The current modified electro-Fenton system was designed to develop a more convenient and efficient undivided system for practical wastewater treatment. The system adopted a cathode portion that employed magnetic stirr...The current modified electro-Fenton system was designed to develop a more convenient and efficient undivided system for practical wastewater treatment. The system adopted a cathode portion that employed magnetic stirring instead of common oxygen gas diffusion or gas sparging to supply oxygen gas for the electrolyte solution. Key factors influencing the cathode fabrication and activit） were investigated. The degradation of acid fuchsine with a self-made graphite-polytetrafluorethylene cathode was studied using spectrophotometer. It was found that the cathode generated hydrogen peroxide with high current efficiency and the hydrogen peroxide yield of the cathode did not decay after 10 times reuse. With the Pt anode at a ferrous ion concentration of 0.5 mmol/L, a pH of 3, and using magnetic stirring, dye decolorization could be rapidly accomplished but the destruction of benzene rings and intermediates was fairly difficult. With a Fe anode, dye degradation was more complete.展开更多
Excessive discharge of dye wastewater has brought serious harm to human health and the environment.In this paper,a magnetic absorbent,ferroferric oxide@β-cyclodextrin(Fe_(3)O_(4)@CD),was prepared for the efficient ad...Excessive discharge of dye wastewater has brought serious harm to human health and the environment.In this paper,a magnetic absorbent,ferroferric oxide@β-cyclodextrin(Fe_(3)O_(4)@CD),was prepared for the efficient adsorption removal of basic fuchsin(BF)from dye wastewater,based on the special amphiphilicity ofβ-CD and the strong magnetism of Fe_(3)O_(4).A series of influence factors including the initial dye concentration,adsorbent dosage,temperature and pH were investigated,as well as the adsorption mechanism.The results show that Fe_(3)O_(4)@CD has the best adsorption and removal effect on BF dye at room temperature and neutral pH,when the initial concentration of dye is 25 mg/L and the adsorbent dosage is 100 mg.The adsorption behavior conforms to the pseudo-second-order kinetics and the Langmuir adsorption isotherm,and the adsorption process is spontaneously endothermic.Fe_(3)O_(4)@CD adsorbed with BF dye can be rapidly separated under an external magnetic field and then easily regenerated by HCl treatment.After 5 times of recycling,the removal rate of the prepared magnetic composite on BF dye is kept above 75%.This work will provide an economic and eco-friendly technology for the treatment of the actual dye wastewater.展开更多
With the development circular economy, the use of agricultural waste to prepare biomass materials to remove pollutants has become a research hotspot. In this study, sunflower straw activated carbon (SSAC) was prepared...With the development circular economy, the use of agricultural waste to prepare biomass materials to remove pollutants has become a research hotspot. In this study, sunflower straw activated carbon (SSAC) was prepared by the one-step activation method, with sunflower straw (SS) used as the raw material and H3PO4 used as the activator. Four types of SSAC were prepared with impregnation ratios (weight of SS to weight of H3PO4) of 1:1, 1:2, 1:3, and 1:5, corresponding to SSAC1, SSAC2, SSAC3, and SSAC4, respectively. The adsorption process of acid fuchsin (AF) in water using the four types of SSAC was studied. The results showed that the impregnation ratio significantly affected the structure of the materials. The increase in the impregnation ratio increased the specific surface area and pore volume of SSAC and improved the adsorption capacity of AF. However, an impregnation ratio that was too large led to a decrease in specific surface area. SSAC3, with an impregnation ratio of 1:3, had the largest specific surface area (1 794.01 m2/g), and SSAC4, with an impregnation ratio of 1:5, exhibited the smallest microporosity (0.052 7 cm3/g) and the largest pore volume (2.549 cm3/g). The adsorption kinetics of AF using the four types of SSAC agreed with the quasi-second-order adsorption kinetic model. The Langmuir isotherm model was suitable to describe SSAC3 and SSAC4, and the Freundlich isotherm model was appropriate to describe SSAC1 and SSAC2. The result of thermodynamics showed that the adsorption process was spontaneous and endothermic. At 303 K, SSAC4 showed a removal rate of 97.73% for 200-mg/L AF with a maximum adsorption capacity of 2 763.36 mg/g, the highest among the four types of SSAC. This study showed that SAAC prepared by the H3PO4-based one-step activation method is a green and efficient carbon material and has significant application potential for the treatment of dye-containing wastewater.展开更多
Visible spectroscopic and electrochemical methods were used to study the interactions between DNA and fuchsin basic（FB）. FB has an irreversible electro-oxidation peak in 5 mmol/L Tris-HCl buffer solution at pH = 7.4...Visible spectroscopic and electrochemical methods were used to study the interactions between DNA and fuchsin basic（FB）. FB has an irreversible electro-oxidation peak in 5 mmol/L Tris-HCl buffer solution at pH = 7.4 on a glassy carbon electrode（GCE）. After adding certain concentration of dsDNA, the oxidation peak current of FB decreases, but the peak potential hardly changes. The visible absorption spectroscopic study shows that the binding mode of FB to dsDNA is intercalative binding and electrostatic binding when the ratio of the concentration of dsDNA to FB is smaller than 0. 2, and anew substance, which produces a new absorption peak, is obtained via a covalent binding between dsDNA and FB apart from intercalative binding and electrostatic binding when the ratio of the concentration of dsDNA to FB is larger than 0. 2. The visible absorption spectra varies no longer when the ratio of the concentration of dsDNA＇to FB is larger than 1.5. A mean binding ratio of dsDNA to FB was determined to be 1.4： 1, suggesting that two complexes FB-dsDNA and FB-2dsDNA be formed. The interaction between FB and ssDNA was only electrostatic binding. The more powerful interaction of FB with dsDNA than with ssDNA may be applied for the recognition of dsDNA and ssDNA, and in DNA biosensor as hybridization indicator.展开更多
Removal of dyestuffs such as Acidic Fuchsine(AF)and Malachite Green(MG)being present in many forms in industries is vital to protect water reservoirs from their catastrophic effects on the ecosystem.This study attempt...Removal of dyestuffs such as Acidic Fuchsine(AF)and Malachite Green(MG)being present in many forms in industries is vital to protect water reservoirs from their catastrophic effects on the ecosystem.This study attempts to effectively eliminate these dyes using a low-cost and eco-friendly material.Eggshell,as a biocompatible by-product,was initially characterized,then some modifications were conducted,and its morphology and chemical structure were then examined through(Atomic force microscopy)AFM,(Fourier-Transform Infrared Spectroscopy)FTIR,(Energy-Dispersive X-ray Spectroscopy)EDS and(Brunauer–Emmett–Teller)BET analyses.They revealed that the modifications on raw material gave rise to a natural nano-adsorbent presenting porous medium appropriate for targeted adsorbate molecules with the average particle size and average pore diameter of 54 and^2 nm,respectively.Functional groups on the adsorbent surface were also of importance to assist the adsorption of AF and MG.The effect of contact time,adsorbent dose,solution p H and initial concentration was evaluated.Pseudo-second order model accurately correlated the experimental kinetic data for both dyes.Moreover,the participation of intra-particle diffusion along with film diffusion in controlling the process was suggested.Langmuir isotherm model fitted very well to the equilibrium data for both dyes and maximum monolayer adsorption capacity of AF and MG was accordingly calculated to be 5000 and 3333.33 mg·g-1 respectively.The inherent characteristics of eggshell make it a potential material to remove contaminants from wastewater in future applications.展开更多
Dosimetric characterization of aqueous solution of basic fuchsin was studied spectrophotometrically for possible application in the low-dose food irradiation dosimetry. Absorption spectra of unirradiated and irradiate...Dosimetric characterization of aqueous solution of basic fuchsin was studied spectrophotometrically for possible application in the low-dose food irradiation dosimetry. Absorption spectra of unirradiated and irradiated solu- tions were determined and the decrease in absorbance with the dose was noted down. Radiation-induced bleaching of the dye was measured at wavelengths of maximum absorption λmax (540nm) as well as 510nm and 460 nm. At all these wavelengths, the decrease in absorbance of the dosimeter was linear with respect to the absorbed dose from 50 Gy to 600 Gy. The stability of dosimetric solution during post-irradiation storage in the dark at room temperature showed that after initial bleaching during first ten to twenty days, the response was almost stable for about 34 days. The study on the effect of different light and temperature conditions also showed that the response gradually decreased during the storage period of 34 days, which shows that basic fuchsin dye is photosensitive as well as thermally sensitive.展开更多
A facile strategy without organic template was developed for the conversion of fly ash to LTA-type zeolite(LTA-Z),which could be used as a good adsorbent for the removal of acid fuchsin(AF).XRD results indicated that ...A facile strategy without organic template was developed for the conversion of fly ash to LTA-type zeolite(LTA-Z),which could be used as a good adsorbent for the removal of acid fuchsin(AF).XRD results indicated that the pure crystalline product was obtained with the structure of LTA-type zeolite.SEM investigations showed that the well-defined LTA-Z crystals exhibited uniform size with the same cubic shape.The maximum AF adsorption amount was observed at pH=5,slightly lower than pHPZC of LTA-Z.Higher temperature favored AF adsorption onto LTA-Z and it was an endothermic process.Furthermore,AF adsorption amount increased with initial AF concentration increasing and LTA-Z dosage decreasing.Surface sorption governed this process at the initial 120 min period,followed by the internal diffusion of AF molecules between porous sites.The Langmuir model was determined as the adsorption isothermal,suggesting that the monolayer coverage of AF on LTA-Z surface was involved.展开更多
The development of sustainable adsorbents that integrate low-cost separation and high contaminant removal efficiency remains a critical challenge in wastewater treatment.This study engineered a sludge-based magnetic f...The development of sustainable adsorbents that integrate low-cost separation and high contaminant removal efficiency remains a critical challenge in wastewater treatment.This study engineered a sludge-based magnetic floatable particle adsorbent(SMFA-800-0.5)through synergistic co-pyrolysis of municipal sludge,red mud,and hollow glass microspheres(HGM)for the removal of basic fuchsin(BF)from dye wastewater.The results indicated that the dual-function separation approach utilizing Fe3O4 in situ formation from red mud(magnetization of 8.24 A·m^(−1))enables excellent recovery efficiency,eliminating the need for external Fe precursors,while the integration of HGM provides a self-floating capability with 76%surface retention over 3 h.The sludge-derived carbon matrix,enhanced by HGM’s structural support,provides hierarchical pores with a Bruner–Emmett–Teller(BET)surface area of 57.98 m^(2)·g^(−1).The addition of bentonite clay effectively addresses powder dispersion issues in flow systems.This material demonstrates superior adsorption performance,achieving a capacity of 106.72 mg·g^(−1)for BF via pseudo-first-order kinetics.The enhanced adsorption performance is driven by multi-mechanism synergies,including electrostatic attraction and pore filling.This work pioneers a“zero-external-input,dual-recovery”paradigm for sustainable dye removal.展开更多
文摘The current modified electro-Fenton system was designed to develop a more convenient and efficient undivided system for practical wastewater treatment. The system adopted a cathode portion that employed magnetic stirring instead of common oxygen gas diffusion or gas sparging to supply oxygen gas for the electrolyte solution. Key factors influencing the cathode fabrication and activit） were investigated. The degradation of acid fuchsine with a self-made graphite-polytetrafluorethylene cathode was studied using spectrophotometer. It was found that the cathode generated hydrogen peroxide with high current efficiency and the hydrogen peroxide yield of the cathode did not decay after 10 times reuse. With the Pt anode at a ferrous ion concentration of 0.5 mmol/L, a pH of 3, and using magnetic stirring, dye decolorization could be rapidly accomplished but the destruction of benzene rings and intermediates was fairly difficult. With a Fe anode, dye degradation was more complete.
基金Project(2017YFC1600306)supported by the National Key R&D Program of ChinaProject(21505005)supported by the National Natural Science Foundation of China+1 种基金Project(2018JJ2424)supported by the Hunan Provincial Natural Science Foundation,ChinaProject(2019IC21)supported by the International Cooperative Project for“Double First-Class”,China。
文摘Excessive discharge of dye wastewater has brought serious harm to human health and the environment.In this paper,a magnetic absorbent,ferroferric oxide@β-cyclodextrin(Fe_(3)O_(4)@CD),was prepared for the efficient adsorption removal of basic fuchsin(BF)from dye wastewater,based on the special amphiphilicity ofβ-CD and the strong magnetism of Fe_(3)O_(4).A series of influence factors including the initial dye concentration,adsorbent dosage,temperature and pH were investigated,as well as the adsorption mechanism.The results show that Fe_(3)O_(4)@CD has the best adsorption and removal effect on BF dye at room temperature and neutral pH,when the initial concentration of dye is 25 mg/L and the adsorbent dosage is 100 mg.The adsorption behavior conforms to the pseudo-second-order kinetics and the Langmuir adsorption isotherm,and the adsorption process is spontaneously endothermic.Fe_(3)O_(4)@CD adsorbed with BF dye can be rapidly separated under an external magnetic field and then easily regenerated by HCl treatment.After 5 times of recycling,the removal rate of the prepared magnetic composite on BF dye is kept above 75%.This work will provide an economic and eco-friendly technology for the treatment of the actual dye wastewater.
基金supported by the National Natural Science Foundation of China(Grant No.41865010)the 2020 Leading Talents of Young Science and Technology Talents in Colleges and Universities of the Inner Mongolia Autonomous Region(Grant No.NJYT-20-A04)the Project of the 10th Group of Grassland Talents of the Inner Mongolia Autonomous Region,the 2022 Inner Mongolia Outstanding Youth Fund Project,and the Key Research and Development and Achievement Transformation Program of the Inner Mongolia Autonomous Region in 2022(Grant No.2022YFHH0035).
文摘With the development circular economy, the use of agricultural waste to prepare biomass materials to remove pollutants has become a research hotspot. In this study, sunflower straw activated carbon (SSAC) was prepared by the one-step activation method, with sunflower straw (SS) used as the raw material and H3PO4 used as the activator. Four types of SSAC were prepared with impregnation ratios (weight of SS to weight of H3PO4) of 1:1, 1:2, 1:3, and 1:5, corresponding to SSAC1, SSAC2, SSAC3, and SSAC4, respectively. The adsorption process of acid fuchsin (AF) in water using the four types of SSAC was studied. The results showed that the impregnation ratio significantly affected the structure of the materials. The increase in the impregnation ratio increased the specific surface area and pore volume of SSAC and improved the adsorption capacity of AF. However, an impregnation ratio that was too large led to a decrease in specific surface area. SSAC3, with an impregnation ratio of 1:3, had the largest specific surface area (1 794.01 m2/g), and SSAC4, with an impregnation ratio of 1:5, exhibited the smallest microporosity (0.052 7 cm3/g) and the largest pore volume (2.549 cm3/g). The adsorption kinetics of AF using the four types of SSAC agreed with the quasi-second-order adsorption kinetic model. The Langmuir isotherm model was suitable to describe SSAC3 and SSAC4, and the Freundlich isotherm model was appropriate to describe SSAC1 and SSAC2. The result of thermodynamics showed that the adsorption process was spontaneous and endothermic. At 303 K, SSAC4 showed a removal rate of 97.73% for 200-mg/L AF with a maximum adsorption capacity of 2 763.36 mg/g, the highest among the four types of SSAC. This study showed that SAAC prepared by the H3PO4-based one-step activation method is a green and efficient carbon material and has significant application potential for the treatment of dye-containing wastewater.
文摘Visible spectroscopic and electrochemical methods were used to study the interactions between DNA and fuchsin basic（FB）. FB has an irreversible electro-oxidation peak in 5 mmol/L Tris-HCl buffer solution at pH = 7.4 on a glassy carbon electrode（GCE）. After adding certain concentration of dsDNA, the oxidation peak current of FB decreases, but the peak potential hardly changes. The visible absorption spectroscopic study shows that the binding mode of FB to dsDNA is intercalative binding and electrostatic binding when the ratio of the concentration of dsDNA to FB is smaller than 0. 2, and anew substance, which produces a new absorption peak, is obtained via a covalent binding between dsDNA and FB apart from intercalative binding and electrostatic binding when the ratio of the concentration of dsDNA to FB is larger than 0. 2. The visible absorption spectra varies no longer when the ratio of the concentration of dsDNA＇to FB is larger than 1.5. A mean binding ratio of dsDNA to FB was determined to be 1.4： 1, suggesting that two complexes FB-dsDNA and FB-2dsDNA be formed. The interaction between FB and ssDNA was only electrostatic binding. The more powerful interaction of FB with dsDNA than with ssDNA may be applied for the recognition of dsDNA and ssDNA, and in DNA biosensor as hybridization indicator.
文摘Removal of dyestuffs such as Acidic Fuchsine(AF)and Malachite Green(MG)being present in many forms in industries is vital to protect water reservoirs from their catastrophic effects on the ecosystem.This study attempts to effectively eliminate these dyes using a low-cost and eco-friendly material.Eggshell,as a biocompatible by-product,was initially characterized,then some modifications were conducted,and its morphology and chemical structure were then examined through(Atomic force microscopy)AFM,(Fourier-Transform Infrared Spectroscopy)FTIR,(Energy-Dispersive X-ray Spectroscopy)EDS and(Brunauer–Emmett–Teller)BET analyses.They revealed that the modifications on raw material gave rise to a natural nano-adsorbent presenting porous medium appropriate for targeted adsorbate molecules with the average particle size and average pore diameter of 54 and^2 nm,respectively.Functional groups on the adsorbent surface were also of importance to assist the adsorption of AF and MG.The effect of contact time,adsorbent dose,solution p H and initial concentration was evaluated.Pseudo-second order model accurately correlated the experimental kinetic data for both dyes.Moreover,the participation of intra-particle diffusion along with film diffusion in controlling the process was suggested.Langmuir isotherm model fitted very well to the equilibrium data for both dyes and maximum monolayer adsorption capacity of AF and MG was accordingly calculated to be 5000 and 3333.33 mg·g-1 respectively.The inherent characteristics of eggshell make it a potential material to remove contaminants from wastewater in future applications.
文摘Dosimetric characterization of aqueous solution of basic fuchsin was studied spectrophotometrically for possible application in the low-dose food irradiation dosimetry. Absorption spectra of unirradiated and irradiated solu- tions were determined and the decrease in absorbance with the dose was noted down. Radiation-induced bleaching of the dye was measured at wavelengths of maximum absorption λmax (540nm) as well as 510nm and 460 nm. At all these wavelengths, the decrease in absorbance of the dosimeter was linear with respect to the absorbed dose from 50 Gy to 600 Gy. The stability of dosimetric solution during post-irradiation storage in the dark at room temperature showed that after initial bleaching during first ten to twenty days, the response was almost stable for about 34 days. The study on the effect of different light and temperature conditions also showed that the response gradually decreased during the storage period of 34 days, which shows that basic fuchsin dye is photosensitive as well as thermally sensitive.
基金supported by the National Natural Science Foundation of China (Grant No. 51002040)New Century Excellent Talents in Heilongjiang Provincial Universities (Grant No. 1253-NCET-010)+2 种基金Natural Science Youth Fund of Heilongjiang Province (Grant No. QC2012C084)Science Foundation of the Heilongjiang Education Office (Grant No. 12521071)Young Outstanding Talents Project of Harbin University of Science and Technology
文摘A facile strategy without organic template was developed for the conversion of fly ash to LTA-type zeolite(LTA-Z),which could be used as a good adsorbent for the removal of acid fuchsin(AF).XRD results indicated that the pure crystalline product was obtained with the structure of LTA-type zeolite.SEM investigations showed that the well-defined LTA-Z crystals exhibited uniform size with the same cubic shape.The maximum AF adsorption amount was observed at pH=5,slightly lower than pHPZC of LTA-Z.Higher temperature favored AF adsorption onto LTA-Z and it was an endothermic process.Furthermore,AF adsorption amount increased with initial AF concentration increasing and LTA-Z dosage decreasing.Surface sorption governed this process at the initial 120 min period,followed by the internal diffusion of AF molecules between porous sites.The Langmuir model was determined as the adsorption isothermal,suggesting that the monolayer coverage of AF on LTA-Z surface was involved.
基金supported by the National Natural Science Foundation of China(No.42067031)the Basic Scientific Research Expenses Program of Universities directly under Inner Mongolia Autonomous Region(Nos.JY20220300 and ZTY2023057),China.
文摘The development of sustainable adsorbents that integrate low-cost separation and high contaminant removal efficiency remains a critical challenge in wastewater treatment.This study engineered a sludge-based magnetic floatable particle adsorbent(SMFA-800-0.5)through synergistic co-pyrolysis of municipal sludge,red mud,and hollow glass microspheres(HGM)for the removal of basic fuchsin(BF)from dye wastewater.The results indicated that the dual-function separation approach utilizing Fe3O4 in situ formation from red mud(magnetization of 8.24 A·m^(−1))enables excellent recovery efficiency,eliminating the need for external Fe precursors,while the integration of HGM provides a self-floating capability with 76%surface retention over 3 h.The sludge-derived carbon matrix,enhanced by HGM’s structural support,provides hierarchical pores with a Bruner–Emmett–Teller(BET)surface area of 57.98 m^(2)·g^(−1).The addition of bentonite clay effectively addresses powder dispersion issues in flow systems.This material demonstrates superior adsorption performance,achieving a capacity of 106.72 mg·g^(−1)for BF via pseudo-first-order kinetics.The enhanced adsorption performance is driven by multi-mechanism synergies,including electrostatic attraction and pore filling.This work pioneers a“zero-external-input,dual-recovery”paradigm for sustainable dye removal.
