Two-dimensional(2D)materials have been widely used in optoelectronic detection due to their excellent physical properties.Nevertheless,there has been comparatively little focus on the differentiation of light-matter i...Two-dimensional(2D)materials have been widely used in optoelectronic detection due to their excellent physical properties.Nevertheless,there has been comparatively little focus on the differentiation of light-matter interactions across distinct channel paths within the same 2D material,as well as on the photoelectric characteristics exhibited by the surface,vertical,and bottom of device.In this paper,dual-parallel device structures utilizing 2Dα-In_(2)Se_(3) semiconductors are fabricated with four conductive channels named by bottom-horizontal channel(BHC),middle-vertical channel(MVC),surface-quasi-horizontal channel(SQHC),and surface-horizontal channel(SHC)devices.The SHC device exhibits superior optical response of 101 A/W and external quantum efficiency of 1.857×104%across all conductive channels,which is over 32 times greater than that of BHC device.The SHC device boasts a fast response time of 41 ms,comparable to 32 ms offered by the nanoscale channel of the MVC device,and has a slow decay time of 319 ms similar to the 424 ms that comes with the longest channel of the SQHC device.The SHC device has the highest degree of learning and the lowest forgetting rate compared to the other three channels.Optoelectronic synapses based on dual-parallelα-In_(2)Se_(3) device can also mimic biological color image perception and memory functions,which can be used to visually determine the synaptic function of the device.In this work,on top of the excellent optoelectronic and semiconducting properties of the van der Waals semiconductorα-In2Se3,the advantages offered by the device structure are further explored to promote the development of integrated optoelectronics.展开更多
Covalent organic frameworks(COFs) are a potential platform for carbon dioxide(CO_(2)) conversion owing to their periodic permanent porosity,adjustable structure,and chemical stability.For good catalytic performance in...Covalent organic frameworks(COFs) are a potential platform for carbon dioxide(CO_(2)) conversion owing to their periodic permanent porosity,adjustable structure,and chemical stability.For good catalytic performance in CO_(2) conversion,collaborative multifunctions should be strategically integrated into the catalytic system design and construction.In this study,a four-in-one high-efficiency catalyst was synthesized and tested for CO_(2) cycloaddition to form cyclic carbonate.The obtained Tp-MPB-BrCOF had a high nitrogen content,which enhanced its CO_(2) affinity through substantial Lewis acid-base or dipole-quadrupole interactions;moreover,the acid(protons transferring from oxygen(–OH) to nitrogen(–NH)),hydrogen bond donor(hydroxyl group),and Br-(nucleophile group) served as three active sites,further improving the catalyst activity.These results provide a basis for designing efficient and stable CO_(2)-conversion catalysts.展开更多
基金supported by the National Natural Science Foundation of China(No.52302174)the Scientific Research Fund of Hunan Provincial Education Department(Nos.22B0726 and 22B0715)the Ultra-Multi-Wavelength LED Sources(UMW-60)of Qingdao Solar Scientific Instrument High-tech Co.,LTD.
文摘Two-dimensional(2D)materials have been widely used in optoelectronic detection due to their excellent physical properties.Nevertheless,there has been comparatively little focus on the differentiation of light-matter interactions across distinct channel paths within the same 2D material,as well as on the photoelectric characteristics exhibited by the surface,vertical,and bottom of device.In this paper,dual-parallel device structures utilizing 2Dα-In_(2)Se_(3) semiconductors are fabricated with four conductive channels named by bottom-horizontal channel(BHC),middle-vertical channel(MVC),surface-quasi-horizontal channel(SQHC),and surface-horizontal channel(SHC)devices.The SHC device exhibits superior optical response of 101 A/W and external quantum efficiency of 1.857×104%across all conductive channels,which is over 32 times greater than that of BHC device.The SHC device boasts a fast response time of 41 ms,comparable to 32 ms offered by the nanoscale channel of the MVC device,and has a slow decay time of 319 ms similar to the 424 ms that comes with the longest channel of the SQHC device.The SHC device has the highest degree of learning and the lowest forgetting rate compared to the other three channels.Optoelectronic synapses based on dual-parallelα-In_(2)Se_(3) device can also mimic biological color image perception and memory functions,which can be used to visually determine the synaptic function of the device.In this work,on top of the excellent optoelectronic and semiconducting properties of the van der Waals semiconductorα-In2Se3,the advantages offered by the device structure are further explored to promote the development of integrated optoelectronics.
基金supported by the National Natural Science Foundation of China (21805173,52273208)Shanxi Agricultural University (SXBYKY2022078,2021BQ120)+1 种基金Shanxi Scholarship Council of China (2022-004)the Natural Science Foundation of Shanxi Province (202203021211289)。
文摘Covalent organic frameworks(COFs) are a potential platform for carbon dioxide(CO_(2)) conversion owing to their periodic permanent porosity,adjustable structure,and chemical stability.For good catalytic performance in CO_(2) conversion,collaborative multifunctions should be strategically integrated into the catalytic system design and construction.In this study,a four-in-one high-efficiency catalyst was synthesized and tested for CO_(2) cycloaddition to form cyclic carbonate.The obtained Tp-MPB-BrCOF had a high nitrogen content,which enhanced its CO_(2) affinity through substantial Lewis acid-base or dipole-quadrupole interactions;moreover,the acid(protons transferring from oxygen(–OH) to nitrogen(–NH)),hydrogen bond donor(hydroxyl group),and Br-(nucleophile group) served as three active sites,further improving the catalyst activity.These results provide a basis for designing efficient and stable CO_(2)-conversion catalysts.
