Since the mid-20th century,the Mongolian Plateau(MP)has experienced decadal droughts coupled with extreme heatwaves,severely affecting regional ecology and social development.However,the mechanisms behind these decada...Since the mid-20th century,the Mongolian Plateau(MP)has experienced decadal droughts coupled with extreme heatwaves,severely affecting regional ecology and social development.However,the mechanisms behind these decadalscale compound heatwavedrought events remain debated.Here,using reconstructions and simulations from the Community Earth System Model Last Millennium Ensemble,we demonstrate that,over the last millennium,decadal droughts on the MP occurred under both warm and cold conditions,differing from recent compound heatwavedrought events.We found that by examining temperature changes during these drought periods,the distinct influences of external forcings and internal variability can be simply and effectively distinguished.Specifically,colddry events were primarily driven by volcanic eruptions that weakened the East Asian summer monsoon and midlatitude westerlies,reducing moisture transport to the MP.In contrast,warmdry events were predominantly induced by internal variability,notably the negative phase of the Atlantic Multidecadal Oscillation and the expansion of the Barents Sea ice extent.The recent extreme compound event was probably influenced by the combined effects of anthropogenic forcings and internal variability.These findings deepen our understanding of how external forcings and internal variability affect decadal drought events on the MP and highlight that recent compound events are unprecedented in the context of the last millennium.展开更多
Subsurface air flow can be induced by natural processes, such as atmospheric or barometric pressure changes, water table fluctuations, topographic effects, and rainfall infiltration. Barometric pressure fluctuations a...Subsurface air flow can be induced by natural processes, such as atmospheric or barometric pressure changes, water table fluctuations, topographic effects, and rainfall infiltration. Barometric pressure fluctuations are the most common cause of subsurface air flow, which can be significant under favourable geological conditions. This process has been studied most extensively because of its application to passive soil vapor extraction. Soil air flow induced by water table fluctuations can be significant, particularly where the fluctuations are of high frequency, for example, in tidal-influenced coastal areas. Topographic effects can lead to strong subsoil air flow in areas with great elevation differences. Rainfall infiltration usually produces only weak airflow. Air flow induced by these natural processes has important environmental and engineering implications. Among the different processes, air flow induced by tidal fluctuations has been studied the least, although it has exciting applications to coastal engineering projects and environmental remediation.展开更多
Characteristics of the total clear-sky greenhouse effect （GA） and cloud radiative forcings （CRFs）, along with the radiative-related water vapor and cloud properties simulated by the Spectral Atmospheric Model deve...Characteristics of the total clear-sky greenhouse effect （GA） and cloud radiative forcings （CRFs）, along with the radiative-related water vapor and cloud properties simulated by the Spectral Atmospheric Model developed by LASGIAP （SAMIL） are evaluated. Impacts of the convection scheme on the simulation of CRFs are discussed by using two AMIP （Atmospheric Model Inter-comparison Project） type simulations employing different convection schemes： the new Zhang-McFarlane （NZH） and Tiedtke （TDK） convection schemes. It shows that both the climatological GA and its response to El Nio warming are simulated well, both in terms of spatial pattern and magnitude. The impact of the convection scheme on GA is not significant. The climatological longwave CRF （LWCRF） and its response to El Nio warming are simulated well, but with a prominently weaker magnitude. The simulation of the climatology （response） of LWCRF in the NZH （TDK） run is slightly more realistic than in the TDK （NZH） simulation, indicating significant impacts of the convection scheme. The shortwave CRF （SWCRF） shows large biases in both spatial pattern and magnitude, and the results from the TDK run are better than those from the NZH run. A spuriously excessive negative climatological SWCRF over the southeastern Pacific and an insufficient response of SWCRF to El Nio warming over the tropical Pacific are seen in the NZH run. These two biases are alleviated in the TDK run, since it produces vigorous convection, which is related to the low threshold for convection to take place. Also, impacts of the convection scheme on the cloud profile are discussed.展开更多
For linear forcing problems, a method is developed to provide a set of forcing modes which form a complete orthonormal basis for the finite-time response to steady forcing in the energy inner product space. The forcin...For linear forcing problems, a method is developed to provide a set of forcing modes which form a complete orthonormal basis for the finite-time response to steady forcing in the energy inner product space. The forcing modes are found by calculating eigenvectors of a positive definite and symmetric matrix determined from given equations of motion. The amplitude of responses to forcing modes is given in terms of the associated eigenvalues. This method is used in a nondivergent barotropic model linearized about the 300 hPa zonally-varying climatological flow both for northern summertime and wintertime. The results show that the amplitude of response varies considerably with different forcing modes. Only a few of forcing modes associated with the leading eigenvalues, called efficient forcing mode, can excite significant response. The efficient forcing modes possess highly localized spatial structure with wavetrain appearance. Most of the efficient forcings are located to the south of regions of the jet cores. The forcings located over polar regions are also efficient. In addition, the response is larger in wintertime than in summertime for a given forcing.展开更多
An analysis of atmospheric SW-radiative forcing and local heating/cooling rate is made using a one year temporal and vertical profiles of aerosol and cloud over Yaoundé (11.51°E, 3.83°N). It appears tha...An analysis of atmospheric SW-radiative forcing and local heating/cooling rate is made using a one year temporal and vertical profiles of aerosol and cloud over Yaoundé (11.51°E, 3.83°N). It appears that the direct influence of aerosols on the surface compared to the TOA can be 3 times larger. Annual mean value obtained at 559 mb altitude is +27.74 W/m2 with range from 0 to +43 W/m2. At 904 mb, we obtained an annual mean of ﹣46.22 W/m2 with range from ﹣65 to ﹣9 W/m2. Frequency distribution indicates that more than 95% of ARF are between +10 and +70 W/m2 at 559 mb (upper limit of UL), and more than 85% of ARF are between ﹣70 and ﹣10 W/m2 at 904 mb (upper limit of PBL). This sign change is explained by the fact that the backscattering peaks at the upper limit of the aerosol PBL layer. The maximum CRF is noted at TOA where it reaches ﹣600 W/m2 based on the time interval and the structure of clouds. The highest values occur between 11.50 and 13.50 LST. Clouds lead to a general heating of the entire atmospheric column with a much greater effect near the surface. Aerosols effect on the heating rate profile show strong cooling during the day for the lower atmosphere, with slight heating at the upper atmosphere. This cooling contribution generally increases from the surface and peacks at the upper boundary of aerosol layer where reflectivity is the most important. Depending on the moment of the day, average heating effect of clouds peacks at surface or within the middle troposphere due to the absorption by clouds particles. Vertical profiles deeply evolve exhibiting differences that exceed ﹣3 K/day according to altitude from one hour to another during a given mean solar day.展开更多
This paper investigates the generation of complex bursting patterns in Van der Pol system with two slowly changing external forcings. Complex bursting patterns, including complex periodic bursting and chaotic bursting...This paper investigates the generation of complex bursting patterns in Van der Pol system with two slowly changing external forcings. Complex bursting patterns, including complex periodic bursting and chaotic bursting, are presented for the cases when the two frequencies are commensurate and incommensurate. These complex bursting patterns are novel and have not been reported in previous work. Based on the fast-slow dynamics, the evolution processes of the slow forcing are presented to reveal the dynamical mechanisms undedying the appearance of these complex bursting patterns. With the change of ampli- tudes and frequencies, the slow forcing may visit the spiking and rest areas in different ways, which leads to the generation of different complex bursting patterns.展开更多
Based on observations and historical simulations from the fifth phase of the Coupled Model Intercomparison Project(CMIP5) archive, the contributions of human activities(including greenhouse gases(GHGs), anthropogenic ...Based on observations and historical simulations from the fifth phase of the Coupled Model Intercomparison Project(CMIP5) archive, the contributions of human activities(including greenhouse gases(GHGs), anthropogenic aerosols(AAs), and land use(LU)) and external natural forcings(Nat) to climate changes in China over the past 50 years were quantified. Both anthropogenic and external natural forcings account for 95%–99% of the observed temperature change from 1951–1975 to 1981–2005. In particular, the temperature changes induced by GHGs are approximately 2–3 times stronger than the observed changes, and AAs impose a significant cooling effect. The total external forcings can explain 65%–78% of the observed precipitation changes over the past 50 years, in which AAs and GHGs are the primary external forcings leading to the precipitation changes; in particular, AAs dominate the main spatial features of precipitation changes in eastern China. Human activities also dominate the long-term non-linear trends in observed temperature during the past several decades, and, in particular, GHGs, the primary warming contributor, have produced significant warming since the 1960 s. Compared to the long-term non-linear trends in observed precipitation, GHGs have largely caused the wetting changes in the arid-semiarid region since the 1970 s, whereas AAs have led to the drying changes in the humid-semihumid region; both LU and Nat can impose certain impacts on the long-term non-linear trends in precipitation. Using the optimal fingerprinting detection approach, the effects of human activities on the temperature changes can be detected and attributed in China, and the effect of GHGs can be clearly detected from the observations in humid-semihumid areas. However, the anthropogenic effects cannot be detected in the observed precipitation changes, which may be due to the uncertainties in the model simulations and to other issues. Although some results in this paper still need improvement due to uncertainties in the coupled models, this study is expected to provide the background and scientific basis for climate changes to conduct vulnerability and risk assessments of the ecological systems and water resources in the arid-semiarid region of China.展开更多
As a key component of shale oil,petroleum fractions,and chemical products,the oxidative pyrolysis behavior of paraffin directly influences energy conversion efficiency and the direction of process optimization.A deep ...As a key component of shale oil,petroleum fractions,and chemical products,the oxidative pyrolysis behavior of paraffin directly influences energy conversion efficiency and the direction of process optimization.A deep understanding of its oxidative pyrolysis mechanism is crucial for addressing wax deposition in oil and gas extraction,enhancing product selectivity in cracking processes,and advancing novel clean fuel technologies.Traditional experimental methods face challenges in capturing transient free-radical reaction pathways at high temperatures,whereas molecular dynamics simulations offer a powerful approach to bridge the research gap in elucidating atomic-scale dynamic mechanisms.This database is constructed based on high-precision molecular dynamics simulations,comprising oxidative pyrolysis trajectory data for three paraffin models featuring different straight-chain hydrocarbon distributions within the temperature range of 2100-2500 K.The COMPASS force field was employed to optimize the initial structures,and the ReaxFF reactive force field was used to simulate the oxidative pyrolysis process.The database includes atomic trajectories,species evolution information,and reaction network analysis results for both heating and isothermal cracking processes,with a total data volume of approximately 141 GB(including 150000 atomic configuration frames).The data is stored in a hierarchical directory structure,supporting multi-scale oxidative pyrolysis mechanism studies and providing atomic-scale dynamic evidence for revealing carbon chain length effects and temperature sensitivity.展开更多
Purpose-Association of American railroads(AAR)standard automatic couplers are designed for much higher capacity than the normal operating loads.However,failure of knuckles and coupler bodies is still a common occurren...Purpose-Association of American railroads(AAR)standard automatic couplers are designed for much higher capacity than the normal operating loads.However,failure of knuckles and coupler bodies is still a common occurrence.Recent studies have shown that fatigue is the main reason behind such failures below the expected load.Moreover,knuckle failures occur more frequently than coupler body failures,which cause operational disruptions and also influence overall coupler life because of nonconforming contact between a new knuckle and an old coupler.In addition to new and old counterparts,undesired contact conditions are often the case with the new assembly due to casting-based manufacturing inaccuracies.Design/methodology/approach-A study is thus carried out in this paper to understand the variation of load transfer paths and its consequences caused by dimensional variability.A finite element model of an E-type coupler’s knuckle is developed and different possible contact conditions of the knuckle with the coupler head are simulated.Knuckles generally fail in pulling mode,during which the possible contacting elements of knuckle are pulling lugs,pin protector regions and pinholes.Due to dimensional variability,contact conditions may exist where an individual or a combination of these elements are in contact.Findings-Simulation results indicate that under regular operational conditions,having only the pulling lugs in contact reduces the risk of knuckle failure and maintains assembly integrity even if the knuckle fails.However,under extreme loading conditions,the safest scenario is when both pulling lugs and pin protector regions are in contact.Originality/value-These findings are believed to assist in defining the dimensional variability limits to ensure the desired contacts between the mating surfaces of the knuckle and coupler body of railway couplers of AAR type.This work contributes to understanding implications of dimensional variability in the railway couplers.The insight presented are useful in design,manufacturing and maintenance of railway coupler’s knuckle.展开更多
The high-quality assembly of Large Aircraft Components(LACs)is essential in modern aviation manufacturing.Numerical control locators are employed for the posture adjustment of LAC,yet the system's multi-input mult...The high-quality assembly of Large Aircraft Components(LACs)is essential in modern aviation manufacturing.Numerical control locators are employed for the posture adjustment of LAC,yet the system's multi-input multi-output,nonlinearity,and strong coupling presents significant challenges.The substantial internal force generated during the adjustment process can potentially damage the LAC and degrade the assembly quality.Hence,a workspace-based hybrid force position control scheme was developed to achieve high quality assembly with high-precision and lower internal force.Firstly,an offline workspace analysis with inherent geometric characteristics to form time-varying posture error constraint.Then,the posture error is integrated into the online position axis control to ensure tracking the ideal posture,while the force control axis compensates for posture deviation by minimizing internal force,thereby achieving high precision and low internal force.Finally,the effectiveness was demonstrated through experiments.The root mean square errors of orientation and position are 104 rad and 0.1 mm,respectively.A reduction in internal force can range from 10.96%to 57.4%compared to the traditional method.Key points'max position error is decreased from 0.32 mm to 0.18 mm,satisfying the 0.5 mm tolerance.Therefore,the proposed method will help promote the development of high-performance manufacturing.展开更多
A shaking table test was performed to investigate the different responses of piles with and without cement-soil reinforcement,considering both inertial and kinematic interactions.A comparison of the dynamic shear stre...A shaking table test was performed to investigate the different responses of piles with and without cement-soil reinforcement,considering both inertial and kinematic interactions.A comparison of the dynamic shear stress−strain hysteresis curves of soil profiles on the pile side with and without cement-soil reinforced piles indicates that cement-soil reinforced piles not only bear more tremendous shear stress but also have smaller strains under the action of cyclic shear stress.Furthermore,the cement-soil on the pile side not only shares part of the shear stress and modifies the bending moment distribution but also significantly enhances the resistance of the pile-side soil,reducing the lateral displacement of the superstructure.Cement-soil reinforcement reduced shear strains,inhibited sand liquefaction,and reduced superstructure displacements by 27%−47%(instantaneous)and 40%−65%(permanent).The proportion of horizontal load sharing between cement-soil reinforcement and saturated sand is considered,along with the change pattern of the subgrade reaction after sand liquefaction.An equivalent subgrade reaction calculation method is proposed,which accounts for the horizontal load-sharing ratios of soils with two different strengths.The test results indicate that the pile stress and displacement,estimated using the equivalent subgrade reaction,are in good agreement with the observed results.展开更多
The intrinsic pressure framework,which treats self-propelling force as an external force,provides a convenient and consistent description of mechanical equilibrium in active matter.However,direct experimental evidence...The intrinsic pressure framework,which treats self-propelling force as an external force,provides a convenient and consistent description of mechanical equilibrium in active matter.However,direct experimental evidence is still lacking.To validate this framework,here we employ a programmable robotic platform,where a single light-controlled wheeled robot travels in an activity landscape.Our experiments quantitatively demonstrate that the intrinsic pressure difference across the activity interface is balanced by the emerged polarization force.This result unambiguously confirms the theoretical predictions,thus validating the intrinsic pressure framework and laying the experimental foundation for the intrinsic pressure-based mechanical description of dry active matter.展开更多
Ice premelting,the formation of a quasi-liquid layer on ice surfaces below the bulk melting point,plays a crucial role in various processes,ranging from glacier dynamics to ice friction and surface chemistry.Despite i...Ice premelting,the formation of a quasi-liquid layer on ice surfaces below the bulk melting point,plays a crucial role in various processes,ranging from glacier dynamics to ice friction and surface chemistry.Despite intensive research,the microscopic structure of the premelting layer and underlying molecular mechanisms remain poorly understood.In this work,we studied the temperature-and pressure-dependent structural disordering of crystalline Ih(0001)surface near the onset of premelting on the atomic scale by qPlus-based cryogenic atomic force microscopy.The linear correlation between the density of planar local structure(PLS)and the fraction of disordered surface region showed that the PLS mediated early-stage premelting by serving as a metastable seeding state.Notably,the associated surface disordering is cooperative,extending over an area of roughly~2 nm^(2) around a PLS.We further found a striking structural similarity between the kinetic-trapped regime below the surface crystallization temperature(T_(c))and the premelting-dominated regime above T_(c).As the deposition pressure increased,the characteristic temperature dependence was preserved,with only T_(c) shifting to higher values due to kinetic effects.Finally,we proposed a surface phase diagram for ice Ih(0001)based on our experimental observations.展开更多
Bentonite is a necessary binder in producing pellets.Its excessive use reduces the iron grade of pellets and increases production costs.Minimizing bentonite dosage is essential for producing high-quality iron ore pell...Bentonite is a necessary binder in producing pellets.Its excessive use reduces the iron grade of pellets and increases production costs.Minimizing bentonite dosage is essential for producing high-quality iron ore pellets.Addressing the gap in the application of organically-intercalated modified bentonite in the pelletizing field,this study introduces an innovative modification process for bentonite that employs the synergistic effect of mechanical force and dimethyl sulfoxide to enhance the intercalation of organic compounds within bentonite,thus significantly enhancing its binding performance.The colloid value and swell capacity of modified bentonite(98.5 m L/3g and 55.0 m L/g)were much higher than the original bentonite(90.5 m L/3g and 17.5 m L/g).With the decrease of bentonite dosage from1.5wt%to 1.0wt%,the drop number of green pellets from a height of 0.5 m and the compressive strengths of roasted pellets using the modified bentonite(6.0 times and 2916 N per pellet)were significantly higher than those of the original bentonite(4.0 times and 2739 N per pellet).This study provides a comprehensive analysis of the intercalation modification mechanism of bentonite,offering crucial technical insights for the development of high-performance modified bentonite as iron ore pellet binders.展开更多
Maintaining the structural integrity of parallel natural gas pipelines during leakage-induced jet fires remains a critical engineering challenge.Existing methods often fail to account for the complex interactions amon...Maintaining the structural integrity of parallel natural gas pipelines during leakage-induced jet fires remains a critical engineering challenge.Existing methods often fail to account for the complex interactions among heat transfer,material behavior,and pipeline geometry,which can lead to overly simplified and potentially unsafe assessments.To address these limitations,this study develops a multiphysics approach that integrates small-orifice leakage theory with detailed thermo-fluid-structural simulations.The proposed framework contributes to a more accurate failure analysis through three main components:(1)coupled modeling that tracks transient heat flow and stress development as fire conditions evolve;(2)risk assessment incorporating spatial layout,material property changes with temperature,and operational limits;and(3)sensitivity analysis to identify key design factors that influence structural performance under high thermal loads.Simulation results demonstrate that thermal radiation from neighboring jet fires significantly accelerates material degradation,with inter-pipeline spacing emerging as a critical determinant of structural response.Notably,increasing the spacing between pipelines reduces thermal interaction and mechanical stress transfer.As a result,systems with optimized spacing exhibit markedly lower deformation than conventional configurations.These findings provide a foundation for re-evaluating pipeline layout strategies and strengthening safety protocols,particularly in high-risk environments where fire exposure can severely compromise structural reliability.The proposed approach offers actionable guidance for engineers and policymakers seeking to enhance the resilience of pipeline infrastructure under extreme thermal conditions.展开更多
Evaluating the effectivenes s of forest restoration projects is crucial for designing adaptive restoration strategies.However,existing studies have primarily focused on ecological outcomes while overlooking cost input...Evaluating the effectivenes s of forest restoration projects is crucial for designing adaptive restoration strategies.However,existing studies have primarily focused on ecological outcomes while overlooking cost inputs.This gap can lead to increased uncertainties in restoration planning.Here we investigated forest dynamics in China's Upper Yangtze River Basin(UYRB)using kernel Normalized Difference Vegetation Index(kNDVI),Leaf Area Index(LAI),Gross Primary Productivity(GPP),Ku-band Vegetation Optical Depth(Ku-VOD)time series and climate data from1982 to 2020.Subsequently,we employed a residual trend analysis integrating temporal effects to determine the relative contributions of climate change and human activities to forest dynamics before and after the implementation of forest restoration engineering in 1998.Additionally,we developed an Afforestation Efficiency Index(AEI)to quantitatively assess the cost efficiency of afforestation projects.Results indicated that forest in the UYRB showed sustained increases during 1982-2020,with most areas experiencing greater growth after 1998 than before.Temporal effects of climatic factors influenced over 42.7%of the forest,and incorporating time-lag and cumulative effects enhanced climate-based explanations of forest variations by 1.61-24.73%.Human activities emerged as the dominant driver of forest dynamics post 1998,whereas climate variables predominated before this period.The cost-effectiveness of forest restoration projects in the UYRB typically ranges from moderate to high,with higher success predominantly observed in the northeastern and eastern counties,while the central,western,and northwestern counties mainly showed relatively low efficiency.These findings stress the need for assessing forest restoration outcomes from both ecological and cost perspectives,and can offer valuable insights for optimizing the layout of forest restoration initiatives in the UYRB.展开更多
This work examines the microstructure and corrosion properties of fine-grained Al 7075 across different regions under varying cooling conditions during friction stir welding.The findings demonstrate that forced coolin...This work examines the microstructure and corrosion properties of fine-grained Al 7075 across different regions under varying cooling conditions during friction stir welding.The findings demonstrate that forced cooling significantly improves the corrosion resistance of the welded joints.Specifically,the corrosion resistance was the highest in the stir zone,followed by the thermo-mechanical affected zone,and then the heat affected zone.Forced cooling mitigates grain growth by controlling the welding thermal effects,thereby increasing the proportion ofΣ3 grain boundaries.The modification of these microstructural characteristics promotes the formation of a dense oxide layer,thereby enhancing the corrosion resistance.Furthermore,forced cooling mitigates the precipitation and coarsening of the anodic phase in the stir zone,which in turn reduces the susceptibility of the joint to pitting corrosion.Additionally,the lower recrystallization texture content in the joint,resulting from forced cooling,contributes to a reduction in the number of corrosion-active sites,thereby further improving the corrosion performance of the welded joint.展开更多
Quantifying the hydrogen bond(H-bond)strength of polymers is essential for rational design of advanced materials.However,direct measurement remains challenging because of the structural complexity of polymers and the ...Quantifying the hydrogen bond(H-bond)strength of polymers is essential for rational design of advanced materials.However,direct measurement remains challenging because of the structural complexity of polymers and the weak nature of H-bonds.Vacuum-based singlemolecule force spectroscopy(Vac-SMFS)offers a new and precise approach for such measurements.Using polyallylamine(PAAm)as a model polymer,the intrinsic strength(i.e.,strength without external influences)of representative N―H…N H-bonds was quantified to be about 5.25 kJ·mol^(–1).Comparative Vac-SMFS analysis across different polymer systems revealed that the N―H…N H-bonds in PAAm are unexpectedly stronger than the N―H…O H-bonds in poly(N-isopropylacrylamide)(PNIPAM)and the O―H…O H-bonds in poly(hydroxyethyl methacrylate)(PHEMA).This trend contrasts with that of established small-molecule systems.These results highlight how side-chain length and spatial configuration dictate polymer H-bond strengths,expanding the fundamental knowledge of polymer interactions and enabling the rational design of next-generation functional materials.展开更多
The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive P...The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive Poisson’s ratio,the NPR bolt exhibits a quasi-ideal plastic response without a prominent yield platform,enabling it to sustain high prestress with a substantial safety margin,which is particularly advantageous for jointed rock masses.However,investigations into the shear resistance mechanisms of NPR bolts under varying prestress levels remain limited.This study conducted full-scale double shear tests to assess the shear strength,deformation behavior,energy absorption,and failure mechanisms of NPR bolts under different prestress conditions.To ensure a fair comparison with PR bolts,a prestress utilization coefficient(PUC)was introduced.The results reveal that at a PUC of 0.25,the NPR bolt achieved peak axial force,shear displacement,and peak shear force values that are 2.41,1.88,and 2.13 times greater than those of the PR bolt,respectively.Shear performance was optimized at a prestress level of 100 kN,with energy absorption reaching 47.1 kJ,which is 2.8 times that of the PR bolt.Furthermore,the necking ratio was significantly reduced,indicating more distributed plastic deformation and delayed failure.Field applications verified the superior performance,resulting in a 27.4%reduction in roof settlement and enhanced structural integrity.These findings confirm that NPR bolts possess excellent shear resistance,energy absorption,and deformation adaptability,and optimizing prestress significantly enhances their support performance,providing a strong basis for geotechnical engineering applications.展开更多
As a controllable power generation method requiring no energy storage,Ocean Thermal Energy Conversion(OTEC)technology demonstrates characteristics of abundant reserves,low pollution,and round-the-clock stable operatio...As a controllable power generation method requiring no energy storage,Ocean Thermal Energy Conversion(OTEC)technology demonstrates characteristics of abundant reserves,low pollution,and round-the-clock stable operation.The free-standing cold-water pipe(CWP)in the system withstands various complex loads during operation,posing potential failure risks.To reveal the deformation and stress mechanisms of OTEC CWPs,this study first analyzes wave particle velocity and acceleration to determine wave loads at different water depths.Based on the Euler-Bernoulli beam model,a quasi-static load calculation model for OTEC CWPs was established.The governing equations were discretized using the finite difference method,and matrix equations were solved to analyze bending deformation,bending moments,and surface stresses at discrete points along the pipe.Results indicate that water depths within 50 m represent a critical zone where wave particle velocity,acceleration,and wave loads exhibit significant variations in harmonic patterns,while beyond 50 m depth wave loads decrease linearly.Ocean currents and surface wind-driven currents substantially influence the CWP’s lateral displacement.Considering the effect of clump weights,the maximum lateral displacement occurs at 600–800 m below sea level.Utilizing large-wall-thickness high-strength pipes at the top section significantly enhances the structural safety of the CWP system.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.42130604)the National Key Research and Development Program of China(Grant No.2023YFF0804704)+2 种基金the National Natural Science Foundation of China(Grant Nos.42105044)Swedish STINT(Grant No.CH2019-8377)the Priority Academic Program Development of Jiangsu Higher Education Institutions(Grant No.164320H116)。
文摘Since the mid-20th century,the Mongolian Plateau(MP)has experienced decadal droughts coupled with extreme heatwaves,severely affecting regional ecology and social development.However,the mechanisms behind these decadalscale compound heatwavedrought events remain debated.Here,using reconstructions and simulations from the Community Earth System Model Last Millennium Ensemble,we demonstrate that,over the last millennium,decadal droughts on the MP occurred under both warm and cold conditions,differing from recent compound heatwavedrought events.We found that by examining temperature changes during these drought periods,the distinct influences of external forcings and internal variability can be simply and effectively distinguished.Specifically,colddry events were primarily driven by volcanic eruptions that weakened the East Asian summer monsoon and midlatitude westerlies,reducing moisture transport to the MP.In contrast,warmdry events were predominantly induced by internal variability,notably the negative phase of the Atlantic Multidecadal Oscillation and the expansion of the Barents Sea ice extent.The recent extreme compound event was probably influenced by the combined effects of anthropogenic forcings and internal variability.These findings deepen our understanding of how external forcings and internal variability affect decadal drought events on the MP and highlight that recent compound events are unprecedented in the context of the last millennium.
文摘Subsurface air flow can be induced by natural processes, such as atmospheric or barometric pressure changes, water table fluctuations, topographic effects, and rainfall infiltration. Barometric pressure fluctuations are the most common cause of subsurface air flow, which can be significant under favourable geological conditions. This process has been studied most extensively because of its application to passive soil vapor extraction. Soil air flow induced by water table fluctuations can be significant, particularly where the fluctuations are of high frequency, for example, in tidal-influenced coastal areas. Topographic effects can lead to strong subsoil air flow in areas with great elevation differences. Rainfall infiltration usually produces only weak airflow. Air flow induced by these natural processes has important environmental and engineering implications. Among the different processes, air flow induced by tidal fluctuations has been studied the least, although it has exciting applications to coastal engineering projects and environmental remediation.
基金supported jointly by the National Natural Science Foundation of China (Grant Nos 40890054 and 40821092)the National Basic Research Program of China (Grant No 2010CB951904)National Key Technologies R&D Program (Grant No 2007BAC29B03)
文摘Characteristics of the total clear-sky greenhouse effect （GA） and cloud radiative forcings （CRFs）, along with the radiative-related water vapor and cloud properties simulated by the Spectral Atmospheric Model developed by LASGIAP （SAMIL） are evaluated. Impacts of the convection scheme on the simulation of CRFs are discussed by using two AMIP （Atmospheric Model Inter-comparison Project） type simulations employing different convection schemes： the new Zhang-McFarlane （NZH） and Tiedtke （TDK） convection schemes. It shows that both the climatological GA and its response to El Nio warming are simulated well, both in terms of spatial pattern and magnitude. The impact of the convection scheme on GA is not significant. The climatological longwave CRF （LWCRF） and its response to El Nio warming are simulated well, but with a prominently weaker magnitude. The simulation of the climatology （response） of LWCRF in the NZH （TDK） run is slightly more realistic than in the TDK （NZH） simulation, indicating significant impacts of the convection scheme. The shortwave CRF （SWCRF） shows large biases in both spatial pattern and magnitude, and the results from the TDK run are better than those from the NZH run. A spuriously excessive negative climatological SWCRF over the southeastern Pacific and an insufficient response of SWCRF to El Nio warming over the tropical Pacific are seen in the NZH run. These two biases are alleviated in the TDK run, since it produces vigorous convection, which is related to the low threshold for convection to take place. Also, impacts of the convection scheme on the cloud profile are discussed.
文摘For linear forcing problems, a method is developed to provide a set of forcing modes which form a complete orthonormal basis for the finite-time response to steady forcing in the energy inner product space. The forcing modes are found by calculating eigenvectors of a positive definite and symmetric matrix determined from given equations of motion. The amplitude of responses to forcing modes is given in terms of the associated eigenvalues. This method is used in a nondivergent barotropic model linearized about the 300 hPa zonally-varying climatological flow both for northern summertime and wintertime. The results show that the amplitude of response varies considerably with different forcing modes. Only a few of forcing modes associated with the leading eigenvalues, called efficient forcing mode, can excite significant response. The efficient forcing modes possess highly localized spatial structure with wavetrain appearance. Most of the efficient forcings are located to the south of regions of the jet cores. The forcings located over polar regions are also efficient. In addition, the response is larger in wintertime than in summertime for a given forcing.
文摘An analysis of atmospheric SW-radiative forcing and local heating/cooling rate is made using a one year temporal and vertical profiles of aerosol and cloud over Yaoundé (11.51°E, 3.83°N). It appears that the direct influence of aerosols on the surface compared to the TOA can be 3 times larger. Annual mean value obtained at 559 mb altitude is +27.74 W/m2 with range from 0 to +43 W/m2. At 904 mb, we obtained an annual mean of ﹣46.22 W/m2 with range from ﹣65 to ﹣9 W/m2. Frequency distribution indicates that more than 95% of ARF are between +10 and +70 W/m2 at 559 mb (upper limit of UL), and more than 85% of ARF are between ﹣70 and ﹣10 W/m2 at 904 mb (upper limit of PBL). This sign change is explained by the fact that the backscattering peaks at the upper limit of the aerosol PBL layer. The maximum CRF is noted at TOA where it reaches ﹣600 W/m2 based on the time interval and the structure of clouds. The highest values occur between 11.50 and 13.50 LST. Clouds lead to a general heating of the entire atmospheric column with a much greater effect near the surface. Aerosols effect on the heating rate profile show strong cooling during the day for the lower atmosphere, with slight heating at the upper atmosphere. This cooling contribution generally increases from the surface and peacks at the upper boundary of aerosol layer where reflectivity is the most important. Depending on the moment of the day, average heating effect of clouds peacks at surface or within the middle troposphere due to the absorption by clouds particles. Vertical profiles deeply evolve exhibiting differences that exceed ﹣3 K/day according to altitude from one hour to another during a given mean solar day.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10872080, 20976075, 10972091 and 11102076)the Research Foundation for Advanced Talents of Jiangsu University (Grant No. 11JDG075)the Natural Science Foundation of Higher Education Institutions of Jiangsu Province (Grant No. 10KJD110006)
文摘This paper investigates the generation of complex bursting patterns in Van der Pol system with two slowly changing external forcings. Complex bursting patterns, including complex periodic bursting and chaotic bursting, are presented for the cases when the two frequencies are commensurate and incommensurate. These complex bursting patterns are novel and have not been reported in previous work. Based on the fast-slow dynamics, the evolution processes of the slow forcing are presented to reveal the dynamical mechanisms undedying the appearance of these complex bursting patterns. With the change of ampli- tudes and frequencies, the slow forcing may visit the spiking and rest areas in different ways, which leads to the generation of different complex bursting patterns.
基金National Basic Research Program of China (Grant No. 2012CB956203)the China Meteorological Administration R&D Special Fund for Public Welfare (Meteorology) (Grant No. GYHY201306027)+1 种基金the Open Research Fund Program of Plateau Atmosphere and Environment Key Laboratory of Sichuan Province (Grant No. PAEKL-2015-C1)the National Science Foundation of China (Grant No. 41405090)
文摘Based on observations and historical simulations from the fifth phase of the Coupled Model Intercomparison Project(CMIP5) archive, the contributions of human activities(including greenhouse gases(GHGs), anthropogenic aerosols(AAs), and land use(LU)) and external natural forcings(Nat) to climate changes in China over the past 50 years were quantified. Both anthropogenic and external natural forcings account for 95%–99% of the observed temperature change from 1951–1975 to 1981–2005. In particular, the temperature changes induced by GHGs are approximately 2–3 times stronger than the observed changes, and AAs impose a significant cooling effect. The total external forcings can explain 65%–78% of the observed precipitation changes over the past 50 years, in which AAs and GHGs are the primary external forcings leading to the precipitation changes; in particular, AAs dominate the main spatial features of precipitation changes in eastern China. Human activities also dominate the long-term non-linear trends in observed temperature during the past several decades, and, in particular, GHGs, the primary warming contributor, have produced significant warming since the 1960 s. Compared to the long-term non-linear trends in observed precipitation, GHGs have largely caused the wetting changes in the arid-semiarid region since the 1970 s, whereas AAs have led to the drying changes in the humid-semihumid region; both LU and Nat can impose certain impacts on the long-term non-linear trends in precipitation. Using the optimal fingerprinting detection approach, the effects of human activities on the temperature changes can be detected and attributed in China, and the effect of GHGs can be clearly detected from the observations in humid-semihumid areas. However, the anthropogenic effects cannot be detected in the observed precipitation changes, which may be due to the uncertainties in the model simulations and to other issues. Although some results in this paper still need improvement due to uncertainties in the coupled models, this study is expected to provide the background and scientific basis for climate changes to conduct vulnerability and risk assessments of the ecological systems and water resources in the arid-semiarid region of China.
基金Supported by Natural Science Foundation of Shanxi Province (202203021221219)Research on the Construction of Scientific and Technological Innovation Think Tank of Shanxi Association for Science and Technology (KXKT202542)Planning Project under Commerce Statistical Society of China (2025STY122)。
文摘As a key component of shale oil,petroleum fractions,and chemical products,the oxidative pyrolysis behavior of paraffin directly influences energy conversion efficiency and the direction of process optimization.A deep understanding of its oxidative pyrolysis mechanism is crucial for addressing wax deposition in oil and gas extraction,enhancing product selectivity in cracking processes,and advancing novel clean fuel technologies.Traditional experimental methods face challenges in capturing transient free-radical reaction pathways at high temperatures,whereas molecular dynamics simulations offer a powerful approach to bridge the research gap in elucidating atomic-scale dynamic mechanisms.This database is constructed based on high-precision molecular dynamics simulations,comprising oxidative pyrolysis trajectory data for three paraffin models featuring different straight-chain hydrocarbon distributions within the temperature range of 2100-2500 K.The COMPASS force field was employed to optimize the initial structures,and the ReaxFF reactive force field was used to simulate the oxidative pyrolysis process.The database includes atomic trajectories,species evolution information,and reaction network analysis results for both heating and isothermal cracking processes,with a total data volume of approximately 141 GB(including 150000 atomic configuration frames).The data is stored in a hierarchical directory structure,supporting multi-scale oxidative pyrolysis mechanism studies and providing atomic-scale dynamic evidence for revealing carbon chain length effects and temperature sensitivity.
文摘Purpose-Association of American railroads(AAR)standard automatic couplers are designed for much higher capacity than the normal operating loads.However,failure of knuckles and coupler bodies is still a common occurrence.Recent studies have shown that fatigue is the main reason behind such failures below the expected load.Moreover,knuckle failures occur more frequently than coupler body failures,which cause operational disruptions and also influence overall coupler life because of nonconforming contact between a new knuckle and an old coupler.In addition to new and old counterparts,undesired contact conditions are often the case with the new assembly due to casting-based manufacturing inaccuracies.Design/methodology/approach-A study is thus carried out in this paper to understand the variation of load transfer paths and its consequences caused by dimensional variability.A finite element model of an E-type coupler’s knuckle is developed and different possible contact conditions of the knuckle with the coupler head are simulated.Knuckles generally fail in pulling mode,during which the possible contacting elements of knuckle are pulling lugs,pin protector regions and pinholes.Due to dimensional variability,contact conditions may exist where an individual or a combination of these elements are in contact.Findings-Simulation results indicate that under regular operational conditions,having only the pulling lugs in contact reduces the risk of knuckle failure and maintains assembly integrity even if the knuckle fails.However,under extreme loading conditions,the safest scenario is when both pulling lugs and pin protector regions are in contact.Originality/value-These findings are believed to assist in defining the dimensional variability limits to ensure the desired contacts between the mating surfaces of the knuckle and coupler body of railway couplers of AAR type.This work contributes to understanding implications of dimensional variability in the railway couplers.The insight presented are useful in design,manufacturing and maintenance of railway coupler’s knuckle.
基金co-supported by the National Natural Science Foundation of China(No.52125504)the Liaoning Revitalization Talents Program(No.XLYC2202017)Dalian Support Policy Project for Innovation of Technological Talents(No.2023RG001)。
文摘The high-quality assembly of Large Aircraft Components(LACs)is essential in modern aviation manufacturing.Numerical control locators are employed for the posture adjustment of LAC,yet the system's multi-input multi-output,nonlinearity,and strong coupling presents significant challenges.The substantial internal force generated during the adjustment process can potentially damage the LAC and degrade the assembly quality.Hence,a workspace-based hybrid force position control scheme was developed to achieve high quality assembly with high-precision and lower internal force.Firstly,an offline workspace analysis with inherent geometric characteristics to form time-varying posture error constraint.Then,the posture error is integrated into the online position axis control to ensure tracking the ideal posture,while the force control axis compensates for posture deviation by minimizing internal force,thereby achieving high precision and low internal force.Finally,the effectiveness was demonstrated through experiments.The root mean square errors of orientation and position are 104 rad and 0.1 mm,respectively.A reduction in internal force can range from 10.96%to 57.4%compared to the traditional method.Key points'max position error is decreased from 0.32 mm to 0.18 mm,satisfying the 0.5 mm tolerance.Therefore,the proposed method will help promote the development of high-performance manufacturing.
基金Project(52078129)supported by the National Natural Science Foundation of ChinaProject(MTF2023009)supported by the Open Project of Key Laboratory of Transport Industry of Comprehensive Transportation Theory(Nanjing Modern Multimodal Transportation Laboratory),ChinaProject(2242024K40037)supported by the Fundamental Research Funds for the Central Universities,China。
文摘A shaking table test was performed to investigate the different responses of piles with and without cement-soil reinforcement,considering both inertial and kinematic interactions.A comparison of the dynamic shear stress−strain hysteresis curves of soil profiles on the pile side with and without cement-soil reinforced piles indicates that cement-soil reinforced piles not only bear more tremendous shear stress but also have smaller strains under the action of cyclic shear stress.Furthermore,the cement-soil on the pile side not only shares part of the shear stress and modifies the bending moment distribution but also significantly enhances the resistance of the pile-side soil,reducing the lateral displacement of the superstructure.Cement-soil reinforcement reduced shear strains,inhibited sand liquefaction,and reduced superstructure displacements by 27%−47%(instantaneous)and 40%−65%(permanent).The proportion of horizontal load sharing between cement-soil reinforcement and saturated sand is considered,along with the change pattern of the subgrade reaction after sand liquefaction.An equivalent subgrade reaction calculation method is proposed,which accounts for the horizontal load-sharing ratios of soils with two different strengths.The test results indicate that the pile stress and displacement,estimated using the equivalent subgrade reaction,are in good agreement with the observed results.
基金supported by the National Natural Science Foundation of China (Grant Nos.T2325027,12274448,T2350007,12404239,12174041,12325405,12090054,and T2221001)the National Key R&D Program of China (Grant No.2022YFF0503504)。
文摘The intrinsic pressure framework,which treats self-propelling force as an external force,provides a convenient and consistent description of mechanical equilibrium in active matter.However,direct experimental evidence is still lacking.To validate this framework,here we employ a programmable robotic platform,where a single light-controlled wheeled robot travels in an activity landscape.Our experiments quantitatively demonstrate that the intrinsic pressure difference across the activity interface is balanced by the emerged polarization force.This result unambiguously confirms the theoretical predictions,thus validating the intrinsic pressure framework and laying the experimental foundation for the intrinsic pressure-based mechanical description of dry active matter.
基金Project supported by the National Key R&D Program of China(Grant Nos.2021YFA1400500 and 2025YFF1502400)the National Natural Science Foundation of China(Grant Nos.92361302,12250001,12535001,and U22A20260)+3 种基金the China Postdoctoral Science Foundation(Grant Nos.BX20230021,2023T160011,and 2024M760068)support from the National Program for Support of Top-notch Young professionalssupport from Beijing Outstanding Young Scientist Program(Grant No.JWZQ20240101002)the New Cornerstone Science Foundation through the New Cornerstone Investigator Program and the XPLORER PRIZE。
文摘Ice premelting,the formation of a quasi-liquid layer on ice surfaces below the bulk melting point,plays a crucial role in various processes,ranging from glacier dynamics to ice friction and surface chemistry.Despite intensive research,the microscopic structure of the premelting layer and underlying molecular mechanisms remain poorly understood.In this work,we studied the temperature-and pressure-dependent structural disordering of crystalline Ih(0001)surface near the onset of premelting on the atomic scale by qPlus-based cryogenic atomic force microscopy.The linear correlation between the density of planar local structure(PLS)and the fraction of disordered surface region showed that the PLS mediated early-stage premelting by serving as a metastable seeding state.Notably,the associated surface disordering is cooperative,extending over an area of roughly~2 nm^(2) around a PLS.We further found a striking structural similarity between the kinetic-trapped regime below the surface crystallization temperature(T_(c))and the premelting-dominated regime above T_(c).As the deposition pressure increased,the characteristic temperature dependence was preserved,with only T_(c) shifting to higher values due to kinetic effects.Finally,we proposed a surface phase diagram for ice Ih(0001)based on our experimental observations.
基金financial support by the National Key Research and Development Program of China(No.2023YFC2907801)the Hunan Provincial Natural Science Foundation of China(No.2023JJ40760)the Scientific and Technological Project of Yunnan Precious Metals Laboratory,China(No.YPML-2023050276)。
文摘Bentonite is a necessary binder in producing pellets.Its excessive use reduces the iron grade of pellets and increases production costs.Minimizing bentonite dosage is essential for producing high-quality iron ore pellets.Addressing the gap in the application of organically-intercalated modified bentonite in the pelletizing field,this study introduces an innovative modification process for bentonite that employs the synergistic effect of mechanical force and dimethyl sulfoxide to enhance the intercalation of organic compounds within bentonite,thus significantly enhancing its binding performance.The colloid value and swell capacity of modified bentonite(98.5 m L/3g and 55.0 m L/g)were much higher than the original bentonite(90.5 m L/3g and 17.5 m L/g).With the decrease of bentonite dosage from1.5wt%to 1.0wt%,the drop number of green pellets from a height of 0.5 m and the compressive strengths of roasted pellets using the modified bentonite(6.0 times and 2916 N per pellet)were significantly higher than those of the original bentonite(4.0 times and 2739 N per pellet).This study provides a comprehensive analysis of the intercalation modification mechanism of bentonite,offering crucial technical insights for the development of high-performance modified bentonite as iron ore pellet binders.
文摘Maintaining the structural integrity of parallel natural gas pipelines during leakage-induced jet fires remains a critical engineering challenge.Existing methods often fail to account for the complex interactions among heat transfer,material behavior,and pipeline geometry,which can lead to overly simplified and potentially unsafe assessments.To address these limitations,this study develops a multiphysics approach that integrates small-orifice leakage theory with detailed thermo-fluid-structural simulations.The proposed framework contributes to a more accurate failure analysis through three main components:(1)coupled modeling that tracks transient heat flow and stress development as fire conditions evolve;(2)risk assessment incorporating spatial layout,material property changes with temperature,and operational limits;and(3)sensitivity analysis to identify key design factors that influence structural performance under high thermal loads.Simulation results demonstrate that thermal radiation from neighboring jet fires significantly accelerates material degradation,with inter-pipeline spacing emerging as a critical determinant of structural response.Notably,increasing the spacing between pipelines reduces thermal interaction and mechanical stress transfer.As a result,systems with optimized spacing exhibit markedly lower deformation than conventional configurations.These findings provide a foundation for re-evaluating pipeline layout strategies and strengthening safety protocols,particularly in high-risk environments where fire exposure can severely compromise structural reliability.The proposed approach offers actionable guidance for engineers and policymakers seeking to enhance the resilience of pipeline infrastructure under extreme thermal conditions.
基金supported by the National Natural Science Foundation of China(42071238)the Jiuzhaigou Post-Disaster Restoration and Reconstruction Program(5132202020000046)+1 种基金the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)the Ministry of Science and Technology of the People's Republic of China(2019QZKK0402)。
文摘Evaluating the effectivenes s of forest restoration projects is crucial for designing adaptive restoration strategies.However,existing studies have primarily focused on ecological outcomes while overlooking cost inputs.This gap can lead to increased uncertainties in restoration planning.Here we investigated forest dynamics in China's Upper Yangtze River Basin(UYRB)using kernel Normalized Difference Vegetation Index(kNDVI),Leaf Area Index(LAI),Gross Primary Productivity(GPP),Ku-band Vegetation Optical Depth(Ku-VOD)time series and climate data from1982 to 2020.Subsequently,we employed a residual trend analysis integrating temporal effects to determine the relative contributions of climate change and human activities to forest dynamics before and after the implementation of forest restoration engineering in 1998.Additionally,we developed an Afforestation Efficiency Index(AEI)to quantitatively assess the cost efficiency of afforestation projects.Results indicated that forest in the UYRB showed sustained increases during 1982-2020,with most areas experiencing greater growth after 1998 than before.Temporal effects of climatic factors influenced over 42.7%of the forest,and incorporating time-lag and cumulative effects enhanced climate-based explanations of forest variations by 1.61-24.73%.Human activities emerged as the dominant driver of forest dynamics post 1998,whereas climate variables predominated before this period.The cost-effectiveness of forest restoration projects in the UYRB typically ranges from moderate to high,with higher success predominantly observed in the northeastern and eastern counties,while the central,western,and northwestern counties mainly showed relatively low efficiency.These findings stress the need for assessing forest restoration outcomes from both ecological and cost perspectives,and can offer valuable insights for optimizing the layout of forest restoration initiatives in the UYRB.
基金Project(ASM-20240)supported by the Key Laboratory of Advanced Structural Materials(Changchun University of Technology),Ministry of Education,ChinaProject(2022TD-30)supported by the Scientific and Technological Innovation Team Project of Shaanxi Innovation Capability Support Plan,China。
文摘This work examines the microstructure and corrosion properties of fine-grained Al 7075 across different regions under varying cooling conditions during friction stir welding.The findings demonstrate that forced cooling significantly improves the corrosion resistance of the welded joints.Specifically,the corrosion resistance was the highest in the stir zone,followed by the thermo-mechanical affected zone,and then the heat affected zone.Forced cooling mitigates grain growth by controlling the welding thermal effects,thereby increasing the proportion ofΣ3 grain boundaries.The modification of these microstructural characteristics promotes the formation of a dense oxide layer,thereby enhancing the corrosion resistance.Furthermore,forced cooling mitigates the precipitation and coarsening of the anodic phase in the stir zone,which in turn reduces the susceptibility of the joint to pitting corrosion.Additionally,the lower recrystallization texture content in the joint,resulting from forced cooling,contributes to a reduction in the number of corrosion-active sites,thereby further improving the corrosion performance of the welded joint.
基金financially supported by the National Natural Science Foundation of China(No.22273079)Fundamental Research Funds for the Central Universities(No.2682025ZTPY004)。
文摘Quantifying the hydrogen bond(H-bond)strength of polymers is essential for rational design of advanced materials.However,direct measurement remains challenging because of the structural complexity of polymers and the weak nature of H-bonds.Vacuum-based singlemolecule force spectroscopy(Vac-SMFS)offers a new and precise approach for such measurements.Using polyallylamine(PAAm)as a model polymer,the intrinsic strength(i.e.,strength without external influences)of representative N―H…N H-bonds was quantified to be about 5.25 kJ·mol^(–1).Comparative Vac-SMFS analysis across different polymer systems revealed that the N―H…N H-bonds in PAAm are unexpectedly stronger than the N―H…O H-bonds in poly(N-isopropylacrylamide)(PNIPAM)and the O―H…O H-bonds in poly(hydroxyethyl methacrylate)(PHEMA).This trend contrasts with that of established small-molecule systems.These results highlight how side-chain length and spatial configuration dictate polymer H-bond strengths,expanding the fundamental knowledge of polymer interactions and enabling the rational design of next-generation functional materials.
基金supported by the State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering(Grant No.SDGZ2505)the Postdoctoral Fellowship Program of the China Postdoctoral Science Foundation(Grant No.GZB20250742)the General Program of the China Postdoctoral Science Foundation(Grant No.2025M773213).
文摘The negative Poisson’s ratio(NPR)bolt is an innovative support element distinguished by its high strength,elongation,and a slightly negative Poisson’s ratio.Unlike conventional prestressed(PR)bolts with a positive Poisson’s ratio,the NPR bolt exhibits a quasi-ideal plastic response without a prominent yield platform,enabling it to sustain high prestress with a substantial safety margin,which is particularly advantageous for jointed rock masses.However,investigations into the shear resistance mechanisms of NPR bolts under varying prestress levels remain limited.This study conducted full-scale double shear tests to assess the shear strength,deformation behavior,energy absorption,and failure mechanisms of NPR bolts under different prestress conditions.To ensure a fair comparison with PR bolts,a prestress utilization coefficient(PUC)was introduced.The results reveal that at a PUC of 0.25,the NPR bolt achieved peak axial force,shear displacement,and peak shear force values that are 2.41,1.88,and 2.13 times greater than those of the PR bolt,respectively.Shear performance was optimized at a prestress level of 100 kN,with energy absorption reaching 47.1 kJ,which is 2.8 times that of the PR bolt.Furthermore,the necking ratio was significantly reduced,indicating more distributed plastic deformation and delayed failure.Field applications verified the superior performance,resulting in a 27.4%reduction in roof settlement and enhanced structural integrity.These findings confirm that NPR bolts possess excellent shear resistance,energy absorption,and deformation adaptability,and optimizing prestress significantly enhances their support performance,providing a strong basis for geotechnical engineering applications.
基金funded by Nansha District Science and Technology Project(Grant Number.2024ZD008)funded by China Geological Survey(Grant number:No.DD20230066,DD20242659).
文摘As a controllable power generation method requiring no energy storage,Ocean Thermal Energy Conversion(OTEC)technology demonstrates characteristics of abundant reserves,low pollution,and round-the-clock stable operation.The free-standing cold-water pipe(CWP)in the system withstands various complex loads during operation,posing potential failure risks.To reveal the deformation and stress mechanisms of OTEC CWPs,this study first analyzes wave particle velocity and acceleration to determine wave loads at different water depths.Based on the Euler-Bernoulli beam model,a quasi-static load calculation model for OTEC CWPs was established.The governing equations were discretized using the finite difference method,and matrix equations were solved to analyze bending deformation,bending moments,and surface stresses at discrete points along the pipe.Results indicate that water depths within 50 m represent a critical zone where wave particle velocity,acceleration,and wave loads exhibit significant variations in harmonic patterns,while beyond 50 m depth wave loads decrease linearly.Ocean currents and surface wind-driven currents substantially influence the CWP’s lateral displacement.Considering the effect of clump weights,the maximum lateral displacement occurs at 600–800 m below sea level.Utilizing large-wall-thickness high-strength pipes at the top section significantly enhances the structural safety of the CWP system.
