In this work,we report a fabrication of recyclable iron oxide decorated MoS_(2)nanosheets via a facile liq-uid exfoliation approach and solvothermal reaction for visible-light photodegradation of tetracycline.The prep...In this work,we report a fabrication of recyclable iron oxide decorated MoS_(2)nanosheets via a facile liq-uid exfoliation approach and solvothermal reaction for visible-light photodegradation of tetracycline.The prepared Fe_(3)O_(4)-MoS_(2)was characterized by X-ray diffraction,transmission electron microscopy,X-ray photoelectron spectros-copy,Raman spectroscopy,magnetic hysteresis,and nitrogen adsorption-desorption isotherms.Experimental results indicate that,successful attachment of Fe_(3)O_(4)nanoparticles to MoS_(2)sheets has been achieved.The enhanced surface area of Fe_(3)O_(4)-MoS_(2)induced high rates of adsorption and the adsorbed tetracycline was degraded to 90%after 150 min of visible exposure,which is better than that from pure MoS_(2).The introduction of Fe_(3)O_(4)not only enhances the photo-catalytic performance of Fe_(3)O_(4)-MoS_(2),but also enables its convenient recovery from water by an external magnetic field.Furthermore,both the photocatalytic activity and composite phase of Fe_(3)O_(4)-MoS_(2)were well-retained over cy-cles.Owing to its efficient photocatalytic activity,good stability and magnetic recyclability,the Fe_(3)O_(4)-MoS_(2)nano-composite is considered to be a promising photocatalyst for wastewater treatment.展开更多
Oxygen carriers play a fundamental role in chemical looping combustion(CLC).Iron-based carriers have been extensively investigated owing to their abundance and environmentally friendly.However,the reactivity and separ...Oxygen carriers play a fundamental role in chemical looping combustion(CLC).Iron-based carriers have been extensively investigated owing to their abundance and environmentally friendly.However,the reactivity and separability of iron-based carriers require further enhancement.This study investigates the effect of the concentration of Mn doping on reactivity,elastic properties and magnetic properties based on density functional theory(DFT)calculations.Theoretical results demonstrate that Mn doping effectively enhances reactivity by reducing the oxygen vacancy formation energy(E_(vac))from 2.33 to 0.87 eV.However,Mn doping introduces HV/EV Ms lattice distortions that deteriorate elastic properties,thereby reducing wear resistance,as evidenced by a 54.54%decrease in the hardness-to-Young's modulus ratio(H_(v)/E_(v))forα-Fe_(2)O_(3)and an 83.33%reduction for Fe_(3)O_(4).Furthermore,Mn doping also modifies magnetic properties.The maximum of saturation magnetization(M_(s))of Fe_(3)O_(4)reaches 121.02 emu/g at 33.33%Mn doping concentration.Finally,systematic evaluation identifies 33.33%as the optimal Mn doping concentration,achieving a balance in enhanced reactivity,superior magnetic performance,and retained elastic stability.展开更多
A facile one-step hydrothermal method has been reported to synthesize theα-Fe_(2)O_(3)nanosheet arrays with the preferred orientation along the[104]direction on the ITO substrate.Theα-Fe_(2)O_(3)nanosheet arrays-bas...A facile one-step hydrothermal method has been reported to synthesize theα-Fe_(2)O_(3)nanosheet arrays with the preferred orientation along the[104]direction on the ITO substrate.Theα-Fe_(2)O_(3)nanosheet arrays-based W/α-Fe_(2)O_(3)/ITO memristor has been achieved by depositing the circular W top electrodes on theα-Fe_(2)O_(3)nanosheet arrays.The as-prepared W/α-Fe_(2)O_(3)/ITO memristor shows a reliable nonvolatile bipolar resistive switching behavior with the high resistance ratio of about 103at the reading voltage of 0.1 V,good resistance retention over 10~3s,ultralow set voltage of-0.6 V and reset voltage of 0.7 V,and good durability.In addition,the tunneling conduction mechanism modified by the oxygen vacancies has been proposed and suggested to be responsible for the nonvolatile resistive switching behavior of the as-prepared W/α-Fe_(2)O_(3)/ITO memristor.This work demonstrates that the as-preparedα-Fe_(2)O_(3)nanosheet arrays-based W/α-Fe_(2)O_(3)/ITO memristor would be a promising candidate for further ultralow power nonvolatile memory applications.展开更多
文摘In this work,we report a fabrication of recyclable iron oxide decorated MoS_(2)nanosheets via a facile liq-uid exfoliation approach and solvothermal reaction for visible-light photodegradation of tetracycline.The prepared Fe_(3)O_(4)-MoS_(2)was characterized by X-ray diffraction,transmission electron microscopy,X-ray photoelectron spectros-copy,Raman spectroscopy,magnetic hysteresis,and nitrogen adsorption-desorption isotherms.Experimental results indicate that,successful attachment of Fe_(3)O_(4)nanoparticles to MoS_(2)sheets has been achieved.The enhanced surface area of Fe_(3)O_(4)-MoS_(2)induced high rates of adsorption and the adsorbed tetracycline was degraded to 90%after 150 min of visible exposure,which is better than that from pure MoS_(2).The introduction of Fe_(3)O_(4)not only enhances the photo-catalytic performance of Fe_(3)O_(4)-MoS_(2),but also enables its convenient recovery from water by an external magnetic field.Furthermore,both the photocatalytic activity and composite phase of Fe_(3)O_(4)-MoS_(2)were well-retained over cy-cles.Owing to its efficient photocatalytic activity,good stability and magnetic recyclability,the Fe_(3)O_(4)-MoS_(2)nano-composite is considered to be a promising photocatalyst for wastewater treatment.
基金Supported by National Natural Science Foundation of China(50976032,51776070)。
文摘Oxygen carriers play a fundamental role in chemical looping combustion(CLC).Iron-based carriers have been extensively investigated owing to their abundance and environmentally friendly.However,the reactivity and separability of iron-based carriers require further enhancement.This study investigates the effect of the concentration of Mn doping on reactivity,elastic properties and magnetic properties based on density functional theory(DFT)calculations.Theoretical results demonstrate that Mn doping effectively enhances reactivity by reducing the oxygen vacancy formation energy(E_(vac))from 2.33 to 0.87 eV.However,Mn doping introduces HV/EV Ms lattice distortions that deteriorate elastic properties,thereby reducing wear resistance,as evidenced by a 54.54%decrease in the hardness-to-Young's modulus ratio(H_(v)/E_(v))forα-Fe_(2)O_(3)and an 83.33%reduction for Fe_(3)O_(4).Furthermore,Mn doping also modifies magnetic properties.The maximum of saturation magnetization(M_(s))of Fe_(3)O_(4)reaches 121.02 emu/g at 33.33%Mn doping concentration.Finally,systematic evaluation identifies 33.33%as the optimal Mn doping concentration,achieving a balance in enhanced reactivity,superior magnetic performance,and retained elastic stability.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.62341305 and 22269002)the Natural Science Foundation of Guangxi Zhuang Autonomous Region,China(Grant No.2024GXNSFFA010007)+2 种基金the Science and Technology Project of Guangxi Zhuang Autonomous Region,China(Grant No.AD19110038)the Key Laboratory of AI and Information Processing,Education Department of Guangxi Zhuang Autonomous Region(Grant No.2024GXZDSY015)the Innovation Project of Guangxi University of Science and Technology Graduate Education(Grant No.GKYC202408)。
文摘A facile one-step hydrothermal method has been reported to synthesize theα-Fe_(2)O_(3)nanosheet arrays with the preferred orientation along the[104]direction on the ITO substrate.Theα-Fe_(2)O_(3)nanosheet arrays-based W/α-Fe_(2)O_(3)/ITO memristor has been achieved by depositing the circular W top electrodes on theα-Fe_(2)O_(3)nanosheet arrays.The as-prepared W/α-Fe_(2)O_(3)/ITO memristor shows a reliable nonvolatile bipolar resistive switching behavior with the high resistance ratio of about 103at the reading voltage of 0.1 V,good resistance retention over 10~3s,ultralow set voltage of-0.6 V and reset voltage of 0.7 V,and good durability.In addition,the tunneling conduction mechanism modified by the oxygen vacancies has been proposed and suggested to be responsible for the nonvolatile resistive switching behavior of the as-prepared W/α-Fe_(2)O_(3)/ITO memristor.This work demonstrates that the as-preparedα-Fe_(2)O_(3)nanosheet arrays-based W/α-Fe_(2)O_(3)/ITO memristor would be a promising candidate for further ultralow power nonvolatile memory applications.
