact on the recovery efficiency,a new dimensionless N_(Glu) considering heterogeneity is proposed to accurately predict GAGD recovery of tight glutenite reservoirs.展开更多
Lithium iron phosphate(LFP)offers excellent structural and performance stability derived from the(PO_(4))^(3-)polyanionic structure,which is beneficial for long-term usage.However,this inherent stability also comes al...Lithium iron phosphate(LFP)offers excellent structural and performance stability derived from the(PO_(4))^(3-)polyanionic structure,which is beneficial for long-term usage.However,this inherent stability also comes along with intrinsically poor ionic and electronic conductivities,which have been notoriously plaguing its high-rate performance and broader applications.Here,we present a gas-assisted transient synthesis(GATS,~30 s)of LFP with controllable oxygen vacancies(O_(v))for enhanced rate performance yet without sacrificing structural integrity or cycling stability.Benefited by the ultrafast heating and a higher synthesis temperature,we revealed that the LFP synthesis in GATS followed an interface reaction mechanism(rapid core shrinking)with a low activation energy(E_(a)),thus reducing the synthesis time from~16.5 h in tube furnace heating(TFH,often nuclei-growth mechanism)to merely seconds.The optimized LFP sample demonstrates an 8-fold enhancement in ionic conductivity and a 12-fold increase in electronic conductivity compared to LFP obtained by TFH and attains exceptional cycling stability even at high rates of 10 C,as evidenced by a higher capacity retention of 93.8%(vs.63.6%of commercial LFP)after 1000 cycles.Our strategy offers a kinetic pathway for rapid synthesis and structural engineering of LFP,thus unlocking its potential for broader energy storage applications.展开更多
基金The research was supported by Significant special research and development project of Guangdong province(2020B020216001)Fundamental Research Funds for the Central Universities(2572018CG06).
文摘Based on the LOM(Laminated Object Manufacturing)process,an inert gas-assisted laser method for wood cutting was proposed.The carbonization degree of wood surface was improved by the introduction of helium(He)gas,and the influence of process parameters on the carbonization layer of wood surface was solved,it was significance to reduce the post-processing of LOM and improve the quality of forming workpiece.The cherry wood veneer was used as the experimental material,under the condition of the same process parameters,the wood was cut with or without inert gas-assisted,and the influence factors of kerf quality were studied by variance analysis.The results showed that under the same condition,compared with traditional laser processing,the kerf width was obviously reduced in the inert gas-assisted cutting.Because the He gas had oxygen-isolation and flame retardant effect,which prevented heat accumulation and conduction.The micro morphology of the kerf surface showed that the flatness was better in the inert gas-assisted cutting.As the excess heat was blown out by the cooling and purging of the gas,the phenomenon of oxidation and burning was reduced,the range of HAZ(heat affected zone)was reduced,and the carbonization phenomenon was obviously improved.The surface quality of kerf was improved effectively.According to the analysis of variance,in addition to the effect of laser power,cutting speed and inert gas flow on the cutting width,the interaction between inert gas flow and laser power,laser power and cutting speed were also the main factors which affected the cutting width.The feasibility of the combined inert gas and laser processing to improve wood cutting quality has been verified through experimental research,which provided a certain reference for the followup research on improving the wood processing quality.
基金The authors gratefully acknowledge the startup funding support by the Dalian University of Technology(DUT)(Award No.82232022,82232043,and DUT22LAB404)。
文摘Focused ion beam (FIB) machining can be used to fabricate gallium arsenide-based devices, which have a surface fnish of several nanometers, and the FIB machining speed and surface fnish can be greatly improved using xenon difuoride (XeF2) gas-assisted etching. Although the refresh time is one of the most important parameters in the gas-assisted etching process, its efect on the machining quality of the surface fnish has rarely been studied. Therefore, in this work, we investigated the efect of the refresh time on the etching process, including the dissociation process of XeF2, the refresh time dependency of the sputter in yield under diferent incident angles, and the surface fnish under diferent refresh times. The results revealed that a selective etching mechanism occurred at diferent refresh times. At an incidence angle of 0°, the sputtering yield increased with the refresh time and reached its maximum value at 500 ms;at an incidence angle of 30°, the sputtering yield reached its minimum value at a refresh time of 500 ms. For surface roughness, the incident angle played a more important role than the refresh time. The surface fnish was slightly better at an incidence angle of 30° than at 0°. In addition, both F and Xe elements were detected in the processed area: Xe elements were evenly distributed throughout the processing area, while F elements tended to accumulate in the whole processing area. The results suggest that the optimum surface can be obtained when a larger refresh time is employed.
基金supported by the National Natural Science Foundation of China(U22B2075)the Fundamental Research Funds for the Central Universities(2024ZKPYSB03)support from Beijing University of Science and Technology.
文摘Tight glutenite reservoirs are known for strong heterogeneity,complex wettability,and challenging development.Gas-Assisted Gravity Drainage(GAGD)technology has the potential to significantly improve recovery efficiency in glutenite reservoir.However,there is currently limited research on GAGD processes specifically designed for glutenite reservoirs,and there is a lack of relevant dimensionless numbers for predicting recovery efficiency.In this study,we developed a theoretical model based on the characteristics of glutenite reservoirs and used phase-field method to track the oil-gas interface for numerical simulations of dynamic GAGD processes.To explore the factors influencing gas-driven recovery,we simulated the effects of strong heterogeneity and dynamic wettability on the construction process under gravity assistance.Additionally,we introduced multiple dimensionless numbers(including capillary number,viscosity ratio,and Bond number)and conducted a series of numerical simulations.The results demonstrate that gravity enhances the stability of the oil-gas interface but causes unstable pressure fluctuations when passing through different-sized throat regions,particularly leading to front advancement in smaller throats.Although strong heterogeneity has negative impacts on GAGD,they can be mitigated by reducing injection velocity.Increasing oil-wettability promotes oil displacement by overcoming capillary forces,particularly in narrower pores,allowing residual oils to be expelled.Among the dimensionless numbers,the recovery efficiency is directly proportional to the Bond number and inversely proportional to the capillary number and viscosity ratio.Through sensitivity analysis of the dimensionless numbers’impact on the recovery efficiency,a new dimensionless N_(Glu) considering heterogeneity is proposed to accurately predict GAGD recovery of tight glutenite reservoirs.
基金supported by the Key R&D Program of Hubei Province(No.2024BCB091)the Natural Science Foundation of Hubei Province(No.2022CFA031).
文摘Lithium iron phosphate(LFP)offers excellent structural and performance stability derived from the(PO_(4))^(3-)polyanionic structure,which is beneficial for long-term usage.However,this inherent stability also comes along with intrinsically poor ionic and electronic conductivities,which have been notoriously plaguing its high-rate performance and broader applications.Here,we present a gas-assisted transient synthesis(GATS,~30 s)of LFP with controllable oxygen vacancies(O_(v))for enhanced rate performance yet without sacrificing structural integrity or cycling stability.Benefited by the ultrafast heating and a higher synthesis temperature,we revealed that the LFP synthesis in GATS followed an interface reaction mechanism(rapid core shrinking)with a low activation energy(E_(a)),thus reducing the synthesis time from~16.5 h in tube furnace heating(TFH,often nuclei-growth mechanism)to merely seconds.The optimized LFP sample demonstrates an 8-fold enhancement in ionic conductivity and a 12-fold increase in electronic conductivity compared to LFP obtained by TFH and attains exceptional cycling stability even at high rates of 10 C,as evidenced by a higher capacity retention of 93.8%(vs.63.6%of commercial LFP)after 1000 cycles.Our strategy offers a kinetic pathway for rapid synthesis and structural engineering of LFP,thus unlocking its potential for broader energy storage applications.
