Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression an...Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.展开更多
Hydraulic fracturing technology has played an important role in the exploitation of unconventional oil and gas resources,however,its application to gas hydrate reservoirs has been rarely studied.Currently,there is sti...Hydraulic fracturing technology has played an important role in the exploitation of unconventional oil and gas resources,however,its application to gas hydrate reservoirs has been rarely studied.Currently,there is still limited understanding of the propagation and extension of fractures around the wellbore during the fracturing process of horizontal wells in hydrate reservoirs,as well as the stress interference patterns between fractures.This study simulates hydraulic fracturing processes in hydrate reservoirs using a fluidsolid coupling discrete element method(DEM),and analyzes the impacts of hydrate saturation and geological and engineering factors on fracture extension and stress disturbance.The results show that hydraulic fracturing is more effective when hydrate saturation exceeds 30%and that fracture pressure increases with saturation.The increase in horizontal stress differential enhances the directionality of fracture propagation and reduces stress disturbance.The distribution uniformity index(DUI)reveals that injection pressure is directly proportional to the number of main fractures and inversely proportional to fracturing time,with fracturing efficiency depending on the spacing between injection points and the distance between wells.This work may provide reference for the commercial exploitation of natural gas hydrates.展开更多
Deep underground excavation causes considerable unloading effects,leading to a pronounced bias pressure phenomenon.The deformation and seepage characteristics of rock masses under different gas and confining pressures...Deep underground excavation causes considerable unloading effects,leading to a pronounced bias pressure phenomenon.The deformation and seepage characteristics of rock masses under different gas and confining pressures were investigated via triaxial loading and unloading seepage tests.When the influential coefficient of effective confining pressure(β)is less than 0.065,the seepage force considerably weakens the strength of fractured rock masses.Conversely,whenβis greater than 0.065,the opposite is true.Moreover,the increase in the axial load leads to an increase in the precast fracture volumetric strain,which is the main reason for the increase in fracture permeability.This effect is particularly significant during the unloading stage.Based on the test results,a method for calculating the dynamic seepage evolution of rock masses,considering the effects of rock mass damage and fracture deformation,is introduced,and the effectiveness of the calculation is validated.The entire description of the seepage under loading and unloading was accomplished.The equivalent relationship between the lateral and normal stresses on fracture surfaces ranges from 0.001 to 0.1,showing an exponential variation between the lateral stress influence coefficient on normal deformation(χ)and seepage pressure.Before the failure of the rock mass,the seepage in the fractures was in a linear laminar flow state.However,after the failure,when the gas pressure reached 2 MPa,the flow state in the fractures transitioned to nonlinear laminar flow.The results are important for predicting hazardous gas leaks during deep underground engineering excavation.展开更多
In the context of global warming and intensified human activities,glacier instability in plateau regions has increased,and glacier debris flows have become active,which poses a significant threat to the lives and prop...In the context of global warming and intensified human activities,glacier instability in plateau regions has increased,and glacier debris flows have become active,which poses a significant threat to the lives and property of people and socioeconomic development.The mass movement process of glacier debris flows is extremely complex,so this paper uses the 2018 Sedongpu glacier debris flow event on the Qinghai-Tibet Plateau as an example and applies a numerical simulation method to invert the whole process of mass movement.In view of the interaction between phases in the process of motion,we use the fluid-solid coupling method to describe the mass movement.The granular-flow model and drift-flux model are employed in FLOW3D software to study the mass movement process of glacier debris flows and explore their dynamic characteristics.The results indicate that the glacier debris flow lasted for 700 s,and the movement process was roughly divided into four stages,including initiation,scraping,surging and deposition;the depositional characteristics calculated by the fluid-solid coupling model are consistent with the actual survey results and have good reliability;strong erosion occurs during the mass movement,the clear volume amplification effect,and the first wave climbs 17.8 m across the slope.The fluid-solid coupling method can better simulate glacier debris flows in plateau regions,which is helpful for the study of the mechanism and dynamic characteristics of such disasters.展开更多
The spatiotemporal distribution characteristics of the regression rate are crucial aspects of the research on Hybrid Rocket Motor(HRM). This study presents a pioneering effort in achieving a comprehensive numerical si...The spatiotemporal distribution characteristics of the regression rate are crucial aspects of the research on Hybrid Rocket Motor(HRM). This study presents a pioneering effort in achieving a comprehensive numerical simulation of fluid dynamics and heat transfer in both the fluid and solid regions throughout the entire operation of an HRM. To accomplish this, a dynamic grid technique that incorporates fluid–solid coupling is utilized. To validate the precision of the numerical simulations, a firing test is conducted, with embedded thermocouple probes being used to measure the inner temperature of the fuel grain. The temperature variations in the solid fuel obtained from both experiment and simulations show good agreement. The maximum combustion temperature and average thrust obtained from the simulations are found to deviate from the experimental results by only 3.3% and 2.4%, respectively. Thus, it can be demonstrated that transient numerical simulations accurately capture the fluid–solid coupling characteristics and transient regression rate. The dynamic simulation results of inner flow field and solid region throughout the entire working stage reveal that the presence of vortices enhances the blending of combustion gases and improves the regression rate at both the front and rear ends of the fuel grain. In addition, oscillations of the regression rate obtained in the simulation can also be well corresponded with the corrugated surface observed in the experiment. Furthermore, the zero-dimension regression rate formula and the formula describing the axial location dependence of the regression rate are fitted from the simulation results, with the corresponding coefficients of determination(R^(2)) of 0.9765 and 0.9298, respectively.This research serves as a reference for predicting the performance of HRM with gas oxygen and polyethylene, and presents a credible way for investigating the spatiotemporal distribution of the regression rate.展开更多
The fluid-solid coupling theory, an interdisciplinary science between hydrodynamics and solid mechanics, is an important tool for response analysis and direct design of structures in naval architecture and ocean engin...The fluid-solid coupling theory, an interdisciplinary science between hydrodynamics and solid mechanics, is an important tool for response analysis and direct design of structures in naval architecture and ocean engineering. By applying the corresponding relations between generalized forces and generalized displacements, convolutions were performed between the basic equations of elasto-dynamics in the primary space and corresponding virtual quantities. The results were integrated and then added algebraically. In light of the fact that body forces and surface forces are both follower forces, the generalized quasi-complementary energy principle with two kinds of variables for an initial value problem is established in non-conservative systems. Using the generalized quasi-complementary energy principle to deal with the fluid-solid coupling problem and to analyze the dynamic response of structures, a method for using two kinds of variables simultaneously for calculation of force and displacement was derived.展开更多
Abstract： A joint solution model of variabk：-mass flow in two-phase region and fluid-solid coupling heat transfer, concerned about the charge process of variable-mass thermodynamic system, is built up and calculated...Abstract： A joint solution model of variabk：-mass flow in two-phase region and fluid-solid coupling heat transfer, concerned about the charge process of variable-mass thermodynamic system, is built up and calculated by the finite element method （FEM）. The results are basically consistent with relative experimental data. The calculated average heat transfer coefficient reaches 1.7~105 W/（m2. K）. When the equal percentage valve is used, the system needs the minimum requirements of valve control, but brings the highest construction cost. With the： decrease of initial steam pressure, the heat transfer intensity also weakens but the steam flow increases. With the initial water filling coefficient increasing or the temperature of steam supply decreasing, the amount of accumulative steam flow increases with the growth of steam pressure. When the pressure of steam supply drops, the steam flow gradient increases during the maximum opening period of control valve, and causes the maximum steam flow to increase.展开更多
Due to their potential properties unlike traditional materials and structures,elastic wave metamaterials have received significant interests in recent years.With the coupling between the acoustic and vibration,their m...Due to their potential properties unlike traditional materials and structures,elastic wave metamaterials have received significant interests in recent years.With the coupling between the acoustic and vibration,their mechanical characteristics can be tuned by the active feedback control system at low frequency ranges in which the traditional passive control is limited.This work illustrates that the superior performances of the effective mass density and sound pressure level(SPL)of an elastic wave metamaterial can be significantly changed by the active control,in which the periodic array of local resonators and orthogonal stiffeners are included.Significantly,based on the locally resonant mechanism,the negative density occurs over a frequency range.Due to the effects of lattice constant,structural damping and other parameters,the SPL with the function of fluid-solid coupling are illustrated and discussed.展开更多
The process of contaminant transport is a problem of multicomponent and multiphase flow in unsaturated zone. Under the presupposition that gas existence affects water transport, a coupled mathematical model of contami...The process of contaminant transport is a problem of multicomponent and multiphase flow in unsaturated zone. Under the presupposition that gas existence affects water transport, a coupled mathematical model of contaminant transport in unsaturated zone has been established based on fluid_solid interaction mechanics theory. The asymptotical solutions to the nonlinear coupling mathematical model were accomplished by the perturbation and integral transformation method. The distribution law of pore pressure, pore water velocity and contaminant concentration in unsaturated zone has been presented under the conditions of with coupling and without coupling gas phase. An example problem was used to provide a quantitative verification and validation of the model. The asymptotical solution was compared with Faust model solution. The comparison results show reasonable agreement between asymptotical solution and Faust solution, and the gas effect and media deformation has a large impact on the contaminant transport. The theoretical basis is provided for forecasting contaminant transport and the determination of the relationship among pressure_saturation_permeability in laboratory.展开更多
As the oil or gas exploration and development activities in deep and ultra- deep waters become more and more, encountering gas hydrate bearing sediments （HBS） is almost inevitable. The variation in temperature and p...As the oil or gas exploration and development activities in deep and ultra- deep waters become more and more, encountering gas hydrate bearing sediments （HBS） is almost inevitable. The variation in temperature and pressure can destabilize gas hydrate in nearby formation around the borehole, which may reduce the strength of the formation and result in wellbore instability. A non-isothermal, transient, two-phase, and fluid-solid coupling mathematical model is proposed to simulate the complex stability performance of a wellbore drilled in HBS. In the model, the phase transition of hydrate dissociation, the heat exchange between drilling fluid and formation, the change of mechanical and petrophysical properties, the gas-water two-phase seepage, and its interaction with rock deformation are considered. A finite element simulator is developed, and the impact of drilling mud on wellbore instability in HBS is simulated. Results indicate that the re- duction in pressure and the increase in temperature of the drilling fluid can accelerate hydrate decomposition and lead to mechanical properties getting worse tremendously. The cohesion decreases by 25% when the hydrate totally dissociates in HBS. This easily causes the wellbore instability accordingly. In the first two hours after the formation is drilled, the regions of hydrate dissociation and wellbore instability extend quickly. Then, with the soaking time of drilling fluid increasing, the regions enlarge little. Choosing the low temperature drilling fluid and increasing the drilling mud pressure appropriately can benefit the wellbore stability of HBS. The established model turns out to be an efficient tool in numerical studies of the hydrate dissociation behavior and wellbore stability of HBS.展开更多
Hydroformed parts are widely used in industrial automotive parts because of their higher stiffness and fatigue strength and reduced weight relative to their corresponding cast and welded parts.This paper reports a hyd...Hydroformed parts are widely used in industrial automotive parts because of their higher stiffness and fatigue strength and reduced weight relative to their corresponding cast and welded parts.This paper reports a hydraulicforming experimental platform for rectangular tube fittings that was constructed to conduct an experiment on the hydraulic forming of rectangular tube fittings.A finite element model was established on the basis of the fluid–solid coupling method and simulation analysis.The correctness of the simulation analysis and the feasibility of the fluid–solid coupling method for hydraulic forming simulation analysis were verified by comparing the experimental results with the simulation results.On the basis of the simulation analysis of the hydraulic process of the torsion beam using the fluid–solid coupling method,a sliding mold suitable for the hydroforming of torsion beams was designed for its structural characteristics.The effects of fluid characteristics,shaping pressure,axial feed rate,and friction coefficient on the wall thicknesses of torsions beams during formation were investigated.Fluid movement speed was related to tube deformation.Shaping pressure had a significant effect on rounded corners and straight edges.The axial feed speed was increased,and the uneven distribution of wall thicknesses was effectively improved.Although the friction coefficient had a nonsignificant effect on the wall thickness of the ladder-shaped region,it had a significant influence on a large deformation of wall thickness in the V-shaped area.In this paper,a method of fluid-solid coupling simulation analysis and sliding die is proposed to study the high pressure forming law in torsion beam.展开更多
About 75% water-inrush accidents in China are caused by geological structure such as faults, therefore, it is necessary to investigate the water-inrush mechanism of faults to provide references for the mining activity...About 75% water-inrush accidents in China are caused by geological structure such as faults, therefore, it is necessary to investigate the water-inrush mechanism of faults to provide references for the mining activity above confined water. In this paper, based on the fluid-solid coupling theory, we built the stress-seepage coupling model for rock, then we combined with an example of water-inrush caused by fault, studied the water-inrush mechanism by using the numerical software COMSOL Mutiphysics, analyzed the change rule of shear stress, vertical stress, plastic area and water pressure for stope with a fault, and estimated the water-inrush risk at the different distances between working faces and the fault. The numerical simula- tion results indicate that： （1） the water-inrush risk will grow as the decrease of the distance between working face and the fault; （2） the failure mode of the rock in floor with fault is shear failure; （3） the rock between water-containing fault and working face failure is the reason for water-inrush.展开更多
The double flapper-nozzle servo valve is widely used to launch and guide the equipment. Due to the large instantaneous flow rate of servo valve working under specific operating conditions, the temperature of servo val...The double flapper-nozzle servo valve is widely used to launch and guide the equipment. Due to the large instantaneous flow rate of servo valve working under specific operating conditions, the temperature of servo valve would reach 120℃ and the valve core and valve sleeve deform in a short amount of time. So the control precision of servo valve significantly decreases and the clamping stagnation phenomenon of valve core appears. In order to solve the problem of degraded control accuracy and clamping stagnation of servo valve under large temperature difference circumstance, the numerical simulation of heat-fluid-solid coupling by using finite element method is done. The simulation result shows that zero position leakage of servo valve is basically impacted by oil temperature and change of fit clearance. The clamping stagnation is caused by warpage-deformation and fit clearance reduction of the valve core and valve sleeve. The distribution roles of the temperature and thermal-deformation of shell, valve core and valve sleeve and the pressure, velocity and temperature field of flow channel are also analyzed. Zero position leakage and electromagnet＇s current when valve core moves in full-stroke are tested using Electro-hydraulic Servo-valve Characteristic Test-bed of an aerospace sciences and technology corporation. The experimental results show that the change law of experimental current at different oil temperatures is roughly identical to simulation current. The current curve of the electromagnet is smooth when oil temperature is below 80℃, but the amplitude of current significantly increases and the hairy appears when oil temperature is above 80℃. The current becomes smooth again after the warped valve core and valve sleeve are reground. It indicates that clamping stagnation is caused by warpage-deformation and fit clearance reduction of valve core and valve sleeve. This paper simulates and tests the heat-fluid-solid coupling of double flapper-nozzle servo valve, and the obtained results provide the reference value for the design of double flapper-nozzle force feedback servo valve.展开更多
Aiming at the synergistic rock-breaking mechanism of supercritical carbon dioxide(SC-CO_(2))jet pressure and tem-perature difference,a heat-fluid-solid calculation model of rock-breaking stress was established and ver...Aiming at the synergistic rock-breaking mechanism of supercritical carbon dioxide(SC-CO_(2))jet pressure and tem-perature difference,a heat-fluid-solid calculation model of rock-breaking stress was established and verified to be effective,and the variations of jet flow field and rock stress with jet standoff distance of SC-CO_(2),water and nitrogen were studied.With the increase of jet standoff distance,the jet pressure of SC-CO_(2) decreases and the jet temperature difference increases.The SC-CO_(2) jet is higher in pressure than the nitrogen jet and differs little from the water jet.Temperature difference of SC-CO_(2) jet is 5 times that of water jet and more than 2.5 ti mes that of nitrogen jet when the jet standoff distance is larger than 10.The tem-perature stress is the main reason why SC-CO_(2) jet is superior to water and nitrogen jets in rock-breaking.The rock under the SC-CO_(2) jet has greater rock stress,effective rock-breaking jet standoff distance and rock-breaking area.The jet pressure plays a major role in rock-breaking when the jet standoff distance is small,while the jet temperature difference plays a major role in rock-breaking when the jet standoff distance is large.The SC-CO_(2) jet is an efficient volume rock-breaking method,which results in tensile and shear failure on the rock surface under short time jet and large area tensile failure inside the rock simultaneously under long time jet.展开更多
The seismic response characteristics of underground structures in saturated soils are investigated.A fully fluid-solid coupling dynamic model is developed and implemented into ABAQUS with a user-defined element to sim...The seismic response characteristics of underground structures in saturated soils are investigated.A fully fluid-solid coupling dynamic model is developed and implemented into ABAQUS with a user-defined element to simulate the dynamic behavior of saturated soils.The accuracy of the model is validated using a classic example in literature.The performance of the model is verified by its application on simulating the seismic response characteristics of a subway station built in saturated soils.The merits of the model are demonstrated by comparing the difference of the seismic response of an underground structure in saturated soils between using the fully coupling model and a single-phase medium model.The study finds that the fully coupling model developed herein can simulate the dynamic response characteristics of the underground structures in saturated soils with high accuracy.The seismic response of the underground structure tends to be underestimated by using the single-phase medium model compared with using the fully coupling model,which provides a weaker confining action to the underground structure.展开更多
Improving the absorbed gas to active desorption and seepage and delaying gas drainage attenuation are considered as key methods for increasing drainage efficiency and gas output.According to the solid mechanics theory...Improving the absorbed gas to active desorption and seepage and delaying gas drainage attenuation are considered as key methods for increasing drainage efficiency and gas output.According to the solid mechanics theory,the nonlinear Darcy seepage theory and thermodynamics,the heat-fluid-solid coupling model for gassy coal has been improved.The numerical model was founded from the improved multi-field coupling model by COMSOL Multiphysics and gas drainage by borehole down the coal seam enhanced by heat injection was modelled.The results show that the heatfluid-solid model with adsorption effects for gassy coal was well simulated by the improved multi-field model.The mechanism of coal seam gas desorption seepage under the combined action of temperature,stress and adsorption can be well described.Gas desorption and seepage can be enhanced by heat injection into coal seams.The gas drainage rate was directly proportional to the temperature of injected heat in the scope of 30-150 ℃ and increasing in the whole modelleddrainage process (0-1000 d).The increased level was maximum in the initial drainage time and decreasing gradually along with drainage time.The increasing ratio of drainage rate was maximum when the temperature raised from 30 to 60 ℃.Although the drainage rate would increase along with increasing temperature,when exceeding 60 ℃,the increasing ratio of drainage rate with rising temperature would decrease.Gas drainage promotion was more effective in coal seams with lower permeability than with higher permeability.The coal seam temperature in a 5 m distance surrounding the heat injection borehole would rise to around 60 ℃ in 3 months.That was much less than the time of gas drainage in the coal mines in sites with low permeability coal seams.Therefore,it is valuable and feasible to inject heat into coal seams to promote gas drainage,and this has strong feasibility for coal seams with low permeability which are widespread in China.展开更多
To study the behavior of overlying strata and the likelihood of water inrush and quicksand with different mining sequences under an unconsolidated alluvium aquifer, a numerical model based on the fluid-solid coupling ...To study the behavior of overlying strata and the likelihood of water inrush and quicksand with different mining sequences under an unconsolidated alluvium aquifer, a numerical model based on the fluid-solid coupling theory was con- structed by FLAC3D. Simulation results revealed that the mining sequences had a significant influence on the seepage, dis- placement and failure characteristics of the overlying strata. In this kind of geological and hydrogeological conditions, the workface close to the outcrop of coal seam easily suffers from water inrush and quicksand during mining. In the simulation re- sults, the plastic zone, vertical displacement and pore water pressure in the overlying strata of the workface decrease more or less using the upward mining sequence than using the downward mining sequence. Therefore, the application of the upward mining sequence in the process of mining is preferential to prevent water inrush and quicksand.展开更多
In this paper,the cores of outcropped black shale of Lower Silurian Longmaxi Fm in the Yibin area,Sichuan Basin,were taken as samples to investigate the effects of extraneous water on shale mechanics and seepage laws ...In this paper,the cores of outcropped black shale of Lower Silurian Longmaxi Fm in the Yibin area,Sichuan Basin,were taken as samples to investigate the effects of extraneous water on shale mechanics and seepage laws during the production of shale gas reservoirs.Firstly,the development of fractures in water saturated cores was observed by using a VHX-5000 optical superdepth microscope.Secondly,water,formation water and slick water,as well as the damage form and compression strength of water saturated/unsaturated cores were investigated by means of a uniaxial compression testing machine and a strain testing&analysis system.Finally,the effects of fluid-solid coupling on shale gas flowing performance in different water saturations were analyzed by using a DYQ-1 multi-function displacement device.Analysis on core components shows that the Longmaxi shale is a highly crushable reservoir with a high content of fragile minerals,so fracturing stimulation is suitable for it.Shale compression strength test reveals that the effects of deionized water,formation water and slick water on shale are different,so the compression strength of shale before being saturated is quite different from that after being saturated.Due to the existence of water,the compression strength of shale drops,so the shale can be fractured easily,more fractures are generated and thus its seepage capacity is improved.Experiments on shale gas seepage under different water saturations show that under the condition of fluid-solid coupling,the higher the water saturation is,the better the propagation and seepage capacity of micro-fractures in shale under the effect of pressure.To sum up,the existence of water is beneficial to fracturing stimulation of shale gas reservoirs and helps to achieve the goal of production improvement.展开更多
Micro-disturbance grouting is a recovery technique to reduce the excessive deformation of operational shield tunnels in urban areas.The grout mass behaves as a fluid in the ground before hardening to form a grout–soi...Micro-disturbance grouting is a recovery technique to reduce the excessive deformation of operational shield tunnels in urban areas.The grout mass behaves as a fluid in the ground before hardening to form a grout–soil mixture,which highlights the necessity of using fluid–solid coupling method in the simulation of grouting process.Within a discrete element modeling environment,this paper proposes a novel fluid-solid coupling method based on the pore density flow calculation.To demonstrate the effectiveness of this method,it is applied to numerical simulation of micro-disturbance grouting process for treatment of large transverse deformation of a shield tunnel in Shanghai Metro,China.The simulation results reveal the mechanism of recovering tunnel convergence by micro-disturbance grouting in terms of compaction and fracture of soil,energy analysis during grouting,and mechanical response of soil-tunnel interaction system.Furthermore,the influence of the three main grouting parameters(i.e.,grouting pressure,grouting distance,and grouting height)on tunnel deformation recovery efficiency is evaluated through parametric analysis.In order to efficiently recover large transverse deformation of shield tunnel in Shanghai Metro,it is suggested that the grouting pressure should be about 0.55 MPa,the grouting height should be in the range of 6.2–7.0 m,and the grouting distance should be in the range of 3.0–3.6 m.The results provide a valuable reference for grouting treatment projects of over-deformed shield tunnel in soft soil areas.展开更多
Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,how...Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.42272153 and 42472195)the Research Fund of PetroChina Tarim Oilfield Company(No.671023060003)the Research Fund of China National Petroleum Corporation Limited(No.2023ZZ16YJ04).
文摘Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.
基金financially supported by the National Key Research and Development Plan(2023YFC2811001)the National Natural Science Foundation of China(42206233)the Taishan Scholars Program(tsqn202312280,tsqn202306297)。
文摘Hydraulic fracturing technology has played an important role in the exploitation of unconventional oil and gas resources,however,its application to gas hydrate reservoirs has been rarely studied.Currently,there is still limited understanding of the propagation and extension of fractures around the wellbore during the fracturing process of horizontal wells in hydrate reservoirs,as well as the stress interference patterns between fractures.This study simulates hydraulic fracturing processes in hydrate reservoirs using a fluidsolid coupling discrete element method(DEM),and analyzes the impacts of hydrate saturation and geological and engineering factors on fracture extension and stress disturbance.The results show that hydraulic fracturing is more effective when hydrate saturation exceeds 30%and that fracture pressure increases with saturation.The increase in horizontal stress differential enhances the directionality of fracture propagation and reduces stress disturbance.The distribution uniformity index(DUI)reveals that injection pressure is directly proportional to the number of main fractures and inversely proportional to fracturing time,with fracturing efficiency depending on the spacing between injection points and the distance between wells.This work may provide reference for the commercial exploitation of natural gas hydrates.
基金supported by the National Natural Science Foundation of China(Grant No.52374079)Chongqing Graduate Research Innovation Project(Grant No.CYB22032)Chongqing Talents and Outstanding Scientists Project(Grant No.cstc2024ycjhbgzxm0032).
文摘Deep underground excavation causes considerable unloading effects,leading to a pronounced bias pressure phenomenon.The deformation and seepage characteristics of rock masses under different gas and confining pressures were investigated via triaxial loading and unloading seepage tests.When the influential coefficient of effective confining pressure(β)is less than 0.065,the seepage force considerably weakens the strength of fractured rock masses.Conversely,whenβis greater than 0.065,the opposite is true.Moreover,the increase in the axial load leads to an increase in the precast fracture volumetric strain,which is the main reason for the increase in fracture permeability.This effect is particularly significant during the unloading stage.Based on the test results,a method for calculating the dynamic seepage evolution of rock masses,considering the effects of rock mass damage and fracture deformation,is introduced,and the effectiveness of the calculation is validated.The entire description of the seepage under loading and unloading was accomplished.The equivalent relationship between the lateral and normal stresses on fracture surfaces ranges from 0.001 to 0.1,showing an exponential variation between the lateral stress influence coefficient on normal deformation(χ)and seepage pressure.Before the failure of the rock mass,the seepage in the fractures was in a linear laminar flow state.However,after the failure,when the gas pressure reached 2 MPa,the flow state in the fractures transitioned to nonlinear laminar flow.The results are important for predicting hazardous gas leaks during deep underground engineering excavation.
基金supported by the National Natural Science Foundation of China(Nos.U20A20111,41977229)the Sichuan Youth Science and Technology Innovation Research Team Project(No.2020JDTD0006).
文摘In the context of global warming and intensified human activities,glacier instability in plateau regions has increased,and glacier debris flows have become active,which poses a significant threat to the lives and property of people and socioeconomic development.The mass movement process of glacier debris flows is extremely complex,so this paper uses the 2018 Sedongpu glacier debris flow event on the Qinghai-Tibet Plateau as an example and applies a numerical simulation method to invert the whole process of mass movement.In view of the interaction between phases in the process of motion,we use the fluid-solid coupling method to describe the mass movement.The granular-flow model and drift-flux model are employed in FLOW3D software to study the mass movement process of glacier debris flows and explore their dynamic characteristics.The results indicate that the glacier debris flow lasted for 700 s,and the movement process was roughly divided into four stages,including initiation,scraping,surging and deposition;the depositional characteristics calculated by the fluid-solid coupling model are consistent with the actual survey results and have good reliability;strong erosion occurs during the mass movement,the clear volume amplification effect,and the first wave climbs 17.8 m across the slope.The fluid-solid coupling method can better simulate glacier debris flows in plateau regions,which is helpful for the study of the mechanism and dynamic characteristics of such disasters.
基金supported by the National Natural Science Foundation of China (No.U20B2034).
文摘The spatiotemporal distribution characteristics of the regression rate are crucial aspects of the research on Hybrid Rocket Motor(HRM). This study presents a pioneering effort in achieving a comprehensive numerical simulation of fluid dynamics and heat transfer in both the fluid and solid regions throughout the entire operation of an HRM. To accomplish this, a dynamic grid technique that incorporates fluid–solid coupling is utilized. To validate the precision of the numerical simulations, a firing test is conducted, with embedded thermocouple probes being used to measure the inner temperature of the fuel grain. The temperature variations in the solid fuel obtained from both experiment and simulations show good agreement. The maximum combustion temperature and average thrust obtained from the simulations are found to deviate from the experimental results by only 3.3% and 2.4%, respectively. Thus, it can be demonstrated that transient numerical simulations accurately capture the fluid–solid coupling characteristics and transient regression rate. The dynamic simulation results of inner flow field and solid region throughout the entire working stage reveal that the presence of vortices enhances the blending of combustion gases and improves the regression rate at both the front and rear ends of the fuel grain. In addition, oscillations of the regression rate obtained in the simulation can also be well corresponded with the corrugated surface observed in the experiment. Furthermore, the zero-dimension regression rate formula and the formula describing the axial location dependence of the regression rate are fitted from the simulation results, with the corresponding coefficients of determination(R^(2)) of 0.9765 and 0.9298, respectively.This research serves as a reference for predicting the performance of HRM with gas oxygen and polyethylene, and presents a credible way for investigating the spatiotemporal distribution of the regression rate.
基金Supported by the National Natural Science Foundation under Grant No.10272034the Doctoral Education Foundation under Grant No.20060217020
文摘The fluid-solid coupling theory, an interdisciplinary science between hydrodynamics and solid mechanics, is an important tool for response analysis and direct design of structures in naval architecture and ocean engineering. By applying the corresponding relations between generalized forces and generalized displacements, convolutions were performed between the basic equations of elasto-dynamics in the primary space and corresponding virtual quantities. The results were integrated and then added algebraically. In light of the fact that body forces and surface forces are both follower forces, the generalized quasi-complementary energy principle with two kinds of variables for an initial value problem is established in non-conservative systems. Using the generalized quasi-complementary energy principle to deal with the fluid-solid coupling problem and to analyze the dynamic response of structures, a method for using two kinds of variables simultaneously for calculation of force and displacement was derived.
基金Project(20080431380) supported by China Postdoctoral Science Foundation
文摘Abstract： A joint solution model of variabk：-mass flow in two-phase region and fluid-solid coupling heat transfer, concerned about the charge process of variable-mass thermodynamic system, is built up and calculated by the finite element method （FEM）. The results are basically consistent with relative experimental data. The calculated average heat transfer coefficient reaches 1.7~105 W/（m2. K）. When the equal percentage valve is used, the system needs the minimum requirements of valve control, but brings the highest construction cost. With the： decrease of initial steam pressure, the heat transfer intensity also weakens but the steam flow increases. With the initial water filling coefficient increasing or the temperature of steam supply decreasing, the amount of accumulative steam flow increases with the growth of steam pressure. When the pressure of steam supply drops, the steam flow gradient increases during the maximum opening period of control valve, and causes the maximum steam flow to increase.
基金the supports by the National Natural Science Foundation of China(Grants 11922209,11991031 and 12021002)for this research work.
文摘Due to their potential properties unlike traditional materials and structures,elastic wave metamaterials have received significant interests in recent years.With the coupling between the acoustic and vibration,their mechanical characteristics can be tuned by the active feedback control system at low frequency ranges in which the traditional passive control is limited.This work illustrates that the superior performances of the effective mass density and sound pressure level(SPL)of an elastic wave metamaterial can be significantly changed by the active control,in which the periodic array of local resonators and orthogonal stiffeners are included.Significantly,based on the locally resonant mechanism,the negative density occurs over a frequency range.Due to the effects of lattice constant,structural damping and other parameters,the SPL with the function of fluid-solid coupling are illustrated and discussed.
文摘The process of contaminant transport is a problem of multicomponent and multiphase flow in unsaturated zone. Under the presupposition that gas existence affects water transport, a coupled mathematical model of contaminant transport in unsaturated zone has been established based on fluid_solid interaction mechanics theory. The asymptotical solutions to the nonlinear coupling mathematical model were accomplished by the perturbation and integral transformation method. The distribution law of pore pressure, pore water velocity and contaminant concentration in unsaturated zone has been presented under the conditions of with coupling and without coupling gas phase. An example problem was used to provide a quantitative verification and validation of the model. The asymptotical solution was compared with Faust model solution. The comparison results show reasonable agreement between asymptotical solution and Faust solution, and the gas effect and media deformation has a large impact on the contaminant transport. The theoretical basis is provided for forecasting contaminant transport and the determination of the relationship among pressure_saturation_permeability in laboratory.
基金supported by the Major National Science and Technology Program(Nos.2008ZX05026-00411 and 2011ZX05026-004-08)the Program for Changjiang Scholars and Innovative Research Team in University(No.RT1086)
文摘As the oil or gas exploration and development activities in deep and ultra- deep waters become more and more, encountering gas hydrate bearing sediments （HBS） is almost inevitable. The variation in temperature and pressure can destabilize gas hydrate in nearby formation around the borehole, which may reduce the strength of the formation and result in wellbore instability. A non-isothermal, transient, two-phase, and fluid-solid coupling mathematical model is proposed to simulate the complex stability performance of a wellbore drilled in HBS. In the model, the phase transition of hydrate dissociation, the heat exchange between drilling fluid and formation, the change of mechanical and petrophysical properties, the gas-water two-phase seepage, and its interaction with rock deformation are considered. A finite element simulator is developed, and the impact of drilling mud on wellbore instability in HBS is simulated. Results indicate that the re- duction in pressure and the increase in temperature of the drilling fluid can accelerate hydrate decomposition and lead to mechanical properties getting worse tremendously. The cohesion decreases by 25% when the hydrate totally dissociates in HBS. This easily causes the wellbore instability accordingly. In the first two hours after the formation is drilled, the regions of hydrate dissociation and wellbore instability extend quickly. Then, with the soaking time of drilling fluid increasing, the regions enlarge little. Choosing the low temperature drilling fluid and increasing the drilling mud pressure appropriately can benefit the wellbore stability of HBS. The established model turns out to be an efficient tool in numerical studies of the hydrate dissociation behavior and wellbore stability of HBS.
基金Natural Science Foundation of China(Grant No.81960332)Guangxi Provincial Innovation driven Development Project(Grant No.GKAA17204062)+1 种基金Guangxi Provincial Natural Science Foundation(Grant No.2016GXNSFAA380211)Liuzhou Municipal Scientific Research and Technology Development Plan(Grant No.2016C050203)。
文摘Hydroformed parts are widely used in industrial automotive parts because of their higher stiffness and fatigue strength and reduced weight relative to their corresponding cast and welded parts.This paper reports a hydraulicforming experimental platform for rectangular tube fittings that was constructed to conduct an experiment on the hydraulic forming of rectangular tube fittings.A finite element model was established on the basis of the fluid–solid coupling method and simulation analysis.The correctness of the simulation analysis and the feasibility of the fluid–solid coupling method for hydraulic forming simulation analysis were verified by comparing the experimental results with the simulation results.On the basis of the simulation analysis of the hydraulic process of the torsion beam using the fluid–solid coupling method,a sliding mold suitable for the hydroforming of torsion beams was designed for its structural characteristics.The effects of fluid characteristics,shaping pressure,axial feed rate,and friction coefficient on the wall thicknesses of torsions beams during formation were investigated.Fluid movement speed was related to tube deformation.Shaping pressure had a significant effect on rounded corners and straight edges.The axial feed speed was increased,and the uneven distribution of wall thicknesses was effectively improved.Although the friction coefficient had a nonsignificant effect on the wall thickness of the ladder-shaped region,it had a significant influence on a large deformation of wall thickness in the V-shaped area.In this paper,a method of fluid-solid coupling simulation analysis and sliding die is proposed to study the high pressure forming law in torsion beam.
基金Supported by the National Basic Research Program of China （2010CB226800） the National Natural Science Foundation of China （50904065） the Program for New Century Excellent Talents in University （NCET-09-0728）
文摘About 75% water-inrush accidents in China are caused by geological structure such as faults, therefore, it is necessary to investigate the water-inrush mechanism of faults to provide references for the mining activity above confined water. In this paper, based on the fluid-solid coupling theory, we built the stress-seepage coupling model for rock, then we combined with an example of water-inrush caused by fault, studied the water-inrush mechanism by using the numerical software COMSOL Mutiphysics, analyzed the change rule of shear stress, vertical stress, plastic area and water pressure for stope with a fault, and estimated the water-inrush risk at the different distances between working faces and the fault. The numerical simula- tion results indicate that： （1） the water-inrush risk will grow as the decrease of the distance between working face and the fault; （2） the failure mode of the rock in floor with fault is shear failure; （3） the rock between water-containing fault and working face failure is the reason for water-inrush.
基金Supposed by National Natural Science Foundation of China(Grant No.51075348)Hebei Provincial Natural Science Foundation of China(Grant No.E2011203151)Research Fund for Doctoral Program of Higher Education of China(Grant No.20101333110002)
文摘The double flapper-nozzle servo valve is widely used to launch and guide the equipment. Due to the large instantaneous flow rate of servo valve working under specific operating conditions, the temperature of servo valve would reach 120℃ and the valve core and valve sleeve deform in a short amount of time. So the control precision of servo valve significantly decreases and the clamping stagnation phenomenon of valve core appears. In order to solve the problem of degraded control accuracy and clamping stagnation of servo valve under large temperature difference circumstance, the numerical simulation of heat-fluid-solid coupling by using finite element method is done. The simulation result shows that zero position leakage of servo valve is basically impacted by oil temperature and change of fit clearance. The clamping stagnation is caused by warpage-deformation and fit clearance reduction of the valve core and valve sleeve. The distribution roles of the temperature and thermal-deformation of shell, valve core and valve sleeve and the pressure, velocity and temperature field of flow channel are also analyzed. Zero position leakage and electromagnet＇s current when valve core moves in full-stroke are tested using Electro-hydraulic Servo-valve Characteristic Test-bed of an aerospace sciences and technology corporation. The experimental results show that the change law of experimental current at different oil temperatures is roughly identical to simulation current. The current curve of the electromagnet is smooth when oil temperature is below 80℃, but the amplitude of current significantly increases and the hairy appears when oil temperature is above 80℃. The current becomes smooth again after the warped valve core and valve sleeve are reground. It indicates that clamping stagnation is caused by warpage-deformation and fit clearance reduction of valve core and valve sleeve. This paper simulates and tests the heat-fluid-solid coupling of double flapper-nozzle servo valve, and the obtained results provide the reference value for the design of double flapper-nozzle force feedback servo valve.
基金Supported by the National Natural Science Foundation of China(51674158,51704324,51934004)。
文摘Aiming at the synergistic rock-breaking mechanism of supercritical carbon dioxide(SC-CO_(2))jet pressure and tem-perature difference,a heat-fluid-solid calculation model of rock-breaking stress was established and verified to be effective,and the variations of jet flow field and rock stress with jet standoff distance of SC-CO_(2),water and nitrogen were studied.With the increase of jet standoff distance,the jet pressure of SC-CO_(2) decreases and the jet temperature difference increases.The SC-CO_(2) jet is higher in pressure than the nitrogen jet and differs little from the water jet.Temperature difference of SC-CO_(2) jet is 5 times that of water jet and more than 2.5 ti mes that of nitrogen jet when the jet standoff distance is larger than 10.The tem-perature stress is the main reason why SC-CO_(2) jet is superior to water and nitrogen jets in rock-breaking.The rock under the SC-CO_(2) jet has greater rock stress,effective rock-breaking jet standoff distance and rock-breaking area.The jet pressure plays a major role in rock-breaking when the jet standoff distance is small,while the jet temperature difference plays a major role in rock-breaking when the jet standoff distance is large.The SC-CO_(2) jet is an efficient volume rock-breaking method,which results in tensile and shear failure on the rock surface under short time jet and large area tensile failure inside the rock simultaneously under long time jet.
基金National Natural Science Foundation of People’s Republic of China under Grant Nos.51178011 and 51778386the Key Fundamental Study Development Project of People’s Republic of China under Grant No.2011CB013602。
文摘The seismic response characteristics of underground structures in saturated soils are investigated.A fully fluid-solid coupling dynamic model is developed and implemented into ABAQUS with a user-defined element to simulate the dynamic behavior of saturated soils.The accuracy of the model is validated using a classic example in literature.The performance of the model is verified by its application on simulating the seismic response characteristics of a subway station built in saturated soils.The merits of the model are demonstrated by comparing the difference of the seismic response of an underground structure in saturated soils between using the fully coupling model and a single-phase medium model.The study finds that the fully coupling model developed herein can simulate the dynamic response characteristics of the underground structures in saturated soils with high accuracy.The seismic response of the underground structure tends to be underestimated by using the single-phase medium model compared with using the fully coupling model,which provides a weaker confining action to the underground structure.
基金The authors acknowledge the financial support from the Natural Science Foundation of China(U1704131)Program for Science&Technology Innovation Talents in Universities of Henan Province(18HASTIT018)the Program for Changjiang Scholars and Innovative Research Team in University(IRT_16R22).
文摘Improving the absorbed gas to active desorption and seepage and delaying gas drainage attenuation are considered as key methods for increasing drainage efficiency and gas output.According to the solid mechanics theory,the nonlinear Darcy seepage theory and thermodynamics,the heat-fluid-solid coupling model for gassy coal has been improved.The numerical model was founded from the improved multi-field coupling model by COMSOL Multiphysics and gas drainage by borehole down the coal seam enhanced by heat injection was modelled.The results show that the heatfluid-solid model with adsorption effects for gassy coal was well simulated by the improved multi-field model.The mechanism of coal seam gas desorption seepage under the combined action of temperature,stress and adsorption can be well described.Gas desorption and seepage can be enhanced by heat injection into coal seams.The gas drainage rate was directly proportional to the temperature of injected heat in the scope of 30-150 ℃ and increasing in the whole modelleddrainage process (0-1000 d).The increased level was maximum in the initial drainage time and decreasing gradually along with drainage time.The increasing ratio of drainage rate was maximum when the temperature raised from 30 to 60 ℃.Although the drainage rate would increase along with increasing temperature,when exceeding 60 ℃,the increasing ratio of drainage rate with rising temperature would decrease.Gas drainage promotion was more effective in coal seams with lower permeability than with higher permeability.The coal seam temperature in a 5 m distance surrounding the heat injection borehole would rise to around 60 ℃ in 3 months.That was much less than the time of gas drainage in the coal mines in sites with low permeability coal seams.Therefore,it is valuable and feasible to inject heat into coal seams to promote gas drainage,and this has strong feasibility for coal seams with low permeability which are widespread in China.
文摘To study the behavior of overlying strata and the likelihood of water inrush and quicksand with different mining sequences under an unconsolidated alluvium aquifer, a numerical model based on the fluid-solid coupling theory was con- structed by FLAC3D. Simulation results revealed that the mining sequences had a significant influence on the seepage, dis- placement and failure characteristics of the overlying strata. In this kind of geological and hydrogeological conditions, the workface close to the outcrop of coal seam easily suffers from water inrush and quicksand during mining. In the simulation re- sults, the plastic zone, vertical displacement and pore water pressure in the overlying strata of the workface decrease more or less using the upward mining sequence than using the downward mining sequence. Therefore, the application of the upward mining sequence in the process of mining is preferential to prevent water inrush and quicksand.
基金Project supported by the National Natural Science Foundation of China(Grant No 11472246)the National program on Key Basic Research project of China(973 program)(Grant No.2013CB228002).
文摘In this paper,the cores of outcropped black shale of Lower Silurian Longmaxi Fm in the Yibin area,Sichuan Basin,were taken as samples to investigate the effects of extraneous water on shale mechanics and seepage laws during the production of shale gas reservoirs.Firstly,the development of fractures in water saturated cores was observed by using a VHX-5000 optical superdepth microscope.Secondly,water,formation water and slick water,as well as the damage form and compression strength of water saturated/unsaturated cores were investigated by means of a uniaxial compression testing machine and a strain testing&analysis system.Finally,the effects of fluid-solid coupling on shale gas flowing performance in different water saturations were analyzed by using a DYQ-1 multi-function displacement device.Analysis on core components shows that the Longmaxi shale is a highly crushable reservoir with a high content of fragile minerals,so fracturing stimulation is suitable for it.Shale compression strength test reveals that the effects of deionized water,formation water and slick water on shale are different,so the compression strength of shale before being saturated is quite different from that after being saturated.Due to the existence of water,the compression strength of shale drops,so the shale can be fractured easily,more fractures are generated and thus its seepage capacity is improved.Experiments on shale gas seepage under different water saturations show that under the condition of fluid-solid coupling,the higher the water saturation is,the better the propagation and seepage capacity of micro-fractures in shale under the effect of pressure.To sum up,the existence of water is beneficial to fracturing stimulation of shale gas reservoirs and helps to achieve the goal of production improvement.
基金supported by the Natural Science Foundation of Henan,China(Grant No.242300421646)the Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education,Tongji University,China(Grant No.KLE-TJGE-B2205).
文摘Micro-disturbance grouting is a recovery technique to reduce the excessive deformation of operational shield tunnels in urban areas.The grout mass behaves as a fluid in the ground before hardening to form a grout–soil mixture,which highlights the necessity of using fluid–solid coupling method in the simulation of grouting process.Within a discrete element modeling environment,this paper proposes a novel fluid-solid coupling method based on the pore density flow calculation.To demonstrate the effectiveness of this method,it is applied to numerical simulation of micro-disturbance grouting process for treatment of large transverse deformation of a shield tunnel in Shanghai Metro,China.The simulation results reveal the mechanism of recovering tunnel convergence by micro-disturbance grouting in terms of compaction and fracture of soil,energy analysis during grouting,and mechanical response of soil-tunnel interaction system.Furthermore,the influence of the three main grouting parameters(i.e.,grouting pressure,grouting distance,and grouting height)on tunnel deformation recovery efficiency is evaluated through parametric analysis.In order to efficiently recover large transverse deformation of shield tunnel in Shanghai Metro,it is suggested that the grouting pressure should be about 0.55 MPa,the grouting height should be in the range of 6.2–7.0 m,and the grouting distance should be in the range of 3.0–3.6 m.The results provide a valuable reference for grouting treatment projects of over-deformed shield tunnel in soft soil areas.
基金financially supported by the National Natural Science Foundation of China(Grants nos.62201411,62371378,22205168,52302150 and 62304171)the China Postdoctoral Science Foundation(2022M722500)+1 种基金the Fundamental Research Funds for the Central Universities(Grants nos.ZYTS2308 and 20103237929)Startup Foundation of Xidian University(10251220001).
文摘Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.
