This paper proposes a distributed event-triggered control(ETC)framework to address cooperative target fencing challenges in UAV swarm.The proposed architecture eliminates the reliance on preset formation parameters wh...This paper proposes a distributed event-triggered control(ETC)framework to address cooperative target fencing challenges in UAV swarm.The proposed architecture eliminates the reliance on preset formation parameters while achieving multi-objective cooperative control for target fencing,network connectivity preservation,collision avoidance,and communication efficiency optimization.Firstly,a differential state observer is constructed to obtain the target's unmeasurable states.Secondly,leveraging swarm selforganization principles,a geometric-constraint-free distributed fencing controller is designed by integrating potential field methods with consensus theory.The controller dynamically adjusts inter-UAV distances via single potential function,enabling coordinated optimization of persistent network connectivity and collision-free motion during target fencing.Thirdly,a dual-threshold ETC mechanism based on velocity consensus deviation and fencing error is proposed,which can be triggered based on task features to dynamically adjust the communication frequency,significantly reduce the communication burden and exclude Zeno behavior.Theoretical analysis demonstrates the stability of closed-loop systems.Multi-scenario simulations show that the proposed method can achieve robust fencing under target maneuverability,partial UAV failures,and communication disturbances.展开更多
In the pursuit of high-performance proton exchange membrane fuel cells(PEMFCs),obtaining durable Pt-based intermetallic catalysts with small particle sizes for oxygen reduction reaction(ORR)stands as a crucial yet cha...In the pursuit of high-performance proton exchange membrane fuel cells(PEMFCs),obtaining durable Pt-based intermetallic catalysts with small particle sizes for oxygen reduction reaction(ORR)stands as a crucial yet challenging topic.Herein,we propose an idea of catalyst design utilizing Fe-phenanthroline(Phen)complex as precursor to integrate metal-nitrogen-carbon(M-N-C)with the strong anchoring effect into carbon shells,synthesizing highly ordered and small-sized(3.59 nm)PtFe intermetallic catalyst coated with iron-nitrogen-carbon(FeNC)shells(L1_(0)-PtFe@FeNC).The strong Fe-Phen interaction ensures the uniform dispersion of Fe species on Pt seeds so as to form protective shells suppressing the agglomeration and dissolution of PtFe nanoparticles(NPs)under the high-temperature annealing or harsh operational conditions.It exhibits excellent mass activity(MA)that is about five-fold increase compared to the commercial Pt/C,as well as the significantly improved MA retention after 30,000 potential cycles(68.2%vs.45.3%).Nitrogen-doped carbon(NC)shells and pure carbon(C)shells are used as comparison to demonstrate the advantages of FeNC shells.Durability test results show that NC and C shells obviously degrade after potential cycles,while well-preserved FeNC shells guarantee catalyst stability.Theoretical calculations reveal that the strong binding between FeNC shells and the Pt surface enhances the stability of both the nanoparticles and the FeNC shells.展开更多
The Milan Gobi area of the Golmud-Korla Railway in northwest China is located in the lower dispersal area of the mountain pass and has strong winds with evident double wind direction characteristics.This study introdu...The Milan Gobi area of the Golmud-Korla Railway in northwest China is located in the lower dispersal area of the mountain pass and has strong winds with evident double wind direction characteristics.This study introduced a novel sand fence deployment technique,termed‘folded linear deployment',designed to position the sand fence orthogonally to the two predominant wind directions for optimal protection.This study used wind tunnel and field tests to evaluate the wind and sand flow characteristics,as well as the windproof and sandresistant performance of folded linear HDPE(Highdensity polyethylene)board sand fences.The results suggest that the airflow around the fence creates clear zoning characteristics.The deceleration area on the BSF(backwind side of the sand fence)is much larger than that on the DSF(downwind side of the sand fence).Thus,sand particles are primarily deposited on the BSF.At different wind speeds,the airflow at 2 and 5 h on the DSF is not disturbed.The WSP(wind speed profile)presents a logarithmic distribution.The airflow is disturbed at 1-20 h on the BSF,and the WSP gradually deviates from the logarithmic law.However,as the airflow moves away from the fence,the WSP gradually approaches a logarithmic distribution.Meanwhile,the WPE(windproof efficiency)and SRE(sand-resistant efficiency)of the sand fence exceed 80%.In addition,the results of wind tunnel tests are compared with those of field tests.The overall dispersion is good,and the best dispersion is found at z/H=2.00,indicating good agreement between the two test results.This study provides a scientific basis for the design of sand hazard control measures,similar to the railway project in the Gobi Gale area.展开更多
One of the goals of grazing management in the desert steppe is to improve its ecosystem.However,relatively little is known about soil microbe communities in the desert steppe ecosystem under grazing management.In this...One of the goals of grazing management in the desert steppe is to improve its ecosystem.However,relatively little is known about soil microbe communities in the desert steppe ecosystem under grazing management.In this study,we investigated the diversity and aboveground biomass of Caragana korshinskii Kom.shrub communities in long-term fencing and grazing areas,combined with an analysis of soil physical-chemical properties and genomics,with the aim of understanding how fence management affects plant-soil-microbial inter-relationships in the desert steppe,China.The results showed that fence management(exclosure)increased plant diversity and aboveground biomass in C.korshinskii shrub area and effectively enhanced soil organic carbon(233.94%),available nitrogen(87.77%),and available phosphorus(53.67%)contents.As well,the Shannon indices of soil bacteria and fungi were greater in the fenced plot.Plant-soil changes profoundly affected the alpha-and beta-diversity of soil bacteria.Fence management also altered the soil microbial community structure,significantly increasing the relative abundances of Acidobacteriota(5.31%-8.99%),Chloroflexi(3.99%-5.58%),and Glomeromycota(1.37%-3.28%).The soil bacterial-fungal co-occurrence networks under fence management had higher complexity and connectivity.Based on functional predictions,fence management significantly increased the relative abundance of bacteria with nitrification and nitrate reduction functions and decreased the relative abundance of bacteria with nitrate and nitrite respiration functions.The relative abundances of ecologically functional fungi with arbuscular mycorrhizal fungi,ectomycorrhizal fungi,and saprotrophs also significantly increased under fence management.In addition,the differential functional groups of bacteria and fungi were closely related to plant-soil changes.The results of this study have significant positive implications for the ecological restoration and reconstruction of dry desert steppe and similar areas.展开更多
Wind and sand hazards are serious in the Milan Gobi area of the Xinjiang section of the Korla Railway. In order to ensure the safe operation of railroads, there is a need for wind and sand protection in heavily sandy ...Wind and sand hazards are serious in the Milan Gobi area of the Xinjiang section of the Korla Railway. In order to ensure the safe operation of railroads, there is a need for wind and sand protection in heavily sandy areas. The wind and sand flow in the region is notably bi-directional. To shield railroads from sand, a unique sand fence made of folded linear high-density polyethylene(HDPE) is used, aligning with the principle that the dominant wind direction is perpendicular to the fence. This study employed field observations and numerical simulations to investigate the effectiveness of these HDPE sand fences in altering flow field distribution and offering protection. It also explored how these fences affect the deposition and erosion of sand particles. Findings revealed a significant reduction in wind speed near the fence corner;the minimum horizontal wind speed on the leeward side of the first sand fence(LSF) decreased dramatically from 3 m/s to 0.64 m/s. The vortex area on the LSF markedly impacted horizontal wind speeds. Within the LSF, sand deposition was a primary occurrence. As wind speeds increased, the deposition zone shrank, whereas the positive erosion zone expanded. Close to the folded corners of the HDPE sand fence, there was a notable shift from the positive erosion zone to a deposition zone. Field tests and numerical simulations confirmed the high windproof efficiency(WE) and sand resistance efficiency(SE) in the HDPE sand fence. Folded linear HDPE sheet sand fence can effectively slow down the incoming flow and reduce the sand content, thus achieving good wind and sand protection. This study provides essential theoretical guidance for the design and improvement of wind and sand protection systems in railroad engineering.展开更多
The latticed dunes in the Tengger Desert are widely distributed,and the sand-blocking fence placed here are highly susceptible to local failure due to complex wind-sand activities,posing a serious threat to the safe o...The latticed dunes in the Tengger Desert are widely distributed,and the sand-blocking fence placed here are highly susceptible to local failure due to complex wind-sand activities,posing a serious threat to the safe operation of the highway.To explore the local failure mechanism of sand-blocking fence in the latticed dune area,the local failure of sand-blocking fence in the latticed dune areas along the Wuhai-Maqin Highway in China was observed.Taking the first main ridge of the latticed dune as the placement location,the structure of the wind-sand flow field of sand-blocking fence placed at top,the bottom and the middle of windward slope was analyzed by Computational Fluid Dynamics(CFD).The results show that when placed at top of the first main ridge,the wind speed near the sand-blocking fence is the highest,up to 15.23 m/s.Therefore,the wind load strength on the sand barrier is correspondingly larger,up to 232.61 N∙m-2.As the strength of material continues to decrease,the nylon net is prone to breakage.The roots of the angle steel posts are susceptible to hollowing by vortex action,which can cause sand-blocking fence to fall over in strong wind conditions.When placed at the bottom of windward slope,wind speed drop near sand-blocking fence is greatest,with the decrease of 12.48-14.32 m/s compared to the original wind speed.This is highly likely to lead to large-scale deposition of sand particles and burial of the sand-blocking fence.When placed in the middle of windward slope,sand-blocking fence is subjected to less wind load strength(168.61N∙m-2)and sand particles are mostly deposited at the bottom of windward slope,with only a small amount of sand accumulating at the root of sand-blocking fence.Based on field observations and numerical modelling results,when the sand-blocking fence is placed in latticed dune area,it should be placed in the middle of the windward slope of the first main ridge as a matter of priority.Besides the sand-blocking fence should be placed at the top of the first main ridge,and sand fixing measures should be added.展开更多
Tumbleweeds participate in a common seasonal biological process in temperate grasslands,creating hanging grass fences during the grass-withering season that result in distinct ecological phenomena.In this study,we add...Tumbleweeds participate in a common seasonal biological process in temperate grasslands,creating hanging grass fences during the grass-withering season that result in distinct ecological phenomena.In this study,we addressed the urgent need to understand and restore the degraded desert steppe in Central Mongolia,particularly considering the observed vegetation edge effects around hanging grass fences.Using field surveys conducted in 2019 and 2021 in the severely degraded desert steppe of Central Mongolia,we assessed vegetation parameters and soil physical and chemical properties influenced by hanging grass fences and identified the key environmental factors affecting vegetation changes.The results indicate that the edge effects of hanging grass fences led to changes in species distributions,resulting in significant differences in species composition between the desert steppe's interior and edge areas.Vegetation parameters and soil physical and chemical properties exhibited nonlinear responses to the edge effects of hanging grass fences,with changes in vegetation coverage,aboveground biomass,and soil sand content peaking at 26.5,16.5,and 6.5 m on the leeward side of hanging grass fences,respectively.In the absence of sand dune formation,the accumulation of soil organic carbon and available potassium were identified as crucial factors driving species composition and increasing vegetation coverage.Changes in species composition and plant density were primarily influenced by soil sand content,electrical conductivity,and sand accumulation thickness.These findings suggest that hanging grass fences have the potential to alter vegetation habitats,promote vegetation growth,and control soil erosion in the degraded desert steppe of Central Mongolia.Therefore,in the degraded desert steppe,the restoration potential of hanging grass fences during the enclosure process should be fully considered.展开更多
The Golmud-Korla Railway in the Gobi area faces operational challenges due to sand hazards,caused by strong and variable winds.This study addresses these challenges by conducting wind tunnel tests to evaluate the prot...The Golmud-Korla Railway in the Gobi area faces operational challenges due to sand hazards,caused by strong and variable winds.This study addresses these challenges by conducting wind tunnel tests to evaluate the protective benefits of High Density Polyethylene(HDPE)board sand fences,focusing on their orientation relative to various wind directions(referred to as'wind angle').This study found that the size of the low-velocity zone on the leeward side of the sand fences(LSF)expanded with an increase in the wind angle(WA).At 1H(the height of the sand fence)and 2H positions on the LSF,the wind speed profiles(WSP)exhibited a segmented logarithmic growth,constrained by Z=H at varying WAs.The efficacy of the sand fence in obstructing airflow escalated as WA increased.The size of the WA has a significant impact on the protective efficiency of HDPE board sand fences.Furthermore,compared to typical sandy surfaces,the rate of sand transport across the Gobi surface diminishes more slowly with height,attributed to the gravel's rebound effect.This phenomenon allows some sand particles to bypass the fences,rendering them less effective at blocking wind and trapping sand than in sandy environments.This paper offers scientific evidence supporting the practical use and enhancement of HDPE board sand fences in varied wind conditions.展开更多
This paper investigates the snowdrifts caused by lightweight fences along the lines on the flatland through the computational fluid dynamics method. The characteristic ambient flows around the solid fences and the por...This paper investigates the snowdrifts caused by lightweight fences along the lines on the flatland through the computational fluid dynamics method. The characteristic ambient flows around the solid fences and the porous fences with varied heights and bottom wind gaps are simulated in the numerical model, and the working mechanism of ＂interception＂ and ＂scouring＂ of the lightweight fences are analyzed. Based on the friction velocities near the ground, two sets of criteria are proposed to evaluate the deposition and erosion effects of different fences. According to flow separation and reattachment, the simplified relationships between the most likely positions for snow accumulations and fence parameters are devel- oped. The study indicates that the capabilities for snow interception by the solid fence without wind gap and the distance from which to the second snow coverage center both increase with the fence height. Furthermore, it is found that the scouring range for snow surface increases significantly with the size of wind gap, and the snow accumulation rate on the leeward side decreases with the increasing fence porosity.展开更多
Fences have been widely used in coastal protection engineering for their low cost,simple deployment,and easy integration with ecosystems.The effects of fence porosity and height on dune development have been investiga...Fences have been widely used in coastal protection engineering for their low cost,simple deployment,and easy integration with ecosystems.The effects of fence porosity and height on dune development have been investigated while not much attention has been paid to the effects of fence opening configurations,such as opening size and geometry,and porosity distributions.In this study,we deployed eight fences with same height and similar porosity,but different opening configurations on a sandy beach in Pingtan,Fujian Province.Results indicate that there is a similar two-dune-one-trough pattern for all fences at the beginning of dune development,and opening size,orientation,and geometry,and porosity distribution control the leeward dune peak locations.Fences with small openings and non-uniform porosity have high trapping efficiency,and upper denser porosity may be the optimal design as these fences have the highest trapping efficiency and capacity.The conclusions from this study can provide guidance on practical fence design.展开更多
Fences are one of the most effective measures to prevent and control wind-blown sand disasters,and the blocking effect of fences is largely determined by their porosity and height(H).This study employed wind tunnel ex...Fences are one of the most effective measures to prevent and control wind-blown sand disasters,and the blocking effect of fences is largely determined by their porosity and height(H).This study employed wind tunnel experiments to measure wind velocities on both sides of wire mesh sand fences with porosities of 75%,63%,56%,36%and heights of 10,5 and 2 cm.The effects of porosity and height on the blocking effect of the fences were evaluated on the basis of velocity variability,flow field,and the wind velocity reduction coefficient.Results show that the smaller the porosity,the stronger the blocking effect.The fence with a porosity of 36%had the strongest windproof efficiency of 0.70 and longest protection range of 9 H,and thus showed the best applicability in preventing and controlling wind-blown sand disasters.The fence with a porosity of 56%showed a windproof efficiency of 0.31 and a protection range of 7 H,which could be considered for adoption.However,fences with porosities of 75%and 63%were not recommended to be adopted,because their windproof efficiency and protection range were very small.Overall,the higher the fence,the stronger the blocking effect.The highest fence(10 cm)had the longest protection range of 90 cm,which was the best in application.Nevertheless,the 5 and 2 cm fences were almost consistent with 10 cm fence in windproof efficiency,which was still suitable for wind and sand fixation.展开更多
狄金森第251首Over the Fence-具有戏剧独白的一些典型特征,如叙述者为充满童趣的小女孩,体现戏剧情境的词语包括"fence"、"strawberries"和"nice",揭示戏剧冲突的词汇或从句包括"over the fence&qu...狄金森第251首Over the Fence-具有戏剧独白的一些典型特征,如叙述者为充满童趣的小女孩,体现戏剧情境的词语包括"fence"、"strawberries"和"nice",揭示戏剧冲突的词汇或从句包括"over the fence"、"but"和"if"条件句。对这些特征的阐释可提供多元解读狄金森诗歌作品的空间,从而既有助于管窥当时社会的总体风貌和两性不平等问题,还能更加丰富对狄金森诗歌作品思想深度和艺术特色的相关研究。展开更多
In order to restore a degraded alkaline grassland, the local government implemented a large restoration project using fences in Changling county, Jilin province, China, in 2000. Grazing was excluded from the protected...In order to restore a degraded alkaline grassland, the local government implemented a large restoration project using fences in Changling county, Jilin province, China, in 2000. Grazing was excluded from the protected area, whereas the grazed area was continuously grazed at 8.5 dry sheep equivalent（DSE）/hm2. In the current research, soil and plant samples were taken from grazed and fenced areas to examine changes in vegetation and soil properties in 2005, 2006 and 2008. Results showed that vegetation characteristics and soil properties improved significantly in the fenced area compared with the grazed area. In the protected area the vegetation cover, height and above- and belowground biomass increased significantly. Soil pH, electrical conductivity and bulk density decreased significantly, but soil organic carbon and total nitrogen concentration increased greatly in the protected area. By comparing the vegetation and soil characteristics with pre-degraded grassland, we found that vegetation can recover 6 years after fencing, and soil pH can be restored 8 years after fencing. However, the restoration of soil organic carbon, total nitrogen and total phosphorus concentrations needed 16, 30 and 19 years, respectively. It is recommended that the stocking rate should be reduced to 1/3 of the current carrying capacity, or that a grazing regime of 1-year of grazing followed by a 2-year rest is adopted to sustain the current status of vegetation and soil resources. However, if N fertilizer is applied, the rest period could be shortened, depending on the rate of application.展开更多
With the rapid development of aquaculture in lakes and reservoirs, its negative effects on water quality and aquatic organisms are clearly emerging. Toward a better understanding of these effects, chemical and biologi...With the rapid development of aquaculture in lakes and reservoirs, its negative effects on water quality and aquatic organisms are clearly emerging. Toward a better understanding of these effects, chemical and biological monitoring was conducted in the Fangbian Reservoir to study the relationship between aquaculture and eutrophication. As a domestic water supply source, this reservoir has reached the mesotrophic level. The concentrations of total nitrogen （TN） and total phosphorus （TP） in the Fangbian Reservoir have frequently exceeded the prescriptive level according to the Environmental Quality Standardgfor SurJace Water （GB3838-2002）. Pond and fence aquaculture feeding is the main cause of high levels of nitrogen and phosphorus, accounting for nearly half of the total pollution, and causing the reservoir environmental capacity to be exceeded. The amounts of nitrogen and phosphorus that went directly to the reservoir through the residual bait and fish droppings in fence aquaculture were 42 768 kg per year and 10 856 kg per year respectively, from 2007 to 2009. About 2 913 kg of nitrogen and 450 kg of phosphorus were imported to the reservoir through the exchange of water from the culturing ponds at the same time. Therefore, controlling the aquaculture scale and promoting eco-aquaculture are key measures for lessening the eutrophication degree and improving the water quality.展开更多
Introducing catalytically-active Fe and N into carbon materials results in promising FeNC catalysts for oxygen reduction reaction. However, the doped Fe and N species are frequently subject to heavy loss in a traditio...Introducing catalytically-active Fe and N into carbon materials results in promising FeNC catalysts for oxygen reduction reaction. However, the doped Fe and N species are frequently subject to heavy loss in a traditional carbonization process owing to Fe agglomeration and evaporation of N-contained small molecules. Besides, pyrolysis may make materials sintering which embeds a large number of active sites in the bulk phase and impedes direct exposure of reactive centers to the reactants. We here report that when calcinations, the addition of ZnCl2, an ordinary salt with very wide melting temperature range well covering the carbonization process of the precursor iron porphyrin, can significantly enhance the doping level of the active species and simultaneously create highly porous structures for FeNC catalysts. The obtained FeNC demonstrates ultrahigh catalytic activities even significantly better than Pt/C in oxygen reduction reaction.展开更多
The Lanzhou-Xinjiang High-speed Railway runs through an expansive windy area in a Gobi Desert, and sand-blocking fences were built to protect the railway from destruction by wind-blown sand. However, the shielding eff...The Lanzhou-Xinjiang High-speed Railway runs through an expansive windy area in a Gobi Desert, and sand-blocking fences were built to protect the railway from destruction by wind-blown sand. However, the shielding effect of the sand-blocking fence is below the expectation. In this study, effects of metal net fences with porosities of 0.5 and 0.7 were tested in a wind tunnel to determine the effectiveness of the employed two kinds of fences in reducing wind velocity and restraining wind-blown sand. Specifically, the horizontal wind velocities and sediment flux densities above the gravel surface were measured under different free-stream wind velocities for the following conditions： no fence at all, single fence with a porosity of 0.5, single fence with a porosity of 0.7, double fences with a porosity of 0.5, and double fences with a porosity of 0.7. Experimental results showed that the horizontal wind velocity was more significantly decreased by the fence with a porosity of 0.5, especially for the double fences. The horizontal wind velocity decreased approximately 65% at a distance of 3.25 m（i.e., 13 H, where H denotes the fence height） downwind the double fences, and no reverse flow or vortex was observed on the leeward side. The sediment flux density decreased exponentially with height above the gravel surface downwind in all tested fences. The reduction percentage of total sediment flux density was higher for the fence with a porosity of 0.5 than for the fence with a porosity of 0.7, especially for the double fences. Furthermore, the decreasing percentage of total sediment flux density decreased with increasing free-stream wind velocity. The results suggest that compared with metal net fence with a porosity of 0.7, the metal net fence with a porosity of 0.5 is more effective for controlling wind-blown sand in the expansive windy area where the Lanzhou-Xinjiang High-speed Railway runs through.展开更多
Four ＂picket fence＂ porphyrin atropisomers were respectively synthesized from the four corresponding atropisomers of meso-tetra（o-aminophenyl）porphyrin that had been chromatographed on a column eluted with petrole...Four ＂picket fence＂ porphyrin atropisomers were respectively synthesized from the four corresponding atropisomers of meso-tetra（o-aminophenyl）porphyrin that had been chromatographed on a column eluted with petroleum ether and ethyl acetate. Results show that each atropisomer could be successfully synthesized by controlling the acylation temperature at 0 ℃. They were characterized by 1H NMR, HRMS, IR, UV-Vis and Langmuir-Blodgett（LB） film analyses. Although the results of HRMS, IR, UV-Vis analyses indicate there is no remarkable difference among the atropisomers, the results of the 1H NMR and the mean molecular areas obtained by LB film technique imply that the atropisomers are significantly discrepant. The former shows that the chemical shifts of the methyl and amide protons of each atropisomer are distinct, while the later presents that the different atropisomer molecules can occupy the different surface areas at the air/water interface.展开更多
Concrete-plate fences have been widely adopted for windblown sand control and mitigation along railways.However,the inclination angles of inserting the concrete plate with respect to the vertical direction,i.e.,straig...Concrete-plate fences have been widely adopted for windblown sand control and mitigation along railways.However,the inclination angles of inserting the concrete plate with respect to the vertical direction,i.e.,straight or obliquely inserted concrete plates(SIP or OIP),significantly influence the efficiency of sand-control.This study performs a comparative evaluation of the SIP and OIP sand-control fences using wind tunnel testing and field monitoring data collected from the Lanzhou–Wulumuqi High-Speed Railway Project.The results show that the fence’s ability to reduce the wind speed and the sand-retaining efficiency gradually weakens with the increasing wind speed.Compared with the SIP fence,the OIP fence has a better wind speed reduction capability,stronger ability to capture fine particles below the top of the fence;it is more efficient for sand-retaining and induces stronger eddy intensity.Generally,the wind tunnel test and field monitoring results are consistent,whereas wind tunnel tests incline to overestimate wind speed reduction and sand-control efficiency.The study also finds that the aeolian sand accumulated around the fence can weaken the protection efficiency,and hence cleaning the aeolian sand accumulated around the fence should be done periodically to ensure the designed functions.展开更多
文摘This paper proposes a distributed event-triggered control(ETC)framework to address cooperative target fencing challenges in UAV swarm.The proposed architecture eliminates the reliance on preset formation parameters while achieving multi-objective cooperative control for target fencing,network connectivity preservation,collision avoidance,and communication efficiency optimization.Firstly,a differential state observer is constructed to obtain the target's unmeasurable states.Secondly,leveraging swarm selforganization principles,a geometric-constraint-free distributed fencing controller is designed by integrating potential field methods with consensus theory.The controller dynamically adjusts inter-UAV distances via single potential function,enabling coordinated optimization of persistent network connectivity and collision-free motion during target fencing.Thirdly,a dual-threshold ETC mechanism based on velocity consensus deviation and fencing error is proposed,which can be triggered based on task features to dynamically adjust the communication frequency,significantly reduce the communication burden and exclude Zeno behavior.Theoretical analysis demonstrates the stability of closed-loop systems.Multi-scenario simulations show that the proposed method can achieve robust fencing under target maneuverability,partial UAV failures,and communication disturbances.
文摘In the pursuit of high-performance proton exchange membrane fuel cells(PEMFCs),obtaining durable Pt-based intermetallic catalysts with small particle sizes for oxygen reduction reaction(ORR)stands as a crucial yet challenging topic.Herein,we propose an idea of catalyst design utilizing Fe-phenanthroline(Phen)complex as precursor to integrate metal-nitrogen-carbon(M-N-C)with the strong anchoring effect into carbon shells,synthesizing highly ordered and small-sized(3.59 nm)PtFe intermetallic catalyst coated with iron-nitrogen-carbon(FeNC)shells(L1_(0)-PtFe@FeNC).The strong Fe-Phen interaction ensures the uniform dispersion of Fe species on Pt seeds so as to form protective shells suppressing the agglomeration and dissolution of PtFe nanoparticles(NPs)under the high-temperature annealing or harsh operational conditions.It exhibits excellent mass activity(MA)that is about five-fold increase compared to the commercial Pt/C,as well as the significantly improved MA retention after 30,000 potential cycles(68.2%vs.45.3%).Nitrogen-doped carbon(NC)shells and pure carbon(C)shells are used as comparison to demonstrate the advantages of FeNC shells.Durability test results show that NC and C shells obviously degrade after potential cycles,while well-preserved FeNC shells guarantee catalyst stability.Theoretical calculations reveal that the strong binding between FeNC shells and the Pt surface enhances the stability of both the nanoparticles and the FeNC shells.
基金financially supported by the Chang Jiang Scholar and Innovation Team Development Plan of China(IRT_15R29)the Basic Research Innovation Group Project of Gansu Province,China(21JR7RA347)the Natural Science Foundation of Gansu Province,China(20JR10RA231)。
文摘The Milan Gobi area of the Golmud-Korla Railway in northwest China is located in the lower dispersal area of the mountain pass and has strong winds with evident double wind direction characteristics.This study introduced a novel sand fence deployment technique,termed‘folded linear deployment',designed to position the sand fence orthogonally to the two predominant wind directions for optimal protection.This study used wind tunnel and field tests to evaluate the wind and sand flow characteristics,as well as the windproof and sandresistant performance of folded linear HDPE(Highdensity polyethylene)board sand fences.The results suggest that the airflow around the fence creates clear zoning characteristics.The deceleration area on the BSF(backwind side of the sand fence)is much larger than that on the DSF(downwind side of the sand fence).Thus,sand particles are primarily deposited on the BSF.At different wind speeds,the airflow at 2 and 5 h on the DSF is not disturbed.The WSP(wind speed profile)presents a logarithmic distribution.The airflow is disturbed at 1-20 h on the BSF,and the WSP gradually deviates from the logarithmic law.However,as the airflow moves away from the fence,the WSP gradually approaches a logarithmic distribution.Meanwhile,the WPE(windproof efficiency)and SRE(sand-resistant efficiency)of the sand fence exceed 80%.In addition,the results of wind tunnel tests are compared with those of field tests.The overall dispersion is good,and the best dispersion is found at z/H=2.00,indicating good agreement between the two test results.This study provides a scientific basis for the design of sand hazard control measures,similar to the railway project in the Gobi Gale area.
基金funded by the National Natural Science Foundation of China(32061123006,32360426).
文摘One of the goals of grazing management in the desert steppe is to improve its ecosystem.However,relatively little is known about soil microbe communities in the desert steppe ecosystem under grazing management.In this study,we investigated the diversity and aboveground biomass of Caragana korshinskii Kom.shrub communities in long-term fencing and grazing areas,combined with an analysis of soil physical-chemical properties and genomics,with the aim of understanding how fence management affects plant-soil-microbial inter-relationships in the desert steppe,China.The results showed that fence management(exclosure)increased plant diversity and aboveground biomass in C.korshinskii shrub area and effectively enhanced soil organic carbon(233.94%),available nitrogen(87.77%),and available phosphorus(53.67%)contents.As well,the Shannon indices of soil bacteria and fungi were greater in the fenced plot.Plant-soil changes profoundly affected the alpha-and beta-diversity of soil bacteria.Fence management also altered the soil microbial community structure,significantly increasing the relative abundances of Acidobacteriota(5.31%-8.99%),Chloroflexi(3.99%-5.58%),and Glomeromycota(1.37%-3.28%).The soil bacterial-fungal co-occurrence networks under fence management had higher complexity and connectivity.Based on functional predictions,fence management significantly increased the relative abundance of bacteria with nitrification and nitrate reduction functions and decreased the relative abundance of bacteria with nitrate and nitrite respiration functions.The relative abundances of ecologically functional fungi with arbuscular mycorrhizal fungi,ectomycorrhizal fungi,and saprotrophs also significantly increased under fence management.In addition,the differential functional groups of bacteria and fungi were closely related to plant-soil changes.The results of this study have significant positive implications for the ecological restoration and reconstruction of dry desert steppe and similar areas.
基金financially supported by the Chang Jiang Scholar and Innovation Team Development Plan of China (IRT_15R29)the Basic Research Innovation Group Project of Gansu Province, China (21JR7RA347)the Natural Science Foundation of Gansu Province, China (20JR10RA231)。
文摘Wind and sand hazards are serious in the Milan Gobi area of the Xinjiang section of the Korla Railway. In order to ensure the safe operation of railroads, there is a need for wind and sand protection in heavily sandy areas. The wind and sand flow in the region is notably bi-directional. To shield railroads from sand, a unique sand fence made of folded linear high-density polyethylene(HDPE) is used, aligning with the principle that the dominant wind direction is perpendicular to the fence. This study employed field observations and numerical simulations to investigate the effectiveness of these HDPE sand fences in altering flow field distribution and offering protection. It also explored how these fences affect the deposition and erosion of sand particles. Findings revealed a significant reduction in wind speed near the fence corner;the minimum horizontal wind speed on the leeward side of the first sand fence(LSF) decreased dramatically from 3 m/s to 0.64 m/s. The vortex area on the LSF markedly impacted horizontal wind speeds. Within the LSF, sand deposition was a primary occurrence. As wind speeds increased, the deposition zone shrank, whereas the positive erosion zone expanded. Close to the folded corners of the HDPE sand fence, there was a notable shift from the positive erosion zone to a deposition zone. Field tests and numerical simulations confirmed the high windproof efficiency(WE) and sand resistance efficiency(SE) in the HDPE sand fence. Folded linear HDPE sheet sand fence can effectively slow down the incoming flow and reduce the sand content, thus achieving good wind and sand protection. This study provides essential theoretical guidance for the design and improvement of wind and sand protection systems in railroad engineering.
文摘The latticed dunes in the Tengger Desert are widely distributed,and the sand-blocking fence placed here are highly susceptible to local failure due to complex wind-sand activities,posing a serious threat to the safe operation of the highway.To explore the local failure mechanism of sand-blocking fence in the latticed dune area,the local failure of sand-blocking fence in the latticed dune areas along the Wuhai-Maqin Highway in China was observed.Taking the first main ridge of the latticed dune as the placement location,the structure of the wind-sand flow field of sand-blocking fence placed at top,the bottom and the middle of windward slope was analyzed by Computational Fluid Dynamics(CFD).The results show that when placed at top of the first main ridge,the wind speed near the sand-blocking fence is the highest,up to 15.23 m/s.Therefore,the wind load strength on the sand barrier is correspondingly larger,up to 232.61 N∙m-2.As the strength of material continues to decrease,the nylon net is prone to breakage.The roots of the angle steel posts are susceptible to hollowing by vortex action,which can cause sand-blocking fence to fall over in strong wind conditions.When placed at the bottom of windward slope,wind speed drop near sand-blocking fence is greatest,with the decrease of 12.48-14.32 m/s compared to the original wind speed.This is highly likely to lead to large-scale deposition of sand particles and burial of the sand-blocking fence.When placed in the middle of windward slope,sand-blocking fence is subjected to less wind load strength(168.61N∙m-2)and sand particles are mostly deposited at the bottom of windward slope,with only a small amount of sand accumulating at the root of sand-blocking fence.Based on field observations and numerical modelling results,when the sand-blocking fence is placed in latticed dune area,it should be placed in the middle of the windward slope of the first main ridge as a matter of priority.Besides the sand-blocking fence should be placed at the top of the first main ridge,and sand fixing measures should be added.
基金supported by the Third Xinjiang Scientific Expedition and Research Program(2021xjkk0305)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA2003020201)the Key Intergovernmental Projects for International Scientific and Technological Innovation Cooperation of the National Key Research and Development Program of China(2017YFE0109200).
文摘Tumbleweeds participate in a common seasonal biological process in temperate grasslands,creating hanging grass fences during the grass-withering season that result in distinct ecological phenomena.In this study,we addressed the urgent need to understand and restore the degraded desert steppe in Central Mongolia,particularly considering the observed vegetation edge effects around hanging grass fences.Using field surveys conducted in 2019 and 2021 in the severely degraded desert steppe of Central Mongolia,we assessed vegetation parameters and soil physical and chemical properties influenced by hanging grass fences and identified the key environmental factors affecting vegetation changes.The results indicate that the edge effects of hanging grass fences led to changes in species distributions,resulting in significant differences in species composition between the desert steppe's interior and edge areas.Vegetation parameters and soil physical and chemical properties exhibited nonlinear responses to the edge effects of hanging grass fences,with changes in vegetation coverage,aboveground biomass,and soil sand content peaking at 26.5,16.5,and 6.5 m on the leeward side of hanging grass fences,respectively.In the absence of sand dune formation,the accumulation of soil organic carbon and available potassium were identified as crucial factors driving species composition and increasing vegetation coverage.Changes in species composition and plant density were primarily influenced by soil sand content,electrical conductivity,and sand accumulation thickness.These findings suggest that hanging grass fences have the potential to alter vegetation habitats,promote vegetation growth,and control soil erosion in the degraded desert steppe of Central Mongolia.Therefore,in the degraded desert steppe,the restoration potential of hanging grass fences during the enclosure process should be fully considered.
基金financially supported by the National Natural Science Foundation of China (42461011, 42071014)the Fellowship of the China Postdoctoral Science Foundation (2021M703466)
文摘The Golmud-Korla Railway in the Gobi area faces operational challenges due to sand hazards,caused by strong and variable winds.This study addresses these challenges by conducting wind tunnel tests to evaluate the protective benefits of High Density Polyethylene(HDPE)board sand fences,focusing on their orientation relative to various wind directions(referred to as'wind angle').This study found that the size of the low-velocity zone on the leeward side of the sand fences(LSF)expanded with an increase in the wind angle(WA).At 1H(the height of the sand fence)and 2H positions on the LSF,the wind speed profiles(WSP)exhibited a segmented logarithmic growth,constrained by Z=H at varying WAs.The efficacy of the sand fence in obstructing airflow escalated as WA increased.The size of the WA has a significant impact on the protective efficiency of HDPE board sand fences.Furthermore,compared to typical sandy surfaces,the rate of sand transport across the Gobi surface diminishes more slowly with height,attributed to the gravel's rebound effect.This phenomenon allows some sand particles to bypass the fences,rendering them less effective at blocking wind and trapping sand than in sandy environments.This paper offers scientific evidence supporting the practical use and enhancement of HDPE board sand fences in varied wind conditions.
基金the supports of the National Natural Science Foundation of China(No.51525804)the Sichuan Province Youth Science and Technology Innovation Team(No.2015TD0004)the Construction Technology Project of China Transport Ministry(No.2014318800240)
文摘This paper investigates the snowdrifts caused by lightweight fences along the lines on the flatland through the computational fluid dynamics method. The characteristic ambient flows around the solid fences and the porous fences with varied heights and bottom wind gaps are simulated in the numerical model, and the working mechanism of ＂interception＂ and ＂scouring＂ of the lightweight fences are analyzed. Based on the friction velocities near the ground, two sets of criteria are proposed to evaluate the deposition and erosion effects of different fences. According to flow separation and reattachment, the simplified relationships between the most likely positions for snow accumulations and fence parameters are devel- oped. The study indicates that the capabilities for snow interception by the solid fence without wind gap and the distance from which to the second snow coverage center both increase with the fence height. Furthermore, it is found that the scouring range for snow surface increases significantly with the size of wind gap, and the snow accumulation rate on the leeward side decreases with the increasing fence porosity.
基金The National Natural Science Foundation of China under contract Nos 41871005 and 42076211the Research Development Fund of Xi’an Jiaotong-Liverpool University under contract No.RDF 14-01-26the High-Level Talent Research Startup Fund of West Anhui University under contract No.WGKQ2022053.
文摘Fences have been widely used in coastal protection engineering for their low cost,simple deployment,and easy integration with ecosystems.The effects of fence porosity and height on dune development have been investigated while not much attention has been paid to the effects of fence opening configurations,such as opening size and geometry,and porosity distributions.In this study,we deployed eight fences with same height and similar porosity,but different opening configurations on a sandy beach in Pingtan,Fujian Province.Results indicate that there is a similar two-dune-one-trough pattern for all fences at the beginning of dune development,and opening size,orientation,and geometry,and porosity distribution control the leeward dune peak locations.Fences with small openings and non-uniform porosity have high trapping efficiency,and upper denser porosity may be the optimal design as these fences have the highest trapping efficiency and capacity.The conclusions from this study can provide guidance on practical fence design.
基金supported by the National Natural Sciences Foundation of China(41871016)。
文摘Fences are one of the most effective measures to prevent and control wind-blown sand disasters,and the blocking effect of fences is largely determined by their porosity and height(H).This study employed wind tunnel experiments to measure wind velocities on both sides of wire mesh sand fences with porosities of 75%,63%,56%,36%and heights of 10,5 and 2 cm.The effects of porosity and height on the blocking effect of the fences were evaluated on the basis of velocity variability,flow field,and the wind velocity reduction coefficient.Results show that the smaller the porosity,the stronger the blocking effect.The fence with a porosity of 36%had the strongest windproof efficiency of 0.70 and longest protection range of 9 H,and thus showed the best applicability in preventing and controlling wind-blown sand disasters.The fence with a porosity of 56%showed a windproof efficiency of 0.31 and a protection range of 7 H,which could be considered for adoption.However,fences with porosities of 75%and 63%were not recommended to be adopted,because their windproof efficiency and protection range were very small.Overall,the higher the fence,the stronger the blocking effect.The highest fence(10 cm)had the longest protection range of 90 cm,which was the best in application.Nevertheless,the 5 and 2 cm fences were almost consistent with 10 cm fence in windproof efficiency,which was still suitable for wind and sand fixation.
文摘狄金森第251首Over the Fence-具有戏剧独白的一些典型特征,如叙述者为充满童趣的小女孩,体现戏剧情境的词语包括"fence"、"strawberries"和"nice",揭示戏剧冲突的词汇或从句包括"over the fence"、"but"和"if"条件句。对这些特征的阐释可提供多元解读狄金森诗歌作品的空间,从而既有助于管窥当时社会的总体风貌和两性不平等问题,还能更加丰富对狄金森诗歌作品思想深度和艺术特色的相关研究。
基金supported by the National Key Basic Research Program of China (2011CB403203)the Strategic Science and Technology Guide Project of Chinese Academy of Sciences (XDA05050401)
文摘In order to restore a degraded alkaline grassland, the local government implemented a large restoration project using fences in Changling county, Jilin province, China, in 2000. Grazing was excluded from the protected area, whereas the grazed area was continuously grazed at 8.5 dry sheep equivalent（DSE）/hm2. In the current research, soil and plant samples were taken from grazed and fenced areas to examine changes in vegetation and soil properties in 2005, 2006 and 2008. Results showed that vegetation characteristics and soil properties improved significantly in the fenced area compared with the grazed area. In the protected area the vegetation cover, height and above- and belowground biomass increased significantly. Soil pH, electrical conductivity and bulk density decreased significantly, but soil organic carbon and total nitrogen concentration increased greatly in the protected area. By comparing the vegetation and soil characteristics with pre-degraded grassland, we found that vegetation can recover 6 years after fencing, and soil pH can be restored 8 years after fencing. However, the restoration of soil organic carbon, total nitrogen and total phosphorus concentrations needed 16, 30 and 19 years, respectively. It is recommended that the stocking rate should be reduced to 1/3 of the current carrying capacity, or that a grazing regime of 1-year of grazing followed by a 2-year rest is adopted to sustain the current status of vegetation and soil resources. However, if N fertilizer is applied, the rest period could be shortened, depending on the rate of application.
文摘With the rapid development of aquaculture in lakes and reservoirs, its negative effects on water quality and aquatic organisms are clearly emerging. Toward a better understanding of these effects, chemical and biological monitoring was conducted in the Fangbian Reservoir to study the relationship between aquaculture and eutrophication. As a domestic water supply source, this reservoir has reached the mesotrophic level. The concentrations of total nitrogen （TN） and total phosphorus （TP） in the Fangbian Reservoir have frequently exceeded the prescriptive level according to the Environmental Quality Standardgfor SurJace Water （GB3838-2002）. Pond and fence aquaculture feeding is the main cause of high levels of nitrogen and phosphorus, accounting for nearly half of the total pollution, and causing the reservoir environmental capacity to be exceeded. The amounts of nitrogen and phosphorus that went directly to the reservoir through the residual bait and fish droppings in fence aquaculture were 42 768 kg per year and 10 856 kg per year respectively, from 2007 to 2009. About 2 913 kg of nitrogen and 450 kg of phosphorus were imported to the reservoir through the exchange of water from the culturing ponds at the same time. Therefore, controlling the aquaculture scale and promoting eco-aquaculture are key measures for lessening the eutrophication degree and improving the water quality.
文摘Introducing catalytically-active Fe and N into carbon materials results in promising FeNC catalysts for oxygen reduction reaction. However, the doped Fe and N species are frequently subject to heavy loss in a traditional carbonization process owing to Fe agglomeration and evaporation of N-contained small molecules. Besides, pyrolysis may make materials sintering which embeds a large number of active sites in the bulk phase and impedes direct exposure of reactive centers to the reactants. We here report that when calcinations, the addition of ZnCl2, an ordinary salt with very wide melting temperature range well covering the carbonization process of the precursor iron porphyrin, can significantly enhance the doping level of the active species and simultaneously create highly porous structures for FeNC catalysts. The obtained FeNC demonstrates ultrahigh catalytic activities even significantly better than Pt/C in oxygen reduction reaction.
基金financially supported by the Scientific and Technological Services Network Planning Project of Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences (HHS-TSS-STS-1504)the Technological Research and Developmental Planning Projects of China Railway Corporation (2015G005-B)the National Natural Science Foundation of China (41501010, 41401611)
文摘The Lanzhou-Xinjiang High-speed Railway runs through an expansive windy area in a Gobi Desert, and sand-blocking fences were built to protect the railway from destruction by wind-blown sand. However, the shielding effect of the sand-blocking fence is below the expectation. In this study, effects of metal net fences with porosities of 0.5 and 0.7 were tested in a wind tunnel to determine the effectiveness of the employed two kinds of fences in reducing wind velocity and restraining wind-blown sand. Specifically, the horizontal wind velocities and sediment flux densities above the gravel surface were measured under different free-stream wind velocities for the following conditions： no fence at all, single fence with a porosity of 0.5, single fence with a porosity of 0.7, double fences with a porosity of 0.5, and double fences with a porosity of 0.7. Experimental results showed that the horizontal wind velocity was more significantly decreased by the fence with a porosity of 0.5, especially for the double fences. The horizontal wind velocity decreased approximately 65% at a distance of 3.25 m（i.e., 13 H, where H denotes the fence height） downwind the double fences, and no reverse flow or vortex was observed on the leeward side. The sediment flux density decreased exponentially with height above the gravel surface downwind in all tested fences. The reduction percentage of total sediment flux density was higher for the fence with a porosity of 0.5 than for the fence with a porosity of 0.7, especially for the double fences. Furthermore, the decreasing percentage of total sediment flux density decreased with increasing free-stream wind velocity. The results suggest that compared with metal net fence with a porosity of 0.7, the metal net fence with a porosity of 0.5 is more effective for controlling wind-blown sand in the expansive windy area where the Lanzhou-Xinjiang High-speed Railway runs through.
基金Supported by the National Natural Science Foundation of China(No.20806025)
文摘Four ＂picket fence＂ porphyrin atropisomers were respectively synthesized from the four corresponding atropisomers of meso-tetra（o-aminophenyl）porphyrin that had been chromatographed on a column eluted with petroleum ether and ethyl acetate. Results show that each atropisomer could be successfully synthesized by controlling the acylation temperature at 0 ℃. They were characterized by 1H NMR, HRMS, IR, UV-Vis and Langmuir-Blodgett（LB） film analyses. Although the results of HRMS, IR, UV-Vis analyses indicate there is no remarkable difference among the atropisomers, the results of the 1H NMR and the mean molecular areas obtained by LB film technique imply that the atropisomers are significantly discrepant. The former shows that the chemical shifts of the methyl and amide protons of each atropisomer are distinct, while the later presents that the different atropisomer molecules can occupy the different surface areas at the air/water interface.
基金This research was supported by the Science and Technology Development Plan of China Railway Group Limited(Grant No.2015-kj035-g004-03).
文摘Concrete-plate fences have been widely adopted for windblown sand control and mitigation along railways.However,the inclination angles of inserting the concrete plate with respect to the vertical direction,i.e.,straight or obliquely inserted concrete plates(SIP or OIP),significantly influence the efficiency of sand-control.This study performs a comparative evaluation of the SIP and OIP sand-control fences using wind tunnel testing and field monitoring data collected from the Lanzhou–Wulumuqi High-Speed Railway Project.The results show that the fence’s ability to reduce the wind speed and the sand-retaining efficiency gradually weakens with the increasing wind speed.Compared with the SIP fence,the OIP fence has a better wind speed reduction capability,stronger ability to capture fine particles below the top of the fence;it is more efficient for sand-retaining and induces stronger eddy intensity.Generally,the wind tunnel test and field monitoring results are consistent,whereas wind tunnel tests incline to overestimate wind speed reduction and sand-control efficiency.The study also finds that the aeolian sand accumulated around the fence can weaken the protection efficiency,and hence cleaning the aeolian sand accumulated around the fence should be done periodically to ensure the designed functions.
