A single-phase Nd_(2)Fe_(14)B powder was prepared from end-of-life(EOL)wind turbine magnets by a combination of hydrogen processing of magnetic scrap(HPMS)and selective leaching with citric acid.The impact of leaching...A single-phase Nd_(2)Fe_(14)B powder was prepared from end-of-life(EOL)wind turbine magnets by a combination of hydrogen processing of magnetic scrap(HPMS)and selective leaching with citric acid.The impact of leaching time on chemical composition,particle size and magnetic properties was investigated.Due to the low reduction potential of rare earth element(REE),the Nd-rich phase was preferentially leached.The use of an acid concentration of 0.5 mol/L,a solid to liquid ratio of 1/10 and a leaching time of 30 min was sufficient to leach the Nd-rich phase.Atomic resolution transmission electron microscopy was employed to examine the surface structure and chemistry of the leached Nd_(2)Fe_(14)B powder.It is revealed that the leaching process affects not only the Nd-rich phase but also the matrix grains,resulting in the formation of a predominant oxygen-rich amorphous reaction layer,25 nm thick.However,the oxygen content is reduced from 3500 to 2500 ppm and the magnetic saturation is increased by 8%.This method is a promising addition to the HPMS process,as the powder can be mixed with fresh,unoxidized grain boundary phase to produce recycled magnets with high remanence.展开更多
To analyze the magnetic properties of Nd_(2)Fe_(14)B compound under high pressure,an improved two-sublattice molecular field model coupled with equivalent stress field was applied to study the effect of pressure on ma...To analyze the magnetic properties of Nd_(2)Fe_(14)B compound under high pressure,an improved two-sublattice molecular field model coupled with equivalent stress field was applied to study the effect of pressure on magnetization,magnetostriction coefficient,susceptibility and Curie temperature.The calculation results show that the pressure has a stronger effect on the magnetization of Fe sublattice compared to that of Nd sublattice at varied temperatures when the external magnetic field is parallel to the alignment direction.Saturated magnetization,initial susceptibility and magnetic moment of Nd_(2)Fe_(14)B compound are found to decrease gradually with pressure increasing,and the Curie temperature of Nd_(2)Fe_(14)B decreases to about 298 K under an applied pressure of 1.15 GPa.The results suggest that the pressure-induced magnetic phase transition of Nd2Fe14B occurs under 1.15 GPa at room temperature.展开更多
The arrangements of the easy magnetization axis[001]of columnar Nd_(2)Fe_(14)B crystals in the laser scanned layer on anisotropic sintered Nd_(15)Fe_(77)B_(8)magnets were investigated by XRD and the Bitter method.The ...The arrangements of the easy magnetization axis[001]of columnar Nd_(2)Fe_(14)B crystals in the laser scanned layer on anisotropic sintered Nd_(15)Fe_(77)B_(8)magnets were investigated by XRD and the Bitter method.The results show that the common effects of both the heat flux and the substrate magnetization orientation constrain the columnar Nd_(2)Fe_(14)B solidified from the laser melting pool to form the c-axis texture orientated with the same direction as that of the substrate,when the geometric relationship between the heat flux in the laser scanning layer and c-axis texture orientation of the substrate is perpendicular to each other,and if the laser scanning velocity is no less than 25 mm·min^(-1).The c-axes of columnar Nd_(2)Fe_(14)B crystals are no longer randomly distributed in the plane normal to their preferential growing direction as they are randomly done in both ingots cooled by water-cooling copper mould and directionally solidified Nd-Fe-B rods.展开更多
基金Project supported by the German Federal Ministry of Education and Research as part of the program"FH-Kooperativ"the European Commission under the Horizon Europe Research and Innovation Program(101058598)。
文摘A single-phase Nd_(2)Fe_(14)B powder was prepared from end-of-life(EOL)wind turbine magnets by a combination of hydrogen processing of magnetic scrap(HPMS)and selective leaching with citric acid.The impact of leaching time on chemical composition,particle size and magnetic properties was investigated.Due to the low reduction potential of rare earth element(REE),the Nd-rich phase was preferentially leached.The use of an acid concentration of 0.5 mol/L,a solid to liquid ratio of 1/10 and a leaching time of 30 min was sufficient to leach the Nd-rich phase.Atomic resolution transmission electron microscopy was employed to examine the surface structure and chemistry of the leached Nd_(2)Fe_(14)B powder.It is revealed that the leaching process affects not only the Nd-rich phase but also the matrix grains,resulting in the formation of a predominant oxygen-rich amorphous reaction layer,25 nm thick.However,the oxygen content is reduced from 3500 to 2500 ppm and the magnetic saturation is increased by 8%.This method is a promising addition to the HPMS process,as the powder can be mixed with fresh,unoxidized grain boundary phase to produce recycled magnets with high remanence.
基金This study was financially supported by the National Natural Science Foundation of China(No.11072036).
文摘To analyze the magnetic properties of Nd_(2)Fe_(14)B compound under high pressure,an improved two-sublattice molecular field model coupled with equivalent stress field was applied to study the effect of pressure on magnetization,magnetostriction coefficient,susceptibility and Curie temperature.The calculation results show that the pressure has a stronger effect on the magnetization of Fe sublattice compared to that of Nd sublattice at varied temperatures when the external magnetic field is parallel to the alignment direction.Saturated magnetization,initial susceptibility and magnetic moment of Nd_(2)Fe_(14)B compound are found to decrease gradually with pressure increasing,and the Curie temperature of Nd_(2)Fe_(14)B decreases to about 298 K under an applied pressure of 1.15 GPa.The results suggest that the pressure-induced magnetic phase transition of Nd2Fe14B occurs under 1.15 GPa at room temperature.
基金This work was financially supported by the Zhejiang Provincial Natural Science Fund of China(No.M503096)by Ministry of Science and Technology(No.2004CCA04000).
文摘The arrangements of the easy magnetization axis[001]of columnar Nd_(2)Fe_(14)B crystals in the laser scanned layer on anisotropic sintered Nd_(15)Fe_(77)B_(8)magnets were investigated by XRD and the Bitter method.The results show that the common effects of both the heat flux and the substrate magnetization orientation constrain the columnar Nd_(2)Fe_(14)B solidified from the laser melting pool to form the c-axis texture orientated with the same direction as that of the substrate,when the geometric relationship between the heat flux in the laser scanning layer and c-axis texture orientation of the substrate is perpendicular to each other,and if the laser scanning velocity is no less than 25 mm·min^(-1).The c-axes of columnar Nd_(2)Fe_(14)B crystals are no longer randomly distributed in the plane normal to their preferential growing direction as they are randomly done in both ingots cooled by water-cooling copper mould and directionally solidified Nd-Fe-B rods.
