Fluxing agents of zinc borate, antimony oxide, galss frit A and glass frit B, with different melting or softening point temperatures, were added into MgO-Al_2O_3-SiO_2/boron phenol formaldehyde resin（MAS/BPF） compos...Fluxing agents of zinc borate, antimony oxide, galss frit A and glass frit B, with different melting or softening point temperatures, were added into MgO-Al_2O_3-SiO_2/boron phenol formaldehyde resin（MAS/BPF） composites to lower the formation temperature of eutectic liquid phase and promote the ceramification of ceramifiable composites. The effects of fluxing agents on the thermogravimetric properties, phase evolution, and microstructure evolution of MAS/BPF composites were characterized by TG-DSC, XRD and SEM analyses. The results reveal that the addition of a fluxing agent highly reduces the decomposition rate of MAS/BPF composites. Fluxing agents lower the formation temperatures of liquid phases of ceramifiable MAS/BPF composites obviously, and then promote the ceramification and densification process. The final residues of composites are ceramic surrounded by large amount of glass phases.展开更多
Waste glass fibers were used as the main raw materials to prepare foamed glass-ceramics with 0-14 wt%H_(3)BO_(3)as a flux agent.The effects of H_(3)BO_(3)on the crystallization process,foaming behavior,and physical pr...Waste glass fibers were used as the main raw materials to prepare foamed glass-ceramics with 0-14 wt%H_(3)BO_(3)as a flux agent.The effects of H_(3)BO_(3)on the crystallization process,foaming behavior,and physical properties of CaO-MgO-Al_(2)O_(3)-SiO_(2)foamed glass-ceramics were investigated.The results showed that the main crystalline phase of the foamed glass-ceramics was anorthite with diopside as a minor crystalline phase,which exhibited a typical surface crystallization process.The addition of H_(3)BO_(3)modified the surface of glass powders and inhibited crystal precipitation obviously.The low melting point of H_(3)BO_(3)and the decrease of crystallinity jointly promoted the growth of pores,resulting in a reduction of bulk density and an increase in porosity.The compressive strength and thermal conductivity of the samples were linearly related to the bulk density.In particular,the sample added with 10 wt%H_(3)BO_(3)exhibited excellent properties,possessing a low coefficient of thermal conductivity 0.081 W/(m·K)and relatively high compressive strength 3.36 MPa.展开更多
文摘Fluxing agents of zinc borate, antimony oxide, galss frit A and glass frit B, with different melting or softening point temperatures, were added into MgO-Al_2O_3-SiO_2/boron phenol formaldehyde resin（MAS/BPF） composites to lower the formation temperature of eutectic liquid phase and promote the ceramification of ceramifiable composites. The effects of fluxing agents on the thermogravimetric properties, phase evolution, and microstructure evolution of MAS/BPF composites were characterized by TG-DSC, XRD and SEM analyses. The results reveal that the addition of a fluxing agent highly reduces the decomposition rate of MAS/BPF composites. Fluxing agents lower the formation temperatures of liquid phases of ceramifiable MAS/BPF composites obviously, and then promote the ceramification and densification process. The final residues of composites are ceramic surrounded by large amount of glass phases.
基金Funded by Shandong Provincial Youth Innovation Team Development Plan of Colleges and Universities(No.2022KJ100)National Natural Science Foundation of China(No.52172019)。
文摘Waste glass fibers were used as the main raw materials to prepare foamed glass-ceramics with 0-14 wt%H_(3)BO_(3)as a flux agent.The effects of H_(3)BO_(3)on the crystallization process,foaming behavior,and physical properties of CaO-MgO-Al_(2)O_(3)-SiO_(2)foamed glass-ceramics were investigated.The results showed that the main crystalline phase of the foamed glass-ceramics was anorthite with diopside as a minor crystalline phase,which exhibited a typical surface crystallization process.The addition of H_(3)BO_(3)modified the surface of glass powders and inhibited crystal precipitation obviously.The low melting point of H_(3)BO_(3)and the decrease of crystallinity jointly promoted the growth of pores,resulting in a reduction of bulk density and an increase in porosity.The compressive strength and thermal conductivity of the samples were linearly related to the bulk density.In particular,the sample added with 10 wt%H_(3)BO_(3)exhibited excellent properties,possessing a low coefficient of thermal conductivity 0.081 W/(m·K)and relatively high compressive strength 3.36 MPa.
