The Maochang bauxite in Guizhou Province is one of the important aluminum ore deposits in southwestern China. Ferruginous spherules, measuring about a few microns across, were found in the transitional layer of the de...The Maochang bauxite in Guizhou Province is one of the important aluminum ore deposits in southwestern China. Ferruginous spherules, measuring about a few microns across, were found in the transitional layer of the deposit. The EDS and XRD results show that the microspherules are composed mostly of iron (hydr)oxide minerals (goethite) with only weak presence of aluminum and silicon. Occasionally, some pyrite micrograins with dissolved surface are found associated with goethite within the spherules. It is thus suggested that microspherules are linked to pyrite oxidization. It is also thought that microbial activities contribute not only to pyrite oxidization, but also to ball-like assemblage of the iron (hydr)oxides. The mechanism of the formation of ferruginous microspherules is also believed to be important in studying geomicrobiology of bauxite.展开更多
The effects of mechanical activation in a planetary mill on the structural changes and microstructural characteristics of the components of ferruginous quartzite beneficiation railings generated by wet magnetic separa...The effects of mechanical activation in a planetary mill on the structural changes and microstructural characteristics of the components of ferruginous quartzite beneficiation railings generated by wet magnetic separation process were studied using X-ray and laser diffraction methods. The results revealed the relationship between variations in the mean particle size of activated powders and the milling time. The crystallite size, microstrain, lattice parameters and unit cell volumes were determined for different milling times in powder samples of quartz, hematite, dolomite, and magnetite from the beneficiation tailings. The main trends in the variation of the crystallite size of quartz, hematite, dolomite, and magnetite as a function mean particle size of powder samples were revealed. Changes in the particle shape as a function of the activation time was also investigated.展开更多
Abstract The use of microbial technologies in agriculture is rapidly expanding with the discovery of new bacterial strains effective in improving plant growth. In this study, we tested and highlighted the efficacy of ...Abstract The use of microbial technologies in agriculture is rapidly expanding with the discovery of new bacterial strains effective in improving plant growth. In this study, we tested and highlighted the efficacy of PGPR (Plant Growth Promoting Rhizobacteria) alone or in a consortium on maize growth. For this purpose, a greenhouse experiment was carried out in pots containing sterilized ferruginous soil for 30 days. The corn seeds of the EVDT 97 SRT C1 variety were inoculated with bacterial suspensions of concentration 108 UFC/ml. The experimental device was a random block of 16 three-repeat treatments. The incidence of PGPR inoculated strains is assessed on the biomass growth and yield parameters of maize. At the end of the trial, the results showed that inoculation stimulated plant growth and development and resulted in a significant increase in the height, diameter at the collar, leaf surface and dry weight of aerial biomass. 20.15%, 21%, 32.77% and 37.73% respectively compared to controls, especially in corn plants inoculated with B. thurengiensis;B.thurengiensis B.panthethonicus- S.marcescens et Pseudomonas cichorii- Pseudomonas. putida- Pseudomonas syringae. These results show the potential of using these rhizobacteria as biological inoculants to improve maize productivity in Benin.展开更多
The authors regret to report some missing information in the synthetic reagents and associated changes of the paper.On page 511,the author information reads:“5.0 mmol of citric acid(C_(6)H_(8)O_(7)),5.0 mmol of ferri...The authors regret to report some missing information in the synthetic reagents and associated changes of the paper.On page 511,the author information reads:“5.0 mmol of citric acid(C_(6)H_(8)O_(7)),5.0 mmol of ferric chloride hexahydrate(FeCl_(3)·6H_(2)O),and 10.0 mmol of o-phenylenediamine(C_(6)H_(8)N_(2))were combined with 40 mL of deionized water and magnetically stirred until fully dissolved.”展开更多
The invasive insect pest, red palm weevil (RPW), Rhynchophorus ferrugineus, poses a significant threat to date production, causing substantial economic damage. If uncontrolled, RPW leads the severely infested host tre...The invasive insect pest, red palm weevil (RPW), Rhynchophorus ferrugineus, poses a significant threat to date production, causing substantial economic damage. If uncontrolled, RPW leads the severely infested host tree to collapse and eventually die. The symbiotic associations with microorganisms and RPW in their gut may help their host insects’ establishment, development, nutrition assimilation, and survival. The objective of this research was the molecular characterization of the microbiome of RPW. In this study, the microbiome was compared among different tissues in females and males of RPW of three different morphs and larvae collected from date palm plantations in the Kingdom of Bahrain. A 251-bp segment of bacterial 16S rRNA was amplified by PCR, sequenced, and processed using the bioinformatics platform QIIME2. One ASV, corresponding to the obligate weevil symbiont Nardonella, predominated in adult female samples, constituting 56 ± 7% of total reads, but was less dominant in male samples (12 ± 3%) and larval samples (2.6 ± 1.9%). For females, samples that included reproductive tissues were almost entirely composed of Nardonella (88% - 99%). When Nardonella was excluded from analyses, there were no differences between adult females and adult males, but larval samples were more species-rich and differed in microbial composition from adults. There were no consistent differences in the microbiomes among morphs. Several specimens showed evidence of infection with host-specific strains of Spiroplasma-like members of the Entomoplasmatales, which are often pathogens or vertically transmitted symbionts. Such close microbial associates deserve additional attention as potential routes to control this destructive date palm pest.展开更多
Jarosite and extracellular polymer substance generated during pure culture and bioleaching process have been widely accepted the main transformation of decreasing iron in the medium.In the present work,acidophilus bio...Jarosite and extracellular polymer substance generated during pure culture and bioleaching process have been widely accepted the main transformation of decreasing iron in the medium.In the present work,acidophilus bioleaching organisms Ferroplasma thermophilum,Leptospirillum ferriphilum and Acidithioobacillus ferrooxidans were cultured.It was found that they can live in low pH environment,and more than10particles in each cell intracellular nano-particles are synthesized in the cells.By analyzing the morphology and chemical composition of nano-particles,they were found to contain iron,and the three microorganisms belonged to high-yielding strains.The results show that the transformation of the decreasing iron ions is not only generating jarosite,but also taken into cells and synthesizing ferruginous nano-particles.展开更多
The aim of the study was to investigate the effects of five plant growth-promoting rhizobacteria (PGPR) (Bacillus panthothenicus;Pseudomonas Cichorii;Pseudomonas Putida;Pseudomonas syringae and Serratia marcescens) on...The aim of the study was to investigate the effects of five plant growth-promoting rhizobacteria (PGPR) (Bacillus panthothenicus;Pseudomonas Cichorii;Pseudomonas Putida;Pseudomonas syringae and Serratia marcescens) on the growth and yield of maize on a ferruginous soil under field condition. Maize seeds were inoculated with 10 ml of bacterial suspension. Study was conducted in a completely randomized design with fifteen treatments and three replicates. A half-dose of recommended (13, 17, 17 kg?ha?1) NPK was applied 15 days after emergence. The results show that the Serratia marcescens + 50% NPK treatment yielded the best results for height, fresh underground biomass, dry aboveground biomass, dry underground biomass, and grain yield with respective increases of 41.09%, 217.5%, 213.34%, 93.82%, and 39.05% compared to the control. Maximum stem diameter (increases of 49.65%) was recorded in the plants treated with 100% NPK (full dose NPK) while the highest leaf area (466.36 ± 9.57 cm2), obtained on plant treated with Pseudomonas putida + 50% NPK was 32.08% greater than in the non-inoculated control. Our results suggest the use of these rhizobacteria as biological fertilizers for enhancing the growth and maize seed yield in ferruginous soil in the North of Benin.展开更多
The compound (1 z)-2-(hydroxymethyl)-dodec-1-ene-1,3-diol was previously isolated from the integument of the red palm weevil Rhynhophorus ferruginous and found to antagonize calcium chloride induced dysrrhythmia i...The compound (1 z)-2-(hydroxymethyl)-dodec-1-ene-1,3-diol was previously isolated from the integument of the red palm weevil Rhynhophorus ferruginous and found to antagonize calcium chloride induced dysrrhythmia in mice. Further calcium-dependent pharmacological actions performed in this study revealed that it has the ability to inhibit platelets aggregation induced in guinea pigs with either ADP or archegonia acids, and the compound also decreased the arterial pressure in rats in a dose-dependent manner and exerted potential ant consultant activity in mice against pentylene tetrazole-induced seizures. However, no complete protection was observed. Analgesic studies in mice using the hot plate (58 ℃) revealed its potential analgesic activities. Its effective dose 50 (ED50) was 85.7 ± 6.3 mg/kg (N= 5). The compound seamed to produce all of the above actions via a calcium antagonistic action.展开更多
The objective of the study was to evaluate the effects of nine plant growth-promoting rhizobacteria (PGPR) alone or in combination on maize seed germination and seedling growth under laboratory and greenhouse conditio...The objective of the study was to evaluate the effects of nine plant growth-promoting rhizobacteria (PGPR) alone or in combination on maize seed germination and seedling growth under laboratory and greenhouse conditions. The germination and growth tests were carried out in square petri dishes and pots. Maize seeds were inoculated with suspension of 108 CFU/ml of rhizobacteria. The experimental device was a random block of 16 treatments with four repetitions. Germination test results showed that seeds inoculated with PGPR including the control induced good germination in the range of 93.75% to 100%. The vigor index and root length of the seeds treated with Bacillus panthothenicus were significantly improved by 76.64% and 58.86%, respectively, while the maximal lengths of the seedlings were obtained with Pseudomonas cichorii with an increase of 118.95%. In greenhouse experience, data demonstrated that Serratia marcescens better improved the leaf area, height and underground biomass, respectively by 58.83%, 108.43%, and 59.16% as compared to the control. The highest fresh aerial biomass and air dry matter was obtained with plants treated only with Pseudomonas putida. These results show the potential to use such rhizobacteria as biofertilizers to improve maize productivity in Benin.展开更多
This paper presents the first work of its kind within the confines of the study area. It unravels the distribution of the layers of conductive sand and their depths of interaction between freshwater from fresh sands a...This paper presents the first work of its kind within the confines of the study area. It unravels the distribution of the layers of conductive sand and their depths of interaction between freshwater from fresh sands and saltwater within the conductive layers in the coastal region of Akwa Ibom State (Nigeria) around the Gulf of Guinea. Vertical electrical sounding (VES) data whose fidelity was achieved by constraining the data by the available nearby logged borehole information during interpretation was the method applied. In the western region of the study area, the ferruginized and saline water layer is found within the depth range of 22 to 75 m deep. In the northern zone, conductive sandy layer is found within 50 to 210 m and in the eastern zone, the saline and ferruginized sandy layer is found within the depth of 88.5 m and above. Generally, the horizontal and vertical cross sections of the subsoil and the flow regime from water table depths have been delineated. With these information, water can be tapped in the area with caution and the flow direction determined can be used as input parameter in detailed contamination study.展开更多
Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alka...Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin. The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure. This dolomite mostly exhibits laminae of 0.1-1 mm thick and is often discovered with other minerals, such as albite, analcite, barite and dickite, which have at least two types of interbedded laminae. Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation, including Sb, Ba, Sr, Mn, and V. In addition, the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly. Oxygen isotope values (C^ISOpDB) range from 5.89%~ to 14.15%o with an average of 9.69%0. The ratio of 87Sr/86Sr is between 0.711648 and 0.719546, with an average of 0.714718. These data indicate that the depositional environment is a stable, blocked, anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults. The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water, consisting of many ions, including Ca2+, Mg2+ and Fe2+. Under the driving flow power of magmatic heat, gravity and compaction, the hy- drothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body, and boiled to explosion, and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered "hydroexplosion breccias". In the low-lying, unperturbed hot brine pool, far from the vent, the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hy- drotherm. This study of special rocks contributes to research into the causes of the formation of lacustrine carbonate rocks and dolostone. In particular, it provides new examples and research insights for future studies of the lacustrine dolomite from the similar Mesozoic and Cenozoic basins in China.展开更多
Biomineralization was a key development in a wide variety of organisms,yet its history prior to the Ediacaran remains poorly understood.In this paper,we describe~1420-1330 million year old microscopic tubes preserved ...Biomineralization was a key development in a wide variety of organisms,yet its history prior to the Ediacaran remains poorly understood.In this paper,we describe~1420-1330 million year old microscopic tubes preserved as siderite(FeCO_(3)).In size and shape these tubes closely resemble cyanobacterial sheaths forming mineralized mats.We consider two competing explanations for their formation.First,the tubes and associated sediment were originally composed of Ca-carbonate that was subsequently replaced by siderite.In this case,siderite mineralization was early,but post-mortem,as in early silicification,and preferentially preserved the more resilient sheath.However,no relict calcite is observed.Second,the Fe-carbonate mineralogy of the tubes and sediment is synsedimentary.In this case,photosynthetic oxygen may have precipitated Fe-oxyhydroxide that was promptly converted to siderite by dissimilatory iron reduction(DIR).Primary siderite mineralization of cyanobacteria has not been described before.Both explanations link photosynthetic processes to preferential sheath mineralization during the life of the cyanobacteria,as observed in present-day calcified cyanobacteria.This process might include CO_(2)-concentrating mechanisms(CCMs)linked to relatively low levels of atmospheric CO_(2),consistent with empirical estimates of mid-Proterozoic CO_(2)levels based on paleosols and weathering rinds.In either case,these cyanobacterium-like fossils preserved in siderite provide an early example of biomineralization and suggest the interactive in-fluences of both metabolic processes and ambient seawater chemistry.展开更多
文摘The Maochang bauxite in Guizhou Province is one of the important aluminum ore deposits in southwestern China. Ferruginous spherules, measuring about a few microns across, were found in the transitional layer of the deposit. The EDS and XRD results show that the microspherules are composed mostly of iron (hydr)oxide minerals (goethite) with only weak presence of aluminum and silicon. Occasionally, some pyrite micrograins with dissolved surface are found associated with goethite within the spherules. It is thus suggested that microspherules are linked to pyrite oxidization. It is also thought that microbial activities contribute not only to pyrite oxidization, but also to ball-like assemblage of the iron (hydr)oxides. The mechanism of the formation of ferruginous microspherules is also believed to be important in studying geomicrobiology of bauxite.
文摘The effects of mechanical activation in a planetary mill on the structural changes and microstructural characteristics of the components of ferruginous quartzite beneficiation railings generated by wet magnetic separation process were studied using X-ray and laser diffraction methods. The results revealed the relationship between variations in the mean particle size of activated powders and the milling time. The crystallite size, microstrain, lattice parameters and unit cell volumes were determined for different milling times in powder samples of quartz, hematite, dolomite, and magnetite from the beneficiation tailings. The main trends in the variation of the crystallite size of quartz, hematite, dolomite, and magnetite as a function mean particle size of powder samples were revealed. Changes in the particle shape as a function of the activation time was also investigated.
基金the West Africa Agricultural Productivity Program(WAAPP/PPAAO),the“Centre National de Specialisationsur le Mais(CNS-Mais)”and the“Fond National pour la Recherche Scientifique et de l’Innovation Technologique(FNRSIT)”of the Benin government for funding this project.
文摘Abstract The use of microbial technologies in agriculture is rapidly expanding with the discovery of new bacterial strains effective in improving plant growth. In this study, we tested and highlighted the efficacy of PGPR (Plant Growth Promoting Rhizobacteria) alone or in a consortium on maize growth. For this purpose, a greenhouse experiment was carried out in pots containing sterilized ferruginous soil for 30 days. The corn seeds of the EVDT 97 SRT C1 variety were inoculated with bacterial suspensions of concentration 108 UFC/ml. The experimental device was a random block of 16 three-repeat treatments. The incidence of PGPR inoculated strains is assessed on the biomass growth and yield parameters of maize. At the end of the trial, the results showed that inoculation stimulated plant growth and development and resulted in a significant increase in the height, diameter at the collar, leaf surface and dry weight of aerial biomass. 20.15%, 21%, 32.77% and 37.73% respectively compared to controls, especially in corn plants inoculated with B. thurengiensis;B.thurengiensis B.panthethonicus- S.marcescens et Pseudomonas cichorii- Pseudomonas. putida- Pseudomonas syringae. These results show the potential of using these rhizobacteria as biological inoculants to improve maize productivity in Benin.
文摘The authors regret to report some missing information in the synthetic reagents and associated changes of the paper.On page 511,the author information reads:“5.0 mmol of citric acid(C_(6)H_(8)O_(7)),5.0 mmol of ferric chloride hexahydrate(FeCl_(3)·6H_(2)O),and 10.0 mmol of o-phenylenediamine(C_(6)H_(8)N_(2))were combined with 40 mL of deionized water and magnetically stirred until fully dissolved.”
文摘The invasive insect pest, red palm weevil (RPW), Rhynchophorus ferrugineus, poses a significant threat to date production, causing substantial economic damage. If uncontrolled, RPW leads the severely infested host tree to collapse and eventually die. The symbiotic associations with microorganisms and RPW in their gut may help their host insects’ establishment, development, nutrition assimilation, and survival. The objective of this research was the molecular characterization of the microbiome of RPW. In this study, the microbiome was compared among different tissues in females and males of RPW of three different morphs and larvae collected from date palm plantations in the Kingdom of Bahrain. A 251-bp segment of bacterial 16S rRNA was amplified by PCR, sequenced, and processed using the bioinformatics platform QIIME2. One ASV, corresponding to the obligate weevil symbiont Nardonella, predominated in adult female samples, constituting 56 ± 7% of total reads, but was less dominant in male samples (12 ± 3%) and larval samples (2.6 ± 1.9%). For females, samples that included reproductive tissues were almost entirely composed of Nardonella (88% - 99%). When Nardonella was excluded from analyses, there were no differences between adult females and adult males, but larval samples were more species-rich and differed in microbial composition from adults. There were no consistent differences in the microbiomes among morphs. Several specimens showed evidence of infection with host-specific strains of Spiroplasma-like members of the Entomoplasmatales, which are often pathogens or vertically transmitted symbionts. Such close microbial associates deserve additional attention as potential routes to control this destructive date palm pest.
基金Project(51374248)supported by the National Natural Science Foundation of ChinaProject(NCET-13-0595)supported by the Program for New Century Excellent Talents in University of China+1 种基金Project(2016-SSRF-PT-006152)supported by the Shanghai Synchrotron Radiation Facility(SSRF),ChinaProject(2016-BEPC-PT-000855)supported by the Beijing Synchrotron Radiation Facility(BSRF),China
文摘Jarosite and extracellular polymer substance generated during pure culture and bioleaching process have been widely accepted the main transformation of decreasing iron in the medium.In the present work,acidophilus bioleaching organisms Ferroplasma thermophilum,Leptospirillum ferriphilum and Acidithioobacillus ferrooxidans were cultured.It was found that they can live in low pH environment,and more than10particles in each cell intracellular nano-particles are synthesized in the cells.By analyzing the morphology and chemical composition of nano-particles,they were found to contain iron,and the three microorganisms belonged to high-yielding strains.The results show that the transformation of the decreasing iron ions is not only generating jarosite,but also taken into cells and synthesizing ferruginous nano-particles.
基金This work was financially supported by“Centre National de Specialisation sur le Mais(CNS-Mais)”the“Fond National pour la Recherche Scientifique et de l’Innovation Technologique(FNRSIT)of the Benin government”The authors sincerely thank Mr AYETITON SOUMANOU Mashoudi,technician at North Agricultural Research Centre(CRA-Nord)for his valuable assistance during executing the experiment.
文摘The aim of the study was to investigate the effects of five plant growth-promoting rhizobacteria (PGPR) (Bacillus panthothenicus;Pseudomonas Cichorii;Pseudomonas Putida;Pseudomonas syringae and Serratia marcescens) on the growth and yield of maize on a ferruginous soil under field condition. Maize seeds were inoculated with 10 ml of bacterial suspension. Study was conducted in a completely randomized design with fifteen treatments and three replicates. A half-dose of recommended (13, 17, 17 kg?ha?1) NPK was applied 15 days after emergence. The results show that the Serratia marcescens + 50% NPK treatment yielded the best results for height, fresh underground biomass, dry aboveground biomass, dry underground biomass, and grain yield with respective increases of 41.09%, 217.5%, 213.34%, 93.82%, and 39.05% compared to the control. Maximum stem diameter (increases of 49.65%) was recorded in the plants treated with 100% NPK (full dose NPK) while the highest leaf area (466.36 ± 9.57 cm2), obtained on plant treated with Pseudomonas putida + 50% NPK was 32.08% greater than in the non-inoculated control. Our results suggest the use of these rhizobacteria as biological fertilizers for enhancing the growth and maize seed yield in ferruginous soil in the North of Benin.
文摘The compound (1 z)-2-(hydroxymethyl)-dodec-1-ene-1,3-diol was previously isolated from the integument of the red palm weevil Rhynhophorus ferruginous and found to antagonize calcium chloride induced dysrrhythmia in mice. Further calcium-dependent pharmacological actions performed in this study revealed that it has the ability to inhibit platelets aggregation induced in guinea pigs with either ADP or archegonia acids, and the compound also decreased the arterial pressure in rats in a dose-dependent manner and exerted potential ant consultant activity in mice against pentylene tetrazole-induced seizures. However, no complete protection was observed. Analgesic studies in mice using the hot plate (58 ℃) revealed its potential analgesic activities. Its effective dose 50 (ED50) was 85.7 ± 6.3 mg/kg (N= 5). The compound seamed to produce all of the above actions via a calcium antagonistic action.
基金the“Centre National de Specialisation sur le Mais(CNS-Mais),the National Fund for scientific research and Innovation Technology(FNRSIT)for theit financial supports.
文摘The objective of the study was to evaluate the effects of nine plant growth-promoting rhizobacteria (PGPR) alone or in combination on maize seed germination and seedling growth under laboratory and greenhouse conditions. The germination and growth tests were carried out in square petri dishes and pots. Maize seeds were inoculated with suspension of 108 CFU/ml of rhizobacteria. The experimental device was a random block of 16 treatments with four repetitions. Germination test results showed that seeds inoculated with PGPR including the control induced good germination in the range of 93.75% to 100%. The vigor index and root length of the seeds treated with Bacillus panthothenicus were significantly improved by 76.64% and 58.86%, respectively, while the maximal lengths of the seedlings were obtained with Pseudomonas cichorii with an increase of 118.95%. In greenhouse experience, data demonstrated that Serratia marcescens better improved the leaf area, height and underground biomass, respectively by 58.83%, 108.43%, and 59.16% as compared to the control. The highest fresh aerial biomass and air dry matter was obtained with plants treated only with Pseudomonas putida. These results show the potential to use such rhizobacteria as biofertilizers to improve maize productivity in Benin.
文摘This paper presents the first work of its kind within the confines of the study area. It unravels the distribution of the layers of conductive sand and their depths of interaction between freshwater from fresh sands and saltwater within the conductive layers in the coastal region of Akwa Ibom State (Nigeria) around the Gulf of Guinea. Vertical electrical sounding (VES) data whose fidelity was achieved by constraining the data by the available nearby logged borehole information during interpretation was the method applied. In the western region of the study area, the ferruginized and saline water layer is found within the depth range of 22 to 75 m deep. In the northern zone, conductive sandy layer is found within 50 to 210 m and in the eastern zone, the saline and ferruginized sandy layer is found within the depth of 88.5 m and above. Generally, the horizontal and vertical cross sections of the subsoil and the flow regime from water table depths have been delineated. With these information, water can be tapped in the area with caution and the flow direction determined can be used as input parameter in detailed contamination study.
基金supported by National Natural Science Foundation of China(Grant No.41002033)National Science and Technology Major Project(Grant No.2011ZX05030-003-02)Foundation for Fostering Middleaged and Young Key Teachers of Chengdu University of Technology
文摘Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin. The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure. This dolomite mostly exhibits laminae of 0.1-1 mm thick and is often discovered with other minerals, such as albite, analcite, barite and dickite, which have at least two types of interbedded laminae. Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation, including Sb, Ba, Sr, Mn, and V. In addition, the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly. Oxygen isotope values (C^ISOpDB) range from 5.89%~ to 14.15%o with an average of 9.69%0. The ratio of 87Sr/86Sr is between 0.711648 and 0.719546, with an average of 0.714718. These data indicate that the depositional environment is a stable, blocked, anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults. The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water, consisting of many ions, including Ca2+, Mg2+ and Fe2+. Under the driving flow power of magmatic heat, gravity and compaction, the hy- drothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body, and boiled to explosion, and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered "hydroexplosion breccias". In the low-lying, unperturbed hot brine pool, far from the vent, the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hy- drotherm. This study of special rocks contributes to research into the causes of the formation of lacustrine carbonate rocks and dolostone. In particular, it provides new examples and research insights for future studies of the lacustrine dolomite from the similar Mesozoic and Cenozoic basins in China.
基金supported by the National Natural Science Foundation of China(Grant Nos.41930320,41972028)the National Key Research and Development Project of China(Grant No.2020YFA0714803)the Chinese"111"Project(Grant No.B20011)。
文摘Biomineralization was a key development in a wide variety of organisms,yet its history prior to the Ediacaran remains poorly understood.In this paper,we describe~1420-1330 million year old microscopic tubes preserved as siderite(FeCO_(3)).In size and shape these tubes closely resemble cyanobacterial sheaths forming mineralized mats.We consider two competing explanations for their formation.First,the tubes and associated sediment were originally composed of Ca-carbonate that was subsequently replaced by siderite.In this case,siderite mineralization was early,but post-mortem,as in early silicification,and preferentially preserved the more resilient sheath.However,no relict calcite is observed.Second,the Fe-carbonate mineralogy of the tubes and sediment is synsedimentary.In this case,photosynthetic oxygen may have precipitated Fe-oxyhydroxide that was promptly converted to siderite by dissimilatory iron reduction(DIR).Primary siderite mineralization of cyanobacteria has not been described before.Both explanations link photosynthetic processes to preferential sheath mineralization during the life of the cyanobacteria,as observed in present-day calcified cyanobacteria.This process might include CO_(2)-concentrating mechanisms(CCMs)linked to relatively low levels of atmospheric CO_(2),consistent with empirical estimates of mid-Proterozoic CO_(2)levels based on paleosols and weathering rinds.In either case,these cyanobacterium-like fossils preserved in siderite provide an early example of biomineralization and suggest the interactive in-fluences of both metabolic processes and ambient seawater chemistry.