For the first time, fluid-melt inclusions are found in fluorite of the Huanggangliang skarn iron-tin deposit (HSID). The fluorite was formed in the main stage of mineralization, named the hydro-skarnization stage. The...For the first time, fluid-melt inclusions are found in fluorite of the Huanggangliang skarn iron-tin deposit (HSID). The fluorite was formed in the main stage of mineralization, named the hydro-skarnization stage. The inclusions contain various components such as Fe, Mg and Cr from deep sources. The melts of primary inclusions are mainly Ca- and F-rich and those of secondary inclusions tend to become Si-rich. During this evolution process, the melts and iron daughter minerals decreased and even vanished. These facts reveal that the evolution of the primary mineralizing fluids and the differentiation of the fluids and melts are the main factors leading to the deposition of Fe, Sn and other elements. This discovery confirms the magmatic genesis of the HSID and has filled in the gaps in the research of magmatogenic skarn deposits and furnished new methods for such research. Furthermore, it has enlarged the scope of the research on fluid inclusions.展开更多
Abundant fluid-melt inc1usions are found in the aegirine-augite-barite pegmatite andcarbonatite veins in the Mianning REE deposit, Sichuan. They were trapped in early stage flu-orite and quartz from a salt-melt system...Abundant fluid-melt inc1usions are found in the aegirine-augite-barite pegmatite andcarbonatite veins in the Mianning REE deposit, Sichuan. They were trapped in early stage flu-orite and quartz from a salt-melt system at temperatures higher than 500℃. Meanwhile, fluidinclusions are also present in large amounts in bastnaesite. Homogenized between 150 and270℃, these inclusions are thought to be representative of the physiccrchemical conditions ofREE minera1ization. These results show that the Mianning REE deposit is of tyPical hy-drothermal origin developed from a salt-melt system.展开更多
Both fractional crystallization and fluid-melt-crystal interaction are involved in the formation of highly fractionated granites.This paper assessed those two processes using geochemistry of muscovite and tourmaline a...Both fractional crystallization and fluid-melt-crystal interaction are involved in the formation of highly fractionated granites.This paper assessed those two processes using geochemistry of muscovite and tourmaline and bulkrock chemistry of multi-phase Wangxianling granitoids,South China.Compositional variations suggest the coarse-grained muscovite granite is produced from fractional crystallization of the two-mica granite whereas the fine-grained muscovite granite represents a distinct magma pulse.Progressive fractionation of quartz,feldspar and biotite leads to elevated boron and aluminum content in melt which promoted muscovite and tourmaline to crystallize,which promotes two-mica granite evolving towards tourmaline-bearing muscovite granite.Fluid-melt-crystal interaction occurred at the magmatichydrothermal transitional stage and resulted in the textural and chemical zonings of tourmaline and muscovite in finegrained muscovite granite.The rims of both tourmaline and muscovite are characterized by the enrichment of fluid mobile elements such as Li,Mn,Cs and Zn and heavierδ^(11)B values of the tourmaline rims(-15.0‰to-13.6‰)compared to cores(-15.7‰to-14.3‰).Meanwhile,significant M-type REE tetrad effects(TE_(1,3)=1.07-1.18)and low K/Rb ratios(48-52)also correspond to fluid-melt-crystal interaction.This study shows zoned muscovite and tourmaline can be excellent tracers of fractional crystallization and late-stage fluid-melt-crystal interaction in highly evolved magmatic systems.展开更多
Highly evolved granite associated with pegmatite shells exhibits significant potential for rare metal mineralization;however,the mechanisms through which these pegmatite shells contribute to magmatic evolution and rar...Highly evolved granite associated with pegmatite shells exhibits significant potential for rare metal mineralization;however,the mechanisms through which these pegmatite shells contribute to magmatic evolution and rare metal enrichment remain poorly understood.The Late Jurassic Shihuiyao Nb-Ta-(Rb-Be-Li)deposit is one of the largest rare-metal deposits in the Southern Great Xing’an Range(SGXR),Northeast China.Exploratory trenches expose distinct layered zones from top to bottom:alternating microcline pegmatite and aplite layers(zone I),topaz lepidolite albite granite and lepidolite amazonite pegmatite(zone II),and muscovite albite granite(zoneⅢ).We conducted U-Pb dating of cassiterite,monazite,and Nb-Ta oxide,monazite Nd isotopes,and whole-rock and mineral geochemistry for the three zones.Multi-mineral U-Pb ages indicate that the three zones formed during the Late Jurassic-Early Cretaceous(147-142 Ma).Geochemical analyses of whole-rock,mica,and microcline suggest an evolutionary sequence from zone I to zoneⅢ,and finally to zone II.The Zr/Hf,Nb/Ta,Y/Ho,and K/Rb ratios combined with the rare earth element(REE)tetrad effects suggest higher degree of differentiation and fluid-melt interaction of the Shihuiyao leucogranite without a pegmatite shell compared to coeval barren granites from both Shihuiyao and the SGXR.A progressive increase in the degree of evolution is evident from the leucogranite without a pegmatite shell to the leucogranite with a discontinuous shell,and ultimately to the leucogranite with a continuous shell.The pegmatite shell acted as a geochemical barrier that facilitated the accumulation of Li and F in the underlying magma,which played a crucial role in lowering the solidus temperature of the granitic magma.This process prolonged the crystallization duration while reducing melt viscosity and density,thereby creating favorable conditions for magma differentiation and fluid-melt interaction.Rapid crystallization of the earlier water-and Be-rich melt led to the Be mineralization in the pegmatite shell.Moreover,the formation of this shell served as a barrier for Li mineralization in the underlying topaz lepidolite albite granite.This study enhances our understanding of the critical contribution of pegmatite shells to magmatic evolution and rare-metal mineralization.展开更多
文摘For the first time, fluid-melt inclusions are found in fluorite of the Huanggangliang skarn iron-tin deposit (HSID). The fluorite was formed in the main stage of mineralization, named the hydro-skarnization stage. The inclusions contain various components such as Fe, Mg and Cr from deep sources. The melts of primary inclusions are mainly Ca- and F-rich and those of secondary inclusions tend to become Si-rich. During this evolution process, the melts and iron daughter minerals decreased and even vanished. These facts reveal that the evolution of the primary mineralizing fluids and the differentiation of the fluids and melts are the main factors leading to the deposition of Fe, Sn and other elements. This discovery confirms the magmatic genesis of the HSID and has filled in the gaps in the research of magmatogenic skarn deposits and furnished new methods for such research. Furthermore, it has enlarged the scope of the research on fluid inclusions.
文摘Abundant fluid-melt inc1usions are found in the aegirine-augite-barite pegmatite andcarbonatite veins in the Mianning REE deposit, Sichuan. They were trapped in early stage flu-orite and quartz from a salt-melt system at temperatures higher than 500℃. Meanwhile, fluidinclusions are also present in large amounts in bastnaesite. Homogenized between 150 and270℃, these inclusions are thought to be representative of the physiccrchemical conditions ofREE minera1ization. These results show that the Mianning REE deposit is of tyPical hy-drothermal origin developed from a salt-melt system.
基金funded by the National Natural Science Foundation of China(Grant Nos.42072089 and 41530206)。
文摘Both fractional crystallization and fluid-melt-crystal interaction are involved in the formation of highly fractionated granites.This paper assessed those two processes using geochemistry of muscovite and tourmaline and bulkrock chemistry of multi-phase Wangxianling granitoids,South China.Compositional variations suggest the coarse-grained muscovite granite is produced from fractional crystallization of the two-mica granite whereas the fine-grained muscovite granite represents a distinct magma pulse.Progressive fractionation of quartz,feldspar and biotite leads to elevated boron and aluminum content in melt which promoted muscovite and tourmaline to crystallize,which promotes two-mica granite evolving towards tourmaline-bearing muscovite granite.Fluid-melt-crystal interaction occurred at the magmatichydrothermal transitional stage and resulted in the textural and chemical zonings of tourmaline and muscovite in finegrained muscovite granite.The rims of both tourmaline and muscovite are characterized by the enrichment of fluid mobile elements such as Li,Mn,Cs and Zn and heavierδ^(11)B values of the tourmaline rims(-15.0‰to-13.6‰)compared to cores(-15.7‰to-14.3‰).Meanwhile,significant M-type REE tetrad effects(TE_(1,3)=1.07-1.18)and low K/Rb ratios(48-52)also correspond to fluid-melt-crystal interaction.This study shows zoned muscovite and tourmaline can be excellent tracers of fractional crystallization and late-stage fluid-melt-crystal interaction in highly evolved magmatic systems.
基金supported by the Key Research Program of the Institute of Geology&Geophysics,CAS(IGGCAS-202205)the National Natural Science Foundation of China(Grant No.92062216 and 42102046)+1 种基金Doctoral Students'Scientific Research and Innovation Capability Enhancement Program of Jilin Province(JJKH20250074BS)Graduate Innovation Fund of Jilin University(2024CX231).
文摘Highly evolved granite associated with pegmatite shells exhibits significant potential for rare metal mineralization;however,the mechanisms through which these pegmatite shells contribute to magmatic evolution and rare metal enrichment remain poorly understood.The Late Jurassic Shihuiyao Nb-Ta-(Rb-Be-Li)deposit is one of the largest rare-metal deposits in the Southern Great Xing’an Range(SGXR),Northeast China.Exploratory trenches expose distinct layered zones from top to bottom:alternating microcline pegmatite and aplite layers(zone I),topaz lepidolite albite granite and lepidolite amazonite pegmatite(zone II),and muscovite albite granite(zoneⅢ).We conducted U-Pb dating of cassiterite,monazite,and Nb-Ta oxide,monazite Nd isotopes,and whole-rock and mineral geochemistry for the three zones.Multi-mineral U-Pb ages indicate that the three zones formed during the Late Jurassic-Early Cretaceous(147-142 Ma).Geochemical analyses of whole-rock,mica,and microcline suggest an evolutionary sequence from zone I to zoneⅢ,and finally to zone II.The Zr/Hf,Nb/Ta,Y/Ho,and K/Rb ratios combined with the rare earth element(REE)tetrad effects suggest higher degree of differentiation and fluid-melt interaction of the Shihuiyao leucogranite without a pegmatite shell compared to coeval barren granites from both Shihuiyao and the SGXR.A progressive increase in the degree of evolution is evident from the leucogranite without a pegmatite shell to the leucogranite with a discontinuous shell,and ultimately to the leucogranite with a continuous shell.The pegmatite shell acted as a geochemical barrier that facilitated the accumulation of Li and F in the underlying magma,which played a crucial role in lowering the solidus temperature of the granitic magma.This process prolonged the crystallization duration while reducing melt viscosity and density,thereby creating favorable conditions for magma differentiation and fluid-melt interaction.Rapid crystallization of the earlier water-and Be-rich melt led to the Be mineralization in the pegmatite shell.Moreover,the formation of this shell served as a barrier for Li mineralization in the underlying topaz lepidolite albite granite.This study enhances our understanding of the critical contribution of pegmatite shells to magmatic evolution and rare-metal mineralization.
