以正硅酸乙酯(TEOS)为硅源,聚乙烯吡咯烷酮(PVP)为偶联剂,采用溶胶-凝胶法,在Fe Si Cr软磁合金表面包覆上SiO_2壳层。对包覆粉末进行压制成型和退火热处理,制备了高频下低损耗的Fe Si Cr/SiO_2软磁复合材料。通过XRD、FTIR、XPS、SEM等...以正硅酸乙酯(TEOS)为硅源,聚乙烯吡咯烷酮(PVP)为偶联剂,采用溶胶-凝胶法,在Fe Si Cr软磁合金表面包覆上SiO_2壳层。对包覆粉末进行压制成型和退火热处理,制备了高频下低损耗的Fe Si Cr/SiO_2软磁复合材料。通过XRD、FTIR、XPS、SEM等手段对包覆粉末的相结构、成分及表面微结构进行表征,通过四探针电阻仪、B-H分析仪等对复合材料电阻率、磁导率、功率损耗、品质因数等性能参数进行研究。结果表明:通过SiO_2绝缘包覆处理可大幅度提高FeSiCr软磁合金电阻率,降低高频下功率损耗,提高材料品质因数;随着TEOS添加量提高,包覆效果及材料性能呈现先提升后恶化的趋势,添加量为12 m L时,软磁复合材料综合性能最佳。展开更多
本文采用真空高压惰性气体雾化法制备了Fe Si Cr合金软磁粉末,适合的雾化参数为雾化压力4.5 MPa,金属熔体温度为1500℃,导液管内径为5 mm,通过场发射扫描电镜对粉末的微观形貌进行了研究;结果表明,气雾化法制备的Fe Si Cr粉末颗粒大部...本文采用真空高压惰性气体雾化法制备了Fe Si Cr合金软磁粉末,适合的雾化参数为雾化压力4.5 MPa,金属熔体温度为1500℃,导液管内径为5 mm,通过场发射扫描电镜对粉末的微观形貌进行了研究;结果表明,气雾化法制备的Fe Si Cr粉末颗粒大部分为近球形,且粉末的粒度分布比较均匀。展开更多
It has been known that metal FeSiCr powders with large average particle sizes have been typically employed to prepare magnetic powder cores(SMCs),with few studies reported on the influence of magnetic properties for o...It has been known that metal FeSiCr powders with large average particle sizes have been typically employed to prepare magnetic powder cores(SMCs),with few studies reported on the influence of magnetic properties for original powders with various average particle sizes less than 10m.In this work,SiO_(2)-coated FeSiCr SMCs with different small particle sizes were synthesized using the sol-gel process.The contribution of SiO_(2)coating amount and voids to the soft magnetic properties was elaborated.The mechanism was revealed such that smaller particle sizes with less voids could be beneficial for reducing core loss in the SMCs.By optimizing the core structure,permeability and magnetic loss of 26 and 262 kW/cm^(3)at 100 kHz and 50 mT were achieved at a particle size of 4.8m and ethyl orthosilicate addition of 0.1 mL/g.The best DC stacking performance,reaching 87%,was observed at an ethyl orthosilicate addition rate of 0.25 mL/g under 100 Oe.Compared to other soft magnetic composites(SMCs),the FeSiCr/SiO_(2)SMCs exhibit significantly reduced magnetic loss.It further reduces the magnetic loss of the powder core,providing a new strategy for applications of SMCs at high frequencies.展开更多
文摘以正硅酸乙酯(TEOS)为硅源,聚乙烯吡咯烷酮(PVP)为偶联剂,采用溶胶-凝胶法,在Fe Si Cr软磁合金表面包覆上SiO_2壳层。对包覆粉末进行压制成型和退火热处理,制备了高频下低损耗的Fe Si Cr/SiO_2软磁复合材料。通过XRD、FTIR、XPS、SEM等手段对包覆粉末的相结构、成分及表面微结构进行表征,通过四探针电阻仪、B-H分析仪等对复合材料电阻率、磁导率、功率损耗、品质因数等性能参数进行研究。结果表明:通过SiO_2绝缘包覆处理可大幅度提高FeSiCr软磁合金电阻率,降低高频下功率损耗,提高材料品质因数;随着TEOS添加量提高,包覆效果及材料性能呈现先提升后恶化的趋势,添加量为12 m L时,软磁复合材料综合性能最佳。
基金supported by the National Natural Science Foundation of China(Grant Nos.U2230119 and U23A20567)2022 Central Guidance on Local Science and Technology Development Projects(Grant No.2022ZYDF073)Outstanding Youth Fund of Sichuan Province(Grant No.22JCQN0005).
文摘It has been known that metal FeSiCr powders with large average particle sizes have been typically employed to prepare magnetic powder cores(SMCs),with few studies reported on the influence of magnetic properties for original powders with various average particle sizes less than 10m.In this work,SiO_(2)-coated FeSiCr SMCs with different small particle sizes were synthesized using the sol-gel process.The contribution of SiO_(2)coating amount and voids to the soft magnetic properties was elaborated.The mechanism was revealed such that smaller particle sizes with less voids could be beneficial for reducing core loss in the SMCs.By optimizing the core structure,permeability and magnetic loss of 26 and 262 kW/cm^(3)at 100 kHz and 50 mT were achieved at a particle size of 4.8m and ethyl orthosilicate addition of 0.1 mL/g.The best DC stacking performance,reaching 87%,was observed at an ethyl orthosilicate addition rate of 0.25 mL/g under 100 Oe.Compared to other soft magnetic composites(SMCs),the FeSiCr/SiO_(2)SMCs exhibit significantly reduced magnetic loss.It further reduces the magnetic loss of the powder core,providing a new strategy for applications of SMCs at high frequencies.
