期刊文献+
共找到252篇文章
< 1 2 13 >
每页显示 20 50 100
Accumulative-Error-Based Event-Triggered Control for Discrete-Time Linear Systems:A Discrete-Time Looped Functional Method
1
作者 Xian-Ming Zhang Qing-Long Han +1 位作者 Xiaohua Ge Bao-Lin Zhang 《IEEE/CAA Journal of Automatica Sinica》 2025年第4期683-693,共11页
This paper is concerned with event-triggered control of discrete-time systems with or without input saturation.First,an accumulative-error-based event-triggered scheme is devised for control updates.When the accumulat... This paper is concerned with event-triggered control of discrete-time systems with or without input saturation.First,an accumulative-error-based event-triggered scheme is devised for control updates.When the accumulated error between the current state and the latest control update exceeds a certain threshold,an event is triggered.Such a scheme can ensure the event-generator works at a relatively low rate rather than falls into hibernation especially after the system steps into its steady state.Second,the looped functional method for continuous-time systems is extended to discrete-time systems.By introducing an innovative looped functional that links the event-triggered scheme,some sufficient conditions for the co-design of control gain and event-triggered parameters are obtained in terms of linear matrix inequalities with a couple of tuning parameters.Then,the proposed method is applied to discrete-time systems with input saturation.As a result,both suitable control gains and event-triggered parameters are also co-designed to ensure the system trajectories converge to the region of attraction.Finally,an unstable reactor system and an inverted pendulum system are given to show the effectiveness of the proposed method. 展开更多
关键词 Discrete-time linear systems event-triggered control input saturation looped functional method
在线阅读 下载PDF
Effect of N-substituents on performance of thiourea collectors by density functional theory calculations 被引量:15
2
作者 刘广义 钟宏 +2 位作者 夏柳荫 王帅 戴塔根 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第4期695-701,共7页
Using density functional methods,some properties were studied such as the energies and compositions of frontier molecular orbitals and the atomic charges,which are related to the reactive behavior of thioureas contain... Using density functional methods,some properties were studied such as the energies and compositions of frontier molecular orbitals and the atomic charges,which are related to the reactive behavior of thioureas containing different N-substituent groupings.The calculation results indicate that the N-substituent groupings have significant effect on the flotation performance of thiourea collectors.The order of electron-donating ability is N-propyl-N'-benzyl-thiourea(PBZYTU)>N-propyl-N'-ethyl-thiourea (PETU)>N-propyl-N'-allyl-thiourea(PALTU)>>N-propyl-N'-acetyl-thiourea(PACTU)>N-propyl-N'-ethoxycarbonyl-thiourea (PECTU)>N-propyl-N'-benzoyl-thiourea(PBZOYTU),and the order of feedback-electron-accepting ability is PBZOYTU> PACTU>PECTU>>PALTU>PETU>PBZYTU.This implies that PBZOYTU,PACTU or PECTU can react with copper atoms having(t2g) 6 (eg) 3Cu(II)or t 6e 4Cu(I)configuration on the surfaces of copper sulfide minerals through normal covalent bond and back donation covalent bond,and exhibit excellently collecting performance for copper sulfide minerals.These are consistent with the experimental data reported in the literatures. 展开更多
关键词 thiourea collector sulfide ore structure-activity relationship density functional method
在线阅读 下载PDF
Density Functional Theory Study on the Adsorption of Dioxygen on Small Pt-Pd Clusters 被引量:1
3
作者 李钠 官文佳 +3 位作者 王艳丽 马琳 孙仁安 孙公权 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第1期63-78,共16页
The electronic and physical properties of PtmPdn (m+n≤5) metal clusters and their interactions with dioxygen have been studied by using hybrid density functional B3LYP method. The total energies, atomization energ... The electronic and physical properties of PtmPdn (m+n≤5) metal clusters and their interactions with dioxygen have been studied by using hybrid density functional B3LYP method. The total energies, atomization energies, vibration frequencies, and charge distributions were reported. The Pt-Pt bridge site modified by Pd atoms was found to be the most active site for the dissociation of dioxygen, which was mainly due to the change of electronic structures of the Pt atoms in bimetallic Pt-Pd clusters. 展开更多
关键词 CLUSTERS bridge site charge transfer density functional theory method
在线阅读 下载PDF
A meshless model for transient heat conduction analyses of 3D axisymmetric functionally graded solids 被引量:3
4
作者 李庆华 陈莘莘 曾骥辉 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第12期51-57,共7页
A meshless numerical model is developed for analyzing transient heat conductions in three-dimensional (3D) axisymmetric continuously nonhomogeneous functionally graded materials (FGMs). Axial symmetry of geometry ... A meshless numerical model is developed for analyzing transient heat conductions in three-dimensional (3D) axisymmetric continuously nonhomogeneous functionally graded materials (FGMs). Axial symmetry of geometry and boundary conditions reduces the original 3D initial-boundary value problem into a two-dimensional (2D) problem. Local weak forms are derived for small polygonal sub-domains which surround nodal points distributed over the cross section. In order to simplify the treatment of the essential boundary conditions, spatial variations of the temperature and heat flux at discrete time instants are interpolated by the natural neighbor interpolation. Moreover, the using of three-node triangular finite element method (FEM) shape functions as test functions reduces the orders of integrands involved in domain integrals. The semi-discrete heat conduction equation is solved numerically with the traditional two-point difference technique in the time domain. Two numerical examples are investigated and excellent results are obtained, demonstrating the potential application of the proposed approach. 展开更多
关键词 meshless method transient heat conduction problem axisymmetric functionally graded materials natural neighbor interpolation
原文传递
Geometries, stabilities, and electronic properties of Be-doped gold clusters: a density functional theory study
5
作者 陈冬冬 邝小渝 +2 位作者 赵亚儒 邵鹏 李艳芳 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第6期230-236,共7页
We have systematically investigated the geometrical structures, relative stabilities and electronic properties of small bimetallic AunBe (n = 1, 2, . .. 8) clusters using a density functional method at BP86 level. T... We have systematically investigated the geometrical structures, relative stabilities and electronic properties of small bimetallic AunBe (n = 1, 2, . .. 8) clusters using a density functional method at BP86 level. The optimized geometries reveal that the impurity beryllium atom dramatically affects the structures of the Aun clusters. The averaged binding energies, fragmentation energies, second-order difference of energies, the highest occupied-lowest unoccupied molecular orbital energy gaps and chemical hardness are investigated, All of them exhibit a pronounced odd-even alternation, manifesting that the clusters with even number of gold atoms possess relatively higher stabilities. Especially, the linear Au2Be cluster is magic cluster with the most stable chemical stability. According to the natural population analysis, it is found that charge-transferring direction between Au atom and Be atom changes at the size of n = 4. 展开更多
关键词 AunBe clusters geometrical configuration density functional method
原文传递
The relativistic density functional investigations on geometries,electronic and magnetic properties of Ir_n (n=1-13) clusters
6
作者 郭平 郑继明 +2 位作者 赵佩 郑琳琳 任兆玉 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第8期356-363,共8页
The Ira (n=1-13) clusters are studied using the relativistic density functional method with generalized gradient approximation. A series of low-lying structures with different spin multiplicities have been considere... The Ira (n=1-13) clusters are studied using the relativistic density functional method with generalized gradient approximation. A series of low-lying structures with different spin multiplicities have been considered. It is found that all the lowest-energy Ira (n=4-13) geometries prefer non-compact structures rather than compact structure growth pattern. And the cube structure is a very stable cell for the lowest-energy Ira (n 〉 8) clusters. The second-order difference of energy, the vertical ionization potentials, the electron affinities and the atomic average magnetic moments for the lowest-energy Ira geometries all show odd even alternative behaviours. 展开更多
关键词 density functional method the lowest-energy structures of Irn clusters electronic and magnetic properties
原文传递
Robust Stability of Neutral Systems:A Discretized Lyapunov Functional Method
7
作者 李旭光 朱新坚 曹广益 《Journal of Shanghai Jiaotong university(Science)》 EI 2009年第3期279-285,共7页
This paper focuses on the robust stability for time-delay systems of neutral type. A new complete Lyapunov-Krasovskii function (LKF) is developed. Based on this function and discretization, stability conditions in ter... This paper focuses on the robust stability for time-delay systems of neutral type. A new complete Lyapunov-Krasovskii function (LKF) is developed. Based on this function and discretization, stability conditions in terms of linear matrix inequalities are obtained. A class of time-varying uncertainty of system matrices can be studied by the method. 展开更多
关键词 STABILITY time-delay systems discretized Lyapunov functional method
原文传递
Developing Reliable Digital Healthcare Service Using Semi-Quantitative Functional Resonance Analysis
8
作者 Zhengshu Zhou Yutaka Matsubara Hiroaki Takada 《Computer Systems Science & Engineering》 SCIE EI 2023年第4期35-50,共16页
Since entering the era of Industry 4.0,the concept of Healthcare 4.0 has also been put forward and explored by researchers.How to use Information Technology(IT)to better serve people’s healthcare is one of the most f... Since entering the era of Industry 4.0,the concept of Healthcare 4.0 has also been put forward and explored by researchers.How to use Information Technology(IT)to better serve people’s healthcare is one of the most featured emerging directions in the academic circle.An important field of Healthcare 4.0 research is the reliability engineering of healthcare service.Because healthcare systems often affect the health and even life of their users,developers must be very cautious in the design,development,and operation of these healthcare systems and services.The problems to be solved include the reliability of business process,system functions,and personal healthcare data.The Functional Resonance Analysis Method(FRAM)has been applied in reliability engineering for safety-critical systems in available studies,using both qualitative and quantitative approaches.However,the method has not been applied in the field of digital healthcare services development.Therefore,to narrow the gap,we present in this paper a semi-quantitative functional resonance analysis method to develop reliable healthcare services for diabetics.Moreover,this paper has tried to improve the reliability design of the service-oriented architecture(SOA)of traditional insulin pump therapy by system thinking. 展开更多
关键词 RELIABILITY safety-critical system functional resonance analysis method systemigram
在线阅读 下载PDF
Solving the Inverse Problems of Wave Equation by a Boundary Functional Method
9
作者 Chein-Shan Liu Yung-Wei Chen 《Journal of Shipping and Ocean Engineering》 2017年第6期233-249,共17页
The inverse problems of wave equation to recover unknown space-time dependent functions of wave speed and wave source are solved in this paper, without needing of initial conditions and no internal measurement of data... The inverse problems of wave equation to recover unknown space-time dependent functions of wave speed and wave source are solved in this paper, without needing of initial conditions and no internal measurement of data being required. After a homogenization technique, a sequence of spatial boundary functions at least the fourth-order polynomials are derived, which satisfy the homogeneous boundary conditions. The boundary functions and the zero element constitute a linear space, and then a new boundary functional is proved in the linear space, of which the energy is preserved for each dynamic energetic boundary function. The linear systems and iterative algorithms used to recover unknown wave speed and wave source functions with the dynamic energetic boundary functions as bases are developed, which converge fast at each time step. The input data are parsimonious, merely the measured boundary strains and the boundary values and slopes of unknown functions to be recovered. The accuracy and robustness of present methods are confirmed by comparing exact solutions with estimated results under large noises up to 20%. 展开更多
关键词 Space-time dependent wave speed space-time dependent wave source dynamic energetic boundary functions BFM(boundary functional method) iterative method.
在线阅读 下载PDF
Kernel Function-Based Primal-Dual Interior-Point Methods for Symmetric Cones Optimization
10
作者 ZHAO Dequan ZHANG Mingwang 《Wuhan University Journal of Natural Sciences》 CAS 2014年第6期461-468,共8页
In this paper, we present a large-update primal-dual interior-point method for symmetric cone optimization(SCO) based on a new kernel function, which determines both search directions and the proximity measure betwe... In this paper, we present a large-update primal-dual interior-point method for symmetric cone optimization(SCO) based on a new kernel function, which determines both search directions and the proximity measure between the iterate and the center path. The kernel function is neither a self-regular function nor the usual logarithmic kernel function. Besides, by using Euclidean Jordan algebraic techniques, we achieve the favorable iteration complexity O( √r(1/2)(log r)^2 log(r/ ε)), which is as good as the convex quadratic semi-definite optimization analogue. 展开更多
关键词 symmetric cones optimization Kernel function Interior-point method polynomial complexity
原文传递
Higher-order crack tip fields for functionally graded material plate with transverse shear deformation
11
作者 Dianhui HOU Xiao CHONG +1 位作者 Guixiang HAO Yao DAI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2016年第6期695-706,共12页
The crack tip fields are investigated for a cracked functionally graded material (FGM) plate by Reissner's linear plate theory with the consideration of the transverse shear deformation generated by bending. The el... The crack tip fields are investigated for a cracked functionally graded material (FGM) plate by Reissner's linear plate theory with the consideration of the transverse shear deformation generated by bending. The elastic modulus and Poisson's ratio of the functionally graded plates are assumed to vary continuously through the coordinate y, according to a linear law and a constant, respectively. The governing equations, i.e., the 6th-order partial differential equations with variable coefficients, are derived in the polar coordinate system based on Reissner's plate theory. Furthermore, the generalized displacements are treated in a separation-of-variable form, and the higher-order crack tip fields of the cracked FGM plate are obtained by the eigen-expansion method. It is found that the analytic solutions degenerate to the corresponding fields of the isotropic homogeneous plate with Reissner's effect when the in-homogeneity parameter approaches zero. 展开更多
关键词 crack tip field Reissner's effect PLATE functionally graded material (FGM) eigen-expansion method
在线阅读 下载PDF
Single-pulse chaotic dynamics of functionally graded materials plate
12
作者 Yu-Gao Huangfu Fang-Qi Chen 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2013年第4期593-601,共9页
Single-pulse chaos are studied for a functionally graded materials rectangular plate. By means of the global perturbation method, explicit conditions for the existence of a SiZnikov-type homoclinic orbit are obtained ... Single-pulse chaos are studied for a functionally graded materials rectangular plate. By means of the global perturbation method, explicit conditions for the existence of a SiZnikov-type homoclinic orbit are obtained for this sys- tem, which suggests that chaos are likely to take place. Then, numerical simulations are given to test the analytical predic- tions. And from our analysis, when the chaotic motion oc- curs, there are a quasi-period motion in a two-dimensional subspace and chaos in another two-dimensional supplemen- tary subspace. 展开更多
关键词 functionally graded materials ~ Single-pulse ~Melnikov's method ~ Homoclinic orbit ~ Numerical simula-tion
在线阅读 下载PDF
An asymmetrically variable wingtip anhedral angles morphing aircraft based on incremental sliding mode control:Improving lateral maneuver capability 被引量:2
13
作者 Xiaodong LIU Yong XU Jianqiao LUO 《Chinese Journal of Aeronautics》 2025年第1期455-470,共16页
This paper presents the design of an asymmetrically variable wingtip anhedral angles morphing aircraft,inspired by biomimetic mechanisms,to enhance lateral maneuver capability.Firstly,we establish a lateral dynamic mo... This paper presents the design of an asymmetrically variable wingtip anhedral angles morphing aircraft,inspired by biomimetic mechanisms,to enhance lateral maneuver capability.Firstly,we establish a lateral dynamic model considering additional forces and moments resulting during the morphing process,and convert it into a Multiple Input Multiple Output(MIMO)virtual control system by importing virtual inputs.Secondly,a classical dynamics inversion controller is designed for the outer-loop system.A new Global Fast Terminal Incremental Sliding Mode Controller(NDO-GFTISMC)is proposed for the inner-loop system,in which an adaptive law is implemented to weaken control surface chattering,and a Nonlinear Disturbance Observer(NDO)is integrated to compensate for unknown disturbances.The whole control system is proven semiglobally uniformly ultimately bounded based on the multi-Lyapunov function method.Furthermore,we consider tracking errors and self-characteristics of actuators,a quadratic programmingbased dynamic control allocation law is designed,which allocates virtual control inputs to the asymmetrically deformed wingtip and rudder.Actuator dynamic models are incorporated to ensure physical realizability of designed allocation law.Finally,comparative experimental results validate the effectiveness of the designed control system and control allocation law.The NDO-GFTISMC features faster convergence,stronger robustness,and 81.25%and 75.0%reduction in maximum state tracking error under uncertainty compared to the Incremental Nonlinear Dynamic Inversion Controller based on NDO(NDO-INDI)and Incremental Sliding Mode Controller based on NDO(NDO-ISMC),respectively.The design of the morphing aircraft significantly enhances lateral maneuver capability,maintaining a substantial control margin during lateral maneuvering,reducing the burden of the rudder surface,and effectively solving the actuator saturation problem of traditional aircraft during lateral maneuvering. 展开更多
关键词 Morphing aircraft Lateral maneuver capability Incremental sliding mode control Multi-Lyapunov function method Control theory Control allocation law
原文传递
Parameter identification of magnetic levitation system based on modulation function method
14
作者 Tingchen Du Xueling Fan Sheng Feng 《Control Theory and Technology》 2025年第4期602-617,共16页
A novel parameter identification method for magnetic levitation bearing rotor systems is proposed,based on the modulation function method.The fundamental principle of the modulation function method for parameter ident... A novel parameter identification method for magnetic levitation bearing rotor systems is proposed,based on the modulation function method.The fundamental principle of the modulation function method for parameter identification is derived on the basis of the characteristics of the modulation function.The transformation of the differential equation model of a continuous system into a general algebraic equation model is effectively achieved,thereby avoiding the influence of errors introduced by the initial value and differential derivation of the system.Modulation function method parameter identification models have been established for single-degree-of-freedom and multi-degree-of-freedom magnetic levitation bearing rotor systems.The influence of different parameters of Hartley modulation function on the accuracy of system parameter identification has been investigated,thus providing a basis for the design of Hartley modulation function parameters.Simulation and experimental results demonstrate that the modulation function method can effectively identify system parameters despite the presence of system noise. 展开更多
关键词 Modulation function method Hartley modulation function Magnetic levitation system Parameter identification
原文传递
New criteria on the existence and global exponential stability of periodic solutions for quaternion-valued cellular neural networks
15
作者 LI Ai-ling ZHOU Zheng ZHANG Zheng-qiu 《Applied Mathematics(A Journal of Chinese Universities)》 2025年第3期523-542,共20页
In this paper,a class of quaternion-valued cellular neural networks(QVCNNS)with time-varying delays are considered.Combining graph theory with the continuation theorem of Mawhin’s coincidence degree theory as well as... In this paper,a class of quaternion-valued cellular neural networks(QVCNNS)with time-varying delays are considered.Combining graph theory with the continuation theorem of Mawhin’s coincidence degree theory as well as Lyapunov functional method,we establish new criteria on the existence and exponential stability of periodic solutions for QVCNNS by removing the assumptions for the boundedness on the activation functions and the assumptions that the values of the activation functions are zero at origin.Hence,our results are less conservative and new. 展开更多
关键词 the existence of periodic solutions exponential stability quaternion-valued cellular neural networks combining graph theory with Mawhin’s continuation theorem of coincidence degree theory Lyapunov function method inequality techniques
在线阅读 下载PDF
Hydrodynamic Interactions of Two Ships Advancing Parallelly in the Head and Oblique Seas
16
作者 DONG Guo-hua YAO Chao-bang +2 位作者 SUN Xiao-shuai YU Jia-wei FENG Da-kui 《China Ocean Engineering》 2025年第3期395-409,共15页
A three-dimensional panel method is developed to investigate the seakeeping performance of two parallel ships advancing in head and oblique waves. In this method, the fluid domain is partitioned into two regions by in... A three-dimensional panel method is developed to investigate the seakeeping performance of two parallel ships advancing in head and oblique waves. In this method, the fluid domain is partitioned into two regions by introducing a virtual control surface. In the inner part, the Taylor expansion boundary element method is used, whose kernel function is the Rankine source;in the outer part, the free surface Green function with the forward speed effect considered is adopted. The velocity potentials and normal velocities on the virtual control surface are equal for the inner and outer domains. Moreover, the numerical estimation method for viscous roll damping recommended by the ITTC is included in the present method. This hybrid method is validated through the previously measured motions of two ship models, and the present numerical results are in good agreement with those of the experiments. Furthermore, the influences of longitudinal distances and wave heading angles on six-degree-of-freedom motions and the hydrodynamic interaction between the present two ship models are discussed in detail. 展开更多
关键词 hybrid Green function method hydrodynamic interaction longitudinal distance
在线阅读 下载PDF
An Improved Local RBF Collocation Method for 3D Excavation Deformation Based on Direct Method and Mapping Technique
17
作者 Cheng Deng Hui Zheng +2 位作者 Liangyong Gong Rongping Zhang Mengqi Wang 《Computer Modeling in Engineering & Sciences》 2025年第2期2147-2172,共26页
Since the plasticity of soil and the irregular shape of the excavation,the efficiency and stability of the traditional local radial basis function(RBF)collocation method(LRBFCM)are inadequate for analyzing three-dimen... Since the plasticity of soil and the irregular shape of the excavation,the efficiency and stability of the traditional local radial basis function(RBF)collocation method(LRBFCM)are inadequate for analyzing three-dimensional(3D)deformation of deep excavation.In this work,the technique known as the direct method,where the local influence nodes are collocated on a straight line,is introduced to optimize the LRBFCM.The direct method can improve the accuracy of the partial derivative,reduce the size effect caused by the large length-width ratio,and weaken the influence of the shape parameters on the LRBFCM.The mapping technique is adopted to transform the physical coordinates of a quadratic-type block to normalized coordinates,in which the deformation problem can easily be solved using the direct method.The stability of the LRBFCM is further modified by considering the irregular shape of 3D excavation,which is divided into several quadratic-type blocks.The soil’s plasticity is described by the Drucker-Prager(D-P)model.The improved LRBFCM is integrated with the incremental method to analyze the plasticity.Five different examples,including strip excavations and circular excavations,are presented to validate the proposed approach’s efficiency. 展开更多
关键词 Radial basis function collocation method irregular shape EXCAVATION elastic-plasticity
在线阅读 下载PDF
Synchronous Membership Function Dependent Event-Triggered H∞Control of T-S Fuzzy Systems Under Network Communications
18
作者 Bo-Lin Xu Chen Peng Wen-Bo Xie 《IEEE/CAA Journal of Automatica Sinica》 2025年第5期1041-1043,共3页
Dear Editor,This letter deals with the controller synthesis problem of networked Takagi-Sugeno(T-S)fuzzy systems.Due to the introduction of network communications,the same premise is no longer shared by fuzzy plants a... Dear Editor,This letter deals with the controller synthesis problem of networked Takagi-Sugeno(T-S)fuzzy systems.Due to the introduction of network communications,the same premise is no longer shared by fuzzy plants and fuzzy controllers.This makes the classic parallel distribution compensation(PDC)control infeasible.To overcome this situation,a novel method for reconstructing the membership functions'grades is proposed,which synchronizes the time scales.Then,the membership function dependent method is adopted to introduce asynchronous errors and detailed membership function information.For the event-triggered control strategy,a series of robust H∞stable conditions in LMI form are derived.Finally,a simulation of a practical system is used to demonstrate the method proposed in this letter can reduce conservatism. 展开更多
关键词 fuzzy plants controller synthesis problem network communicationsthe event triggered control reconstructing membership functionsgrades synchronizes time scalesthenthe synchronous membership functions membership function dependent method
在线阅读 下载PDF
Framework-solvent interactional mechanism and effect of NMP/DMF on solvothermal synthesis of [Zn_4O(BDC)_3]_8 被引量:3
19
作者 吴争平 王明雪 +4 位作者 周丽姣 尹周澜 谈进 张锦玲 陈启元 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第11期3722-3731,共10页
In order to explore the effect mechanism of solvent on the synthesis of the metal organic framework materials, the microscopic interaction between solvent and framework and the effects of N,N-dimethyl-formamide(DMF) o... In order to explore the effect mechanism of solvent on the synthesis of the metal organic framework materials, the microscopic interaction between solvent and framework and the effects of N,N-dimethyl-formamide(DMF) or N-methyl- 2-pyrrolidone(NMP) on solvothermal synthesis of [Zn4O(BDC)3]8 were investigated through a combined DFT and experimental study. XRD and SEM showed that the absorbability of NMP in the pore of [Zn4O(BDC)3]8 was weaker than that of DMF. The thermal decomposition temperature of [Zn4O(BDC)3]8 synthesized in DMF was higher than that in NMP according to TG and FT-IR. In addition, the nitrogen sorption isotherms indicated that NMP improved gas sorption property of [Zn4O(BDC)3]8. The COSMO optimized calculations indicated that the total energy of Zn4O(BDC)3 in NMP was higher than that in DMF, and compared with non-solvent system, the charge of zinc atoms decreased and the charge value was the smallest in NMP. Furthermore, the interaction of DMF, NMP or DEF in [Zn4O(BDC)3]8 crystal model was calculated by DFT method. The results suggested that NMP should be easier to be removed from pore of materials than DMF from the point of view of energy state. It can be concluded that NMP was a favorable solvent to synthesize [Zn4O(BDC)3]8 and the microscopic mechanism was that the binding force between Zn4O(BDC)3 and NMP molecule was weaker than DMF. 展开更多
关键词 solvothermal synthesis [Zn4O(BDC)3]8 N-METHYL-2-PYRROLIDONE interactional mechanism COSMO solvation model density functional method
在线阅读 下载PDF
New Formulation for Arbitrary Cracks Problem and Its Stress Intensity Factor of Plane Elasticity 被引量:4
20
作者 杨晓春 范天佑 刘士强 《Journal of Beijing Institute of Technology》 EI CAS 1999年第4期364-369,共6页
Aim The general arbitrary cracked problem in an elastic plane was discussed. Methods For the purpose of acquiring the solution of the problem, a new formulation on the problem was proposed. Compared with the classic... Aim The general arbitrary cracked problem in an elastic plane was discussed. Methods For the purpose of acquiring the solution of the problem, a new formulation on the problem was proposed. Compared with the classical plane elastic crack model, only the known conditions were revised in the new formulation, which are greatly convenient to solve the problem, and no other new condition was given. Results and Conclusion The general exact analytic solution is given here based on the formulation though the problem is very complicated. Furthermore, the stress intensity factors K Ⅰ, K Ⅱ of the problem are also given. 展开更多
关键词 complex variable function method general curve cracks Riemann Hilbert boundary value problem closed form solution stress intensity factors
在线阅读 下载PDF
上一页 1 2 13 下一页 到第
使用帮助 返回顶部