The Fourier transform spectrometer(FTS)is a core instrument for solar observation with high spectral resolution,especially in the infrared.The Infrared System for the Accurate Measurement of Solar Magnetic Field(AIMS)...The Fourier transform spectrometer(FTS)is a core instrument for solar observation with high spectral resolution,especially in the infrared.The Infrared System for the Accurate Measurement of Solar Magnetic Field(AIMS),working at 10-13μm,will use an FTS to observe the solar spectrum.The Bruker IFS-125 HR,which meets the spectral resolution requirement of AIMS but simply equips with a point source detector,is employed to carry out preliminary experiment for AIMS.A sun-light feeding experimental system is further developed.Several experiments are taken with them during 2018 and 2019 to observe the solar spectrum in the visible and near infrared wavelength,respectively.We also proposed an inversion method to retrieve the solar spectrum from the observed interferogram and compared it with the standard solar spectrum atlas.Although there is a wavelength limitation due to the present sun-light feeding system,the results in the wavelength band from 0.45-1.0μm and 1.0-2.2μm show a good consistency with the solar spectrum atlas,indicating the validity of our observing configuration,the data analysis method and the potential to work in longer wavelength.The work provided valuable experience for the AIMS not only for the operation of an FTS but also for the development of its scientific data processing software.展开更多
Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of pre...Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of precision spectroscopy and trace gas detection.Here,we report the development of a mid-infrared Fourier transform spectrometer based on an optical frequency comb combined with a Herriott-type multipass cell.Using this instrument,the broadband absorption spectra of several important molecules,including methane,acetylene,water molecules and nitrous oxide,are measured by near real-time data acquisition in the 2800-3500 cm^(-1)spectral region.The achieved minimum detectable absorption of the instrument is 4.4×10^(-8)cm^(-1)·Hz^(-1/2)per spectral element.Broadband spectra of H_(2)0 are fited using the Voigt profile multispectral fitting technique and the consistency of the concentration inversion is 1%.Our system also enables precise spectroscopic measurements,and it allows the determination of the spectral line positions and upper state constants of N_(2)O in the(0002)-(1000)band,with results in good agreement with those reported by Toth[Appl.Opt.30,5289(1991)].展开更多
The miniaturization of spectrometer opens a new application area with real-time and on-site measurements.The Fourier transform spectrometer(FTS)is much attractive considering its particular advantages among the approa...The miniaturization of spectrometer opens a new application area with real-time and on-site measurements.The Fourier transform spectrometer(FTS)is much attractive considering its particular advantages among the approaches.This paper reviews the current status of micro FTS in worldwide and describes its developments;In addition,analyzed are the key problems in designing and fabricating FTS to be settled during the miniaturization.Finally,a novel model of micro FTS with no moving parts is proposed and analyzed,which may provide new concepts for the design of spectrometers.展开更多
The method of FRactional Fourier Transform (FRFT) is introduced to Transform Domain Communication System (TDCS) for signal transforming in the paper after theoretical analysis. The method yields optimal Basis Function...The method of FRactional Fourier Transform (FRFT) is introduced to Transform Domain Communication System (TDCS) for signal transforming in the paper after theoretical analysis. The method yields optimal Basis Function (BF) by FRFT with optimal transform angle. The TDCS using the proposed method has wider usable spectrum, stronger robustness and better ability of anti non-stationary jamming than using usual methods, such as Fourier Transform (FT), Auto Regressive (AR), Wavelet Transform (WT), etc. The main simulation results are as follows. First, the Bit Error Rate (BER) Pb is close to theoretical bound of no jamming no matter in single tone or in linear chirp interference. Second, the interference-to-signal ratio J /E is at least 12dB more than that of Direct Spread Spectrum System (DSSS) under the same BER if the spectrum hopping-to-signal ratio is 1:20 in chirp plus hopping interfering. Third, the Eb /N 0(when estimation difference is 90% between trans- mitter and receiver) is about 3.5dB or about 0.5dB (when estimation difference is 10% between transmitter and receiver) more than that of theoretical result when no estimation difference un-der Pb=10-2.展开更多
The sequence analysis of peptides was performed by nano-electrospray ionization Fourier transform ion cyclotron resonance tandem mass spectrometry（Nano-ESI-FT-ICR-MSn） and several peptides were chosen as examples. W...The sequence analysis of peptides was performed by nano-electrospray ionization Fourier transform ion cyclotron resonance tandem mass spectrometry（Nano-ESI-FT-ICR-MSn） and several peptides were chosen as examples. With the aid of the collision induced dissociation（CID）, FT-ICR provides not only precise mass/charge ratio, but also structure information of the selected peptides. The fragment ions were identified according to the observed molecular weights and peptide sequence was determined successfully. So Nano-ESI-FT-ICR-MSn is a useful tool for identification of the amino acid sequence of peptides with high confidence. Besides, a pathway for the dehydration of y ions without amino acids containing carboxylic acid under sustained off-resonance irradiation collision-induced dissociation（SORI-CID） condition was proposed.展开更多
Miniaturized spectrometers for Raman spectroscopy have the potential to open up a new chapter in sensing.Raman spectroscopy is essential for material characterization and biomedical diagnostics,however,its weak signal...Miniaturized spectrometers for Raman spectroscopy have the potential to open up a new chapter in sensing.Raman spectroscopy is essential for material characterization and biomedical diagnostics,however,its weak signal and the need for sub-nanometer resolution pose challenges.Conventional spectrometers,with footprints proportional to optical throughput and resolution,are difficult to integrate into compact devices such as wearables.Waveguide-based Fourier Transform Spectrometers(FTS)enable compact spectrometers,and multi-aperture designs can achieve high throughput for applications such as Raman spectroscopy;however,experimental research in this domain remains limited.In this work,we present a multi-aperture SiN waveguide-based FTS overcoming these limitations and enabling Raman spectroscopy of isopropyl alcohol,glucose,Paracetamol,and Ibuprofen with enhanced throughput.Our spectrometer chip,fabricated on a 200mm SiN wafer,with 160 edge-coupled waveguide apertures connected to an array of ultra-compact interferometers and a small footprint of just 1.6mm×3.2 mm,achieves a spectral range of 40 nm and a resolution of 0.5 nm.Experimental results demonstrate that the least absolute shrinkage and selection operator(LASSO)regression significantly enhances Raman spectrum reconstruction.Our work on waveguide-based spectrometry paves the way for integrating accurate and compact Raman sensors into consumer electronics and space exploration instruments.展开更多
Because of its all-reflective layout based on the Fresnel double-mirror interference system, the newly developed Fourier transform imaging spectrometer has a very large spectral bandwidth ranged from a cut-off wavelen...Because of its all-reflective layout based on the Fresnel double-mirror interference system, the newly developed Fourier transform imaging spectrometer has a very large spectral bandwidth ranged from a cut-off wavelength (related to the cut-off wave number σ max ) to far infrared. According to the signal's symmetry and wide-band characteristics, a simple method that can efficiently weaken the low frequency noise in the reconstructed spectrum is presented. Also, according to the symmetry, the eigenvector method is applied to the reconstruction of the spectrum.展开更多
Spectrometer is an essential and necessary optical element used for measuring the chemical components and content of the matter. The development of miniature spectrometers can be traced back to 1980s. The development ...Spectrometer is an essential and necessary optical element used for measuring the chemical components and content of the matter. The development of miniature spectrometers can be traced back to 1980s. The development state and different manufacturing methods of micro-spectrometers are presented. Finally, we analyze the miniaturization trend of spectrometers. Some groundwork for the scientific research is offered by introducing micro-spectrometers development.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.11873062,11427901,11673038,11803002,11973056,11973061,12003051 and 12073040)supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDA15320102 and XDA15052200)。
文摘The Fourier transform spectrometer(FTS)is a core instrument for solar observation with high spectral resolution,especially in the infrared.The Infrared System for the Accurate Measurement of Solar Magnetic Field(AIMS),working at 10-13μm,will use an FTS to observe the solar spectrum.The Bruker IFS-125 HR,which meets the spectral resolution requirement of AIMS but simply equips with a point source detector,is employed to carry out preliminary experiment for AIMS.A sun-light feeding experimental system is further developed.Several experiments are taken with them during 2018 and 2019 to observe the solar spectrum in the visible and near infrared wavelength,respectively.We also proposed an inversion method to retrieve the solar spectrum from the observed interferogram and compared it with the standard solar spectrum atlas.Although there is a wavelength limitation due to the present sun-light feeding system,the results in the wavelength band from 0.45-1.0μm and 1.0-2.2μm show a good consistency with the solar spectrum atlas,indicating the validity of our observing configuration,the data analysis method and the potential to work in longer wavelength.The work provided valuable experience for the AIMS not only for the operation of an FTS but also for the development of its scientific data processing software.
基金supported by the National Natural Science Foundation China(No.42022051,No.U21A2028)Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y202089)the HFIPS Director's Fund(No.YZJJ202101,No.BJPY2023A02).
文摘Optical frequency combbased Fourier transform spectroscopy has the features of broad spectral bandwidth,high sensitivity,andmultiplexed trace gas detection,which has valuable application potential in the fields of precision spectroscopy and trace gas detection.Here,we report the development of a mid-infrared Fourier transform spectrometer based on an optical frequency comb combined with a Herriott-type multipass cell.Using this instrument,the broadband absorption spectra of several important molecules,including methane,acetylene,water molecules and nitrous oxide,are measured by near real-time data acquisition in the 2800-3500 cm^(-1)spectral region.The achieved minimum detectable absorption of the instrument is 4.4×10^(-8)cm^(-1)·Hz^(-1/2)per spectral element.Broadband spectra of H_(2)0 are fited using the Voigt profile multispectral fitting technique and the consistency of the concentration inversion is 1%.Our system also enables precise spectroscopic measurements,and it allows the determination of the spectral line positions and upper state constants of N_(2)O in the(0002)-(1000)band,with results in good agreement with those reported by Toth[Appl.Opt.30,5289(1991)].
基金National Natural Science Fundation of China(60578036)
文摘The miniaturization of spectrometer opens a new application area with real-time and on-site measurements.The Fourier transform spectrometer(FTS)is much attractive considering its particular advantages among the approaches.This paper reviews the current status of micro FTS in worldwide and describes its developments;In addition,analyzed are the key problems in designing and fabricating FTS to be settled during the miniaturization.Finally,a novel model of micro FTS with no moving parts is proposed and analyzed,which may provide new concepts for the design of spectrometers.
基金Supported by Fund of National Key Lab.of Communication.
文摘The method of FRactional Fourier Transform (FRFT) is introduced to Transform Domain Communication System (TDCS) for signal transforming in the paper after theoretical analysis. The method yields optimal Basis Function (BF) by FRFT with optimal transform angle. The TDCS using the proposed method has wider usable spectrum, stronger robustness and better ability of anti non-stationary jamming than using usual methods, such as Fourier Transform (FT), Auto Regressive (AR), Wavelet Transform (WT), etc. The main simulation results are as follows. First, the Bit Error Rate (BER) Pb is close to theoretical bound of no jamming no matter in single tone or in linear chirp interference. Second, the interference-to-signal ratio J /E is at least 12dB more than that of Direct Spread Spectrum System (DSSS) under the same BER if the spectrum hopping-to-signal ratio is 1:20 in chirp plus hopping interfering. Third, the Eb /N 0(when estimation difference is 90% between trans- mitter and receiver) is about 3.5dB or about 0.5dB (when estimation difference is 10% between transmitter and receiver) more than that of theoretical result when no estimation difference un-der Pb=10-2.
基金Supported by the National Natural Science Foundation of China(No.20675079)
文摘The sequence analysis of peptides was performed by nano-electrospray ionization Fourier transform ion cyclotron resonance tandem mass spectrometry（Nano-ESI-FT-ICR-MSn） and several peptides were chosen as examples. With the aid of the collision induced dissociation（CID）, FT-ICR provides not only precise mass/charge ratio, but also structure information of the selected peptides. The fragment ions were identified according to the observed molecular weights and peptide sequence was determined successfully. So Nano-ESI-FT-ICR-MSn is a useful tool for identification of the amino acid sequence of peptides with high confidence. Besides, a pathway for the dehydration of y ions without amino acids containing carboxylic acid under sustained off-resonance irradiation collision-induced dissociation（SORI-CID） condition was proposed.
基金supported by the National Key Research and Development Program of China(No.2024YFF1206300)Guangci Innovative Technology Program(KY2023810)Guangci Talent Program(RC20240018).
文摘Miniaturized spectrometers for Raman spectroscopy have the potential to open up a new chapter in sensing.Raman spectroscopy is essential for material characterization and biomedical diagnostics,however,its weak signal and the need for sub-nanometer resolution pose challenges.Conventional spectrometers,with footprints proportional to optical throughput and resolution,are difficult to integrate into compact devices such as wearables.Waveguide-based Fourier Transform Spectrometers(FTS)enable compact spectrometers,and multi-aperture designs can achieve high throughput for applications such as Raman spectroscopy;however,experimental research in this domain remains limited.In this work,we present a multi-aperture SiN waveguide-based FTS overcoming these limitations and enabling Raman spectroscopy of isopropyl alcohol,glucose,Paracetamol,and Ibuprofen with enhanced throughput.Our spectrometer chip,fabricated on a 200mm SiN wafer,with 160 edge-coupled waveguide apertures connected to an array of ultra-compact interferometers and a small footprint of just 1.6mm×3.2 mm,achieves a spectral range of 40 nm and a resolution of 0.5 nm.Experimental results demonstrate that the least absolute shrinkage and selection operator(LASSO)regression significantly enhances Raman spectrum reconstruction.Our work on waveguide-based spectrometry paves the way for integrating accurate and compact Raman sensors into consumer electronics and space exploration instruments.
文摘Because of its all-reflective layout based on the Fresnel double-mirror interference system, the newly developed Fourier transform imaging spectrometer has a very large spectral bandwidth ranged from a cut-off wavelength (related to the cut-off wave number σ max ) to far infrared. According to the signal's symmetry and wide-band characteristics, a simple method that can efficiently weaken the low frequency noise in the reconstructed spectrum is presented. Also, according to the symmetry, the eigenvector method is applied to the reconstruction of the spectrum.
文摘Spectrometer is an essential and necessary optical element used for measuring the chemical components and content of the matter. The development of miniature spectrometers can be traced back to 1980s. The development state and different manufacturing methods of micro-spectrometers are presented. Finally, we analyze the miniaturization trend of spectrometers. Some groundwork for the scientific research is offered by introducing micro-spectrometers development.
