Searching for advanced anode materials with excellent electrochemical properties in sodium-ion battery is essential and imperative for next-generation energy storage system to solve the energy shortage problem.In this...Searching for advanced anode materials with excellent electrochemical properties in sodium-ion battery is essential and imperative for next-generation energy storage system to solve the energy shortage problem.In this work,two-dimensional(2D)ultrathin FePS3 nanosheets,a typical ternary metal phosphosulfide,are first prepared by ultrasonic exfoliation.The novel 2D/2D heterojunction of FePS3 nanosheets@MXene composite is then successfully synthesized by in situ mixing ultrathin MXene nanosheets with FePS3 nanosheets.The resultant FePS3 nanosheets@MXene hybrids can increase the electronic conductivity and specific surface area,assuring excellent surface and interfacial charge transfer abilities.Furthermore,the unique heterojunction endows FePS3 nanosheets@MXene composite to promote the diffusion of Na^+ and alleviate the drastic change in volume in the cyclic process,enhancing the sodium storage capability.Consequently,the few-layered FePS3 nanosheets uniformly coated by ultrathin MXene provide an exceptional reversible capacity of 676.1 mAh g^−1 at the current of 100 mA g^−1 after 90 cycles,which is equivalent to around 90.6% of the second-cycle capacity(746.4 mAh g^−1).This work provides an original protocol for constructing 2D/2D material and demonstrates the FePS3@MXene composite as a potential anode material with excellent property for sodium-ion batteries.展开更多
As a preferable material in the field of photo-detection and catalysis,the characteristics of FePS3 in broad wavelength range have been proven by many experimental studies.However,FePS3 has not been used as a saturabl...As a preferable material in the field of photo-detection and catalysis,the characteristics of FePS3 in broad wavelength range have been proven by many experimental studies.However,FePS3 has not been used as a saturable absorber(SA)in fiber lasers yet.We propose and demonstrate the generation of a single wavelength and dual-wavelength based on an Er-doped fiber laser(EDFL)at 1.5μm by using an innovative FePS3 saturable absorber for the first time.The result shows that a stable passively Q-switched pulse can be generated,which demonstrates that the new two-dimensional(2D)material FePS3 served as SA provides a valid method to realize passively Q-switched laser.In addition,we achieve the output of the dual-wavelength pulse by properly rotating the polarization controller.To the best of our knowledge,the dual-wavelength pulse EDFL could be applied in biomedicine,spectroscopy,and sensing research.展开更多
FePS3,a classical 2D layered material with transition metal phosphorous trichalcogenides,was investigated as an anode material for Mg ion batteries.We used density functional theory to calculate the Mg storage propert...FePS3,a classical 2D layered material with transition metal phosphorous trichalcogenides,was investigated as an anode material for Mg ion batteries.We used density functional theory to calculate the Mg storage properties of FePS3,such as Mg adsorption energy,theoretical specific capacity,average voltage,diffusion energy barriers,volume change,and electronic conductivity.The theoretical specific capacity of the FePS3 monolayer is 585.6 mA h/g with a relatively low average voltage of 0.483 V(vs.Mg/Mg^2+),which is favorable to a high energy density.The slight change in volume and good electronic conductivity of bulk FePS 3 are beneficial to electrode stability during cycling.展开更多
The crystallographic and magnetic properties are presented for van der Waals antiferromagnetic FePS_3. High-quality single crystals of millimeter size have been successfully synthesized through the chemical vapor tran...The crystallographic and magnetic properties are presented for van der Waals antiferromagnetic FePS_3. High-quality single crystals of millimeter size have been successfully synthesized through the chemical vapor transport method. The layered structure and cleavability of the compound are apparent, which are beneficial for a potential exploration of the interesting low dimensional magnetism, as well as for incorporation of FePS_3 into van der Waals heterostructures. For the sake of completeness, we have measured both direct current(dc) and alternating current(ac) magnetic susceptibility.The paramagnetic to antiferromagnetic transition occurs at approximately T_N 115 K. The effective moment is larger than the spin-only effective moment, suggesting that an orbital contribution to the total angular momentum of the Fe^(2+) could be present. The ac susceptibility is independent of frequency, which means that the spin freezing effect is excluded.Strong anisotropy of out-of-plane and in-plane susceptibility has been shown, demonstrating the Ising-type magnetic order in FePS_3 system.展开更多
The layered van der Waals antiferromagnetic Fe PS_(3) has received considerable attention because long range magnetic ordering can remain with single atoms layer,which offers potential applications in future ultrathin...The layered van der Waals antiferromagnetic Fe PS_(3) has received considerable attention because long range magnetic ordering can remain with single atoms layer,which offers potential applications in future ultrathin devices.Here,we perform Raman spectroscopy to systematically explore the variations of lattice vibration and crystal structure under pressure up to 18.9 GPa.We observe two structural phase transitions at approximately 4 GPa and 13 GPa,respectively.Moreover,by monitoring spin-related Raman modes,we demonstrate a pressure-induced magnetic structure transition above 2 GPa.These modes disappear accompanying the second structural phase transition and insulator-to-metal transition(IMT),indicating the suppression of long-range magnetic ordering,in agreement with earlier neutron powder diffraction experiments.展开更多
A 60%Fe/Al_2O_3 catalyst was prepared by the co-precipitation method.It was reduced by H_2 to produce metallic Fe,which was then sulfided by CS_2 to Fe_(0.96) S and Fe_3S_4 or phosphided by triphenylphosphine(PPh3) in...A 60%Fe/Al_2O_3 catalyst was prepared by the co-precipitation method.It was reduced by H_2 to produce metallic Fe,which was then sulfided by CS_2 to Fe_(0.96) S and Fe_3S_4 or phosphided by triphenylphosphine(PPh3) in liquid phases to Fe2 P and Fe P.It was found that the iron sulfides(Fe0.96 S and Fe_3S_4) exhibited the low activity for the hydrodesulfurization(HDS) reactions.The HDS activity was also low on the Fe(metal)/Al_2O_3 and Fe_2 P/Al_2O_3 catalysts since they were converted into Fe0.96 S and Fe_3S_4 during the HDS reactions.In contrast,the FeP/Al_2O_3 was found to be stable and active for the HDS reactions.In particular,Fe P/Al_2O_3 possessed significantly smaller Fe P particles than Fe P/C,leading to the significant higher HDS activity of FeP/Al_2O_3 than Fe P/C.展开更多
Two new intercalation compounds Fe0.90PS3(phen)0.41 (1) (phen stands for 1,10-phenanthroline including a part of 1, 10-phenanthroline H+) and Fe0.83PS3(bipy)0.34 (2) (bipy stands for 2,2'-bipyridine H+ ) were synt...Two new intercalation compounds Fe0.90PS3(phen)0.41 (1) (phen stands for 1,10-phenanthroline including a part of 1, 10-phenanthroline H+) and Fe0.83PS3(bipy)0.34 (2) (bipy stands for 2,2'-bipyridine H+ ) were synthesized by the reaction of the layered FePS, with 1,10-phenanthroline or 2,2'-bipyridine in the presence of anilinium chloride. They were characterized by elemental analyses, powder X-ray diffraction (XRD), infrared spectroscopy. The lattice spacing of the intercalate was expanded by 0.90 nm for Fe0.90PS3(phen)0.41 and 0.57 nm for Fe0.83PS3(bipy)0.34 withrespect to the pristine FePS3, indicating that the ring plane of the vips is perpendicular to the layer of the host. The UV-vis absorption spectra of the filtrate in preparation of the intercalates indicate that 1, 10-phenanthroline or 2,2'-bipyridine also acts as a complexing agent to remove intralamellar Fe2+ ions into the solution during intercalation. The magnetic properties of 1 and 2 were studied.展开更多
基金support funding is from the National Natural Science Foundation of China(51871119 and 51901100)China Jiangsu Specially Appointed Professor,Jiangsu Provincial Founds for Natural Science Foundation(BK20170793 and BK20180015)+2 种基金China Postdoctoral Science Foundation(2018M640481 and 2019T120426)Jiangsu Postdoctoral Research Fund(2019K003 and 2019K201)Jiangsu-Innovate UK Business Competition(BZ2017061)
文摘Searching for advanced anode materials with excellent electrochemical properties in sodium-ion battery is essential and imperative for next-generation energy storage system to solve the energy shortage problem.In this work,two-dimensional(2D)ultrathin FePS3 nanosheets,a typical ternary metal phosphosulfide,are first prepared by ultrasonic exfoliation.The novel 2D/2D heterojunction of FePS3 nanosheets@MXene composite is then successfully synthesized by in situ mixing ultrathin MXene nanosheets with FePS3 nanosheets.The resultant FePS3 nanosheets@MXene hybrids can increase the electronic conductivity and specific surface area,assuring excellent surface and interfacial charge transfer abilities.Furthermore,the unique heterojunction endows FePS3 nanosheets@MXene composite to promote the diffusion of Na^+ and alleviate the drastic change in volume in the cyclic process,enhancing the sodium storage capability.Consequently,the few-layered FePS3 nanosheets uniformly coated by ultrathin MXene provide an exceptional reversible capacity of 676.1 mAh g^−1 at the current of 100 mA g^−1 after 90 cycles,which is equivalent to around 90.6% of the second-cycle capacity(746.4 mAh g^−1).This work provides an original protocol for constructing 2D/2D material and demonstrates the FePS3@MXene composite as a potential anode material with excellent property for sodium-ion batteries.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61875223 and 11574349)the Natural Science Foundation of Hunan Province,China(Grant No.2018JJ3610)+1 种基金the Natural Science Foundation of Jiangsu Province,China(Grant Nos.BK20150365 and BK20170424)the Natural Science Foundation of Hainan Province,China(Grant No.117111)
文摘As a preferable material in the field of photo-detection and catalysis,the characteristics of FePS3 in broad wavelength range have been proven by many experimental studies.However,FePS3 has not been used as a saturable absorber(SA)in fiber lasers yet.We propose and demonstrate the generation of a single wavelength and dual-wavelength based on an Er-doped fiber laser(EDFL)at 1.5μm by using an innovative FePS3 saturable absorber for the first time.The result shows that a stable passively Q-switched pulse can be generated,which demonstrates that the new two-dimensional(2D)material FePS3 served as SA provides a valid method to realize passively Q-switched laser.In addition,we achieve the output of the dual-wavelength pulse by properly rotating the polarization controller.To the best of our knowledge,the dual-wavelength pulse EDFL could be applied in biomedicine,spectroscopy,and sensing research.
基金supported by Tianjin Science and Technology Project(19YFSLQY00070)the National Natural Science Foundation of China(No.21878216)the Opening Foundation of State Key Laboratory of Organic-Inorganic Composites,Beijing University of Chemical Technology(oic-201901004,oic-201801003).
文摘FePS3,a classical 2D layered material with transition metal phosphorous trichalcogenides,was investigated as an anode material for Mg ion batteries.We used density functional theory to calculate the Mg storage properties of FePS3,such as Mg adsorption energy,theoretical specific capacity,average voltage,diffusion energy barriers,volume change,and electronic conductivity.The theoretical specific capacity of the FePS3 monolayer is 585.6 mA h/g with a relatively low average voltage of 0.483 V(vs.Mg/Mg^2+),which is favorable to a high energy density.The slight change in volume and good electronic conductivity of bulk FePS 3 are beneficial to electrode stability during cycling.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11404169,51602159,and 11704196)the Scientific Research Foundation of Nanjing University of Posts&Telecommunications,China(Grant Nos.NY217043 and NY218021)the Postgraduate Research&Practice Innovation Program of Jiangsu Province,China(Grant Nos.KYCX17 0754 and SJCX18 0287)
文摘The crystallographic and magnetic properties are presented for van der Waals antiferromagnetic FePS_3. High-quality single crystals of millimeter size have been successfully synthesized through the chemical vapor transport method. The layered structure and cleavability of the compound are apparent, which are beneficial for a potential exploration of the interesting low dimensional magnetism, as well as for incorporation of FePS_3 into van der Waals heterostructures. For the sake of completeness, we have measured both direct current(dc) and alternating current(ac) magnetic susceptibility.The paramagnetic to antiferromagnetic transition occurs at approximately T_N 115 K. The effective moment is larger than the spin-only effective moment, suggesting that an orbital contribution to the total angular momentum of the Fe^(2+) could be present. The ac susceptibility is independent of frequency, which means that the spin freezing effect is excluded.Strong anisotropy of out-of-plane and in-plane susceptibility has been shown, demonstrating the Ising-type magnetic order in FePS_3 system.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52002372,12004387,51672279,51727806,11874361,and 11774354))Science Challenge Project(Grant No.TZ2016001)the CASHIPS Director’s Fund(Grant No.YZJJ201705)。
文摘The layered van der Waals antiferromagnetic Fe PS_(3) has received considerable attention because long range magnetic ordering can remain with single atoms layer,which offers potential applications in future ultrathin devices.Here,we perform Raman spectroscopy to systematically explore the variations of lattice vibration and crystal structure under pressure up to 18.9 GPa.We observe two structural phase transitions at approximately 4 GPa and 13 GPa,respectively.Moreover,by monitoring spin-related Raman modes,we demonstrate a pressure-induced magnetic structure transition above 2 GPa.These modes disappear accompanying the second structural phase transition and insulator-to-metal transition(IMT),indicating the suppression of long-range magnetic ordering,in agreement with earlier neutron powder diffraction experiments.
基金Financial supports from the NSFC-DFG (21761132006),NSFC (21773108)fundamental research funds for central universities are acknowledged
文摘A 60%Fe/Al_2O_3 catalyst was prepared by the co-precipitation method.It was reduced by H_2 to produce metallic Fe,which was then sulfided by CS_2 to Fe_(0.96) S and Fe_3S_4 or phosphided by triphenylphosphine(PPh3) in liquid phases to Fe2 P and Fe P.It was found that the iron sulfides(Fe0.96 S and Fe_3S_4) exhibited the low activity for the hydrodesulfurization(HDS) reactions.The HDS activity was also low on the Fe(metal)/Al_2O_3 and Fe_2 P/Al_2O_3 catalysts since they were converted into Fe0.96 S and Fe_3S_4 during the HDS reactions.In contrast,the FeP/Al_2O_3 was found to be stable and active for the HDS reactions.In particular,Fe P/Al_2O_3 possessed significantly smaller Fe P particles than Fe P/C,leading to the significant higher HDS activity of FeP/Al_2O_3 than Fe P/C.
基金Project supported by the National Science Foundation of China (No. 29582001) and the Education Ministry of China (No. 96048610).
文摘Two new intercalation compounds Fe0.90PS3(phen)0.41 (1) (phen stands for 1,10-phenanthroline including a part of 1, 10-phenanthroline H+) and Fe0.83PS3(bipy)0.34 (2) (bipy stands for 2,2'-bipyridine H+ ) were synthesized by the reaction of the layered FePS, with 1,10-phenanthroline or 2,2'-bipyridine in the presence of anilinium chloride. They were characterized by elemental analyses, powder X-ray diffraction (XRD), infrared spectroscopy. The lattice spacing of the intercalate was expanded by 0.90 nm for Fe0.90PS3(phen)0.41 and 0.57 nm for Fe0.83PS3(bipy)0.34 withrespect to the pristine FePS3, indicating that the ring plane of the vips is perpendicular to the layer of the host. The UV-vis absorption spectra of the filtrate in preparation of the intercalates indicate that 1, 10-phenanthroline or 2,2'-bipyridine also acts as a complexing agent to remove intralamellar Fe2+ ions into the solution during intercalation. The magnetic properties of 1 and 2 were studied.
