AIM:To investigate effects of perirenal space blocking(PSB)on gastrointestinal function in patients with severe acute pancreatitis(SAP).METHODS:Forty patients with SAP were randomly allocated to receive PSB or no PSB(...AIM:To investigate effects of perirenal space blocking(PSB)on gastrointestinal function in patients with severe acute pancreatitis(SAP).METHODS:Forty patients with SAP were randomly allocated to receive PSB or no PSB(NPSB).All the SAP patients received specialized medical therapy(SMT).Patients in the PSB group received PSB+SMT when hospitalized and after diagnosis,whereas patients in the NPSB group only received SMT.A modifed gastrointestinal failure(GIF)scoring system was used to assess the gastrointestinal function in SAP patients after admission.Pain severity(visual analog scale,0 to100)was monitored every 24 h for 72 h.RESULTS:Modified GIF score decreased in both groups during the 10-d study period.The median score decrease was initially significantly greater in the PSB group than in the NPSB group after PSB was per-formed.During the 72-h study period,pain intensity decreased in both groups.The median pain decrease was significantly greater in the PSB group than in the NPSB group at single time points.Patients in the PSB group had significantly lower incidences of hospital mortality,multiple organ dysfunction syndrome,systemic inflammatory response syndrome,and pancreatic infection,and stayed in the intensive care unit for a shorter duration.However,no difference in terms of operation incidence was found between the two groups.CONCLUSION:PSB could ameliorate gastrointestinal dysfunction or failure during the early stage of SAP.Moreover,PSB administration could improve prognosis and decrease the mortality of SAP patients.展开更多
Diabetes mellitus is an independent risk factor for ischemic stroke.Both diabetes mellitus and stroke are linked to systemic inflammation that aggravates patient outcomes.Stellate ganglion block can effectively regula...Diabetes mellitus is an independent risk factor for ischemic stroke.Both diabetes mellitus and stroke are linked to systemic inflammation that aggravates patient outcomes.Stellate ganglion block can effectively regulate the inflammatory response.Therefore,it is hypothesized that stellate ganglion block could be a potential therapy for ischemic stroke in diabetic subjects.In this study,we induced diabetes mellitus in rats by feeding them a high-fat diet for 4 successive weeks.The left middle cerebral artery was occluded to establish models of ischemic stroke in diabetic rats.Subsequently,we performed left stellate ganglion block with 1%lidocaine using the percutaneous posterior approach 15 minutes before reperfusion and again 20 and 44 hours after reperfusion.Our results showed that stellate ganglion block did not decrease the blood glucose level in diabetic rats with diabetes mellitus but did reduce the cerebral infarct volume and the cerebral water content.It also improved the recovery of neurological function,increased 28-day survival rate,inhibited Toll like receptor 4/nuclear factor kappa B signaling pathway and reduced inflammatory response in the plasma of rats.However,injection of Toll like receptor 4 agonist lipopolysaccharide 5 minutes before stellate ganglion block inhibited the effect of stellate ganglion block,whereas injection of Toll like receptor 4 inhibitor TAK242 had no such effect.We also found that stellate ganglion block performed at night had no positive effect on diabetic ischemic stroke.These findings suggest that stellate ganglion block is a potential therapy for diabetic ischemic stroke and that it may be mediated through the Toll like receptor 4/nuclear factor kappa B signaling pathway.We also found that the therapeutic effect of stellate ganglion block is affected by circadian rhythm.展开更多
The great potential of liquid-crystalline block copolymers(LCBCs)containing photoresponsive mesogens toward novel applications in photonics and nanotechnology has been attracting increasing attention,due to the combin...The great potential of liquid-crystalline block copolymers(LCBCs)containing photoresponsive mesogens toward novel applications in photonics and nanotechnology has been attracting increasing attention,due to the combination of the inherent property of microphase separation of block copolymers and the hierarchically-assembled structures of liquid-crystalline polymers(LCPs).The periodically ordered nanostructures in bulk film of LCBCs can be acquired by supramolecular cooperative motion,derived from the interaction between liquid-crystalline elastic deformation and microphase separation,which are able to improve physical properties of polymer film toward advanced functional applications.Moreover,various micro/nano-patterned structures have been fabricated via light manipulation of photoresponsive LCBCs with good reproducibility and mass production.Thanks to recent developments in synthesis and polymerization techniques,diverse azobenzene-containing LCBCs have been designed,resulting in the creation of a wide variety of novel functions.This review illustrates recent progresses in macroscopic regulation of hierarchical nanostructures in LCBCs towards functional materials.The existing challenges are also discussed,showing perspectives for future studies.展开更多
The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification proc...The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification process,which cannot provide sufficient protection.In the current study,we design a double-layer epoxy composite coating on Mg alloy with enhanced anti-corrosion/wear properties,via the spin-assisted assembly technique.The outer layer is functionalized graphene(FG)in waterborne epoxy resin(WEP)and the inner layer is Ce-based conversion(Ce)film.The FG sheets can be homogeneously dispersed within the epoxy matrix to fill the intrinsic defects and improve the barrier capability.The Ce film connects the outer layer with the substrate,showing the transition effect.The corrosion rate of Ce/WEP/FG composite coating is 2131 times lower than that of bare Mg alloy,and the wear rate is decreased by~90%.The improved corrosion resistance is attributed to the labyrinth effect(hindering the penetration of corrosive medium)and the obstruction of galvanic coupling behavior.The synergistic effect derived from the FG sheet and blocking layer exhibits great potential in realizing the improvement of multi-functional integration,which will open up a new avenue for the development of novel composite protection coatings of Mg alloys.展开更多
Solid polymer electrolytes have been considered as the promising candidates to improve the safety and stability of high-energy lithium metal batteries.However,the practical applications of solid polymer electrolytes a...Solid polymer electrolytes have been considered as the promising candidates to improve the safety and stability of high-energy lithium metal batteries.However,the practical applications of solid polymer electrolytes are still limited by the low ionic conductivity,poor interfacial contact with electrodes,narrow electrochemical window and weak mechanical strength.Here,a series of novel block copolymer electrolytes with three-dimensional networks are designed by cross-linked copolymerization of the polyethylene glycol soft segments and hexamethylene diisocyanate trimer hard segments.Their ionic migration performances and interface compatibilities with Li metal anode have been optimized delicately by tailoring the ratio of these functional units.The optimized block copolymer electrolyte has shown an amorphous crystalline structure,a high ionic conductivity of ~5.7×10^(-4)S cm^(-1),high lithium ion transference number(~0.49),wide electrochemical window up to ~4.65 V(vs.Li+/Li) and favorable mechanical strength at 55℃.Furthermore,the enhanced interface compatibility can well support the normal operations of lithium metal batteries using both LiFePO4 and LiNi0.8Co0.15Al0.05O2 cathodes.This study not only paves a new way to develop solid polymer electrolyte with optimizing functional units,but also provides a polymer electrolyte design strategy for the application demand of lithium metal battery.展开更多
This work uses a block copolymer architecture[(A′B)nA2]m to unify the scattering function and spinodal transition of typical AB-type block copolymers.The key roles of block number,junction points and asymmetry ratios...This work uses a block copolymer architecture[(A′B)nA2]m to unify the scattering function and spinodal transition of typical AB-type block copolymers.The key roles of block number,junction points and asymmetry ratios of block length are(1)to determine the form factor of each block copolymer at the molecular scale;(2)to affect the entropy loss across the spinodal transition and may result in deflection of spinodal curves.The common features are validated in typical linear and nonlinear block copolymers,including AB diblock,asymmetric A′BA triblock,miktoarm stars of ABn,AnBn,(AB)n,(A′B)nA,A′BAm,and multi-graft combs of(BnA2)m and[(A′B)nA2]m.The explicit scattering functions and form factors of various block copolymers can be directly applied in radiation experiments(i.e.neutron or X-ray scattering)to unravel the effect of molecular architecture in solution and microphase separation in disordered melt.The molecular model used in this study is also helpful to guide the chemical synthesis to explore more potentially interesting block copolymers.展开更多
The paper presents a parallel ATPG algorithm - PTGBP, which aims at decreasing the complexity of the ATPG by partitioning circuit under test (CUT) to big function blocks (BFB) and processing them parallelly. PTGBP ado...The paper presents a parallel ATPG algorithm - PTGBP, which aims at decreasing the complexity of the ATPG by partitioning circuit under test (CUT) to big function blocks (BFB) and processing them parallelly. PTGBP adopts hybrid circuit mode and hybrid fault model, and organizes the parallel course in term of master/slave mode. Master processor loads the whole netlist of CUT based on BFB, every slave processor loads logic level (gate/function block/basic logic units) netlist of a BFB. Test generation (TG) uses BFB input/output s-a-0/s-a-1 fault model; fault simulation uses logic level single stuck fault model. Master controls the PTGBP’s running course and ensures the correctness of its running result; slaves provide the results of fault sensitization compatible computation and fault simulation to master parallelly. PTGBP algorithm is under implementation.展开更多
This paper investigates the numerical solution of two-dimensional nonlinear stochastic Itô-Volterra integral equations based on block pulse functions. The nonlinear stochastic integral equation is transformed...This paper investigates the numerical solution of two-dimensional nonlinear stochastic Itô-Volterra integral equations based on block pulse functions. The nonlinear stochastic integral equation is transformed into a set of algebraic equations by operational matrix of block pulse functions. Then, we give error analysis and prove that the rate of convergence of this method is efficient. Lastly, a numerical example is given to confirm the method.展开更多
This paper presents the TDS-1 GNSS reflectometry wind Geophysical Model Function(GMF)response to GPS block types.The observables were extracted from Delay Doppler Maps(DDMs)after taking the receiver antenna gains effe...This paper presents the TDS-1 GNSS reflectometry wind Geophysical Model Function(GMF)response to GPS block types.The observables were extracted from Delay Doppler Maps(DDMs)after taking the receiver antenna gains effects and GNSS-R geometry effects into account.Since the DDM is affected by GPS EffectiveIsotropic Radiated Power(EIRP),we first investigate the sensitivity of observables to the GPS block.Additionally,the observables at high SNRs are more sensitive to wind speed,but the spatial coverage at high signal to noise ratios(SNRs)is lower,while DDMs at low SNRs have the opposite characteristics.To balance the accuracy and spatial coverage,the DDM datasets are divided into two parts:high SNR(>0 dB)and low SNR(>−10 dB and≤0 dB)to develop wind GMF.Then,the influences of GPS block on wind speed retrieval both at high and low SNR is analyzed.Results show that the block types have impacts on wind GMF and the use of a prior GPS block can contribute to a better wind speed retrieval both at high and low SNR.Compared with ASCAT,the Root Mean Square Error(RMSE)value of wind speed retrieval at high and low SNR are 2.19 m/s and 3.13 m/s,respectively,when all TDS data are processed without distinguishing GPS block types.However,if the TDS data are separately processed and used to develop wind GMF through different blocks,both the accuracy and correlation coefficient can be improved to some extent.Finally,the influence of significant height of the swell(Hs)on SNR observables is analyzed,and it is demonstrated that there is no obvious linear or nonlinear relationship between them.展开更多
Both terminated functional isotactic polypropylene （iPP） and block copolymers containing iPP segment are desirable for commercial applications. This paper provides a convenient, highly-efficient method to prepare hy...Both terminated functional isotactic polypropylene （iPP） and block copolymers containing iPP segment are desirable for commercial applications. This paper provides a convenient, highly-efficient method to prepare hydroxyl-terminated isotactic polypropylene （iPP-t-OH） and functional di-block copolymer containing the iPP segment through a combination of coordination polymerization and coupling reaction. The coordination polymerization was catalyzed by TiCI4/MgCI2/AIEt3 catalyst system using ZnEt2 as chain transfer agent. Further, the Zn-terminated iPP was oxidized and subsequently hydrolyzed to provide iPP-t-OH. Soxhlet extraction and 13C NMR were used to calculate the isotacticity of iPP-t-OH. The degree of polymerization and the number of hydroxyl groups at the chain end of iPP-t-OH were measured by GPC and 1H NMR. Despite the high molecular weight and heterogeneous reaction, iPP-t-OH is effectively linked with PEG-t-NCO to produce di-block copolymers. DSC analysis of the di-block copolymer shows an obvious decrease in Tm and To, which indicated that PEG was successfully linked to the terminal end of iPP.展开更多
Background: Pectoral nerves (PECS) block has been reported to be effective for a perioperative analgesia for breast cancer surgery. In addition, we may consider that the PECS block is also effective for motor function...Background: Pectoral nerves (PECS) block has been reported to be effective for a perioperative analgesia for breast cancer surgery. In addition, we may consider that the PECS block is also effective for motor function in postoperative period. Therefore, we investigated the effect of PECS block for motor function in postoperative period. Methods: This study selected the patients performed the breast cancer surgery between April and September, 2015. The study surveyed the difficulty of movement of the upper limbs at postoperative day 5 (D5) and postoperative month 6 (M6) by performing telephone survey. We counted the number of patients who complained of the difficulty of movement of the upper limbs. All results were compared using the chi- squared test. P < 0.05 was considered statistically significant. Results: 93 patients received only general anesthesia (G group). 85 patients received PECS block with general anesthesia (P group). The number of the P group at D5 was 2 patients. On the other hand, the number of the G group was 15 patients (P = 0.042). In the same way, the number of the P group M6 was no patient. On the other hand, the number of the G group was 10 patients (P = 0.043). Conclusion: A PECS block is effective for motor function recovery in the early postoperative period after breast cancer surgery.展开更多
The South China block(SC),composed of Cathaysia(CA),Jiangnan Orogenic belt(JNB),and Yangtze block(YB),is one of the most important poly-metallic metallogenic provinces in the world(Zhang et al.,2013),containing of fou...The South China block(SC),composed of Cathaysia(CA),Jiangnan Orogenic belt(JNB),and Yangtze block(YB),is one of the most important poly-metallic metallogenic provinces in the world(Zhang et al.,2013),containing of four famous major Mesozoic metallogenic belts,involving the Middle-Lower Yangtze Fe-Cu-Au metallogenic belt(MYMB).展开更多
For the 64 most basic ways to construct a hash function H:{0,1} → {0,1}n from a block cipher E:{0,1}n × {0,1}n → {0,1}n, Black et al.provided a formal and quantitative treatment of the 64 constructions, and pro...For the 64 most basic ways to construct a hash function H:{0,1} → {0,1}n from a block cipher E:{0,1}n × {0,1}n → {0,1}n, Black et al.provided a formal and quantitative treatment of the 64 constructions, and proved that 20 schemes are collision resistant.This paper improves the upper and lower bounds and make contrast with a hash constructed from a random oracle.These 20 schemes have only one kind of collision resistance upper and lower bounds.In addition, we present new advantages for finding second preimages.展开更多
A conventional global contrast enhancement is difficult to apply in various images because image quality and contrast enhancement are dependent on image characteristics largely. And a local contrast enhancement not on...A conventional global contrast enhancement is difficult to apply in various images because image quality and contrast enhancement are dependent on image characteristics largely. And a local contrast enhancement not only causes a washed-out effect, but also blocks. To solve these drawbacks, this paper derives an optimal global equalization function with variable size block based local contrast enhancement. The optimal equalization function makes it possible to get a good quality image through the global contrast enhancement. The variable size block segmentation is firstly exeoated using intensity differences as a measure of similarity. In the second step, the optimal global equalization function is obtained from the enhanced contrast image having variable size blocks. Conformed experiments have showed that the proposed algorithm produces a visually comfortable result image.展开更多
FBS-3A feedback broadband seismometer has been widely utilized in observation networks up to now. Therefore, it is very important and practically meaningful for the application of this kind of sensor to fulfill some r...FBS-3A feedback broadband seismometer has been widely utilized in observation networks up to now. Therefore, it is very important and practically meaningful for the application of this kind of sensor to fulfill some relative research work about its transfer function and for the analysis to the data recorded and the further development of the seismometer. In this paper, from the viewpoint of achieving its working principle, method of systematic analysis is applied to deduce the transfer functions, including both the transfer function for calibration and that for measurement. Moreover, on the basis of that, the distribution of its zeroes and poles in a complex frequency domain is analyzed, which provides a convincing evidence to simplify this seismometer system from a high-order one to a two-order one. And the emulation of the frequency characteristics of FBS-3A is presented in this paper. On the whole, the aim of this article is to do some theoretical work about the earthquake observation sensor, and also to introduce the method of making systematic analysis in a complex frequency domain to the research and the development of the seismometers.展开更多
Objective:To investigate the effect of dexmedetomidine combined with ultrasound guided nerve block on the hemodynamics, immune function and cortisol level in the patients undergoing inguinal surgery.Methods:A total of...Objective:To investigate the effect of dexmedetomidine combined with ultrasound guided nerve block on the hemodynamics, immune function and cortisol level in the patients undergoing inguinal surgery.Methods:A total of 120 patients who underwent unilateral inguinal surgery in our hospital were randomly divided into control group and observation group, 60 cases in each group. The control group was induced by intravenous anesthesia with sufentanil. The observation group was given dexmedetomidine combined with ultrasound guided ilioinguinal/iliac hypogastric nerve block. Hemodynamics, immune function and cortisol levels were compared between the two groups before and after anesthesia induction. Results:After anesthesia, in surgical incision and recovery time, the levels of HR in the two groups were significantly lower than that before the anesthesia, and the levels of HR in the observation group were significantly lower than that in the control group. After anesthesia, in surgical incision and recovery time, the levels of CD3+, CD4+ and CD4+/CD8+ in the control group were significantly lower than that of the group before anesthesia. After anesthesia, the levels of CD3+, CD4+ and CD4+/CD8+ in the observation group were significantly lower than that of the group before anesthesia. In surgical incision and recovery time, there was no significant difference in the levels of CD3+, CD4+ and CD4+/CD8+ in the observation group before anesthesia. After anesthesia, in surgical incision and recovery time, the levels of CD3+, CD4+ and CD4+/CD8+ in the observation group were significantly higher than that of the control group. The levels of serum PI3K, ET -1, CRP and cortisol of the two groups were significantly higher than those before anesthesia, and the levels of PI3K, ET -1, CRP and cortisol in the serum of the patients in the observation group were significantly lower than those in the control group.Conclusion: The effect of dexmedetomidin combined with ultrasound guided nerve block anesthesia on the patients with inguinal surgery can effectively maintain the hemodynamic stability of the patients and have less influence on the immune function and the stress response. The security is higher.展开更多
文摘AIM:To investigate effects of perirenal space blocking(PSB)on gastrointestinal function in patients with severe acute pancreatitis(SAP).METHODS:Forty patients with SAP were randomly allocated to receive PSB or no PSB(NPSB).All the SAP patients received specialized medical therapy(SMT).Patients in the PSB group received PSB+SMT when hospitalized and after diagnosis,whereas patients in the NPSB group only received SMT.A modifed gastrointestinal failure(GIF)scoring system was used to assess the gastrointestinal function in SAP patients after admission.Pain severity(visual analog scale,0 to100)was monitored every 24 h for 72 h.RESULTS:Modified GIF score decreased in both groups during the 10-d study period.The median score decrease was initially significantly greater in the PSB group than in the NPSB group after PSB was per-formed.During the 72-h study period,pain intensity decreased in both groups.The median pain decrease was significantly greater in the PSB group than in the NPSB group at single time points.Patients in the PSB group had significantly lower incidences of hospital mortality,multiple organ dysfunction syndrome,systemic inflammatory response syndrome,and pancreatic infection,and stayed in the intensive care unit for a shorter duration.However,no difference in terms of operation incidence was found between the two groups.CONCLUSION:PSB could ameliorate gastrointestinal dysfunction or failure during the early stage of SAP.Moreover,PSB administration could improve prognosis and decrease the mortality of SAP patients.
基金The study was approved by Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province,No.LBH-Q18074(to WCY).
文摘Diabetes mellitus is an independent risk factor for ischemic stroke.Both diabetes mellitus and stroke are linked to systemic inflammation that aggravates patient outcomes.Stellate ganglion block can effectively regulate the inflammatory response.Therefore,it is hypothesized that stellate ganglion block could be a potential therapy for ischemic stroke in diabetic subjects.In this study,we induced diabetes mellitus in rats by feeding them a high-fat diet for 4 successive weeks.The left middle cerebral artery was occluded to establish models of ischemic stroke in diabetic rats.Subsequently,we performed left stellate ganglion block with 1%lidocaine using the percutaneous posterior approach 15 minutes before reperfusion and again 20 and 44 hours after reperfusion.Our results showed that stellate ganglion block did not decrease the blood glucose level in diabetic rats with diabetes mellitus but did reduce the cerebral infarct volume and the cerebral water content.It also improved the recovery of neurological function,increased 28-day survival rate,inhibited Toll like receptor 4/nuclear factor kappa B signaling pathway and reduced inflammatory response in the plasma of rats.However,injection of Toll like receptor 4 agonist lipopolysaccharide 5 minutes before stellate ganglion block inhibited the effect of stellate ganglion block,whereas injection of Toll like receptor 4 inhibitor TAK242 had no such effect.We also found that stellate ganglion block performed at night had no positive effect on diabetic ischemic stroke.These findings suggest that stellate ganglion block is a potential therapy for diabetic ischemic stroke and that it may be mediated through the Toll like receptor 4/nuclear factor kappa B signaling pathway.We also found that the therapeutic effect of stellate ganglion block is affected by circadian rhythm.
基金supported by the National Key R&D Program of China(No.2018YFB0703702)the National Natural Science Foundation of China(Nos.51773002,51921002).
文摘The great potential of liquid-crystalline block copolymers(LCBCs)containing photoresponsive mesogens toward novel applications in photonics and nanotechnology has been attracting increasing attention,due to the combination of the inherent property of microphase separation of block copolymers and the hierarchically-assembled structures of liquid-crystalline polymers(LCPs).The periodically ordered nanostructures in bulk film of LCBCs can be acquired by supramolecular cooperative motion,derived from the interaction between liquid-crystalline elastic deformation and microphase separation,which are able to improve physical properties of polymer film toward advanced functional applications.Moreover,various micro/nano-patterned structures have been fabricated via light manipulation of photoresponsive LCBCs with good reproducibility and mass production.Thanks to recent developments in synthesis and polymerization techniques,diverse azobenzene-containing LCBCs have been designed,resulting in the creation of a wide variety of novel functions.This review illustrates recent progresses in macroscopic regulation of hierarchical nanostructures in LCBCs towards functional materials.The existing challenges are also discussed,showing perspectives for future studies.
基金the National Natural Science Foundation of China(Grant number 51771178)Shaanxi Outstanding Youth Fund project(Grant number 2021JC-45)+2 种基金Key international cooperation projects in Shaanxi Province(Grant number 2020KWZ-007)the Major Program of Science and Technology in Shaanxi Province(Grant number20191102006)Open Fund of State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body(Grant number 32115019)。
文摘The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification process,which cannot provide sufficient protection.In the current study,we design a double-layer epoxy composite coating on Mg alloy with enhanced anti-corrosion/wear properties,via the spin-assisted assembly technique.The outer layer is functionalized graphene(FG)in waterborne epoxy resin(WEP)and the inner layer is Ce-based conversion(Ce)film.The FG sheets can be homogeneously dispersed within the epoxy matrix to fill the intrinsic defects and improve the barrier capability.The Ce film connects the outer layer with the substrate,showing the transition effect.The corrosion rate of Ce/WEP/FG composite coating is 2131 times lower than that of bare Mg alloy,and the wear rate is decreased by~90%.The improved corrosion resistance is attributed to the labyrinth effect(hindering the penetration of corrosive medium)and the obstruction of galvanic coupling behavior.The synergistic effect derived from the FG sheet and blocking layer exhibits great potential in realizing the improvement of multi-functional integration,which will open up a new avenue for the development of novel composite protection coatings of Mg alloys.
基金supported financially by the National Key R&D Program of China (Grant No. 2018YFB0104300)Beijing Natural Science Foundation (JQ19003, KZ201910005002 and L182009)+1 种基金National Natural Science Foundation of China (Grants 21875007, 51622202, and 21974007)the Project of Youth Talent Plan of Beijing Municipal Education Commission (CIT&TCD201804013)。
文摘Solid polymer electrolytes have been considered as the promising candidates to improve the safety and stability of high-energy lithium metal batteries.However,the practical applications of solid polymer electrolytes are still limited by the low ionic conductivity,poor interfacial contact with electrodes,narrow electrochemical window and weak mechanical strength.Here,a series of novel block copolymer electrolytes with three-dimensional networks are designed by cross-linked copolymerization of the polyethylene glycol soft segments and hexamethylene diisocyanate trimer hard segments.Their ionic migration performances and interface compatibilities with Li metal anode have been optimized delicately by tailoring the ratio of these functional units.The optimized block copolymer electrolyte has shown an amorphous crystalline structure,a high ionic conductivity of ~5.7×10^(-4)S cm^(-1),high lithium ion transference number(~0.49),wide electrochemical window up to ~4.65 V(vs.Li+/Li) and favorable mechanical strength at 55℃.Furthermore,the enhanced interface compatibility can well support the normal operations of lithium metal batteries using both LiFePO4 and LiNi0.8Co0.15Al0.05O2 cathodes.This study not only paves a new way to develop solid polymer electrolyte with optimizing functional units,but also provides a polymer electrolyte design strategy for the application demand of lithium metal battery.
基金by the Fundamental Research Funds for the Central Universities,Nankai University(No.000082)the National Natural Science Foundation of China(No.21973050).
文摘This work uses a block copolymer architecture[(A′B)nA2]m to unify the scattering function and spinodal transition of typical AB-type block copolymers.The key roles of block number,junction points and asymmetry ratios of block length are(1)to determine the form factor of each block copolymer at the molecular scale;(2)to affect the entropy loss across the spinodal transition and may result in deflection of spinodal curves.The common features are validated in typical linear and nonlinear block copolymers,including AB diblock,asymmetric A′BA triblock,miktoarm stars of ABn,AnBn,(AB)n,(A′B)nA,A′BAm,and multi-graft combs of(BnA2)m and[(A′B)nA2]m.The explicit scattering functions and form factors of various block copolymers can be directly applied in radiation experiments(i.e.neutron or X-ray scattering)to unravel the effect of molecular architecture in solution and microphase separation in disordered melt.The molecular model used in this study is also helpful to guide the chemical synthesis to explore more potentially interesting block copolymers.
基金Supported by National Natural Science Founding of China.
文摘The paper presents a parallel ATPG algorithm - PTGBP, which aims at decreasing the complexity of the ATPG by partitioning circuit under test (CUT) to big function blocks (BFB) and processing them parallelly. PTGBP adopts hybrid circuit mode and hybrid fault model, and organizes the parallel course in term of master/slave mode. Master processor loads the whole netlist of CUT based on BFB, every slave processor loads logic level (gate/function block/basic logic units) netlist of a BFB. Test generation (TG) uses BFB input/output s-a-0/s-a-1 fault model; fault simulation uses logic level single stuck fault model. Master controls the PTGBP’s running course and ensures the correctness of its running result; slaves provide the results of fault sensitization compatible computation and fault simulation to master parallelly. PTGBP algorithm is under implementation.
基金NSF Grants 11471105 of China, NSF Grants 2016CFB526 of Hubei Province, Innovation Team of the Educational Department of Hubei Province T201412, and Innovation Items of Hubei Normal University 2018032 and 2018105
文摘This paper investigates the numerical solution of two-dimensional nonlinear stochastic Itô-Volterra integral equations based on block pulse functions. The nonlinear stochastic integral equation is transformed into a set of algebraic equations by operational matrix of block pulse functions. Then, we give error analysis and prove that the rate of convergence of this method is efficient. Lastly, a numerical example is given to confirm the method.
基金supported by the Funds for Creative Research Groups of China[Grant no.41721003]the National Natural Science Foundation of China[Grant nos.41825009 and 41774034].
文摘This paper presents the TDS-1 GNSS reflectometry wind Geophysical Model Function(GMF)response to GPS block types.The observables were extracted from Delay Doppler Maps(DDMs)after taking the receiver antenna gains effects and GNSS-R geometry effects into account.Since the DDM is affected by GPS EffectiveIsotropic Radiated Power(EIRP),we first investigate the sensitivity of observables to the GPS block.Additionally,the observables at high SNRs are more sensitive to wind speed,but the spatial coverage at high signal to noise ratios(SNRs)is lower,while DDMs at low SNRs have the opposite characteristics.To balance the accuracy and spatial coverage,the DDM datasets are divided into two parts:high SNR(>0 dB)and low SNR(>−10 dB and≤0 dB)to develop wind GMF.Then,the influences of GPS block on wind speed retrieval both at high and low SNR is analyzed.Results show that the block types have impacts on wind GMF and the use of a prior GPS block can contribute to a better wind speed retrieval both at high and low SNR.Compared with ASCAT,the Root Mean Square Error(RMSE)value of wind speed retrieval at high and low SNR are 2.19 m/s and 3.13 m/s,respectively,when all TDS data are processed without distinguishing GPS block types.However,if the TDS data are separately processed and used to develop wind GMF through different blocks,both the accuracy and correlation coefficient can be improved to some extent.Finally,the influence of significant height of the swell(Hs)on SNR observables is analyzed,and it is demonstrated that there is no obvious linear or nonlinear relationship between them.
基金supported by the National Natural Science Foundation of China(No.51173157)National High-Tech R&D Program of China(No.2012AA040305)the Major State Basic Research Programs(No.2011CB606001)
文摘Both terminated functional isotactic polypropylene （iPP） and block copolymers containing iPP segment are desirable for commercial applications. This paper provides a convenient, highly-efficient method to prepare hydroxyl-terminated isotactic polypropylene （iPP-t-OH） and functional di-block copolymer containing the iPP segment through a combination of coordination polymerization and coupling reaction. The coordination polymerization was catalyzed by TiCI4/MgCI2/AIEt3 catalyst system using ZnEt2 as chain transfer agent. Further, the Zn-terminated iPP was oxidized and subsequently hydrolyzed to provide iPP-t-OH. Soxhlet extraction and 13C NMR were used to calculate the isotacticity of iPP-t-OH. The degree of polymerization and the number of hydroxyl groups at the chain end of iPP-t-OH were measured by GPC and 1H NMR. Despite the high molecular weight and heterogeneous reaction, iPP-t-OH is effectively linked with PEG-t-NCO to produce di-block copolymers. DSC analysis of the di-block copolymer shows an obvious decrease in Tm and To, which indicated that PEG was successfully linked to the terminal end of iPP.
文摘Background: Pectoral nerves (PECS) block has been reported to be effective for a perioperative analgesia for breast cancer surgery. In addition, we may consider that the PECS block is also effective for motor function in postoperative period. Therefore, we investigated the effect of PECS block for motor function in postoperative period. Methods: This study selected the patients performed the breast cancer surgery between April and September, 2015. The study surveyed the difficulty of movement of the upper limbs at postoperative day 5 (D5) and postoperative month 6 (M6) by performing telephone survey. We counted the number of patients who complained of the difficulty of movement of the upper limbs. All results were compared using the chi- squared test. P < 0.05 was considered statistically significant. Results: 93 patients received only general anesthesia (G group). 85 patients received PECS block with general anesthesia (P group). The number of the P group at D5 was 2 patients. On the other hand, the number of the G group was 15 patients (P = 0.042). In the same way, the number of the P group M6 was no patient. On the other hand, the number of the G group was 10 patients (P = 0.043). Conclusion: A PECS block is effective for motor function recovery in the early postoperative period after breast cancer surgery.
基金jointly sponsored by the National Natural Science Foundation of China(Grant Nos.41630320,92062108)the Geology Survey Project(Grant Nos.DD20190012,DD20160082)the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resource,Institute of Geology,Chinese Academy of Geological Sciences(Grant No.J1901-16)
文摘The South China block(SC),composed of Cathaysia(CA),Jiangnan Orogenic belt(JNB),and Yangtze block(YB),is one of the most important poly-metallic metallogenic provinces in the world(Zhang et al.,2013),containing of four famous major Mesozoic metallogenic belts,involving the Middle-Lower Yangtze Fe-Cu-Au metallogenic belt(MYMB).
基金the National Natural Science Foundation of China (No. 60573028)
文摘For the 64 most basic ways to construct a hash function H:{0,1} → {0,1}n from a block cipher E:{0,1}n × {0,1}n → {0,1}n, Black et al.provided a formal and quantitative treatment of the 64 constructions, and proved that 20 schemes are collision resistant.This paper improves the upper and lower bounds and make contrast with a hash constructed from a random oracle.These 20 schemes have only one kind of collision resistance upper and lower bounds.In addition, we present new advantages for finding second preimages.
文摘A conventional global contrast enhancement is difficult to apply in various images because image quality and contrast enhancement are dependent on image characteristics largely. And a local contrast enhancement not only causes a washed-out effect, but also blocks. To solve these drawbacks, this paper derives an optimal global equalization function with variable size block based local contrast enhancement. The optimal equalization function makes it possible to get a good quality image through the global contrast enhancement. The variable size block segmentation is firstly exeoated using intensity differences as a measure of similarity. In the second step, the optimal global equalization function is obtained from the enhanced contrast image having variable size blocks. Conformed experiments have showed that the proposed algorithm produces a visually comfortable result image.
文摘FBS-3A feedback broadband seismometer has been widely utilized in observation networks up to now. Therefore, it is very important and practically meaningful for the application of this kind of sensor to fulfill some relative research work about its transfer function and for the analysis to the data recorded and the further development of the seismometer. In this paper, from the viewpoint of achieving its working principle, method of systematic analysis is applied to deduce the transfer functions, including both the transfer function for calibration and that for measurement. Moreover, on the basis of that, the distribution of its zeroes and poles in a complex frequency domain is analyzed, which provides a convincing evidence to simplify this seismometer system from a high-order one to a two-order one. And the emulation of the frequency characteristics of FBS-3A is presented in this paper. On the whole, the aim of this article is to do some theoretical work about the earthquake observation sensor, and also to introduce the method of making systematic analysis in a complex frequency domain to the research and the development of the seismometers.
文摘Objective:To investigate the effect of dexmedetomidine combined with ultrasound guided nerve block on the hemodynamics, immune function and cortisol level in the patients undergoing inguinal surgery.Methods:A total of 120 patients who underwent unilateral inguinal surgery in our hospital were randomly divided into control group and observation group, 60 cases in each group. The control group was induced by intravenous anesthesia with sufentanil. The observation group was given dexmedetomidine combined with ultrasound guided ilioinguinal/iliac hypogastric nerve block. Hemodynamics, immune function and cortisol levels were compared between the two groups before and after anesthesia induction. Results:After anesthesia, in surgical incision and recovery time, the levels of HR in the two groups were significantly lower than that before the anesthesia, and the levels of HR in the observation group were significantly lower than that in the control group. After anesthesia, in surgical incision and recovery time, the levels of CD3+, CD4+ and CD4+/CD8+ in the control group were significantly lower than that of the group before anesthesia. After anesthesia, the levels of CD3+, CD4+ and CD4+/CD8+ in the observation group were significantly lower than that of the group before anesthesia. In surgical incision and recovery time, there was no significant difference in the levels of CD3+, CD4+ and CD4+/CD8+ in the observation group before anesthesia. After anesthesia, in surgical incision and recovery time, the levels of CD3+, CD4+ and CD4+/CD8+ in the observation group were significantly higher than that of the control group. The levels of serum PI3K, ET -1, CRP and cortisol of the two groups were significantly higher than those before anesthesia, and the levels of PI3K, ET -1, CRP and cortisol in the serum of the patients in the observation group were significantly lower than those in the control group.Conclusion: The effect of dexmedetomidin combined with ultrasound guided nerve block anesthesia on the patients with inguinal surgery can effectively maintain the hemodynamic stability of the patients and have less influence on the immune function and the stress response. The security is higher.
