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Ideal Resolution Principle for Lattice-Valued First-Order Logic Based on Lattice Implication Algebra 被引量:1
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作者 许伟涛 徐扬 《Journal of Shanghai Jiaotong university(Science)》 EI 2012年第2期178-181,共4页
As a continuate work,ideal-based resolution principle for lattice-valued first-order logic system LF(X) is proposed,which is an extension of α-resolution principle in lattice-valued logic system based on lattice impl... As a continuate work,ideal-based resolution principle for lattice-valued first-order logic system LF(X) is proposed,which is an extension of α-resolution principle in lattice-valued logic system based on lattice implication algebra.In this principle,the resolution level is an ideal of lattice implication algebra,instead of an element in truth-value field.Moreover,the soundness theorem is given.In the light of lifting lemma,the completeness theorem is established.This can provide a new tool for automated reasoning. 展开更多
关键词 automated reasoning lattice-valued logic lattice implication algebra generalized clause
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10-Elements Linguistic Truth-Valued Intuitionistic Fuzzy First-Order Logic System
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作者 Yingxin Wang Xin Wen Li Zou 《国际计算机前沿大会会议论文集》 2015年第1期117-119,共3页
This paper presents 10-elements linguistic truth-valued intuitionistic fuzzy algebra and the properties based on the linguistic truth-valued implication algebra which is fit to express both comparable and incomparable... This paper presents 10-elements linguistic truth-valued intuitionistic fuzzy algebra and the properties based on the linguistic truth-valued implication algebra which is fit to express both comparable and incomparable information.This method can also deal with the uncertain problem which has both positive evidence and negative evidence at the same time.10-elements linguistic truthvalued intuitionistic fuzzy first-order logic system has been established in the intuitionistic fuzzy algebra. 展开更多
关键词 LINGUISTIC truth-value 10-elements LINGUISTIC truth-valued intuitionistic fuzzy logic first-order logic system
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Resolution Method of Six-Element Linguistic Truth-Valued First-Order Logic System
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作者 Li Zou Di Liu +1 位作者 Yingxin Wang Juan Qu 《国际计算机前沿大会会议论文集》 2015年第1期10-12,共3页
Based on 6-elements linguistic truth-valued lattice implication algebras this paper discusses 6-elements linguistic truth-valued first-order logic system. With some special properties of 6-elements linguistic truth-va... Based on 6-elements linguistic truth-valued lattice implication algebras this paper discusses 6-elements linguistic truth-valued first-order logic system. With some special properties of 6-elements linguistic truth-valued first-order logic, we discussed the satisfiable problem of 6-elements linguistic truth-valued first-order logic and proposed a resolution method of 6-elements linguistic truth-valued firstorder logic. Then the resolution algorithm is presented and an example illustrates the effectiveness of the proposed method. 展开更多
关键词 LINGUISTIC truth-valued lattice IMPLICATION ALGEBRA 6-elements LINGUISTIC truth-valued first-order logic Automated reasoning
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A “Tonebusting” Technique to Build a DAC from a First-Order Digital ΣΔ Modulator
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作者 Yves Leduc Gilles Jacquemod +1 位作者 Yoann Charlon Fabrice Muller 《Journal of Electronic Research and Application》 2025年第4期8-13,共6页
In this paper,we present a novel first-order digitalΣΔconverter tailored for digital-to-analog applications,focusing on achieving both high yield and reduced silicon estate.Our approach incorporates a substantial le... In this paper,we present a novel first-order digitalΣΔconverter tailored for digital-to-analog applications,focusing on achieving both high yield and reduced silicon estate.Our approach incorporates a substantial level of dithering noise into the input signal,strategically aimed at mitigating the spurious frequencies commonly encountered in such converters.Validation of our design is performed through simulations using a high-level simulator specialized in mixed-signal circuit analysis.The results underscore the enhanced performance of our circuit,especially in reducing spurious frequencies,highlighting its efficiency and effectiveness.The final circuit exhibits an effective number of bits of 13. 展开更多
关键词 first-order digital SD modulator Digital to analog converter Spurious frequencies Dithering
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Improved Inverse First-Order Reliability Method for Analyzing Long-Term Response Extremes of Floating Structures
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作者 Junrong Wang Zhuolantai Bai +3 位作者 Botao Xie Jie Gui Haonan Gong Yantong Zhou 《哈尔滨工程大学学报(英文版)》 2025年第3期552-566,共15页
Long-term responses of floating structures pose a great concern in their design phase. Existing approaches for addressing long-term extreme responses are extremely cumbersome for adoption. This work aims to develop an... Long-term responses of floating structures pose a great concern in their design phase. Existing approaches for addressing long-term extreme responses are extremely cumbersome for adoption. This work aims to develop an approach for the long-term extreme-response analysis of floating structures. A modified gradient-based retrieval algorithm in conjunction with the inverse first-order reliability method(IFORM) is proposed to enable the use of convolution models in long-term extreme analysis of structures with an analytical formula of response amplitude operator(RAO). The proposed algorithm ensures convergence stability and iteration accuracy and exhibits a higher computational efficiency than the traditional backtracking method. However, when the RAO of general offshore structures cannot be analytically expressed, the convolutional integration method fails to function properly. A numerical discretization approach is further proposed for offshore structures in the case when the analytical expression of the RAO is not feasible. Through iterative discretization of environmental contours(ECs) and RAOs, a detailed procedure is proposed to calculate the long-term response extremes of offshore structures. The validity and accuracy of the proposed approach are tested using a floating offshore wind turbine as a numerical example. The long-term extreme heave responses of various return periods are calculated via the IFORM in conjunction with a numerical discretization approach. The environmental data corresponding to N-year structural responses are located inside the ECs, which indicates that the selection of design points directly along the ECs yields conservative design results. 展开更多
关键词 Long-term response analysis Floating structures Inverse first-order reliability method Convolution model Gradient-based retrieval algorithm Environmental contour method
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Variant quantifiers in L_(3)-valued first-order logic
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作者 Wei LI Yuefei SUI 《Frontiers of Computer Science》 SCIE EI CSCD 2021年第5期151-159,共9页
Traditional first-order logic has four definitions for quantifiers,which are defined by universal and existential quantifiers.In L_(3)-valued(three-valued)first-order logic,there are eight kinds of definitions for qua... Traditional first-order logic has four definitions for quantifiers,which are defined by universal and existential quantifiers.In L_(3)-valued(three-valued)first-order logic,there are eight kinds of definitions for quantifiers;and corresponding Gentzen deduction systems will be given and their soundness and completeness theorems will be proved. 展开更多
关键词 L_(3)-valued(three-valued)first-order logic sequent QUANTIFIER soundness theorem completeness theorem
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Efficient slope reliability and sensitivity analysis using quantile-based first-order second-moment method 被引量:2
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作者 Zhiyong Yang Chengchuan Yin +2 位作者 Xueyou Li Shuihua Jiang Dianqing Li 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第10期4192-4203,共12页
This paper introduces a novel approach for parameter sensitivity evaluation and efficient slope reliability analysis based on quantile-based first-order second-moment method(QFOSM).The core principles of the QFOSM are... This paper introduces a novel approach for parameter sensitivity evaluation and efficient slope reliability analysis based on quantile-based first-order second-moment method(QFOSM).The core principles of the QFOSM are elucidated geometrically from the perspective of expanding ellipsoids.Based on this geometric interpretation,the QFOSM is further extended to estimate sensitivity indices and assess the significance of various uncertain parameters involved in the slope system.The proposed method has the advantage of computational simplicity,akin to the conventional first-order second-moment method(FOSM),while providing estimation accuracy close to that of the first-order reliability method(FORM).Its performance is demonstrated with a numerical example and three slope examples.The results show that the proposed method can efficiently estimate the slope reliability and simultaneously evaluate the sensitivity of the uncertain parameters.The proposed method does not involve complex optimization or iteration required by the FORM.It can provide a valuable complement to the existing approximate reliability analysis methods,offering rapid sensitivity evaluation and slope reliability analysis. 展开更多
关键词 Slope reliability Sensitivity analysis QUANTILE first-order second-moment method(FOSM) first-order reliability method(FORM)
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Transient response of doubly-curved bio-inspired composite shells resting on viscoelastic foundation subject to blast load using improved first-order shear theory and isogeometric approach 被引量:1
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作者 Thuy Tran Thi Thu Tu Nguyen Anh +1 位作者 Hue Nguyen Thi Hong Nguyen Thi 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第8期171-193,共23页
Investigating natural-inspired applications is a perennially appealing subject for scientists. The current increase in the speed of natural-origin structure growth may be linked to their superior mechanical properties... Investigating natural-inspired applications is a perennially appealing subject for scientists. The current increase in the speed of natural-origin structure growth may be linked to their superior mechanical properties and environmental resilience. Biological composite structures with helicoidal schemes and designs have remarkable capacities to absorb impact energy and withstand damage. However, there is a dearth of extensive study on the influence of fiber redirection and reorientation inside the matrix of a helicoid structure on its mechanical performance and reactivity. The present study aimed to explore the static and transient responses of a bio-inspired helicoid laminated composite(B-iHLC) shell under the influence of an explosive load using an isomorphic method. The structural integrity of the shell is maintained by a viscoelastic basis known as the Pasternak foundation, which encompasses two coefficients of stiffness and one coefficient of damping. The equilibrium equations governing shell dynamics are obtained by using Hamilton's principle and including the modified first-order shear theory,therefore obviating the need to employ a shear correction factor. The paper's model and approach are validated by doing numerical comparisons with respected publications. The findings of this study may be used in the construction of military and civilian infrastructure in situations when the structure is subjected to severe stresses that might potentially result in catastrophic collapse. The findings of this paper serve as the foundation for several other issues, including geometric optimization and the dynamic response of similar mechanical structures. 展开更多
关键词 Blast load Modified first-order shear theory Biological composite structures
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Euler’s First-Order Explicit Method–Peridynamic Differential Operator for Solving Population Balance Equations of the Crystallization Process
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作者 Chunlei Ruan Cengceng Dong +2 位作者 Kunfeng Liang Zhijun Liu Xinru Bao 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第3期3033-3049,共17页
Using Euler’s first-order explicit(EE)method and the peridynamic differential operator(PDDO)to discretize the time and internal crystal-size derivatives,respectively,the Euler’s first-order explicit method–peridyna... Using Euler’s first-order explicit(EE)method and the peridynamic differential operator(PDDO)to discretize the time and internal crystal-size derivatives,respectively,the Euler’s first-order explicit method–peridynamic differential operator(EE–PDDO)was obtained for solving the one-dimensional population balance equation in crystallization.Four different conditions during crystallization were studied:size-independent growth,sizedependent growth in a batch process,nucleation and size-independent growth,and nucleation and size-dependent growth in a continuous process.The high accuracy of the EE–PDDO method was confirmed by comparing it with the numerical results obtained using the second-order upwind and HR-van methods.The method is characterized by non-oscillation and high accuracy,especially in the discontinuous and sharp crystal size distribution.The stability of the EE–PDDO method,choice of weight function in the PDDO method,and optimal time step are also discussed. 展开更多
关键词 Population balance equation CRYSTALLIZATION peridynamic differential operator Euler’s first-order explicit method
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Estimation of Landfill Gas and Its Renewable Energy Potential from the Polesgo Controlled Landfill Using First-Order Decay (FOD) Models
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作者 Haro Kayaba Ouarma Issoufou +4 位作者 Dabilgou Téré Compaore Abdoulaye Sanogo Oumar Bere Antoine Koulidiati Jean 《Journal of Environmental Protection》 2024年第10期975-993,共19页
Methane generation in landfills and its inadequate management represent the major avoidable source of anthropogenic methane today. This paper models methane production and the potential resources expected (electrical ... Methane generation in landfills and its inadequate management represent the major avoidable source of anthropogenic methane today. This paper models methane production and the potential resources expected (electrical energy production and potential carbon credits from avoided CH4 emissions) from its proper management in a municipal solid waste landfill located in Ouagadougou, Burkina Faso. The modeling was carried out using two first-order decay (FOD) models (LandGEM V3.02 and SWANA) using parameters evaluated on the basis of the characteristics of the waste admitted to the landfill and weather data for the site. At the same time, production data have been collected since 2016 in order to compare them with the model results. The results obtained from these models were compared to experimental one. For the simulation of methane production, the SWANA model showed better consistency with experimental data, with a coefficient of determination (R²) of 0.59 compared with the LandGEM model, which obtained a coefficient of 0.006. Thus, despite the low correlation values linked to the poor consistency of experimental data, the SWANA model models methane production much better than the LandGEM model. Thus, despite the low correlation values linked to the poor consistency of the experimental data, the SWANA model models methane production much better than the LandGEM V3.02 model. It was noted that the poor consistency of the experimental data justifies these low coefficients, and that they can be improved in the future thanks to ongoing in situ measurements. According to the SWANA model prediction, in 27 years of operation a biogas plant with 33% electrical efficiency using biogas from the Polesgo landfill would avoid 1,340 GgCO2e. Also, the evaluation of revenues due to electricity and carbon credit gave a total revenue derived from methane production of US$27.38 million at a cost of US$10.5/tonne CO2e. 展开更多
关键词 first-order Decay METHANE Modeling LANDFILL Renewable Energy
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基于AnyLogic的地铁换乘站客流组织仿真与优化 被引量:3
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作者 李昌宇 曹忠伟 张若楠 《现代城市轨道交通》 2025年第2期123-129,共7页
对于客流量庞大的地铁换乘站而言,合理的客流组织是保证地铁安全运营的重要措施之一。以徐州地铁彭城广场换乘站为例,分析地铁站乘客的换乘特征及换乘方式,并结合该站的实际客流换乘现状,运用基于社会力模型的AnyLogic仿真平台对站内乘... 对于客流量庞大的地铁换乘站而言,合理的客流组织是保证地铁安全运营的重要措施之一。以徐州地铁彭城广场换乘站为例,分析地铁站乘客的换乘特征及换乘方式,并结合该站的实际客流换乘现状,运用基于社会力模型的AnyLogic仿真平台对站内乘客换乘过程进行仿真,深度分析建筑拐角区域的客流拥堵现象。为缓解客流压力,从合理设置导流围栏的角度出发,提出针对性解决措施,并再次通过仿真模拟进行验证,结果显示,该措施可显著减少客流交叉情况,有效避免拥堵。当优化方案应用于彭城广场站后,实际拥堵情况得到明显改善,为同类型地铁换乘站客流组织提供参考。 展开更多
关键词 地铁 换乘站 客流组织优化 Any logic 社会力模型
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Lewisian Connexive Logics
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作者 Chen Huang Xuefeng Wen 《逻辑学研究》 2025年第3期96-114,共19页
In connexive logic,two fundamental ideas are observed:first,no proposition im-plies or is implied by its own negation;second,if a proposition implies p then it will not imply the negation of 4p.In classical logic,neit... In connexive logic,two fundamental ideas are observed:first,no proposition im-plies or is implied by its own negation;second,if a proposition implies p then it will not imply the negation of 4p.In classical logic,neither of the ideas holds,which makes it difficult to give a natural semantics for connexive logic.By combining Kleene's three valued logic and Lewis'conditional logic,we propose a new natural semantics for connexive logic.We give four ax-iomatic systems characterizing different classes of selection models in the new semantics.We prove soundness and completeness of these logics and compare them with some comexive 1og-ics in the literature. 展开更多
关键词 natural semantics Lewisian Kleenes Three valued combining kleenes three valued logic Connexive logic lewisconditional logicwe
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Research and Application of EMUs Braking System Control Logic Based on MBSE
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作者 Wen-yu Wang Yong-qiang Wang Yue Lin 《Journal of Electronic Research and Application》 2025年第1期314-321,共8页
As Model-Based Systems Engineering(MBSE)was applied to the Electric Multiple Unit(EMU)braking system control logic,a preliminary exploration was conducted for bullet train braking system control logic research using a... As Model-Based Systems Engineering(MBSE)was applied to the Electric Multiple Unit(EMU)braking system control logic,a preliminary exploration was conducted for bullet train braking system control logic research using an MBSE practice framework.The framework mainly includes the requirement analysis phase,functional analysis phase,and design phase.Systems Modeling Language(SysML)was used as the modeling language,and Cameo Systems Modeler(CSM)was employed as the modeling tool.By integrating the EMU braking system control logic and utilizing a top-down design approach,the implementation of MBSE in the bullet train braking system was analyzed and studied.The results show that,according to the MBSE practice framework,a unified description of the requirement analysis,functional analysis,and design synthesis of the EMU braking system control logic can be achieved.Additionally,the correlation and traceability between models can be established. 展开更多
关键词 MBSE Braking system Control logic SYSML
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On Modal Logics of Subset Spaces
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作者 Shengyang Zhong 《逻辑学研究》 2025年第3期1-24,共24页
In modal logic,topological semantics is an intuitive and natural special case of neighbourhood semantics.This paper stems from the observation that the satisfaction relation of topological semantics applies to subset ... In modal logic,topological semantics is an intuitive and natural special case of neighbourhood semantics.This paper stems from the observation that the satisfaction relation of topological semantics applies to subset spaces which are more general than topological spaces.The minimal modal logic which is strongly sound and complete with respect to the class of subset spaces is found.Soundness and completeness results of some famous modal logics(e.g.S4,S5 and Tr)with respect to various important classes of subset spaces(eg intersection structures and complete fields of sets)are also proved.In the meantime,some known results,e.g.the soundness and completeness of Tr with respect to the class of discrete topological spaces,are proved directly using some modifications of the method of canonical mode1,without a detour via neighbourhood semantics or relational semantics. 展开更多
关键词 subset spaces modal logics topological semantics modal logics egs s satisfaction relation modal logictopological semantics neighbourhood semanticsthis
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Institutional Logics and Its Application in Entrepreneurship Research
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作者 Mengxuan Qin 《Proceedings of Business and Economic Studies》 2025年第4期409-419,共11页
Institutional logic theory,a pivotal framework within organizational studies,delineates the multifaceted and intricate logics that underpin organizational fields.This theoretical perspective elucidates the manner in w... Institutional logic theory,a pivotal framework within organizational studies,delineates the multifaceted and intricate logics that underpin organizational fields.This theoretical perspective elucidates the manner in which diverse individuals or groups within an organization internalize and manifest distinct institutional logics,alongside the ensuing political and cultural conflicts.Furthermore,the theory endeavors to elucidate the complexities inherent in institutional logic across organizational fields,examining the reflection of these logics among various individuals or groups and their associated political and cultural dichotomies.Central to this discourse is the acknowledgment of the core systems that constitute the fabric of a country,encompassing the state,market,familial structures,corporate entities,professional bodies,and religious institutions.These components not only coexist with inherent conflicts but also exhibit a high degree of interdependence,underlined by their shared institutional logics.This literature attempts to review and analysis institutional logic in the field of entrepreneurship and integrates institutional logic into entrepreneurs’personal background,experience,and other social characteristics,and study how institutional logic operates.It is recommended that future researchers take entrepreneurs as the research object and conduct more in-depth research on the evolution of organizational response strategies when political and cultural conflicts occur between different groups within the enterprise,combined with institutional logic theory. 展开更多
关键词 Institutional logic ENTREPRENEURSHIP ENTREPRENEUR
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Discrete and Topological Correspondence Theory for Modal MeetImplication Logic and Modal MeetSemilattice Logic in Filter Semantics
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作者 Fei Liang Zhiguang Zhao 《逻辑学研究》 2025年第3期25-66,共42页
In the present paper,we give a systematic study of the discrete correspondence the-ory and topological correspondence theory of modal meet-implication logic and moda1 meet-semilattice logic,in the semantics provided i... In the present paper,we give a systematic study of the discrete correspondence the-ory and topological correspondence theory of modal meet-implication logic and moda1 meet-semilattice logic,in the semantics provided in[21].The special features of the present paper include the following three points:the first one is that the semantic structure used is based on a semilattice rather than an ordinary partial order,the second one is that the propositional vari-ables are interpreted as filters rather than upsets,and the nominals,which are the“first-order counterparts of propositional variables,are interpreted as principal filters rather than principal upsets;the third one is that in topological correspondence theory,the collection of admissi-ble valuations is not closed under taking disjunction,which makes the proof of the topological Ackermann 1emma different from existing settings. 展开更多
关键词 topological correspondence theory SEMILATTICE modal meet implication logic modal meet semilattice logic discrete correspondence theory semantic structure propositional variables filter semantics
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Retraced Multi-dimensional Chinese Logic System behind Chinese Medicine
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作者 Edwin C.L.Yu 《Chinese Medicine and Culture》 2025年第1期1-12,共12页
The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed... The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed out from such logic system. This article aims to rearticulate the underlying lucid multi-dimensional logic system, which faded in obscurity only because of time-out loss of the mid-right concept. Retracing this past tacit but important concept could uncover a multi-dimensional system over a point relating to all matters while capturing the central core of the matter. The seemingly unmanageable multidimensional logic was strengthened by verification processes which affirmed its further extensions, and made up the language of the people, the concepts of yin-yang(阴阳), and the development of extensions of Ba Gua(八卦) derivatives, which furthered the interpretation of the space-time properties and Chinese medicine. 展开更多
关键词 Multi-dimensional logic system Traditional Chinese medicine YIN-YANG
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Logic and Practice of Ideological and Political Thinking in Advanced Mathematics Courses
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作者 Yaxian Hao Keyan Liu 《Journal of Contemporary Educational Research》 2025年第6期42-49,共8页
As a fundamental course in science and engineering education at universities,advanced mathematics plays an irreplaceable role in cultivating students’logical thinking,scientific spirit,and comprehensive qualities.Int... As a fundamental course in science and engineering education at universities,advanced mathematics plays an irreplaceable role in cultivating students’logical thinking,scientific spirit,and comprehensive qualities.Integrating ideological and political education into advanced mathematics teaching is not only an inevitable requirement for achieving the goal of“three-dimensional and holistic education”but also a crucial path for promoting students’comprehensive development.This article delves into the necessary logic,practical possibilities,and real-world challenges of ideological and political education in advanced mathematics courses,systematically analyzing the implementation pathways and illustrating practical approaches through specific cases.Meanwhile,to address issues such as insufficient teacher capability,lagging resource development,disconnected instructional design,and inadequate evaluation mechanisms encountered during implementation,this article proposes practical improvement strategies.It aims to provide theoretical insights and practical guidance for the further advancement of ideological and political education in advanced mathematics courses. 展开更多
关键词 Advanced mathematics Curriculum ideology and politics logical framework Practical pathways
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Deep Embedding of Literature Logical Structure in LBL-RBL Pedagogy:A Novel Pathway to Enhance Thesis Proposal Competency in Neuropathophysiology Courses
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作者 Rongrong Mao Guangya He +1 位作者 Heng Tan Qian Wang 《Journal of Contemporary Educational Research》 2025年第7期48-55,共8页
Graduate students universally struggle with vague topics,insufficient innovation,and logical gaps in research proposals,highlighting the need for structured scientific training.This study presents an innovative pedago... Graduate students universally struggle with vague topics,insufficient innovation,and logical gaps in research proposals,highlighting the need for structured scientific training.This study presents an innovative pedagogical model embedding scholarly literature’s logical architecture into LBL-RBL hybrid teaching,implemented in Kunming Medical University’s Neuropathophysiology course.Targeting the complexity of neurological disease mechanisms,the course integrates lecture-based learning(LBL)and research-based learning(RBL)through a small-cohort framework featuring personalized literature-logic embedding→targeted lecture reinforcement→multi-round proposal iteration.Faculty deconstructed domain literature to establish a three-phase training system(“Logic Demonstration-Methodology Mapping-Proposal Embedding”),systematically merging academic logic with research methodology over 9 weeks.Results demonstrate that this problem-driven approach creates authentic scientific inquiry scenarios,activating student knowledge co-construction and collaborative exploration.It successfully enables dynamic competency progression through“cognitive deconstruction→methodological practice→proposal refinement,”significantly enhancing proposal rigor and innovation.This study offers a scalable dual-track solution for cultivating advanced scientific capabilities in medical graduate education. 展开更多
关键词 Literature logical structure LBL-RBL pedagogy Thesis proposal Neuropathophysiology Research competency cultivation
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Logically ordered control of organic room-temperature long-lived supramolecular luminophors
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作者 Xinhui Fan Yonghao Fan +10 位作者 Yuli Dang Puhui Xie Xin Li Zhanqi Cao Song Jiang Lijie Liu Xin Zheng Lixia Xie Caoyuan Niu Guoxing Liu Yong Chen 《Chinese Chemical Letters》 2025年第8期303-308,共6页
Herein,a ternary supramolecular assembly(BPP-BQ?CB[8]-SCD)is successfully constructed by a bromophenylpyridine-tethered-bromoisoquinoline(BPP-BQ),cucurbit[8]uril(CB[8])and sulfonatedβ-cyclodextrin(SCD)via successive ... Herein,a ternary supramolecular assembly(BPP-BQ?CB[8]-SCD)is successfully constructed by a bromophenylpyridine-tethered-bromoisoquinoline(BPP-BQ),cucurbit[8]uril(CB[8])and sulfonatedβ-cyclodextrin(SCD)via successive assembling way,exhibiting progressively enhanced green roomtemperature phosphorescence(RTP).The self-aggregates of BPP-BQ?CB[8]-SCD accommodate an energy acceptor rhodamine B(Rh B)to form a light-harvesting system(BPP-BQ?CB[8]-SCD@Rh B)with further enhanced yellow long-lifetime luminescence with large Stokes shift based on triplet-singlet F?rster resonance energy transfer(TS-FRET).Crucially,the introduction of a photoactive diarylethene achieves the long-lived photoluminescence of BPP-BQ?CB[8]-SCD@Rh B to be switched with the efficiency of up to98%through logically ordered lowering/enhancing RTP performance of the energy donor and intercepting/restoring TS-FRET pathway,when stimulated by host-vip competition and light illumination in sequence.Moreover,BPP-BQ?CB[8]-SCD@Rh B is evenly doped into polyvinyl alcohol or polyacrylamide to obtain high-performance luminescent films with long afterglow.The abovementioned logically ordered stimulus-switched long-lived emission enables the light-harvesting system in both solution and solid state to be applied in high-security-level information encryption and transformation,and anticounterfeiting. 展开更多
关键词 Supramolecular chemistry logically ordered control Long-lived luminescentswitch TS-FRET Stepwise assembly RTP
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